• 제목/요약/키워드: Kaolin

검색결과 531건 처리시간 0.019초

지도 도석광상에 대한 광물학적 및 지구화학적 연구 (Mineralogy and Geochemistry of Jido kaolin deposits)

  • 박영석;김진
    • 한국광물학회지
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    • 제6권2호
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    • pp.80-93
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    • 1993
  • Jido kaolin deposits developed in the rhyolitic tuff of Cretaceous are located in the western part of Sinan-gun, Jeonranam-do. Jido kaolin deposits is predominantly composed of pyrophyllite, kaolinite and illite. On the basis of mineral assemblage Jido kaolin deposits can be divided into three alteraion zone from the center of alteration to the margin; kaolinite, kaolinite-pyrophyillite and pyrophyillite zones. Discriminant analysis show that $Al_2O_3$, $K_2O$, $Na_2O$, CaO of major elements are discriminant elements classifying kaolinite, kaolinite-pyrophyllite and pyrophyllite zones, while in case of trace elements Cr, Ni, Sc, Zn, and Zr are discriminant elements. Kaolin deposits has been formed by the hydrothermal alterations of the volcano rocks such as rhyolitic tuff and lapilli tuff, in late cretaceous. On the basis of the results of X-ray diffraction analysis, the deposits can be classified into three types of minerals assemblages; kaolinite, kaolinite-pyrophyllite and pyrophyllite zones. All the assemblages contain quartz and muscovite, but the kaolinite zone contains kaolinite, illite and chlorite, the kaolinite-pyrophyllite zone contains kaolinite, pyrophyllite and the pyrophyllite zone contains illite and pyrite.

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TEOS와 카올린으로부터 제조한 $\beta$-Sialon의 기계적 성질 (Mechanical Properties of Beta-Sialon Ceramics Prepared from TEOS and Kaolin)

  • 임헌진;이홍림
    • 한국세라믹학회지
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    • 제26권5호
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    • pp.637-644
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    • 1989
  • Beta-sialon powder(Z=1) was synthesized by the simultaeous reduction and nitridation of the mixed powders of Hadong kaolin and silica. Silicon hydroxide was prepared from Si-alkoxide by a hydrolysis method and amorphous silica was obtained from the calcination of the prepared silicon hydroxide. Hadong kaolin was mixed with both the silicon hydroxide and amorphous silica, respectively. The average particle size was 4${\mu}{\textrm}{m}$ and the morphology of particle was rod-like and equiaxed in the case of beta-sialon powder prepared form Hadong kaolin and silicon hydroxide(COMPOSITION A), whereas the average particle size was 3${\mu}{\textrm}{m}$ and the morphology of particle was equiaxed in the case of beta-sialon powder prepared from Hadong kaolin and amorphous silica(COMPOSITION B). The synthesized beta-sialon powders were hot-pressed at 175$0^{\circ}C$ for 2 hours under 30 MPa in a nitrogen atmosphere after YAG composition(8wt%) was added to these powders as a sintering agent. The hot-pressed specimens were annealed a 140$0^{\circ}C$ for 4 hours in a nitrogen atmosphere. The mechanical properties of sintered bodies were investigated in terms of M.O.R., fracture toughness and hardness. The measured values are as follows. COMPOSITION A : M.O.R. 508MPa, KIC 3.5MN/m3/2, hardness 13.6GPa. COMPOSITION B : M.O.R. 653MPa, KIC 5.4MN/m3/2, hardness 13.5GPa.

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자연토양 및 카올린에 대한 코발트, 스트론튬, 세슘의 흡착 특성 (Adsorption Characteristics of Cobalt, Strontium, and Cesium on Natural Soil and Kaolin)

  • 천경호;최정학;신원식;최상준
    • 한국환경과학회지
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    • 제23권9호
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    • pp.1609-1618
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    • 2014
  • In this study, as a fundamental study for the remediation of the radionuclides-contaminated soil, the adsorption of cobalt, strontium, and cesium on natural soil and kaolin were experimently investigated and adsorption characteristics were evaluated by using several adsorption kinetic and isotherm models. The pseudo-first-order kinetic model (PFOM), pseudo-second-order kinetic model (PSOM), one-site mass transfer model (OSMTM), and two compartment first-order kinetic model (TCFOKM) were used to evaluate the kinetic data and the pseudo-second-order kinetic model was the best with good correlation. The adsorption equilibria of cobalt, strontium, and cesium on natural soil were fitted successfully by Redlich-Peterson and Sips models. For kaolin, the adsorption equilibria of cobalt, strontium, and cesium were fitted well by Redlich-Peterson, Freundlich, and Sips models, respectively. The amount of adsorbed radionuclides on natural soil and kaolin was in the order of cesium > strontium > cobalt. It is considered that these results could be useful to predicting the adsorption behaviors of radionuclides such as cobalt, strontium, and cesium in soil environments.

브라질 까핌 카올린 광상에 대한 예비 연구 (Preliminary Study for the Capim Kaolin Mine in Brazil)

  • 김인준;이재호
    • 자원환경지질
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    • 제41권5호
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    • pp.587-595
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    • 2008
  • 브라질 까핌 지역의 지질은 하부 중생대-제삼기 마이오세의 이픽우아층, 제삼기 마이오세의 퇴적층, 제삼기 플라이오세의 퇴적층인 바레이라스층 및 제사기 홀로세의 퇴적물이 넓게 분포한다. 카올린 광상은 마이오세-프라이오세 시대의 바레이라스층이 넓게 분포하며 층의 평균 두께는 120m에 달하며 주로 사암, 점토 및 미사로 구성된다. 모든 카올린층은 모래층 사이에 나타나며, 최상급의 카올린 광체는 백색 카올린으로 평균 두께가 7 m에 이른다. 광체를 형성하는 카올린은 XRD에 의해 카올리나이트로 판명되었고, 이는 모두 육각판상이며, 내화도가 33이상으로 정제하지 않고도 제지용으로 적합한 A등급이다. 카올린 광상의 매장량은 브라질지질조사소에 의하면 566,819,164톤으로 추정된다.

실리케이트 광물을 이용한 내열충격성 LAS계 세라믹스의 제조에 관한 연구: (II) Sillimanite, Kaolin 및 Pyrophyllite족 광물을 이용한 Spodumene 분말합성 (The Study on Fabrication of LAS System Ceramics for Thermal Shock Resistance from Silicate Minerals: (II) Preparation of Spodumene Powders with Sillimanite, Kaolin and Pyrophyllite Group Minerals)

  • 박한수;조경식;문종수
    • 한국세라믹학회지
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    • 제31권7호
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    • pp.784-794
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    • 1994
  • Though spodumene have a law theraml expension and good thermal shock resistance, its sintering temperature is too close to its melting point in the application for industral purpose. Solving the problems, impurities within the silicate minerals act as a frit during firing, so its densification is expected through enlargement of sintering temperature range. By the heat treatment of starting materials, mixtures of silicate mineral, lithium carbonate, if necessary SiO2 or Al2O3 were added for stoichiometric correction, in the range of 1000~125$0^{\circ}C$ for 10 hrs, $\beta$-spodumene single phase was synthesized. Mixtures with sillimanite group minerals, $\beta$-spodumene was formed at 120$0^{\circ}C$ or 125$0^{\circ}C$ via intermediate phases of petalite, Li2SiO3 and LiAlO2. For the case of kaolin group minerals, synthesis were completed at 110$0^{\circ}C$ for Hadon pink kaolin, 120$0^{\circ}C$ for New Zealand white kaolin, When pyrophyllite group minerals were used, those were at the range of 1000~125$0^{\circ}C$. Spodumene was completed at lowest temperature, 100$0^{\circ}C$ from the mixture of Wando pyrophyllite among them. Microstructure of synthesized powders showed the inrregular lump shape such as densed crystallines.

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카올린으로부터 조성이 다른$\beta$다-Sialon의 합성 (Synthesis of $\beta$다-Sialon with Various Compositions from Kaolin)

  • 최상욱;서규식;이종진
    • 한국세라믹학회지
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    • 제23권5호
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    • pp.17-24
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    • 1986
  • β'-Sialon with different compositions was synthesized by the carbothermal reduction-nitridation of compacts containing kaolin graphite and silicon or aluminum at temperature of 1300-1450℃ under flowing gas of 90% N2-10% H2 or 20hrs. Quantitative analysis of minerals which were formed in the specimens was carried out by using the calibration curve which has been prepared from X-ray diffraction patterns. The obtained results were as follows : 1. In the formation of β'-Sialon by carbothermal reduction-nutridation of Si-Al-O-C system mixtures at 1400℃ for 20hrs. (2) β'-Sialon as a major mineral and α-Al2O3 as a minor mineral were identified in the specimen which was prepared of kaolin and graphite. (3)α-Al2O3 and 15R as a minor minerals were measured in the specimen which was prepared of kaolin aluminum and graphite. (4) AlN instead of α-Al2O3 and 15R was formed in the compacts that excess graphite(=35 wt%) was added to the mixture of kaolin and aluminium. 2. As the reaction time and temperature were increased the formation of β'-Sialon was increased whereas the phases of mllite SiC and Si2ON2 were decreased gradually.

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천연 황색안료 염색한지의 패션소재 적용 가능성 평가에 관한 연구 (Properties of Hanji with natural pigment dyeing for use as a fashion material)

  • 김기훈;임현아
    • 복식문화연구
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    • 제22권2호
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    • pp.339-345
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    • 2014
  • This study analyzes and compares Hanji made with loess to Hanji made with kaolin, two yellow-based inorganic pigments, in terms of its physical properties, optical properties, and color fastness to light with the aim of using it as a fashion material. Hanji made by adding inorganic pigments showed an approximately 20% retention ratio on average. This figure was similar to those of loess and kaolin. Physical properties were analyzed, with the following results. A higher amount of additives lowered the apparent density and increased thickness and bulk. In general, inorganic pigment-added Hanji had lower tensile strength, bursting strength, and folding endurance compared to non-additive Hanji. The analysis of optical properties showed a lower brightness index for Hanji made with inorganic pigments compared to non-additive Hanji. When comparing the two inorganic pigments, the brightness of Hanji made with kaolin was higher. Regarding color fastness to light, loess showed level 4 and kaolin showed level 5 when 25% inorganic pigments on pulp were added to Hanji. Thus, Hanji made by adding inorganic pigments during the manufacturing process may perform well as materials for fashion because the additives enhanced both the color fastness to light and the bulk while maintaining the strength. In addition, Hanji dyed with inorganic pigments may have the potential to serve as materials for the fashion industry while still retaining the characteristics of Hanji.

하동 고령토로부터 Zeolite A 합성 반응기구 (Reaction Mechanism for Zeolite A Synthesis from Hadong Kaolin)

  • 권영수;김면섭
    • 한국세라믹학회지
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    • 제20권3호
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    • pp.255-259
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    • 1983
  • Am(rphous aluminosilicate zeolite A and hydroxysodalite were obtained by reaction of Hadong kaolin(halloysite) with IN sodium hydroxide solntion in the temperature range of 60 to 10$0^{\circ}C$ For determination of the mechanism of the reaction Various possible mechanisms were compared with the experimental results. It was observed that the reaction mechamism of zeolite A synthesis from Hadong kaolin was first order consecu-tive reaction as follows : halloysitelongrightarrowamorphous aluminosilicatelongrightarrowzeolite Alongrightarrowhydroxysodalite

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고령토로부터 알루미나 추출에 관한 연구 (Study on the Alumina Extraction from Kaolin)

  • 맹중재;김철주;신병식
    • 한국세라믹학회지
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    • 제17권1호
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    • pp.35-41
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    • 1980
  • Alumina extraction from raw Hadong kaolin with sulfuric acid was studied to obtain relatively pure alumina. Factors as acid concentration, heating temperature and conditions of ammonium alum crystal formation from extracted solution are also surveyed and most of iron oxide in kaolin is eliminated in crystallization of ammonium alum. Pure crystal obtained from the extracted solution with ammonium sulfate is relatively free from iron containment in mother liquor. Alumina in ammonium alum crystal is converted to gibbsite form after complete hydrolysis in ammonia gas.

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고형연료사용 순환유동층 연소로에서의 유동사 대체 및 다기능성 첨가제에 관한 연구 (Research on the Replacement of Bed Material and Multifunctional Additives in Circulating Fluidized Bed Combustion Using Solid Fuels)

  • 박인수;남정수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2023년도 가을학술발표대회논문집
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    • pp.115-116
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    • 2023
  • In this study, it was confirmed whether kaolin can play a role as a bed materials and a role in reducing clinkers by using kaolin with a bed materials for the purpose of removing clinkers such as slagging and fouling generated in circulating fluidized bed combustion furnaces using solid fuel.

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