• Bulletin of the Korean Chemical Society
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• v.29 no.3
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• pp.580-584
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• 2008

Second-order rate constants (kN) have been measured spectrophotometrically for reactions of Y-substituted phenyl benzoates (1a-h) with azide ion (N3) in 80 mol % H2O/20 mol % DMSO at 25.0 0.1 oC. The Brnsted-type plot for the azidolysis exhibits a downward curvature, i.e., the slope (b lg) changes from 0.97 to 0.20 as the basicity of the leaving group decreases. The pKao (defined as the pKa at the center of the Brnsted curvature) is 4.8, which is practically identical to the pKa of the conjugate acid of N3 ion (4.73). Hammett plots correlated with s o and s constants exhibit highly scattered points for the azidolysis. On the contrary, the corresponding Yukawa-Tsuno plot results in an excellent linear correlation with r = 2.45 and r = 0.40, indicating that the leaving group departs in the rate-determining step. The curved Brnsted-type plot has been interpreted as a change in the rate-determining step in a stepwise mechanism. The microscopic rate constants (k1 and k2/k1 ratio) have been calculated for the azidolysis and found to be consistent with the proposed mechanism.

• Bulletin of the Korean Chemical Society
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• v.29 no.3
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• pp.585-589
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• 2008

Second-order rate constants (kN) have been measured for reactions of Y-substituted phenyl 2-thiophenecarboxylates (6a-h) with morpholine and piperidine in 80 mol % H2O/20 mol % DMSO at 25.0 0.1 oC. The Brnsted-type plot for the reactions of 6a-h with morpholine is linear with b lg = 1.29, indicating that the reactions proceed through a tetrahedral zwitterionic intermediate (T?). On the other hand, the Brnsted-type plot for the reactions of 6a-h with piperidine exhibits a downward curvature, implying that a change in the rate-determining step occurs on changing the substituent Y in the leaving group. Dissection of kN into microscopic rate constants (i.e., k1 and k2/k1 ratio) has revealed that k1 is smaller for the reactions of 6a-h than for those of Y-substituted phenyl 2-furoates (5a-h), while the k2/k1 ratio is almost the same for the reactions of 5a-h and 6a-h. It is also reported that modification of the nonleaving group from the furoyl (5a-h) to the thiophenecarbonyl (6a-h) does not influence pKao (defined as the pKa at the center of the Brnsted curvature) as well as the k2/k1 ratio.

• The Journal of the Convergence on Culture Technology
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• v.6 no.2
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• pp.419-428
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• 2020

SNS media is gaining its media share with the benefits of digital technology, such as the convenience of physical access and the entertainment and interactivity of contents, and are becoming a part of users' lives. As media contents consumers move from traditional media to SNS, marketing communication activities are rapidly adapting to leading SNS platforms such as Facebook. This study compares how users perceive four advertisement attributes in each SNS, focusing on Facebook, Instagram, Kakao Story, and Twitter, where the media content creation and consumption systems are relatively similar to each other. The impact on eWOM intention was identified. In addition, we discussed effective SNS operation.

• Bulletin of the Korean Chemical Society
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• v.28 no.2
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• pp.220-224
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• 2007

Second-order rate constants (kN) have been determined spectrophotometrically for reactions of 2,4-dintrophenyl 2-furoate (2) with a series of alicyclic secondary amines in 80 mol % H2O/20 mol % dimethyl sulfoxide (DMSO) at 25.0 oC. The furoate 2 is more reactive than 2,4-dintrophenyl benzoate (1) toward all the amines studied. The higher acidity of 2-furoic acid (pKa = 3.16) compared with benzoic acid (pKa = 4.20) has been suggested to be responsible for the reactivity order, at least in part. The Brønsted-type plots for the reactions of 1 and 2 are curved downwardly, indicating that the aminolyses of both 1 and 2 proceed through a zwitterionic tetrahedral intermediate (T±) with a change in the rate-determining step on changing the amine basicity. Dissection of the kN values into their microscopic rate constants has revealed that the pKao and k2/k-1 ratios for the reactions of 1 and 2 are identical, indicating that the nature of the nonleaving group (i.e., benzoyl and 2-furoyl) does not affect the reaction mechanism. The k1 values have been found to be larger for the reactions of 2 than for those of 1, which is fully responsible for the fact that the former is more reactive than the latter.

• Steel and Composite Structures
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• v.10 no.3
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• pp.245-260
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• 2010

In this paper, experimental and theoretical investigations on the response and collapse of 310 stainless steel tubes with different diameter-to-thickness ratios subjected to cyclic bending are discussed. The tube-bending device and curvature-ovalization measurement apparatus were used to conduct the experiment. The endochronic theory combined with the principle of virtual work and finite element software, ANSYS, were used to simulate the moment-curvature and ovalization-curvature relationships. It is shown that although the two methods lead to good simulation of the moment-curvature relationship, the endochronic theory combined with the principle of virtual work has the better simulation of the ovalization-curvature response when compared with experimental data and the simulation by ANSYS. In addition, the theoretical formulations proposed by Kyriakides and Shaw (1987) and Lee et al. (2001) were used to simulate the controlled curvature-number of cycles to produce buckling relationship. It is shown that the theoretical formulations effectively simulate the experimental data.

• Steel and Composite Structures
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• v.5 no.5
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• pp.359-374
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• 2005

This paper presents the experimental and theoretical results of the viscoplastic response and collapse of 316L stainless steel tubes subjected to cyclic bending. The tube bending machine and curvature-ovalization measurement apparatus, which was designed by Pan et al. (1998), were used for conducting the cyclic curvature-controlled experiment. Three different curvature-rates were controlled to highlight the characteristic of viscoplastic response and collapse. Next, the endochronic theory and the principle of virtual work were used to simulate the viscoplastic response of 316L stainless steel tubes under cyclic bending. In addition, a proposed theoretical formulation (Lee and Pan 2001) was used to simulate the relationship between the controlled cyclic curvature and the number of cycles to produce buckling under cyclic bending at different curvature-rates (viscoplastic collapse). It has been shown that the theoretical simulations of the response and collapse correlate well with the experimental data.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.22 no.3
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• pp.217-223
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• 2004

In order to improve real-time positioning accuracy, a number of methods have been tested and one of those is the inverted RTK(Real-time kinematic) that gives a precise positioning by handling carrier phase measurements. For the inverted RTK positioning, it needs the L1 phase measurement at least for 1～2 minutes and the additional reference stations/communication system and a data processing server are required. The L1 code and carrier phase measurements for real-time application are used simultaneously and then Kalman filter is applied to estimate integer ambiguities. Double differenced integer ambiguities are resolved by utilizing the FARA(Fast Ambiguity Resolution Approach). In this paper, we propose the method to improve the positioning accuracy and performed the field tests for several baselines from DAEJ reference station in KAO(Korea Astronomy Observatory).

• Journal of Astronomy and Space Sciences
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• v.19 no.4
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• pp.341-350
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• 2002

Near Earth Object Patrol Team (National Research Lab.) at KAO and YSTAR team at Yonsei University Observatory jointly developed a dome enclosure to be installed abroad together with a survey telescope. It has a fully-open clam shell type design to maximize the fast slew capability of the telescope and is also sturdy enough to protect the observation system under extreme weather conditions. We also developed an electric control circuit for the enclosure so that it can become a part of automated observing system. The enclosure has been installed at the Sutherland Observatory of South African Astronomical Observatory in April 2002, and has been successfully operational.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.5 no.2
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• pp.269-286
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• 2011

In this paper, we study a problem that is concerning how to construct a delay-constrained multicast tree on a wireless mesh network (WMN) such that the number of serviced clients is maximized. In order to support high-quality and concurrent interference-free transmission streams, multiple radios are implemented in each mesh node in the WMNs. Instead of only orthogonal channels used for the multicast in the previous works, both orthogonal and partially overlapping channels are considered in this study. As a result, the number of links successfully allocated channels can be expected to be much larger than that of the approaches in which only orthogonal channels are considered. The number of serviced subscribers is then increased dramatically. Hence, the goal of this study is to find interference-free and delay-constrained multicast trees that can lead to the maximal number of serviced subscribers. This problem is referred as the MRDCM problem. Two heuristics, load-based greedy algorithm and load-based MCM algorithm, are developed for constructing multicast trees. Furthermore, two load-based channel assignment procedures are provided to allocate interference-free channels to the multicast trees. A set of experiments is designed to do performance, delay and efficiency comparisons for the multicast trees generated by all the approximation algorithms proposed in this study.

• Current Applied Physics
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• v.18 no.11
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• pp.1205-1211
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• 2018

The frustrated magnet has been regarded as a system that could be a promising host material for the quantum spin liquid (QSL). However, it is difficult to determine the spin configuration and the corresponding mechanism in this system, because of its geometrical frustration (i.e., crystal structure and symmetry). Herein, we systematically investigate one of the geometrically frustrated magnets, the $TbB_4$ compound. Using resonant soft x-ray scattering (RSXS), we explored its spin configuration, as well as Tb's quadrupole. Comprehensive evaluations of the temperature and photon energy/polarization dependences of the RSXS signals reveal the mechanism of spin reorientation upon cooling down, which is the sophisticated interplay between the Tb spin and the crystal symmetry rather than its orbit (quadrupole). Our results and their implications would further shed a light on the search for possible realization of QSL.