• Journal of the Korean Chemical Society
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• v.17 no.2
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• pp.73-79
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• 1973

The ultrasonic absorption of Dodecyl pyridinium bromide (D.P.B.) in aqueous solution has been measured at $20^{\circ}C$ over a range of frequencies between 0.1 mc and 90 mc and a range of concentrations from 5 to 100 mM. The excess absorption was observed only in the solutions the concentration of which was higher than the critical micellar concentration (c.m.c.) both in the presence and absence of salt. The excess absorption of sound and the relaxation frequencies obtained from the absorption curves show a discontinuity with the variation of the concentration of D.P.B. in the neighborhood of 60 mM. Other properties such as viscosity, conductivity and velocity of sound also exhibit such a change near the same concentration. It is concluded that a change in the properties of the micelles of D.P.B. occurs in the neighborhood of this concentration. The mechanism of the observed ultrasonic excess absorption in attributed to the reaction $M_2{\rightleftarrow}M_1+2Br^-$where$M_2$ and$M_1$are two types of micelles. The rate constants of forward and backward reactions are found to be $6.9 {\times} 10^5 sec^{-1)$and $6.7{\times}10^{10}sec^{-1}mole{-2}$ respectively. Some kinetic characteristics including free energy, enthalpy, entropy and activation energy were calculated.

• PNF and Movement
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• v.4 no.1
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• pp.45-50
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• 2006

Purpose : This study shows the movements of the ankle and the foot in walking stages, and helps to diagnose and treat the problems of the ankle and the foot. The foot in human is a mean of the transportation, body support, and shock absorber. However, the slightest changes in the anatomical position can cause a significant increase of the stress and force in the ankle and the foot. The regular compressive force in the ankle of the normal person is generated by the contraction of the gastrocnemius and popliteus muscles, and transmitted to the achilles tendon. The plantar flexion about 10 degrees occurs immediately after the heel strike, getting ready for the weight acceptance. The shear force about 80 % of the body weight is generated immediately after the heel off of the mid stance phase. In those who have a problem in the ankle, the compression force at the ankle decreased to 1/3 of the body weight, and the shear force decreased, and the compressive force was reached at their maximum level earlier than the normal people. Conclusion : Analysis of the movements at the ankle and the foot in walking phase can make the effort to diagnose and treat the ankle and foot with the problems. However, the further study is necessary.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.17 no.2
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• pp.119-129
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• 2004

A three dimensional (3D) method of analysis is presented for determining the free vibration frequencies and mode shapes of thick, circular and annular plates with nonlinear thickness variation along the radial direction. Unlike conventional plate theories, which are mathematically two dimensional (2D), the present method is based upon the 3D dynamic equations of elasticity. Displacement components u/sub s/, u/sub z/, and u/sub θ/ in the radial, thickness, and circumferential directions, respectively, are taken to be sinusoidal in time, periodic in θ, and algebraic polynomials in the s and z directions. Potential (strain) and kinetic energies of the plates are formulated, and the Ritz method is used to solve the eigenvalue problem thus yielding upper bound values of the frequencies by minimizing the frequencies. As the degree of the polynomials is increased, frequencies converge to the exact values. Convergence to four digit exactitude is demonstrated for the first five frequencies of the plates. Numerical results we presented for completely free, annular and circular plates with uniform linear, and quadratic variations in thickness. Comparisons are also made between results obtained from the present 3D and previously published thin plate (2D) data.

• Polymer(Korea)
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• v.39 no.2
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• pp.210-218
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• 2015

The reaction behavior of rigid polyurethane foams were studied on the effects of gelling catalysts of amine type, such as; dimethylcyclohexyl amine (DMCHA) and of potassium type, such as; potassium octoate (PO). Rigid polyurethane foams were provided with polymeric 4,4'-diphenylmethane diisocyanate, polyester polyol, silicone surfactant, blowing agent and a few gelling catalysts. As the contents of catalyst, DMCHA increased from 0 to 2.0 g, the reaction time decreased from ca. 330 to ca. 35 sec and due to the exothermic reaction, the maximum temperature increased from ca. 217 to ca. $234^{\circ}C$, respectively. As the contents of PO increased from 0 to 2.5 g, the reaction time decreased from ca. 79 to ca. 38 sec and the maximum temperature increased from ca. 182 to ca. $271^{\circ}C$, respectively. The kinetic parameters were calculated and the conversions were based on the temperature rising method of adiabatic process. As the content of DMCHA increased, the rate constant $k_0$ increased. But in the case of PO catalyst, $k_0$ did hardly depend upon its amount, and showed us similar reaction rate constants.

• Journal of Life Science
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• v.24 no.8
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• pp.915-926
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• 2014

The ribosome is a protein synthesizing machinery and a ribonucleoprotein complex that consists of three ribosomal RNAs (23S, 16S and 5S) and 54 ribosomal proteins in bacteria. In the course of ribosome assembly, ribosomal proteins (r-protein) and rRNAs are modified, the r-proteins bind to rRNAs to form ribonucleoprotein complexes which are folded into mature ribosomal subunits. In this process, a number of non-ribosomal trans-acting factors organize the assembly process of the components. Those factors include GTP- and ATP-binding proteins, rRNA and r-protein modification enzymes, chaperones, and RNA helicases. During ribosome biogenesis, they participate in the modifications of ribosomal proteins and RNAs, and the assemblies of ribosomal proteins with rRNAs. Ribosomes can be assembled from a discrete set of components in vitro, and it is notable that in vivo ribosome assembly is much faster than in vitro ribosome assembly. This suggests that non-ribosomal ribosome assembly factors help to overcome several kinetic traps in ribosome biogenesis process. In spite of accumulation of genetic, structural, and biochemical data, not only the entire procedure of bacterial ribosome synthesis but also most of roles of ribosome assembly factors remain elusive. Here, we review ribosome assembly factors involved in the ribosome maturation of Escherichia coli, and summarize the contributions of several ribosome assembly factors which associate with 50S and 30S ribosomal subunits, respectively.

• Korean Journal of Applied Biomechanics
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• v.16 no.1
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• pp.31-41
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• 2006

The primary purpose of a TKA is to restore normal knee function Therefore, ideally, a TKA should: (a) maintain the natural leverage of the knee joint muscles to ensure generating adequate knee muscle moments to accomplish daily tasks such as rising from climbing stairs; (b) provide adequate knee joint stability. A 16-channel MyoResearch XP EMG system was used to collect the differential input surface electromyography signals VM, VL, RF, BF, ST during climbing/descending stair tests. A Peak Motion Measurement System was used to collect the kinematic and kinetic data. AKIN-COM Ill isokinetic dynamometer was used for EMG of VM, VL, RF, BF and ST during maximal voluntary contraction. I Quadriceps EMG results for the VM of the passed 1year group limb demonstrated significant less RMS EMG than that of the passed 3year group limb $60^{\circ}-15^{\circ}$ of knee flexion(p<0.05). The VL of the passed 1year group limb also demonstrated significants less RMS EMG than that of the passed 3year group limb from $60^{\circ}-45^{\circ}$ of knee flexion(p<0.05). Similar to the VM and VL, the RF of the passed 1year group limb showed less RMS EMG than that of the passed 3year group limb from $60^{\circ}-30^{\circ}$ do knee flexion(p<0.05). Hamstring EMG results for the BF of the passed 1year group limb demonstrated less RMS EMG than that of the passed 3year group limb from $75^{\circ}-15^{\circ}$ of knee flexion(p<0.05). The passed 1year group limb tended to have less ADD displacement(p<0.071) than that of the passed 3year group limb. There was no significant difference of the ABD displacement between the passed 1year group and the passed 3year group limbs(p<0.73). The passed 3year group used compensatory adaptation movement strategies to compensate for the strength deficit of passed 3year group limbs. The passed 3year group limb also increased the quadriceps muscle activation level to produce more knee extension moment to compensate for the short quadriceps moment arm. The passe 3year group limb might have an unstable knee joint in the medio-Iateral direction during the climbing/descending by showing a tendency of more ADD displacement and greater hamming co-activation EMG than the passed 1year group limbs. The TKA design was not able to help the knee joint to produce adequate knee extension moment with less quadriceps muscle effort. I think that old man needs continuous exercise for muscle strength.

• Korean Journal of Applied Biomechanics
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• v.19 no.2
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• pp.273-286
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• 2009

The objective of this research is to evaluate both quantitative analysis and qualitative analysis by comparing vital variable factors of the golf swing successes and the failures. At the moment of swing, each body segment and the movement of the club as well as kinematical parameters were produced by utilizing the 3-D swing analysis for the high school female golfers. As kinematical parameters, it analyzes the 3-D analysis and ground reaction force about the location change, velocity and angle. The 3-D swing analysis and ground reaction force location change, velocity and angle are analyzed for Kinematical parameters. As a result, the stable swing is maintained by club head showing very few front-back movement (X) when the address and the top swing. Also, the center of mass velocity contributes to the momentum increase by showing very rapid velocity when successful comparing with when failed at the time of top swing of left-right(Y) and it is thought that by lessening the cocking angle when successful from the top swing to the impact, it influences the linear velocity increase and has a good effect on a non-distance increase. It shows that Ground reaction force (GRF) is examined by showing the stable approval rating in a front-back(X) direction and left-right(Y) and connected to a successful swing.

• Korean Journal of Food Science and Technology
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• v.28 no.6
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• pp.1095-1103
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• 1996

In order to minimize the deterioration of dried apple quality, changes of free sugar content, organic acid and ascorbic and during osmotic dehydration with sucrose at various temperature, concentration and immersion time were investigated in this study, total sugar increased as the temperature, concentration and immersion time were increased. Sucrose showed the largest change in content while fructose and glucose showed no and small changes, respectively. Large amounts of malic and fumaric acids, and small amounts of oxalic, citric, maleic and succinic acids were detected. Organic acids were high at low temperature treatment, and became higher with increasing concentration. Loss of ascorbic acid was small at the low temperature and high concentration. Effect of immersion time was negligible. Changes of free sugar, and organic and ascorbic acid followed the first-order and second-order reaction rate equations, respectively. Arrhenius equation was applied to determine the effect of temperature on reaction rate constants with high $r^2$. To predict the changes of quality, a model was established by using the optimum functions of temperature, concentration and immersion time. The model had high $r^2$ value for the quality changes during drying.

• Journal of the Korean Society of Combustion
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• v.20 no.4
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• pp.34-41
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• 2015

Oxy-methane nonpremixed flames diluted with $CO_2$ were investigated to clarify impact of radiation heat loss and chemical effects of additional $CO_2$ to oxidizer stream on flame extinction. Flame stability maps were presented with functional dependencies of critical diluents mole fraction upon global strain rate at several oxidizer stream temperatures in $CH_4-O_2/N_2$, $CH_4-O_2/CO_2$, and $CH_4-O_2/CO_2/N_2$ counterflow flames. The effects of radiation heat loss on the critical diluent mole fractions for flame extinction are not significant even at low strain rate in nonpremixed $CH_4-O_2/N_2$ diffusion flame, whereas those are significant at low strain rate and are negligible at high strain rate (> $200s^{-1}$) in $CH_4-O_2/CO_2$ and $CH_4-O_2/CO_2/N_2$ counterflow flames. Chemical effects of additional $CO_2$ to oxidizer stream on the flame extinction curves were appreciable in both $CH_4-O_2/CO_2$ and $CH_4-O_2/CO_2/N_2$ flames. A scaling analysis based on asymptotic solution of stretched flame extinction was applied. A specific radical index, which could reflect the OH population in main reaction zone via controlling the mixture composition in the oxidizer stream, was identified to quantify the chemical kinetic contribution to flame extinction. A good correlation of predicted extinction limits to those calculated numerically were obtained via the ratio between radical indices and oxidizer Lewis numbers for the target and baseline flames. This offered an effective approach to estimate extinction strain rate of nonpremixed oxy-methane flames permitting air infiltration when the baseline flame was taken to nonpremixed $CH_4-O_2/N_2$ flame.

• Journal of Microbiology and Biotechnology
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• v.22 no.3
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• pp.292-300
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• 2012

We report the expression, purification, and characterization of L-asparaginase (AnsA) from Rhizobium etli. The enzyme was purified to homogeneity in a single-step procedure involving affinity chromatography, and the kinetic parameters $K_m$, $V_{max}$, and $k_{cat}$ for L-asparagine were determined. The enzymatic activity in the presence of a number of substrates and metal ions was investigated. The molecular mass of the enzyme was 47 kDa by SDS-PAGE. The enzyme showed a maximal activity at $50^{\circ}C$, but the optimal temperature of activity was $37^{\circ}C$. It also showed maximal and optimal activities at pH 9.0. The values of $K_m$, $V_{max}$, $k_{cat}$, and $k_{cat}/K_m$ were $8.9{\pm}0.967{\times}10^{-3}$ M, $128{\pm}2.8$ U/mg protein, $106{\pm}2s^{-1}$, and $1.2{\pm}0.105{\times}10^4M^{-1}s^{-1}$, respectively. The L-asparaginase activity was reduced in the presence of $Mn^{2+}$, $Zn^{2+}$, $Ca^{2+}$, and $Mg^{2+}$ metal ions for about 52% to 31%. In addition, we found that $NH_4{^+}$, L-Asp, D-Asn, and ${\beta}$-aspartyl-hydroxamate in the reaction buffer reduced the activity of the enzyme, whereas L-Gln did not modify its enzymatic activity. This is the first report on the expression and characterization of the L-asparaginase (AnsA) from R. etli. Phylogenetic analysis of asparaginases reveals an increasing group of known sequences of the Rhizobial-type asparaginase II family.