• Title/Summary/Keyword: KIER

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Characteristics of Silicon Nanoparticles Depending on H2 Gas Flow During Nanoparticle Synthesis via CO2 Laser Pyrolysis (CO2 레이저 열분해법을 이용한 실리콘 나노입자 합성 시 H2 유량이 나노입자 특성에 미치는 영향)

  • Lee, Jae Hee;Kim, Seongbeom;Kim, Jongbok;Hwang, Taekseong;Lee, Jeong Chul
    • Korean Journal of Materials Research
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    • v.23 no.5
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    • pp.260-265
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    • 2013
  • Silicon nanoparticle is a promising material for electronic devices, photovoltaics, and biological applications. Here, we synthesize silicon nanoparticles via $CO_2$ laser pyrolysis and study the hydrogen flow effects on the characteristics of silicon nanoparticles using high resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), and UV-Vis-NIR spectrophotometry. In $CO_2$ laser pyrolysis, used to synthesize the silicon nanoparticles, the wavelength of the $CO_2$ laser matches the absorption cross section of silane. Silane absorbs the $CO_2$ laser energy at a wavelength of $10.6{\mu}m$. Therefore, the laser excites silane, dissociating it to Si radical. Finally, nucleation and growth of the Si radicals generates various silicon nanoparticle. In addition, researchers can introduce hydrogen gas into silane to control the characteristics of silicon nanoparticles. Changing the hydrogen flow rate affects the nanoparticle size and crystallinity of silicon nanoparticles. Specifically, a high hydrogen flow rate produces small silicon nanoparticles and induces low crystallinity. We attribute these characteristics to the low density of the Si precursor, high hydrogen passivation probability on the surface of the silicon nanoparticles, and low reaction temperature during the synthesis.

Redox activities of spinel type metal oxides as oxygen carriers (산소공여매체로서의 스핀넬 구조 금속산화물의 redox 활성 연구)

  • Jeong, J.H.;Park, J.W.;Joo, Y.K.;Park, J.S.;Jung, H.;Lee, H.T.;Yoon, W.L.
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2002.11a
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    • pp.191-194
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    • 2002
  • 매체 순환식 연소(Chemical-Looping Combustion, CLC)는 금속 산화물(산소공여매체, oxygen carrier)의 산소를 이용하여 화석연료를 산화(연료 연소 공정)시키고, 환원된 금속을 다시 산화(매체 산화 공정)시키는 간접적인 연소 공정의 하나이다. 이 방식은 온실효과의 주발생원인 $CO_2$를 원천적으로 회수할 수 있고, 또한 화염이 없는 상태에서 연소반응이 진행됨으로 thermal NOx의 발생을 미연에 방지할 수 있어 고효율의 환경친화적인 연소공정이다.(중략)

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The Wind Resource Database KIER-WindJeju (제주도 풍력자원 데이터베이스 KIER-WindJeju)

  • Kim, Hyun-Goo;Lee, Jong-Nam;Jang, Moon-Seok;Kyong, Nam-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.420-422
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    • 2007
  • In order to support wind power development in Jejudo, the island of winds, the wind resource database KIER-WindJeju has been established by meteor-statistical analysis on met-mast measurements of KIER. The analysis includes tower shading, exposure category, wind profile exponent for wind speed extrapolation to hub height of wind turbine, and correlation matrix between neighboring sites to assist choice of appropriate reference site for long-term correlation. KIER-WindJeju will be provided as an add-on of Google $Earth^{TM}$ and will be used as a guideline of future wind resource assessment in Jejudo.

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Thermal Characteristics of Domestic Solar Collector for Low-Temperature Applications (국내 저온용 집열기의 열성능 특성)

  • Kim, Jeong-Bae;Rhie, Soon-Myeong;Yoon, Eung-Sang;Lee, Jin-Kook;Joo, Moon-Chang;Baek, Nam-Choon
    • 한국태양에너지학회:학술대회논문집
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    • 2008.04a
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    • pp.215-220
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    • 2008
  • This study shows the results on thermal performance test with domestic solar collector for low-temperature applications using KS, then reveals the efficiency difference between KS and EN standard. Using the test results, this study presents the status of thermal performance with domestic solar collector including flat-plate, single evacuated, and double evacuated (with mirror or U-tube) solar collector.

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Optical Properties of ZnS:Mn,Cu,Cl Phosphor for Inorganic ELD (무기 ELD용 ZnS:Mn,Cu,Cl 형광체의 광학적 특성 연구)

  • Lee, Hak-Soo;Gwak, Ji-Hye;Han, Sang-Do;Han, Chi-Hwan;Kim, Jung-Duk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.424-425
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    • 2006
  • Zinc sulfide is a well-known host material of phosphor emitting different radiations dependent on different doping impurities of metallic ion. It emits green, blue, orange-yellow or white colors by doping with activators such as copper, silver, manganese and so on. In this study, manganese, copper and chlorine doped ZnS phosphor (ZnS:Mn,Cu,Cl) was synthesized by solid-state reaction method. The optical properties were investigated according to different concentrations of sulfur and activators used during the synthesis process.

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