• Title/Summary/Keyword: K2PS

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Photoluminescence Tuning of Porous Silicon by Electrochemical Etching in Mixed Electrolytes

  • Lee, Ki-Hwan;Jeon, Ki-Seok;Lee, Seung-Koo;Choi, Chang-Shik
    • Journal of Photoscience
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    • v.10 no.3
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    • pp.257-261
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    • 2003
  • We have systematically studied the evolution of the photoluminescence(PL) tuning of porous silicon(PS) by electrochemical etching in various mixed electrolytes. The electrolytes employed as an etchants were mixtures of HF:CH$_3$COOH:HNO$_3$:C$_2$H$\_$5/OH solutions where the composition ratios (%) were varied from 10:1.98:0:88.02 to 10: 1.98:8.4:79.62 under constant concentration of HF and CH$_3$COOH with a total volume of 100 ml. Changes in the surface morphology of the samples caused by variations in the etching process were investigated by scanning electron microscopy (SEM) and atomic force microscopy (AFM). After samples are etched in various mixed electrolytes, FTIR analyses show that there is the non-photoluminescent state and the photoluminescent state simultaneously. The PL spectra show the PL tuning in the ranging from 560 to 700 nm with the increase of HNO$_3$ concentration. An analysis of the subsequent PL relaxation mechanism was carried out by time-correlated single photon counting (TCSPC) method. Based on experimental results, it is assumed that a red shift of the main PL peak position is related to the HNO$_3$ activated formation of silicon oxygen compounds. Therefore, the use of electrolyte mixtures with composition ratios can be obtained adequate and reproducible results for PL tuning.

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A Study on Design and Fabrication of SRD Impulse Generator and Antenna for Ground Penetrating Radar System (지반투과 레이더 시스템을 위한 SRD 임펄스 발생기 및 안테나의 설계 및 제작에 관한 연구)

  • Kim, Hyoung-Jong;Shin, Suk-Woo;Choi, Gil-Wong;Choi, Jin-Joo;Shin, Shang-Youal
    • Journal of the Korea Institute of Military Science and Technology
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    • v.14 no.3
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    • pp.509-516
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    • 2011
  • In this paper, a ground penetrating radar(GPR) system is implemented for landmine detection. The performance of the GPR system is associated with the characteristics of local soil and buried target. The choice of the center frequency and the bandwidth of the GPR system are the key factors in the GPR system design. To detect a small and shallow target, the higher frequencies are needed for high depth resolution. We have been designed, fabricated and tested a new impulse generator using step recovery diodes. The measured impulse response has an amplitude of 6.2V and a pulse width of 250ps. The implemented GPR system has been tested real environmental conditions and has proved its ability to detect a small buried target.

Efficient keV X-ray Generation from Irradiation of in-situ Produced Silver Clusters by Ti:sapphire Laser Pulses

  • Chakravarty, U.;Naik, P.A.;Kumbhare, S.R.;Gupta, P.D.
    • Journal of the Optical Society of Korea
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    • v.13 no.1
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    • pp.80-85
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    • 2009
  • An experimental study of energy absorption and x-ray emission from ultrashort laser pulse irradiation of in-situ produced solid clusters has been performed. Silver clusters produced by a 30 mJ, 300 ps laser pulse were irradiated up to an intensity of $3{\times}10^{17}\;W/cm^2$ by a 70 mJ, 45 fs compressed laser pulse from the same Ti:sapphire laser. Absorption of the laser light exceeding 70% was observed, resulting in an x-ray yield (>1 keV) of ${\sim}60{\mu}J$ pulse. This may constitute a much simpler means of intense x-ray generation using ultrashort laser pulses as compared to the irradiation of structured / pre-deposited cluster targets, and it offers higher x-ray conversion efficiency than that from gas clusters and planar solid targets.

Photodecomposition Properties of Formaldehyde Using PS Nanofiber and Photocatalyst (극세섬유와 광촉매를 이용한 포름알데히드의 광분해 특성)

  • An H.H.
    • Journal of the Korean Institute of Gas
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    • v.10 no.2 s.31
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    • pp.1-6
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    • 2006
  • In this study we proposed on effect of the photodecomcomposition of coated nanofiber by $Pd/TiO_2$ for the removal of formaldehyde gas as indoor air pollutant. The photocatalytic reactor was setup in the inside of rectangular box (volume 2 l), UV lamp and the coating nanofiber with $Pd/TiO_2$. This study investigated the reaction rate and the adsorption constant of Langmuir-Heinshelwood, conversion of formaldehyde gas on temperature ($40^{\circ}C{\sim}80^{\circ}C$), effect of conversion (%) under different concentration, and effect of conversion (%) with humidity level on added $SO_2$ gas. As results, the rate constant (k) and adsorption constant (ft) were 114.94ppmv/min, $0.0036ppmv^{-1}$, respectively. and the conversion (%) of formaldehyde gas on temperature ($40^{\circ}C{\sim}80^{\circ}C$) was decreased to about 24%, compare with the first conversion (%). In conversion effect of increasing humidity levels, the presence of sulfur dioxide further decreased than without sulfur dioxide. the decreasing reason of conversion with presence sulfur dioxide judged as a cause of interference factor on the decrease of contact chance with photocatalysts.

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Identification of Antimicrobial Peptide Hexamers against Oral Pathogens through Rapid Screening of a Synthetic Combinatorial Peptide Library

  • Song, Je-Seon;Cho, Kyung Joo;Kim, Joungmok;Kim, Jeong Hee
    • International Journal of Oral Biology
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    • v.39 no.4
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    • pp.169-176
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    • 2014
  • A positional scanning synthetic peptide combinatorial library (PS-SCL) was screened in order to identify antimicrobial peptides against the cariogenic oral bacteria, Streptococcus mutans. Activity against Streptococcus gordonii and Aggregatibacter actinomycetemcomitans was also examined. The library was comprised of six sub-libraries with the format $O_{(1-6)}XXXXX-NH_2$, where O represents one of 19 amino acids (excluding cysteine) and X represents equimolar mixture of these. Each sub-library was tested for antimicrobial activity against S. mutans and evaluated for antimicrobial activity against S. gordonii and A. actinomycetemcomitans. The effect of peptides was observed using transmission electron microscopy (TEM). Two semi-mixture peptides, RXXXXN-$NH_2$ (pep-1) and WXXXXN-$NH_2$ (pep-2), and one positioned peptide, RRRWRN-$NH_2$ (pep-3), were identified. Pep-1 and pep-2 showed significant antimicrobial activity against Gram positive bacteria (S. mutans and S. gordonii), but not against Gram negative bacteria (A. actinomycetemcomitans). However, pep-3 showed very low antimicrobial activity against all three bacteria. Pep-3 did not form an amphiphilic ${\alpha}$-helix, which is a required structure for most antimicrobial peptides. Pep-1 and pep-2 were able to disrupt the membrane of S. mutans. Small libraries of biochemically-constrained peptides can be used to generate antimicrobial peptides against S. mutans and other oral microbes. Peptides derived from such libraries may be candidate antimicrobial agents for the treatment of oral microorganisms.

Photosynthetic Characteristics of Porphyra yezoensis Ueda Measured in situ by Diving Pulse-Amplitude Modulated (PAM) Fluorometry on the Southwestern Coast of the Korean Peninsula (남서해역에서 양식되는 방사무늬김(Porphyra yezoensis Ueda)의 Diving-PAM에 의한 광합성 특성)

  • Kim, Jeong Bae;Lee, Won-Chan;Kim, Hyung Chul;Choi, Hee-Gu;Park, Jung-Im;Cho, Yoonsik;Park, Hwan Hee
    • Korean Journal of Environmental Biology
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    • v.30 no.3
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    • pp.210-218
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    • 2012
  • The morphological characteristics, carbon and nitrogen concentrations, stable isotope values and photosynthetic rates of Porphyra yezoensis were studied at the main purple lavers production areas on southwestern coast of Korea. The morphological characteristics of leaf length, leaf width and weight of Porphyra blades were between 11.6~16.3 (average 13.8) cm, 4.6~6.3 (average 5.4) cm, $1.1{\sim}2.6(average\;1.86)g\;DW\;m^{-2}$, respectively. Photosynthetic pigment of Chl a concentration of Porphyra blades was between $2.18{\sim}17.77(average\;9.65)mg\;DW\;Chl\;a\;m^{-2}$. Carbon and nitrogen concentrations of Porphyra blades was between $201{\sim}317(average\;240)mg\;DW\;g^{-1}$, $39.8{\sim}50.0(average\;43.5)mg\;DW\;g^{-1}$ and C/N ratio 5.0~6.7 (average 5.5). The range of average ${\delta}^{13}C$ and ${\delta}^{15}N$ values of Porphyra blades was between - 25.6 to - 24.0 (average - 24.7)‰ for ${\delta}^{13}C$, and 1.3 to 4.1 (average 2.1)‰ for ${\delta}^{15}N$. Photosynthetic characteristics of seaweeds measured by pulse amplitude modulation (PAM) fluorometry was used as an indicator of photosynthetic activity. We use Diving-PAM fluorometry to examine photosynthetic rates of the seaweeds Porphyra yezoensis at each station. Maximum quantum yield of Porphyra blades was between 0.46~0.55 (average 0.52), the variance of the effective PS II maximum quantum yield of the station was broadly similar. Maximum relative electron transport rate (rETRmax) of Porphyra blades was between $4.71{\sim}5.84(average\;5.33){\mu}mol\;electrons\;m^{-2}\;s^{-1}$, the changes of maximum relative electron transport rate (rETRmax) of Porphyra yezoensis were similar to those of PS II maximum quantum yield. Photosynthetic efficiency (${\alpha}$) was between 0.027~0.045 (average 0.036). Minimum saturating irradiance ($E_k$) range was $139{\sim}180(average\;156){\mu}mol\;photons\;m^{-2}\;s^{-1}$. Minimum saturating irradiance ($E_k$) made a difference by station within the area on southwestern coast. Carbon and nitrogen concentrations and photosynthetic rates of Porphyra blades production areas on southwestern coast were broadly similar. The photosynthetic characteristics showed low photosynthetic rates because the low maximum quantum yields and low maximum relative electron transport rate.

Characterization of Chl a Fluorescence of Hydrophytes under Cadmium Stress (카드뮴 스트레스에 대한 수생식물 5종의 엽록소형광 반응)

  • Oh, Soon-Ja;Zhin, Kook-Lhim;Koh, Seok-Chan
    • Journal of Environmental Science International
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    • v.18 no.12
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    • pp.1361-1368
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    • 2009
  • The effects of $Cd^{2+}$ ions on the Chl a fluorescence of 5 hydrophytes (e.g. Lemna, Salvinia, Ricciocarp, Nymph, Typha plants) were investigated in order to select $Cd^{2+}$-sensitive plant species and to get informations on physiological responses of plants to $Cd^{2+}$ stress. Lemna plants were most sensitive to cadmium stress, while Nymph plants were tolerant. However, in all $Cd^{2+}$-treated plants, Fv/Fm, the maximum photochemical efficiency of PS II, decreased in proportion to the increase of $Cd^{2+}$ concentration and treatment time. The Chl a fluorescence transient O-J-I-P was also considerably affected by $Cd^{2+}$ ions; the fluorescence yield decreased consid- erably in steps J, I and P in $Cd^{2+}$ treated plants, although it followed a typical polyphasic rise in non-treated plants. In Lemna plants, the functional parameters, ABS/CS, TRo/CS와 ETo/CS and RC/CS, decreased in proportion to the increase of $Cd^{2+}$ concentration, while N, Mo and Kn increased. The structural parameters, ${\Phi}po$, ${\Phi}po$/($1-{\Phi}po$), Plabs, SFlabs, Kp and RC/ABS, also decreased according to the increase of $Cd^{2+}$ concentration. Consequently, Lemna plants will be useful as a experimental model system to investigate responses of plants. And several functional or structural parameters could be applied to determine quantitatively the physiological states of plants under stresses.

Trajectory Studies of Methyl Radical Reaction with Iodine Molecule

  • Lee, Sang-Kwon;Ree, Jong-Baik;Kim, Yoo-Hang;Shin, Hyung-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.26 no.9
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    • pp.1369-1380
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    • 2005
  • The reaction of methyl radical with iodine molecule on an attractive potential energy surface is studied by classical trajectory procedures. The reaction occurs over a wide range of impact parameters with the majority of reactive events occurring in the backward rebound region on a subpicosecond scale. A small fraction of reactive events take place in the forward hemisphere on a longer time scale. The ensemble average of reaction times is 0.36 ps. The occurrence of reactive events is strongly favored when the incident radical and the target molecule align in the neighborhood of collinear geometry. Since the rotational velocity of I2 is slow, the preferential occurrence of reactive events at the collinear configuration of $CH_3{\ldots}I{\ldots}$I leads to the reaction exhibiting an anisotropic dependence on the orientation of $I_2$. During the collision, there is a rapid flow of energy from the $H_3C{\ldots}$I interaction to the I-I bond. The $CH_3I$ translation and $H_3C$-I vibration share nearly all the energy released in the reaction, and the distribution of the vibrational energy is statistical. The reaction probability is $\cong$0.4 at the $CH_3$ and I2 temperatures maintained at 1000 K and 300 K, respectively. The probability is weakly dependent on the $CH_3\;and\;I_2$ temperatures between 300 K and 1500 K.

Dynamic Rate Adaptation of Centralized AP for WLAN Performance Enhancement (무선랜 성능향상을 위한 AP의 동적 전송속도 할당 기법)

  • Park, Byoung-Chang;Woo, Hee-Kyoung;Kim, Chong-Kwon
    • Proceedings of the Korean Information Science Society Conference
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    • 2005.11a
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    • pp.391-393
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    • 2005
  • 최근 유비쿼터스 네트워크 환경을 구축하기 위해 많은 무선 통신 기술들이 등장하였다. 그 중 무선랜 기술은 쉬운 설치와 저렴한 비용 덕에 폭발적인 보급이 이루어 겼다. IEEE 802.11 표준을 기반으로 만들어진 무선랜은 여러 개의 전송속도를 지원한다. 대표적으로 802.11b는 1, 2, 5.5, 11MbPs의 4가지 전송속도를 지원한다. 낮은 전송속도로 전송을 하면 패킷 전송시간은 증가하지만 비트 에러율은 감소된다. 각각의 전송속도에 따라 다른 패킷 전송 성공률을 갖게 된다. 한 무선랜 AP에 연결된 노드들은 각자 자신의 처리율을 최대화할 수 있는 전송속도를 결정하여 사용하게 된다. 이러한 상황은 전체 시스템 성능에는 문제를 발생시킬 수 있다. 본 논문에서는 각자의 전송속도를 각자가 결정하는 것이 전체 시스템 성능에 문제를 발생시키는 경우를 보이고, 그것을 해결하기 위해 AP가 각 노드의 전송속도를 결정하는 기법을 제안한다. 나아가 무선랜에서의 문제점인 Performance Anomaly 현상을 해결하고, [3]에서 언급된 Inefficient Equilibria 현상도 막아본다.

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Change of the Lipid in Frog Legs during Frozen storage (냉동 저장기간에 따른 개구리 다리의 지질변화)

  • Park, Su-Kyung;Cho, Jeong-Soon;Jeong, Seung-Tai
    • Journal of the Korean Applied Science and Technology
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    • v.8 no.1
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    • pp.69-78
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    • 1991
  • Frog legs were stored before and after 30, 60, 90, 120 days at $-30^{\circ}C$ and $-70^{\circ}C$. The amounts of triglycerides, glycolipide and phospholipids by TLC and composition of fatty acids by GC were shown in this experiment, there fore, I have got these following results. 1. The amount of PL in frog legs consisted of 80% of the total lipids before storage. As the days of storage was longer, the amount of TG was increased, while PL and GL were decreased. 2. TG and ES & HC were composed of 66% to 77% of the neutral lipids composition before storage. As the days of storage was longer, the amount of MG, DG. FFA and ES & HC were increased, while FS and TG were decreased. 3. PE and PC were composed of 78% to 81% of the phospholipids composition before storage. As the days of storage was longer, the amount of FA and PS were increased, while PC and PE were decreased. 4. The composition of fatty acids in neutral lipids of frozen frog legs at $-30^{\circ}C$, 120 days was studied, Capric acid. Stearic acid, Behnic acid. Oleic acid and Linoleic acid were increased as compared with initial neutral lipids.