• Title/Summary/Keyword: K-장석

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Study of Utilization of Natural Zeolites as Functional Materials for Water Purification (I): Cation Exchange Property of Domestic Zeolites (천연 제올라이트의 수환경 개선용 기능성 소재로의 활용에 관한 연구 (I): 국내산 제올라이트의 양이온 교환 특성)

    • Journal of the Mineralogical Society of Korea
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    • v.16 no.2
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    • pp.135-149
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    • 2003
  • Domestic zeolite ores are mostly composed of Ca-type clinoptilolite, accompanying a little amounts of mordenite. However, other types of zeolite ores rich in ferrierite, heulandite, or mordenite are less commonly found. Based on the quantitative XRD analysis, zeolite contents are determined to be nearly 50∼90 wt%. Impurities (mostly > 10 wt%) in the zeolite ores chiefly consist of quartz, feldspar, smectite, and opal-CT. The determined CEC values ($CEC_{AA}$ ) of powdery samples (grain size: < 125 $\mu\textrm{m}$) of zeolite ores by the Ammonium Acetate method are mostly higher than 100 meq/100 g. Some zeolites from the Guryongpo area, corresponding to the clinoptilolite ore, are measured to be dominantly high in CEC values ranging 170∼190 meq/100 g. Cation exchange property of the zeolite ores varies greatly depending on the types or zeolite species present in the ores. Despite of the lower grade in zeolite content, the $CEC_{AA}$ of ferrierite ore is comparatively high. Compared to this, the $CEC_{AA }$ of heulandite ore is very low, though the zeolite ore exhibits the highest grade ranging up to about 90 wt%. In addition, the CEC values calculated theoretically from the framework composition of clinoptilolite-heulandite series are not consistent with those determined by the cation exchage experiment. The measured $CEC_{AA}$ of clinoptilolite ores are generally higher than those of heulandite ores. This may be due to the higher Ca abundance in exchangeable cation composition and the presence of probable stacking faults in heulandite. The variation of $CEC_{CEC}$ is roughly proportional, though not strictly compatible, to the zeolite contents in clinoptilolite ores. It seems to be caused by the fact that the $CEC_{AA}$ of clinoptilolite locally varies depending on crystal-chemical diversity, i. e., the variation in framework composition (Si/Al) and exchangeable cation composition (especially, the contents of Ca and K). In addition, the determined CEC values ($CEC_{MB}$ ) of zeolite ores by the Methylene Blue method are much higher than those calculated from smectite contents. It suggests a probable reaction of Methylene Blue ion ($C_{16}$ $H_{18}$ $N_3$S+) with larger-pore zeolites than clinoptlolite-heulandite series, i.e., ferrierite and mordenite as well as with smectite. This can be supported by the fact that the ferrierite ore accompanying little amount of smectite has the highest value in CE $C_{MB}$ .

Effect of Boxing Aerobic Dance on Body Composition, Blood Component and Vascular Compliance in Obese Middle Aged Women (복싱에어로빅 참여가 비만 중년여성의 신체조성, 혈액성분 및 혈관탄성에 미치는 영향)

  • Zhang, Seok-Am;Kim, Seung-Suk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.9
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    • pp.4009-4017
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    • 2012
  • This study was conducted to test the effects of participation in 12-week program of boxing aerobics by obese middle-aged women on their body composition, blood constituents, and vascular compliance The samples are the middle-aged women in their forties or more, who has 30% or more body fat percentage, but has no medical history in cardiovascular disorders or metabolic diseases. The samples are divided into 8 of exercising group, and 8 of control group by random assignment. The intensity of boxing aerobics was HRmax 50% for the initial 4 weeks, HRmax 60% for the 5th to 8th week, and HRmax 70% for the 9th to 12th week. Each session took 60 minutes. The result is as follows. First, as a result of participating in the boxing aerobics program, body weight, body fat percentage, and muscle showed significant differences depending on the measuring period and the interacting term of the group and measuring period(p<.001), and the result of t-test on the sample matched to each group's measuring time also showed the significant increase or decrease in the exercising group(p<.001). Second, as a result of participating in the boxing aerobics program, the exercising group's TC, TG, HDL-C, and LDL-C, all showed significant differences in accordance with each group, measuring time, and the interaction term between groups and measuring time(p<.01, p<.001), and the result of t-test on each group's samples matched to the measuring time also shows significant increase or decrease in the exercising group(p<.01). Third, as a result of participating in the boxing aerobics programs, the vascular compliance of right hand, left hand, right hand, and left hand showed significant differences in accordance with each group, measuring time, and the interacting term between the measuring time and the group(p<.001), the t-test results of the samples matched to the each group's measuring time also showed significant differences in the exercising group(p<.001). To summarize the results above, it is suggested that the 12-week boxing aerobics program can improve body composition, blood constituents, and the blood circulation, which may prevent or enhance relevant diseases such as cardiovascular disorders.

A Study of Optimum Application of Fertilizers for Major Crops in Korea (우리나라 주요작물(主要作物)에 대(對)한 적정시비량(適正施肥量)에 관(關)하여)

  • Oh, W.K.;Chang, S.H.
    • Korean Journal of Soil Science and Fertilizer
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    • v.2 no.1
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    • pp.39-44
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    • 1969
  • Discussions on the adequacy of present level of supply of fertilizers on the basis of the results obtained from experiments conducted on farmers' fields. 1. No differences have been found between present supply and optimum doses of nitrogen and phosphorus for rice except potash of which present amount of supply is 2.26kg/10a which is lower than the optimum dose by 1.90kg/10a. About 1.2% increase in the yield of paddy may be expected by increasing the level of potash to 4.2kg/10a. 2. Increasing the present supply of nitrogen, phosphorus and potash by 3.4, 4.7 and 3.3kg/10a, respectively for barley is required in order to increase its yield by 8.6%. 3. About 17% increase in the yield of wheat may be expected by increasing the supply of nitrogen, phosphorus and potash by 3.4, 3.9 and 6.4kg/10a. 4. An additional quantity of 7.5kg/10a of nitrogen, 6.4kg/10a of phosphorus and 7.5kg of potash on corn may incrase its yield by 45% 5. 8% increase in the yield of sweet-potato is expected when 3.8, 1.8 and 15.1kg/10a of additional nitrogen, phosphorus and potash, respecitvely is applied to the crop. 6. 21% increase in the yield of potato may arise with 0.6, 3.3 and 3.6kg/10a additional nitrogen, phosphorus and potash, respectively. 7. 15% increase in the yield of soybean may result with the application of 2.8, 1.9 and 2.9kg/10a additional nitrogen, phosphorus and potash, respectively. 8. The present quantity of fertilizer supply, it is necessary hereafter to supply fertilizer with attentions on such crops as corn, sweet-potato and white-potato etc. Needs to be revised in view of such crops as corn, sweet-potato and white-potato.

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Hydrochemistry and Formation Environment of $CO_2$-rich Springs from the Kangwon Province (강원지역에서 산출되는 탄산천의 수리화학 및 생성환경)

  • 정찬호
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.1
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    • pp.61-73
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    • 2004
  • The purposes of this study are to investigate the occurrence, the hydrochemical characteristics and the origin of the $CO_2$-rich springs from the Kangwon Province, and to reanalyze the previous studied results of other researchers. The $CO_2$-rich water samples were collected at 13 locations in the Kangwon Province. The $CO_2$-rich water shows a high $CO_2$ concentration ($P_{CO2}$ 0.787 to 4.78 atm), weak acidic pHs, electrical conductivity values ranging from 422 to 2,280 $\mu$S/cm, and high Fe and F contents. The chemical compositions of $CO_2$-rich water from this study area are classified into three types; $Ca-HCO_3$, Ca(Na)-$HCO_3$, $Na-HCO_3$ types. The chemical data of $CO_2$-rich waters and their host rocks indicate that $Na-HCO_3$ type water are mainly influenced by biotite, K-feldspar granite, and Ca(Na)-HC $O_3$, type water is chiefly influenced by gneiss and carbonate minerals in granite. F and Fe contents of $CO_2$-rich waters are abundant in $Na-HCO_3$, and $Ca-HCO_3$ types, respectively. The results of this study suggest that the chemical composition $CO_2$-rich water is mainly controlled by the mineralogical composition of aquifer host rocks. Oxygen and deuterium isotope data indicate that $CO_2$-rich water is meteoric origin. The $\delta^{13}$C values (-0.3$\textperthousand$ to -6.2$\textperthousand$ PDB) suggest that dissolved carbonates are mainly derived from a deep-seated $CO_2$ and partly from carbonate minerals.

A Study on Relationship between Social Entrepreneurship and Organizational Performance - Focused on Moderating Effect of Government support - (사회적 기업가정신이 조직성과에 미치는 영향 - 정부지원 조절효과를 중심으로 -)

  • Lim, Jae-Woong;Chang, Sug-In
    • Management & Information Systems Review
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    • v.37 no.2
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    • pp.235-258
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    • 2018
  • This study is an empirical analysis on Moderating Effect of Government support on Relationship between Social Entrepreneurship and Organizational Performance. Previous studies have focused on case studies for specific companies and studies on Social entrepreneurship have been carried out in recent years. As the interest in social enterprises is increasing due to the problem of social polarization, it is necessary to study the causal relationship between social entrepreneurship and organizational performance deeply, and the government continues to provide government support for social enterprises. However, there is a lack of research on the effects of government support on social entrepreneurship and organizational performance. Therefore, this study analyzes the Proactiveness and Risk-taking of social entrepreneurship and examines the causal relationship between the organization's economic performance and social performance and the moderating effect of government support on the members of the social enterprise in Chungcheong area based on the previous research It is expected that the researcher will give academic and practical value to practitioners. As a result of this study, it is shown that the risk sensitivity of social entrepreneurship has a significant effect on the economic performance, and the Proactiveness of entrepreneurship and Risk-taking of social entrepreneurship all have a positive effect on the social performance, The results of the study show that government support has only a positive effect on the moderating effects of the variables of enterprising and social performance among the variables. The results of this study suggest that social entrepreneurship in social enterprises is an important factor affecting organizational performance. Therefore, if managers of social enterprises continue to educate and apply social entrepreneurship to their members, The social and economic performance of social enterprises will increase, which will help to enhance the competitiveness of enterprises. In addition, although the government has implemented various policies to support social enterprises, there is no expectation of government support for organizational performance because of the lack of support from the government after social enterprise certification. And to develop the government's fine - tuned upbringing policy that can improve organizational performance.

Geochemistry and Petrogenesis of the Granitic Rocks in the Vicinity of the Mt. Sorak (설악산 부근의 화강암류에 대한 지구화학 및 성인)

  • Kyoung-Won Min;Sung-Bum Kim
    • The Journal of the Petrological Society of Korea
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    • v.5 no.1
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    • pp.35-51
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    • 1996
  • The granitic rocks in the vicinity of the Mt. Sorak, the northeastern part of the NE-SW elongated Mesozoic granitic batholith in the Kyeonggi massif, consist of granodiorite, biotite granite, two-mica granite and alkali feldspar granite. Variations In major and most trace elemental abundances show a typical differentiation trend in a granitic magma. Granitic rocks all display a calc-alkaline trend in the AFM diagram. Also, In the ACF diagram discriminating between I- and S-type granitic rocks, granodiorite and most biotite granite in the southeastern area represent I-type and magnetite-series characteristics, while most biotire granite and two-mica granite in the northwestern area exhibit S-type and ilmenite-series ones.According to recent studies of the granitle rocks In the Inje-Hongcheon district. all ihe granitic rocks distributed in the northeastern part of the Kyeonggi massif have been classified as late Triassic to early Jurassic Daebo granite. With reference of the formerly published ages, an age oi $125.6{\pm}4.4$ Ma calculated by the slope in the plot of $^{87}Rb/^{86}Sr-^{87}Sr/^{86}Sr$ for the biotite granite samples from the southeastern area is inferred as an emplacement age for the granitic rocks in the vicinity of the Mt. Sorak. On the basis of elemental variations and Sr isotope compositions, an possible evolutional process for the granitic magmas in this area is suggested. The primary magma of I-type and magnetite-series generated about 125 Ma by partial melting of igneous originated crustal materials, might be emplaced and evolved through fractional crystallization, convection and assimilation of the surrounding Precambrian metasediments to become S-type and ilmenlte-serles in the outer area, and then solidified to granodiorite, biotite granite and two-mica granite.At the latest stage, the evolved hydrothermal solution altered the formerly solidified biotite granite to alkali feldspar granite and probably later local igneous activities affected the alkali feldspar granite again.

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Geochemistry, Secondary Contamination and Heavy Metal Behavior of Soils and Sediments in the Tohyun Mine Creek, Korea (토현광산 수계에 분포하는 토양과 퇴적물의 지구화학적 특성, 이차적 오염 및 중금속의 거동)

  • 이찬희;이현구;윤경무
    • Economic and Environmental Geology
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    • v.34 no.1
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    • pp.39-53
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    • 2001
  • Environmental pollution of the Tohyun mine creek area was investigated on the basis of geology, mineralogy and geochemistry. In soils and sediments of the mine area, ${Al_2}{O_3}/{Na_2O}$ and ${K_2}O/{Na_2}O$ ratios are partly negative correlation against ${SiO_2}/{Al_2}{O_3}$, respectively. Geochemical characteristics of some trace and rare earth elements such as V/Ni, Ni/Co, La/Ce, Th/Yb, Th/U, La/Th, ${La_N}/{Yb_N}$, La/Sc and Sc/Th are revealed a narrow range and homogeneous compositions may be explained by simple source lithology. These results suggest that sediments source of the host shale around the mine area could be originated by basic to intermediate igneous rocks. Mineral compositions of soil and sediment near the mine area were partly variable mineralogy, which are composed of quartz, mica, feldspar, chlorite, clay minerals and some pyrite. Soils and sediments with highly concentrated heavy minerals, gravity separated mineralogy, are composed of some pyrite, arsenopyrite, chalcopyrite, sphalerite, galena, goethite and various kinds of hydroxide minerals on the polished sections. As normalized by bed rock composition, average enrichment indices of major elements in sediments, precipitates, farmland soils and paddy soils are 1.0, 1.7, 0.9 and 0.8, respectively. Maximum concentration of environmental toxic elements in the mine creek are detected with Ag = 186 ppm, As = 17,100 ppm, Bi = ]27 ppm, Cd = 77 ppm, Cu = 12,299 ppm, Pb = 8,897 ppm, Sb = 1,350 ppm, W = 599 ppm and Zn = 12,250 ppm, which are increasing with total FeO increasing, and extremely high concentrations of surface sediments and precipitates near the waste rock dump. These toxic elements (As, Bi, Cd, Cu, Pb, Sb, W and Zn) of the samples, normalizing by host rock concentration, revealed that average enrichment index is 106.0 for sediments, 279.6 for precipitates, 3.5 for farmland soils and 1.6 for paddy soils. However, on the basis of EPA values, enrichment indices of all the samples are 40.7, 121.4, 1.3 and 0.6, respectively.

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Relationship between Higher Fungi Distribution and Climatic Factors in Naejangsan National Park (내장산국립공원의 고등균류 발생과 기후환경 요인과의 관계)

  • Jang, Seog-Ki;Kim, Sang-Wook
    • The Korean Journal of Mycology
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    • v.40 no.1
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    • pp.19-38
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    • 2012
  • This study was conducted to investigate the diversity of higher fungi and relationship between higher fungi and climatic factors in Naejangsan National Park from April 2004 to October 2010. The obtained results from investigation were as follows. The higher fungi were classified into 48 families, 158 genera and 451 species in Basidiomycotina, 13 families, 26 genera and 39 species in Ascomycotina, and 4 families, 7 genera and 7 species in Myxomycetes, and most of them belonged to Hymenomycetidae in Basidiomycotina. Dominant species belonged to Ttricholomataceae (72 species), Russulaceae (39 species), Polyporaceae (41 species), Boletaceae (40 species), Cortinariaceae (35 species) and Amamtaceae (28 species). For the habitat environment, the ectomycorrhizal mushrooms were 38.8% (15 families, 36 genera and 193 species), litter decomposing and wood rotting fungi 39.4% (36 families, 107 genera and 196 species), grounding Fungi 19.9% (24 families, 51 genera and 99 species) and others 1.8% (3 families, 4 genera and 9 species). Monthly, most of higher fungi were found in July, August and September, and least found in November. In climatic conditions, most higher fungi were occurred in $23^{\circ}C$and above of mean temperature, $20^{\circ}C$and above of minimum temperature, and $29^{\circ}C$and above of maximum temperature. most of higher fungi were found in 73% and above of relative humidity and 200 mm and above of monthly precipitation. In case of ectomycorrhizal fungi like Amamtaceae, Boletaceae and Cortinariaceae, significance levels are not high in $32^{\circ}C$ and above of maximum temperature which mostly affects species occurrence than other climatic factors of mean and minimum temperature and monthly precipitation.

Early Proterozoic Moyitic Series in Daqingshan, Inner Mongolia : Their Characteristics and Tectonis, Magmatic and Thermodynamic Model (내몽고 다큉샨내의 초기원생대 모이아이트계열 : 특성과 지구조, 마그마 그리고 열역학적 모델)

  • Lin CAO;Wei JIN
    • The Journal of the Petrological Society of Korea
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    • v.6 no.2
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    • pp.77-85
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    • 1997
  • The Early Proterozoic reworked rock association occurs within the Preacmbrian high grade metamorphic rocks in the area of Daqingshan, Inner Molgolia. In this association, the various large scale ductile deformation belts, form a nappe structure where the foliation steeply dips to north and the lineation ($340^{circ}-30^{\circ}$) plunges at $45^{\circ}55^{\circ}$. This result indicates the subduction/extension with northern part thrusting over the southern part at high angle. The southern subducted microlithon has the characteristics of prograde metamorphism. The northern thrusted microlithon shows the evidence of retrograde metamorphism with decreasing pressure and increasing temperature. The main rock types of Early Proterozoic Moyites are biotite adamellite and syenogranites occurring in the form of small batholiths or stocks and alkali-feldspar granites in veins. The biotite adamellites are progressively contacted with the Archean and Early Proterozoic rocks and contain a great deal of enclaves of metamorphosed rocks, suggesting an anatexis origin. The geochemical characteristics of moyites show the typical features of anatexis granite. At middle to late Early Proterozoic time, the continent-continent collision formed the large scale thrusting and imbrication of Archean basement rocks. According to the mineral assemblage and thermobarometer of Paria et al. (1988) give the following P-T condition : up-faulted block; $700-710^{\circ}C$, 0.72-0.78 Gpa (early stage) and $600^{\circ}C$, 0.44 Gpa (late stage), footwall block; $620^{\circ}C$, 0.8 Gpa (early stage), $620-840^{\circ}C$, 0.64-0.45 Gpa (peak) and $620-630^{\circ}C$, 0.35Gpa (late stage). These results suggest a clockwise P-T-t path (jin et al., 1991, 1994). According to the depth-temperature model in the comperature subduction zone and the experimental data of Wyllie et al. (1983), we propose a tectonic-magmatic-thermal model to account for metamorphism-anatexis of moyite occurring in subduction-shear zone.

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Study for the Conservation Treatment of the Stele for National Preceptor Hongbeop from the Jeongtosa Temple Site in Chungju (충주 정토사지 홍법국사탑비의 보존과학적 연구)

  • Chae, Woomin;Hwang, Hyunsung
    • Conservation Science in Museum
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    • v.19
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    • pp.1-18
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    • 2018
  • The Stele for National Preceptor Hongbeop from the Jeongtosa Temple site in Chungju is one of the most important stone cultural heritage items for exemplifying the style of the Goryeo era. Despite its obvious value, this relic has been stored in a weathered condition at the National Museum of Korea. It had suffered various dismantling and displacements during the Japanese colonial period and had long been exposed in the open air. The stele was selected as a subject for the Stone Monuments Restoration Project launched by the National Museum of Korea in 2015. In preparation for its outdoor exhibition as part of the restoration project, this study investigated the characteristics of its materials, produced a map of its deterioration from weathering, and carried out ultrasonic analysis of the materials to provide findings useful for conservation treatment. The materials analysis revealed that the turtle-shaped pedestal of the stele was made from two-mica granite consisting of medium-grained quartz, plagioclase, alkali feldspar, biotite, and muscovite. Its body stone is crystalline marble, the rock-forming mineral in which is medium-grained calcite in a rose-pink color with dark grey spots. The dragon top of the stele is made of crystalline marble, the major component of which is medium-grained calcite of a light-grey color. The deterioration consists of 21.5% abrasion on the stone body, with its south face most damaged, and 18.6% granular disintegration, with the north face most damaged. The ultrasonic material characterization conducted for mapping the general condition of weathering shows low values on the parts-assembly area of the turtle-shaped pedestal and on the upper portion of the stone body. It is considered that there is dislocation due to partial blistering and fracturing as well as to the differences in surface treatment. Prior to the outdoor exhibition of the stele, the surface was cleaned of contaminants and was consolidated based on the scientific investigation in order to prevent weathering from the external environment.