• Title/Summary/Keyword: K feldspar

Search Result 349, Processing Time 0.029 seconds

Feldspar Diagenesis and Reseuoir History of the Miocene Temblor Formation, Kettleman North Dome, California, U.S.A. (미국 캘리포니아주 케틀만 노스돔의 마이오세 템블러층에서 장석의 속성작용과 저류암의 발달사)

  • Lee Yong Il;Boles James R.
    • The Korean Journal of Petroleum Geology
    • /
    • v.3 no.1 s.4
    • /
    • pp.16-27
    • /
    • 1995
  • The Early Miocene Temblor Formation forms an important sandstone reservoir at Kettleman North Dome oil field, California. Sandstones are mostly arkosic in composition except deepest sandstones containing much volcanic rock fragments. Arranged in paragenetic sequence prior to feldspar alteration, the Temblor sandstones contain cements of early calcite, dolomite, quartz, albite, mixed-layer ohloriteismectite (C/S) and smectite, and anhydrite. Diagenetic changes associated with feldspar are albitization of plagioclase, late calcite and laumontite cementation and grain replacement, plagioclase dissolution, and kaolinite cementation. Plagioclase albitization and late calcite and laumontite cementation in Temblor sandstones occurred at the time of maximum burial with temperatures up to $130^{\circ}C$. Volcanic plagioclases were selectively albitized. Most diagenetic changes are interpreted to have occurred before the maior uplift which occurred within the last one million years ago. Since then to the time of hydrocarbon emplacement plagioclase dissolution and kaolinite cementation occurred. This reaction occurred in relatively closed system due to the occurrence of kaolinite next to the site of plagioclase dissolution. Unaltered part of volcanic plagioclase and plutonic plagioclase which escaped albitization during maximum burial were preferentially dissolved to make plagioclase porosity. Secondary porosity resulting from dissolution of plagioclase and carbonate and anhydrite cements was mainly produced by formation waters containing organic acids released during atagenesis of organic matter.

  • PDF

Soil Components and Elution Characteristics of Heavy Metals in Sediments of Andong and Imha Reservoir (안동・임하호 저니토의 토양 성분과 중금속 용출 특성)

  • Seo, Eulwon;Kim, Younjung;Baek, Seungcheol
    • Journal of the Korean GEO-environmental Society
    • /
    • v.9 no.4
    • /
    • pp.47-52
    • /
    • 2008
  • In this study, it was analyzed the soil components and elution characteristics of heavy metal ions in sediment samples to examine the effect of sediments embedded in Andong and Imha reservoirs on water quality. Major elements of sediments were shown to be Al, Si, K, and Fe by EDS analysis and major soil components of the collected 6 different sediments were illite (I), kaolinite (Ka), quartz (Q) and feldspar (F). And especially quartz took up a considerable part of sediments by XRD analysis. The total concentrations of Zn, As, Cr, Cu and Pb in sediments of Andong reservoir were relatively higher than those of Imha reservoir. The elution property of heavy metal from sediments had various aspects according to pH. Among the heavy metals in Andong reservoir sediments, As and Zn were significantly eluted at pH 6 compared with the other heavy metals. In the case of the adsorption tests using the sediments, the adsorptive capacities of Zn, Cd and Cu were very weak, on the while those of Pb and Cr were high.

  • PDF

SrAl2Si2O8 ceramic matrices for 90Sr immobilization obtained via spark plasma sintering-reactive synthesis

  • Papynov, E.K.;Belov, A.A.;Shichalin, O.O.;Buravlev, I. Yu;Azon, S.A.;Golub, A.V.;Gerasimenko, A.V.;Parotkina, Yu. А.;Zavjalov, A.P.;Tananaev, I.G.;Sergienko, V.I.
    • Nuclear Engineering and Technology
    • /
    • v.53 no.7
    • /
    • pp.2289-2294
    • /
    • 2021
  • In the present study, an original spark plasma sintering-reactive synthesis (SPS-RS) method for minerallike ceramic materials based on SrAl2Si2O8 feldspar-like skeleton structure was used for the first time, promising solid-state matrices for reliable immobilization of high-energy 90Sr. The method is based on the "in-situ" reaction of a mixture of SrO, Al2O3 and SiO2 oxides when heated by a unipolar pulsed current under compacting pressure. The phase and elemental composition structure were studied. The dynamics of the consolidation of the reaction mixture of oxides was studied in the range of 900-1200 ℃. The study found the temperature of the high-speed (minutes) SPS-RS formation of single-phase SrAl2Si2O8 composition ceramic in the absence of intermediate reaction products with a relative density of up to 99.2% and compressive strength up to 145 MPa and a strontium leaching rate of 10-4g/cm2·day.

A Study on Characteristics of Suspension Insulator for 400kN Transmission Lines (400kN 송전용 현수애자의 특성연구)

  • Choi, I.H.;Shin, T.W.;Choi, Y.G.;Min, B.W.;Lee, D.I.
    • Proceedings of the KIEE Conference
    • /
    • 2002.07c
    • /
    • pp.1434-1436
    • /
    • 2002
  • The 400KN suspended insulator was fabricated with feldspar, quartz, clay and $Al_2O_3$ wt% for extra high voltage. These materials were grinded with ball milling for 25 hours after mixing them. The grinded materials were sintered at $1300^{\circ}C$ for 50 minutes in the tunnel kiln after mading with jiggering method. The sintered density of specimen was reached at 97% in comparison with that of theory. The specimen had the characteristic of temperature rise with the increase of electrical losses. Also, the flexural strength and the fracture toughness of sintered parts respectively were 1658 kg/$cm^2$ and 2.3 $MPa{\cdot}m^{1/2}$.

  • PDF

K-Ar ages and geochemistry of granitic rocks in the northeastern geongsang basin (북동부 경상분지의 화강암류에 대한 지구화학 및 K-Ar 연대)

  • 김상중
    • Economic and Environmental Geology
    • /
    • v.32 no.2
    • /
    • pp.141-150
    • /
    • 1999
  • The granitic rocks are distributed in the northeastern Gyeongsang basin, and are subdivided into the Youngduk, Younghae, Jangsadong and Onjeong granite. Based on the chondrite normalized patterns of REE by primitive mantle, the Jangsadong granite is more negative Eu anomaly than other granites. On the patterns of trace and rare earcth elements normalized by primitive mantle, Sr, P, Nd, Sm and Ti contents of t도 Youngduk and Younghae granites are higher than those of Jangsadong and Onjeong granites. Based on K-Ar ages, the Youngduk granite is 166.5 Ma for biotite, Younghae granite is 158.7 to 178.0 Ma for hornblende, Jangsadong granite is 113.8 to 118.4 Ma for K-feldspar and hornblende, and Onjeong granite is 67.4 Ma for biotite. Thus, geochemical and geochronological results suggest two plutonic episodes :the Youngduk-Younghae granites and Jangsadong-Onjeong granites suggest two plutonic episodes : the Youngduk-Younghae granites and Jangsadong-Onjeong granites. Jurassic plutonism cooled faster than Cretacous plutonism in the study area.

  • PDF

Properties of Kaolinite as a Raw Material for Porcelain

  • Kim, Jong-Young;Hwang, Kwang-Taek
    • Journal of the Korean Ceramic Society
    • /
    • v.56 no.6
    • /
    • pp.566-576
    • /
    • 2019
  • In this work, we investigated kaolinite raw materials from China, Vietnam, and Seongju (Korea) used for the manufacture of porcelain products in Korea. According to chemical analysis results, for the kaolinites from Seongju, more feldspar components containing CaO, K2O, and Na2O are found than in those from China or Vietnam, of which the composition is close to that of pure kaolinite. Through X-ray Rietveld quantitative analysis, kaolinite and muscovite are found to be the main phases for all the raw materials. Halloysite, quartz, gibbsite, and andesine are found at more than 5% for KM-85 (China), LKC-60 (Vietnam), KC-009 (China), and WA (Seongju). Absorption rate is on order of LKC-60 < KC-009 < KM-85 < PA < WA, and the sample, sintered in reductive atmosphere, exhibits the lowest absorption rate. Comparing the color of the sintered samples, kaolinites of KM-85, LKC-60, and KC-009 (L*: 94 - 97%) show higher whiteness value than those of WA and PA (L*: 82 - 91%).

The Geochemical and Zircon Trace Element Characteristics of A-type Granitoids in Boziguoer, Baicheng County, Xinjiang (중국 신장 위그루자치구 바이청현 보즈구얼의 A형화강암류의 지화학 및 지르콘 미량원소특징에 대한 연구)

  • Yin, Jingwu;Liu, Chunhua;Park, Jung Hyun;Shao, Xingkun;Yang, Haitao;Xu, Haiming;Wang, Jun
    • Economic and Environmental Geology
    • /
    • v.46 no.2
    • /
    • pp.179-198
    • /
    • 2013
  • The Boziguoer A-type granitoids in Baicheng County, Xinjiang, belong to the northern margin of the Tarim platform as well as the neighboring EW-oriented alkaline intrusive rocks. The rocks comprise an aegirine or arfvedsonite quartz alkali feldspar syenite, an aegirine or arfvedsonite alkali feldspar granite, and a biotite alkali feldspar syenite. The major rock-forming minerals are albite, K-feldspar, quartz, arfvedsonite, aegirine, and siderophyllite. The accessory minerals are mainly zircon, pyrochlore, thorite, fluorite, monazite, bastnaesite, xenotime, and astrophyllite. The chemical composition of the alkaline granitoids show that $SiO_2$ varies from 64.55% to 72.29% with a mean value of 67.32%, $Na_2O+K_2O$ is high (9.85~11.87%) with a mean of 11.14%, $K_2O$ is 2.39%~5.47% (mean = 4.73%), the $K_2O/Na_2O$ ratios are 0.31~0.96, $Al_2O_3$ ranges from 12.58% to 15.44%, and total $FeO^T$ is between 2.35% and 5.65%. CaO, MgO, MnO, and $TiO_2$ are low. The REE content is high and the total ${\sum}REE$ is $(263{\sim}1219){\times}10^{-6}$ (mean = $776{\times}10^{-6}$), showing LREE enrichment HREE depletion with strong negative Eu anomalies. In addition, the chondrite-normalized REE patterns of the alkaline granitoids belong to the "seagull" pattern of the right-type. The Zr content is $(113{\sim}1246){\times}10^{-6}$ (mean = $594{\times}10^{-6}$), Zr+Nb+Ce+Y is between $(478{\sim}2203){\times}10^{-6}$ with a mean of $1362{\times}10^{-6}$. Furthermore, the alkaline granitoids have high HFSE (Ga, Nb, Ta, Zr, and Hf) content and low LILE (Ba, K, and Sr) content. The Nb/Ta ratio varies from 7.23 to 32.59 (mean = 16.59) and the Zr/Hf ratio is 16.69~58.04 (mean = 36.80). The zircons are depleted in LREE and enriched in HREE. The chondrite-normalized REE patterns of the zircons are of the "seagull" pattern of the left-inclined type with strong negative Eu anomaly and without a Ce anomaly. The Boziguoer A-type granitoids share similar features with A1-type granites. The average temperature of the granitic magma was estimated at $832{\sim}839^{\circ}C$. The Boziguoer A-type granitoids show crust-mantle mixing and may have formed in an anorogenic intraplate tectonic setting under high-temperature, anhydrous, and low oxygen fugacity conditions.

Geochemical Characteristics of the Continental Shelf and Slope Sediments off the Southeastern Coast of Korea (한국 동남해역 대륙붕과 대륙사면 표층퇴적물의 지화학적 특성)

  • Lee, Chang-Bok;Park, Yong-Ahn;Kang, Hyo-Jin;Kim, Dae-Chul
    • The Korean Journal of Quaternary Research
    • /
    • v.5 no.1
    • /
    • pp.15-31
    • /
    • 1991
  • A total of 90 surface sediment samples, collected from the continental margin area bordering east and southeast coast of Korea, were subject to the geochemical analyses with the aim of filling the gap in our knowledge of this environment. The analyzed items included the major elements (Al, Fe, Mg, Ca, K, Na, p and Mn), organic carbon, and some trace metals (Ba, Co, Cu, Sr and Zn). The sediment grain-size exerted a predominant influence on the contents of most elements, with the exceptions of Ca, K, Sr and Ba. The Ca and Sr contents, being closely interrelated each other, were mainly controlled by the calcium carbonate content. The K content, on the other hand, appeared to be influenced by both illite and feldspar. The Ba content showed a certain relationship with that of K, suggesting a common source of these two elements; potassium feldspar. The R-mode factor analysis result also reaffirmed the above-mentioned controlling factors on the sediment geochemistry. The grain-size dependency of trace metals obscures their areal distribution pattern from the total contents. However, with the metal/aluminum ratios we could differentiate the subtle difference in the metal enrichment. Hence, sediments of the southern coastal area appear to receive some anthropogenic inputs of metals, though the effect is still negligible.

  • PDF

Effects of Alkali Oxides on the Cristobalitization of Quartz in Whiteware Body (자기소지에서 Quartz의 Cristobalite화에 미치는 알칼리 금속산화물의 영향)

  • 정창주;김남일;오경영
    • Journal of the Korean Ceramic Society
    • /
    • v.29 no.12
    • /
    • pp.981-989
    • /
    • 1992
  • This is a study on the effects of cristobalite transition of quartz in semi-vitrious whiteware body, as addition of alkali and alkali earth oxides, prepared by pottery stone, feldspar, kaolin and clay minerals. The amounts of ${\alpha}$-quartz to ${\alpha}$-cristobalite transition, F.O.C. (fraction of cristobalite), were increased with firing temperature. In MgO added body, ${\alpha}$-quartz was decreased and the formation of cristobalite was increased. Effects of K2O addition was remarkably decreased the formation of cristobalite. Additive effects of MgO and K2O were confirmed that it was very different to variation of transition temperature of metakaolinite to Si-Al spinel structure in thermal reaction of kaolinite minerals. Result CaO addition was ineffective to transition temperature, and the transition temperature in Na2O added body was decreased, but relative intensity of quartz and cristobalite crystal in XRD results was decreased. This was characterized by the effects on the formation of liquid phase much more.

  • PDF

A Geochemistry Experiments Study of the Yangdan Cave Speleothem in Korea (양단굴 생성물의 이화학적 특성에 관한 연구)

  • Oh, Jong-Woo;Oh, Sung-Hoon;Shiin, Dae-Bong
    • Journal of the Speleological Society of Korea
    • /
    • no.75
    • /
    • pp.21-33
    • /
    • 2006
  • Yangdan Cave displays as a Vadose Cave rathre than a Phreatic Cave due to its fluvial activated ramnants of the cave beds and walls. Geochemistry experiments of the speleothem (stalactite and stalagmite)were generated in order to find out the cave material characteristics using XRD. The results present that the composition of the cave materials consists of Calcite, Dolomite, Quartz, K, K-Feldspar. Plagioclasc, Illite, and Kaolinite. These materials commonly exhibited less mineral composition than other caves. In terms of calcite compostion of the cave the upper cave materials (d=3.049) contain less than lower cave materials (d=3.055). Finally the calcite compostion of the cave materials between stalactite (d=3.055) and stalagmite (d=3.054) displays simillar values.