• Korean Chemical Engineering Research
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• v.60 no.2
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• pp.217-222
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• 2022

It is very important to analyze the OCV change behavior during the open circuit potential holding (OCV holding) process, which accelerates the evaluation of the electrochemical durability of the PEMFC membrane. In this study, an empirical formula using the experimental data of three MEAs with different durability was created and compared. The durability evaluation time of the reinforced membrane MEA without radical scavenger inside the membrane was 383 h, and the durability evaluation time of the reinforced membrane MEA with radical scavenger inside the membrane was 1,000 and 1,650 h, respectively. The degradation of the membrane was divided into the reversible degradation that can be recovered by activation and the irreversible degradation that is not recovered. The irreversible degradation of the membrane was indicated by an increase in hydrogen permeability, and the change in hydrogen permeability was similar to the irreversible degradation constant c of all three MEAs. The initiation of irreversible deterioration without recovery is indicated by an increase in hydrogen permeability, and the OCV is not recovered due to an increase in hydrogen permeability, so the slope of the OCV recovery line (ORL) decreases, which can be confirmed by an increase in the constant c value of the empirical formula.

• Progress in Superconductivity and Cryogenics
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• v.6 no.1
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• pp.6-11
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• 2004

The influences of mixed strain mode of bending-tension on the critical current. Ic in externally reinforced Bi-2223 tapes and their interaction were investigated in this study. A test fixture which providing a mixed deformation mode of bending-tension to HTS tapes has been newly devised. When the total strain induced in the tape in the mixed strain mode was expressed by the superposition of the bending and tensile strains the irreversible strain for the critical current degradation of Bi-2223 tapes increased, as compared with the simple bending mode case. The $I_c$ degradation at the region exceeding the irreversible strain showed a medium between the simple bending case and the simple tension case. As the initial bending strain imparted increased , namely as the diameter of mandrel adopted decreased. the apparent irreversible strain in Bi-2223 tapes increased . but the increment became smaller As a result. it can be found that the tension to be applied to bent Bi-2223 tapes during cabling should be smaller. as the mandrel diameter becomes smaller.

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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• 2003.10a
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• pp.134-138
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• 2003

The influences of mixed mode of bending-tension on the Ic degradation and their interaction on the strain effect were evaluated in this study. A test fixture which applies a mixed deformation mode of bending-tension to HTS tapes has been newly devised. When the strain induced in the tape due to the mixed deformation mode was expressed as a total tensile strain, the irreversible strain to the critical current degradation of Bi-2223 tapes increased when compared with the case of simple bending mode, and the value at both ends were larger than that at the central region of the bend part. The Ic degradation behavior at the region exceeding the irreversible strain showed quiet a rapid drop of the Ic when compared with the simple bending cases. As the applied bending strain increased namely as the diameter of mandrel adopted decreased, the apparent irreversible strain of Bi-2223 tapes increased However, the increment decreased as the mandrel diameter decreased. As a result, it could be found that the tension to be applied to the Bi-2223 tapes during cabling of HTS tapes should be smaller, as the mandrel diameter becomes smaller.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2000.05a
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• pp.101-107
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• 2000

Column tests using KCl and Benzene as tracers were conducted for four different cases: 1) no hydrogen peroxide and no microorganism; 2) hydrogen peroxide only; 3) microorganism only; 4) hydrogen and microorganism to investigate the sorption and degradation characteristics of Benzene. The observed BTCs of KCl and Benzene in all cases showed that the arrival times of the peaks of both tracers coincided well but the peak concentration of Benzene was much lower than that of KCl. This result reveals that a predominant process affecting the transport of Benzene in a sandy soil is an irreversible sorption and/or degradation rather than retardation. Decay of Benzene through sorption and degradation increased with the addition of hydrogen peroxide and/or microorganism. Dissolved oxygen decreased with the increase of Benzene in all cases indicating that Benzene was degraded by dissolved oxygen. For BTCs with the addition of microorganisms (case 3 and case 4), microorganism showed much lower concentrations compared to the initial levels and an increasing tendency with time although concentrations of Benzene returned to zero, indicating a possible retardation of microorganism due to reversible and irreversible sorption to the particle surfaces.

• International Journal of Naval Architecture and Ocean Engineering
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• v.13 no.1
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• pp.674-690
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• 2021

This study proposes a hybrid marine power system combining dual-fuel generators, a fuel cell, and Vanadium Redox Flow Batteries (VRFB). Rigorous verification and validation of the dynamic modelling and integration of the system are conducted. A case study for the application of the hybrid propulsion system to a passenger ship is conducted to examine its time-variant behaviour. A comprehensive model of the reversible and irreversible capacity degradation of the VRFB stack unit is proposed and validated. The capacity retention of the VRFB stack is simulated by being integrated within the hybrid propulsion system. Reversible degradation of the VRFB stack is precisely predicted and rehabilitated based on the predefined operational schedule, while the irreversible portion is retained until the affected components are replaced. Consequently, the advantages of the VRFB system as an on-board ESS are demonstrated through the application of a hybrid propulsion system for liner shipping with fixed routes.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.04a
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• pp.128-131
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• 2001

We evaluated natural attenuation of petroleum hydrocarbons in a shallow aquifer using a modeling study. The studied shallow aquifer was severely contaminated with petroleum hydrocarbons, especially toluene, ethylbenzene and xylenes (i.e, TEX). The exact spill history was not known. Therefor we used a contaminant level in May 1999 (the first sampling date of our integrated study) as an initial contaminant concentration. we calibrated required transport parameters using the contamination levels obtained from groundwater analyses in September of 1999. For fate and transport of the petroleum contaminants, five case 2 with sorption and degradation. case 3 with sorption and degradation (half decay constant compared with case 2), case 4 with degradation but no sorption, and case 5 with sorption but no degradation. For sorption and degradation, a linear sorption isotherm and first order irreversible decay was assumed, respectively and no additional contamination source to groundwater is also assumed.

• Composites Research
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• v.21 no.2
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• pp.8-14
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• 2008

Decrease of strength in composite material is generally caused by water absorption. It makes fracture of material, and loss of money or human lives. The objective of this study is to investigate the causes of decrease in strength by water absorption. Mechanism of water absorption was supposed as three steps. This mechanism is consisted of absorption into resin, absorption between resin and surface treatment agent, and delamination between fiber and resin. Conditions of test were supplied differently; kinds of fiber and resin, immersion time etc. Both of reversible reaction and irreversible reaction occurred simultaneously. Most of decrease in strength was finished at 2.5% water absorption, and the strength was recovered. At 4% water absorption, most of decrease was caused by irreversible reaction, therefore, there was a tendency not to be recovered in strength.

• Journal of Microbiology and Biotechnology
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• v.16 no.4
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• pp.590-596
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• 2006

Clavulanic acid (CA) produced by Streptomyces clavuligerus is degraded during the bacterial cultivation. The degradation was examined in three different aspects, including physical, chemical, and enzymatic effects, in order to understand the degradation during the cultivation. The result showed that CA was unstable in the production medium containing ammonium salts and amino acids, owing to ammonium ions and amine groups. In addition, the degradation was not only due to instability of CA by metabolites and proteins, but also enzymes from S. clavuligerus such as $\beta-lactamase$ and penicillin-binding proteins. However, the degradation caused by these enzymes was not highly significant compared with the degradation during the cultivation, owing to irreversible reactions between CA and enzymes.

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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• v.16 no.3
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• pp.305-314
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• 1987

Thermodynamic analysis of a mixed refrigerant refrigeration cycle has been performed by computing thermodynamic properties of various refrigerants. The analyses are carried cut to identify the sources and distribution of the energy degradation by irreversible processes. Heat exchange process with the surroundings produces the entropy and the irreversible loss can be reduced by the mixed refrigerant whose phase change temperature varies during the phase change processes in the evaporator and the condenser. The concept has been applied to find the minimum compression work and thus the minimum energy loss in the overall system, specifically in the case of the mixed refrigerant of R12 and R114. Parametric studies have been added to recognize the various factors affecting the system performance.

• Computers and Concrete
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• v.33 no.3
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• pp.301-308
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• 2024

This paper proposes a numerically-based methodology to implicitly model irreversible deformations in concrete through a damage model. Plasticity theory is not explicitly employed, although resemblances are still present. A scalar isotropic damage model is adopted and the damage variable is split in two: one contributing for stiffness degradation (cracking) and other contributing for irreversible deformations (plasticity). The proposed methodology is thermodynamically consistent as it consists in a damage model rewritten in different terms. Its Finite Element coding is presented, indicating that minor changes are necessary. It is also demonstrated that nonlinear algorithms are unnecessary to model concrete cracking and plasticity. Experimental data from direct tension and four-point bending tests under cyclic loading are compared to the proposed methodology. A numerical case study of a low-cycle fatigue is also presented. It can be concluded that the model is simple, feasible and capable to capture the essentials concerning cracking and plasticity.