• 제목/요약/키워드: Irradiation Temperature

검색결과 1,204건 처리시간 0.031초

Fabrication of Photo Sensitive Graphene Transistor Using Quantum Dot Coated Nano-Porous Graphene

  • 장야무진;이재현;최순형;임세윤;이종운;배윤경;황종승;황성우;황동목
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.658-658
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    • 2013
  • Graphene is an attractive material for various device applications due to great electrical properties and chemical properties. However, lack of band gap is significant hurdle of graphene for future electrical device applications. In the past few years, several methods have been attempted to open and tune a band gap of graphene. For example, researchers try to fabricate graphene nanoribbon (GNR) using various templates or unzip the carbon nanotubes itself. However, these methods generate small driving currents or transconductances because of the large amount of scattering source at edge of GNRs. At 2009, Bai et al. introduced graphene nanomesh (GNM) structures which can open the band gap of large area graphene at room temperature with high current. However, this method is complex and only small area is possible. For practical applications, it needs more simple and large scale process. Herein, we introduce a photosensitive graphene device fabrication using CdSe QD coated nano-porous graphene (NPG). In our experiment, NPG was fabricated by thin film anodic aluminum oxide (AAO) film as an etching mask. First of all, we transfer the AAO on the graphene. And then, we etch the graphene using O2 reactive ion etching (RIE). Finally, we fabricate graphene device thorough photolithography process. We can control the length of NPG neckwidth from AAO pore widening time and RIE etching time. And we can increase size of NPG as large as 2 $cm^2$. Thin CdSe QD layer was deposited by spin coatingprocess. We carried out NPG structure by using field emission scanning electron microscopy (FE-SEM). And device measurements were done by Keithley 4200 SCS with 532 nm laser beam (5 mW) irradiation.

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초기 톨루엔 농도가 톨루엔 -NOx- 공기 혼합물의 광산화 반응에 미치는 영향 - I. 가스상 물질의 변화 (Effect of Initial Toluene Concentration on the Photooxidation of Toluene -NOx- Air Mixture - I. Change of Gaseous Species)

  • 이영미;배귀남;이승복;김민철;문길주
    • 한국대기환경학회지
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    • 제21권1호
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    • pp.15-26
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    • 2005
  • An experimental investigation of the gas-phase photooxidation of toluene-NO$_{x}$-air mixtures at sub-ppm concentrations has been carried out in a 6.9 m3, indoor smog chamber irradiated by blacklights. Measured parameters in the toluene-NO$_{x}$ experiments included $O_3$, NO, NO$_2$, NO$_{x}$, CO, SO$_2$ toluene, and air temperature. The initial toluene concentration ranged from 225 ppb to 991 ppb and the initial concentration ratio of toluene/NO$_{x}$ in ppbC/ppb was in the range of 5~20. It was found that the variation of gaseous species with irradiation time caused by the photooxidation of toluene-NO$_{x}$-air mixtures depended on the initial toluene concentration for similar concentration ratio of toluene/NO$_{x}$. The dependency of initial toluene concentration on the photooxidation of toluene-NO$_{x}$-air mixtures for toluene/NO$_{x}$=5~6 seemed to be opposite to that for toluene/NO$_{x}$=10~11. The arriving time at maximum ozone concentration depended on both initial toluene concentration and initial concentration ratio of toluene/NO$_{x}$. However, the maximum concentration of ozone formed by photooxidation depended only on the initial toluene concentration.luene concentration.

초기 톨루엔 농도가 톨루엔- NOx-공기 혼합물의 광산화 반응에 미치는 영향 - II. 입자상 물질의 생성 및 성장 (Effect of Initial Toluene Concentration on the Photooxidation of Toluene-NOx-Air Mixture -II. Aerosol Formation and Growth)

  • 이영미;배귀남;이승복;김민철;문길주
    • 한국대기환경학회지
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    • 제21권1호
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    • pp.27-38
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    • 2005
  • An experimental investigation of the gas-phase photooxidation of toluene-NO$_{x}$-air mixtures at sub-ppm concentrations has been carried out in a 6.9 ㎥, indoor smog chamber irradiated by blacklights. Measured parameters in the toluene-NO$_{x}$ experiments included aerosol, $O_3$, NO, NO$_2$, NO$_{x}$ CO, SO$_2$ toluene, and air temperature. The initial toluene concentration ranged from 225 ppb to 991 ppb and the initial concentration ratio of toluene/NO$_{x}$ in ppbC/ppb was in the range of 5~20. It was found that the variation of aerosol number concentration with irradiation time caused by the photooxidation of toluene-NO$_{x}$-air mixtures depended on the initial toluene concentration for similar concentration ratio of toluene/NO$_{x}$. The dependency of initial toluene concentration on the photooxidation of toluene-NO$_{x}$-air mixtures for toluene/NO$_{x}$= 5~6 seemed to be opposite to that for toluene/NO$_{x}$=10~11. The maximum number concentration of aerosols formed by photooxidation and the aerosol yield depended on both initial toluene concentration and initial concentration ratio of toluene/NO$_{x}$. In this study, the aerosol yield, defined as aerosol formed per unit toluene consumed, was found to be 0.01~0.16.und to be 0.01~0.16.

Enhancement of 1,3-Dihydroxyacetone Production from Gluconobacter oxydans by Combined Mutagenesis

  • Lin, Xi;Liu, Sha;Xie, Guangrong;Chen, Jing;Li, Penghua;Chen, Jianhua
    • Journal of Microbiology and Biotechnology
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    • 제26권11호
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    • pp.1908-1917
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    • 2016
  • Wild strain L-6 was subjected to combined mutagenesis, including UV irradiation, atmospheric and room temperature plasma, and ion beam implantation, to increase the yield of 1,3-dihydroxyacetone (DHA). With application of a high-throughput screening method, mutant Gluconobacter oxydans I-2-239 with a DHA productivity of 103.5 g/l in flask-shake fermentation was finally obtained with the starting glycerol concentration of 120 g/l, which was 115.7% higher than the wild strain. The cultivation time also decreased from 54 h to 36 h. Compared with the wild strain, a dramatic increase in enzyme activity was observed for the mutant strain, although the increase in biomass was limited. DNA and amino acid sequence alignment revealed 11 nucleotide substitutions and 10 amino acid substitutions between the sldAB of strains L-6 and I-2-239. Simulation of the 3-D structure and prediction of active site residues and PQQ binding site residues suggested that these mutations were mainly related to PQQ binding, which was speculated to be favorable for the catalyzing capacity of glycerol dehydrogenase. RT-qPCR assay indicated that the transcription levels of sldA and sldB in the mutant strain were respectively 4.8-fold and 5.4-fold higher than that in the wild strain, suggesting another possible reason for the increased DHA productivity of the mutant strain.

$Er^{3+}$를 첨가한 $CaZrO_3$ 축광성 형광체의 합성 및 발광 특성 분석 (Synthesis and luminescent properties of $Er^{3+}$ doped $CaZrO_3$ long persistent phosphors)

  • 박병석;최종건
    • 한국결정성장학회지
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    • 제18권1호
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    • pp.27-32
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    • 2008
  • 새로운 $CaZrO_3:Er^{3+}$ 축광성 형광체를 전통적인 고상반응법으로 제조하였으며, 분쇄한 축광성 형광체를 X 선 회절 분석, 광발광 분석, 열발광 분석과 휘도계를 통하여 장잔광 특성을 분석하였다. X 선 회절 분석 결과 순수한 $CaZrO_3$ 결정상을 확인 하였으며, 고온의 질소 분위기에서 합성한 경우 446 nm 와 550 nm의 넓은 발광 피크가 나타났다. 합성한 장잔광 특성의 형광체의 발광 지속시간은 254 nm UV lamp로 여기 시킨 후 어두운 곳에서 6시간 이상 스스로 발광 하였다. 발광 피크는 $Er^{3+}$ 이온의 $^5D_{5/2}{\rightarrow}^4F_{9/2},\;^2H_{12/2},\;^4S_{3/2}{\rightarrow}^4I_{13/2}$ 그리고 $^2G_{9/2}{\rightarrow}^4I_{13/2}$ 전이에 의한 것이며, 잔광 특성은 $CaZrO_3$ 격자 내에 적당한 trap center가 형성 된 것으로 판단된다.

실내 미생물 입자 살균을 위한 광촉매 기술의 효율 (Effectiveness of Photocatalytic Techniques for Disinfection of Indoor Bioaerosols)

  • 신승호;김모근;조완근
    • 한국환경과학회지
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    • 제16권7호
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    • pp.785-791
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    • 2007
  • The current study evaluated the technical feasibility of the application of titanium dioxide ($TiO_{2}$) photo-catalytic air cleaners for the disinfection of bioaerosols present in indoor air. The evaluation included both laboratory and field tests and the tests of hydraulic diameter (HD) and lamp type (LT). Disinfection efficiency of photocatalytic oxidation (PCO) technique was estimated by survival ratio of bacteria or fungi calculated from the number of viable cells which form colonies on the nutrient agar plates. It was suggested that the reactor coating with $TiO_{2}$ did not enhance the adsorption of bioaerosols, and that the UV irradiation has certain extent of disinfection efficiency. The disinfection efficiency increased as HD decreased, most likely due to the decrease in the light intensity since the distance of the catalyst from the light source increased when increasing the HD. It was further suggested that the mass transfer effects were not as important as the light intensity effects on the PCO disinfection efficiency of bioaerosols. Germicidal lamp was superior to the black lamp for the disinfection of airborne bacteria and fungi, which is supported by the finding that the disinfection efficiencies were higher when the germicidal lamp was used compared to the black lamp in the laboratory test. These findings, combined with operational attributes such as a low pressure drop across the reactor and ambient temperature operation, can make the PCO reactor a possible tool in the effort to improve indoor bioaerosol levels.

GIS를 이용한 지표화 확산예측모델의 개발 (Development of the Surface Forest Fire Behavior Prediction Model Using GIS)

  • 이병두;정주상;이명보
    • 한국산림과학회지
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    • 제94권6호
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    • pp.481-487
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    • 2005
  • 이 연구에서는 지표화 중심의 산불확산예측 알고리즘을 기반으로 GIS 환경에서 운용이 가능한 지표화 확산예측모델을 개발하였다. 이 모델은 지형, 연료, 기상 등 산불환경인자를 분석하고 입력하는 부분과 시간에 따라 확산속도, 화선에서의 산불강도, 연소면적을 예측하는 지표화 확산예측 부분, 마지막으로 예측결과를 사용자에게 제시하는 출력 부분으로 구성되었다. 산불확산속도를 계산하기 위해서 산불행동에 영향을 미치는 산불환경인자중에서 지형인자는 경사, 기상인자는 풍속, 풍향, 실효습도를 고려하였다. 또한 연료인자는 수치임상도를 이용하여 연료깊이, 연료량, 소화습도를 계산할 수 있는 연료모듈을 개발하여 입력되도록 하였다. 연료습도는 실효습도, 최고온도, 강수량, 일일 적산량의 함수관계로 추정하였다. 모델을 2002년 청양에서 발생한 산불에 적용한 결과 확산속도에 대해 61%의 일치도를 보였다.

Cryosurgery를 이용(利用)한 Keloid의 치료(治療) (Cryosurgery in the Treatment of Keloids)

  • 정영식;최시호;설정현;이태숙
    • Journal of Yeungnam Medical Science
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    • 제2권1호
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    • pp.23-30
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    • 1985
  • Keloids are abnormally healed skin wounds that develop in the subpapillary layer of the dermis. They are a lesion with wide, raised and deep scars. They exceed the original dimensions of the wound and grow mounds upon mounds of collagen in a pseudotumor fashion. Their treatment may take several forms such as surgery, intralesional injection of steroid, compression, superficial irradiation, and combination therapy. However, absolute method is nothing until now. Recently, the cryosurgery shows relatively good effect in treatment, so we tried the clinical experience with cryosurgery in the treatment of keloids. Material and methods: During the past 2 years, we treated 20 individuals of the keloids with severe itching and pain. The age ranged from 5 to 45 years old. Only 6 cases were biopsied before and after cryotherapy. The cryosurgery set we used was Toitu model CR 201 $N_2O$ gas (tip temperature is $-80^{\circ}C$) and was applied directly on the lesion about 4 to 5 minutes with slight compression. After cryosurgery in keloids, the following results were obtained: 1. It is both quick and easy method. 2. It causes little or no pain and no loss of blood. 3. Integumentary normalization is rapid. The new scar tissue is smaller, and more elastic and soft. 4. The pain, itching and paresthesia commonly associated with keloid is usually disappeared. 5. Other treatment can be used after cryosurgery. 6. Histologic picture after cryosurgery is similar with the result of steroid injection. 7. The mechanism of the cryosurgery in keloids is the result of the direct tissue destroying action and cryoimmunologic reaction.

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$PEO-EDA-LiClO_4$ 블렌드계 탄성체 전해질의 제조와 특성 (Preparation and Characterization of Elastomeric Solid Electrolyte Based on $PEO-EDA-LiClO_4$ Blends)

  • 장영욱;주현석
    • Elastomers and Composites
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    • 제39권1호
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    • pp.36-41
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    • 2004
  • Poly(ethylene oxide)(PEO)와 epoxy diacrylate(EDA) 및 금속염인 LiClO_4$를 블렌드하고 자외선 가교시킴으로써 이온전도특성을 나타내는 고체 전해질을 제조하고, 제조된 전해질의 이온 전도도를 블렌드조성 염농도 및 온도 변화에 따가 측정하였다. PEO/EDA의 조성비가 70/30 wt%이고 ethylene $oxide/Li^+$의 몰비가 10인 전해질이 $25^{\circ}C$에서 $1.2{\times}10^{-5} S/cm$에 달하는 높은 이온전도도를 나타내었다. 제조된 전해질 필름은 투명하였으며 고무와 같은 탄성을 나타내었다. DSC, XRD 및 편광현미경을 이용한 모폴로지 분석으로부터 에폭시 사슬이 PEO의 결정화를 억제함으로써 완전히 무정형인 블렌드를 제조할 수 있음을 확인할 수 있었다.

10 kW급 접시형 태양열발전시스템 사업모델 개발 및 운전특성 분석 (Development of 10 kW Dish-Stirling System for Commercialization and Analysis of Operating Characteristics)

  • 김종규;이상남;강용혁
    • 한국태양에너지학회 논문집
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    • 제30권6호
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    • pp.118-124
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    • 2010
  • In order to develop commercial model of 10kW dish-Stirling solar thermal power system, modification for the exiting facility was taken for a year as a Leading Project in KIER. During the project, solar tracking system, control and monitoring system and high durability reflector were developed and long term operation were performed. The solar tracking system was tested for four months to investigate the degree of precision and adapted to the control system for an actual operation from October in 2009. The sun tracking accuracy of ${\pm}4$ mrad using modified control system was obtained and the system operated successfully during the experimental period. The monitoring system displays engine pressure, electric generation amounts, generator RPM, receiver temperatures, and etc. from Stirling engine and weather data of Direct Normal Irradiation, Horizontal Global Insolation, wind speed & direction, and atmosphere temperature from weather station. According to the operating results in a clear sky day, electric power of 6,890 W was generated at the DNI value of 850 W/$m^2$ and the averaged solar-to-electricity efficiency during a whole day reached to 18.99%. From the overall operating results, linear power generation trend could be observed with increasing DNI value. The solar-to-electricity efficiency achieved to 19% around the DNI value of 700 W/$m^2$ and increased to 20% when the DNI value goes up to 900 W/$m^2$.