• Title/Summary/Keyword: Iron-oxide

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An Oxidation Behavior with Heat-treatment in STS 304 and 316 (STS 304, 316강의 열처리에 따른 산화거동)

  • Lee, Kyung-Ku;Yoon, Dong-Ju;Ghi, Whe-Bong;Kang, Chang-Sug;Lee, Doh-Jae
    • Journal of the Korean Society for Heat Treatment
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    • v.11 no.3
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    • pp.186-191
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    • 1998
  • An oxidation behavior of 304 and 316 stainless steels were studied in dry air. After solution treatment, specimens were polished up to $1{\mu}m$ $A1_2O_3$ grade and then subjected to oxidation treatment in dry air at $800^{\circ}C{\sim}1200^{\circ}C$. The oxidation behavior between matrix and oxide scale was analyzed with SEM, EDS and XRD. When oxidation treatment was conducted at $1200^{\circ}C$, large thickness of Fe oxide scale was formed on top of surface and fine $(Cr,Fe)_2O_3$ oxide film was formed below it. Cr rich zone existed at interface between metal and $(Cr,Fe)_2O_3$ oxide layer, and it was believed that this zone acted as obstacle to oxidation. Most of Ni was detected at the interface between metal and $(Cr,Fe)_2O_3$ and also detected at the interface between $Fe_2O_3$ and $(Cr,Fe)_2O_3$.

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Cyanide Degradation from Plating Wastewater Using Iron Oxide Nanocomposite Layer (산화철 나노구조박막 이용한 도금폐수내의 시안제거)

  • Jang, Jun-Won;Kim, Hye-Ran;Lim, Hyeong-Seok;Park, Jae-Woo
    • Journal of Korean Society on Water Environment
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    • v.30 no.3
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    • pp.292-297
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    • 2014
  • We synthesized the self-organized nanoporous oxide with potentiostatic anodization of iron foil. The iron oxide nanocomposite (INCs) were fabricated in 1M $Na_2SO_4$ containing 0.5wt% NaF electrolyte holding the potential at 20, 40 and 60 V for 20min, respectively. Field Emmision Scanning Electron Microscopy (FESEM) and X-ray Diffractometer (XRD) were used to evaluate the micromorphology and crystalline structure of INC film. Also, this study was performed to evaluate the fenton reaction using INC film with hydroperoxide for degradation of cyanide dissolved in water. In case of INC-40V in the presence of $H_2O_2$ 3%, the first-order rate constant was found to be $1.7{\times}10^{-2}min^{-1}$, and indicated to be $1.2{\times}10^{-2}min^{-1}$ on commercial hematite powder. This result is shown to be good performance enough to replace the powder type for treatment of wastewater.

A Study on the Magnetic Separation of Magnetite from Spent Iron-oxide Catalyst (폐 산화철촉매로부터 마그네타이트의 자력선별에 관한 연구)

  • 현종영;이효숙;이우철;채영배
    • Resources Recycling
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    • v.11 no.3
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    • pp.31-36
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    • 2002
  • Magnetic separation was carried out in order to improve the magnetite grade of the spent iron oxide catalyst, that was composed with magnetite, ceria and soluble alkaline salt. The recovery of magnetite from the spent iron oxide catalyst was over 99%, and the magnetite contents was upgraded to about 80% from 70% via wet type magnetic separation at 500 Gauss. This improvement was due to the removal of alkaline salt by water instead of the magnetic separation.

Fabrication of Iron Oxide Nanotubes by Anodization for Phosphorus Adsorption in Water (양극산화 공정을 이용한 Iron Oxide Nanotubes의 제조 및 수중 인 흡착)

  • Lee, Won-Hee;Lim, Han-Su;Kim, Jong-Oh
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.6
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    • pp.691-698
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    • 2016
  • This study was carried out to investigate the characterization of iron oxide nanotubes (INTs) by anodization method and applied adsorption isotherms and kinetic models for phosphate adsorption. SEM analysis was conducted to examine the INTs surface formation. Further XRD and XPS analysis were performed to observe the crystal structure of INTs before and after phosphate adsorption. AFM analysis was conducted to determine of Fe foil surface before and after anodization. Phosphate stock solution for adsorption experiment was prepared by $KH_2PO_4$. The batch experiment was conducted using 20 ml phosphate stock solution and $40cm^3$ of INTs in 50 ml conical tube. Adsorption isotherms were applied Langmuir and Freundlich models for adsorption equilibrium test of INTs. Pseudo first order and pseudo second order models were applied for interpretation of adsorption rate by reaction time. The determination coefficient ($R^2$) values of Langmuir and Freundlich models were 0.9157 and 0.8876 respectively.

Critical Enhancement of Photothermal Effect by Integrated Nanocomposites of Gold Nanorods and Iron Oxide on Graphene Oxide

  • Yun, Kum-Hee;Seo, Sun-Hwa;Kim, Bo-Mi;Joe, Ara;Han, Hyo-Won;Kim, Jong-Young;Jang, Eue-Soon
    • Bulletin of the Korean Chemical Society
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    • v.34 no.9
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    • pp.2795-2799
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    • 2013
  • Irradiation of gold nanorods (GNRs) with laser light corresponding to the longitudinal surface plasmon oscillation results in rapid conversion of electromagnetic energy into heat, a phenomenon commonly known as the photothermal effect of GNRs. Herein, we propose a facile strategy for increasing the photothermal conversion efficiency of GNRs by integration to form graphene oxide (GO) nanocomposites. Moreover, conjugation of iron oxide (IO) with the GO-GNR nanohybrid allowed magnetic enrichment at a specific target site and the separated GO-IO-GNR assembly was rapidly heated by laser irradiation. The present GO-IO-GNR nanocomposites hold great promise for application in various biomedical fields, including surface enhanced Raman spectroscopy imaging, photoacoustic tomography imaging, magnetic resonance imaging, and photothermal cancer therapy.

Fabrication and hydrogen storage property of eutectic Mg-Ni based alloy powder (공정 Mg-Ni계 합금 분말의 제조 및 수소저장 특성)

  • Hong, Seong-Hyeon;Bae, Jong-Soo;Yim, Chang-Dong;Na, Young-Sang;Song, Myoung-Youp
    • Journal of Hydrogen and New Energy
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    • v.17 no.2
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    • pp.174-180
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    • 2006
  • The eutectic Mg-23.5%Ni alloy was casted by melting and solidification. The powders of Mg-23.5%Ni and (Mg-23.5%Ni)-10% iron oxide were prepared by mechanical grinding of casted Mg-Ni alloy and casted Mg-Ni alloy+oxide, respectively. As milling time increases, hydriding and dehydriding rates of Mg-Ni and Mg-Ni-oxide alloy powders increase. The additions of iron oxide to Mg-Ni alloy and Mg-Ni-oxide increase hydriding rates and slightly decrease dehydriding rates.

The Factors Influencing Latent Fingermark Development on Adhesive Side of Iron Oxide Powder-based Small Particle Reagent (사삼산화철 기반의 소립자시약(Small Particle Reagent)의 접착면 잠재지문 현출 효과에 영향을 미치는 요인)

  • Kim, Sun-Min;Go, Gang-Seok;Lee, Seul-Bi;Yu, Je-Seol
    • The Journal of the Korea Contents Association
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    • v.16 no.8
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    • pp.209-216
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    • 2016
  • Latent fingerprint left on the adhesive sides of tapes can be easily found at a crime scene. Small Particle Reagents(SPR) based on iron oxide($Fe_3O_4$) is a technique for the detection of a latent fingerprint adhesive surface. In this study, found out that the causes affecting the quality of the fingerprints developed when used SPR based on iron oxide. To a suspension of 0.5g of iron oxide in 100ml of distilled water, 0.5ml or more surfactant were added can be developed latent fingerprints of good quality. In addition, using surfactants HLB(hydrophile-lipophile balance) value of 11~18 showed good contrast to the background and latent fingerprint.

Magnetic fields-assisted movement of iron oxide-nanoparticles-incorporated large scale alginate capsules

  • Lee, Dohyeon;Park, Sunho;Kim, Daun;Nam, Hyeun;Kim, Jangho
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2017.04a
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    • pp.27-27
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    • 2017
  • Biocompatible capsules have recently been highlighted as novel delivery platforms of any "materials" (e.g., drug, food, agriculture pesticide) to address current problems of living systems such as humans, animals, and plats in academia and industry for agriculture, biological, biomedical, environmental, food applications. For example, biocompatible alginate capsules were proposed as a delivery platform of biocontrol agents (e.g., bacterial antagonists) for an alternative to antibiotics, which will be a potential strategy in future agriculture. Here, we proposed a new platform based on biocompatible alginate capsules that can control the movements as an active target delivery strategy for various applications including agriculture and biological engineering. We designed and fabricated large scale biocompatible capsules using alginates and custom-made nozzles as well as gelling solutions. To develop the active target delivery platforms, we incorporated the iron oxide nanoparticles in the large scale alginate capsules. It was found that the sizes of large scale alginate capsules could be controlled via various working conditions such as concentrations of alginate solutions and iron oxide nanoparticles. As a proof of concept work, we showed that the iron oxide particles-incorporated large scale alginate capsules could be moved actively by the magnetic fields, which would be a strategy as active target delivery platforms for agriculture and biological engineering (e.g., controlled delivery of agriculture pesticides and biocontrol agents).

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Iron Oxide Nanoparticle-incorporated Alginate Capsules as Magnetic Field-assisted Potential Delivery Platforms for Agriculture Pesticides and Biocontrol Agents

  • Lee, Dohyeon;Choi, Kyoung Soon;Kim, Daun;Park, Sunho;Kim, Woochan;Jang, Kyoung-Je;Lim, Ki-Taek;Chung, Jong Hoon;Seonwoo, Hoon;Kim, Jangho
    • Journal of Biosystems Engineering
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    • v.42 no.4
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    • pp.323-329
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    • 2017
  • Purpose: Biocompatible capsules have recently been highlighted as a novel platform for delivering various components, such as drug, food, and agriculture pesticides, to overcome the current limitations of living systems, such as those in agriculture, biology, the environment, and foods. However, few active targeting systems using biocompatible capsules and physical forces simultaneously have been developed in the agricultural engineering field. Methods: Here, we developed an active targeting delivery platform that uses biocompatible alginate capsules and controls movements by magnetic forces for agricultural and biological engineering applications. We designed and fabricated large-scale biocompatible capsules, using custom-made nozzles ejecting alginate solutions for encapsulation. Results: To develop the active target delivery platforms, we incorporated iron oxide nanoparticles in the large-scale alginate capsules. The sizes of alginate capsules were controlled by regulating the working conditions, such as concentrations of alginate solutions and iron oxide nanoparticles. Conclusions: We confirmed that the iron oxide particle-incorporated large-scale alginate capsules moved actively in response to magnetic fields, which will be a good strategy for active targeted delivery platforms for agriculture and biological engineering applications, such as for the controlled delivery of agriculture pesticides and biocontrol agents.