• 한국환경농학회:학술대회논문집
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• 2011.07a
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• pp.128-135
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• 2011

Consortia demonstrated the high capacities of anaerobic degradation of various aromatic compounds, which were successfully enriched from gley paddy soils under different conditions. Phenol and cresol was decomposed anaerobically using nitrate, ferric oxide or sulfate as electron acceptors. Biphenyl was degraded to $CO_2$, especially without addition of external electron acceptor. Alkylphenols with middle length of alkyl chain, were co-metaboliocally degraded with the presence of hydroxylbenzoate as the co-substrate under nitrate reducing conditions. The microorganisms responsible for the anaerobic co-metabolism was Thauera sp. Reductive dechlorination activity was also observed for polychlorophenols, fthalide, polychlorinated biphenyls, polychlorinated dibenzo-p-dioxins with the presence of lactate, formate or $H_2$ as electron donor. The fthalide dechlorinator was classified as Dehalobacter sp. Coupling of two physiologically-distinct anaerobic consortia, aromatic ring degrader and reductive dechlorinator, resulted in the mineralization of pentachlorophenol under anaerobic conditions. These results suggested that gley paddy soils harbored anaerobic microbial community with versatile capacity degrading aromatic compounds under anaerobic conditions.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.37-38
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• 2007

It needs several large reservoirs and long time to remove suspended solid like steel fines and iron oxide in hot rolling coolant. If removing rate of suspended solid in rolling coolant is improved by using high gradient magnetic separation (HGMS) system, the productivity of working process can be increased and the area of reservoir can be reduced. Pre-treatment process that react magnetic floc with inorganic and organic flocculant in coolant was studied. Horizontal type superconducting HGMS system was manufactured successfully, which was constituted with automatic filter transportation apparatus, 6 T He-free superconducting magnet system and water circulation system. The solid suspension removal ratio in hot rolling coolant was increased by flocculation with inorganic and organic flocculant.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.07a
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• pp.328-331
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• 2004

Hot filament 플라즈마 화학기상 증착법(HFPECVD)를 사용하여 질산화철의 농도에 따른 탄소나노튜브의 성장 특성을 관찰하기 위해 실험을 진행하였다. 암모니아($NH_3$)를 희석가스로 사용하였고, 아세틸렌($C_2H_2$)를 탄소 원료가스로 각각 사용하였다. 암모니아 가스 플라즈마를 사용하여 전처리 된 질산화철 촉매층의 SEM(Scanning Electron Microscopy) 이미지를 관찰하여 본 결과, 나노 사이즈의 촉매 그레인(grain)을 발견할 수 있었다. 그리고 탄소 나노튜브의 직경과 성장 밀도 또한 전처리 된 촉매 층에 따라 다른 양상을 보였다. TEM(Transmission Electron Microscopy)를 사용하여 탄소나노튜브를 관찰한 결과 bamboo 구조를 한 다중벽 탄소 나노튜브(MWCNT)를 관찰할 수 있었다.

• Korean Journal of Metals and Materials
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• v.50 no.2
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• pp.171-175
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• 2012

By measuring the absorbed hydrogen quantity as a function of the number of cycles, the cycling properties of the Mg-15 wt%Ni-5 wt%$Fe_2O_3$ alloy were investigated. The absorbed hydrogen quantity decreased as the number of cycles increased. The $H_a$ value varied almost linearly with the number of cycles. The maintainability of absorbed hydrogen quantity at n=100 was 89.0% for the hydriding reaction time of 10 min. After the $150^{th}$ hydriding-dehydriding cycle, Mg, $Mg_2Ni$, $Mg(OH)_2$, MgO, and Fe were observed. The phases were analyzed by Rietveld analysis from the XRD patterns of the Mg-15 wt%Ni-5 wt%$Fe_2O_3$ alloy after 150 hydriding-dehydriding cycles. The crystallite size and strain of Mg were then estimated with the Williamson-Hall technique.

• Korean Journal of Metals and Materials
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• v.50 no.5
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• pp.383-387
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• 2012

The activation of Mg-10 wt%$Fe_2O_3$ was completed after one hydriding-dehydriding cycle. Activated Mg-10 wt%$Fe_2O_3$ absorbed 5.54 wt% H for 60 min at 593 K under 12 bar $H_2$, and desorbed 1.04 wt% H for 60 min at 593 K under 1.0 bar $H_2$. The effect of the reactive grinding on the hydriding and dehydriding rates of Mg was weak. The reactive grinding of Mg with $Fe_2O_3$ is believed to increase the $H_2$-sorption rates by facilitating nucleation (by creating defects on the surface of the Mg particles and by the additive), by making cracks on the surface of Mg particles and reducing the particle size of Mg and thus by shortening the diffusion distances of hydrogen atoms. The added $Fe_2O_3$ and the $Fe_2O_3$ pulverized during mechanical grinding are considered to help the particles of magnesium become finer. Hydriding-dehydriding cycling is also considered to increase the $H_2$-sorption rates of Mg by creating defects and cracks and by reducing the particle size of Mg.

• Korean Journal of Metals and Materials
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• v.50 no.6
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• pp.463-468
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• 2012

A 71.5 wt%Mg-23.5 wt%Ni-5 wt%$Fe_2O_3$ (Mg-23.5Ni-$5Fe_2O_3$) sample was prepared by a quite simple process, reactive mechanical grinding, and its hydriding and dehydriding properties were then investigated. The reactive mechanical grinding of Mg with Ni and $Fe_2O_3$ is considered to facilitate nucleation and shorten the diffusion distances of the hydrogen atoms. After the hydriding-dehydriding cycling, the Mg-23.5Ni-$5Fe_2O_3$ sample contained $Mg_2Ni$ phase. Expansion and contraction of the hydride-forming materials (Mg and $Mg_2Ni$) with the hydriding and dehydriding reactions are also considered to increase the hydriding and dehydriding rates of the mixture by forming defects and cracks leading to the fragmentation of the particles. The temperature dependence of the hydriding rate of the sample is discussed.

• Korean Journal of Remote Sensing
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• v.15 no.4
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• pp.307-319
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• 1999

The aim of this study is to assess the OSMI (Ocean Scanning Multi-spectral Imager), whose central bands are 443nm, 490nm, 510nm, 555nm, 670nm, and 865nm, for agricultural applications. Radiance measurements, used to determine per cent reflectance of canopies and soils, were acquired with spectro-radiometers (Li-1800;330∼1,100nm, GER-SFOV;350∼2,500nm, and MSR-7000; 300∼2,500nm) in situ for crops and indoors for soils. OSMI equivalent bands and their ratio values were prepared(20nm interval for bands 1∼5; 40nm interval for band 6) by averaging spectral reflectance values to the real OSMI bands and analyzed as to crop growth parameters, leaf area index (LAI), total dry matter, and growth index in crops and physiochemical properties in soils. Spectral variations for each growth stage in rice and for crop discrimination in upland crops were significant statistically. In soils, clay and water content, CEC (Cation Exchange Capacity), free iron oxide, and some cation content were correlated with the OSMI equivalent bands. The result of this study shows OSMI wave bands would be promising for agricultural application in terms of spectral information and resolution.

• Korean Journal of Metals and Materials
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• v.49 no.1
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• pp.46-51
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• 2011

Real-time formation of $L1_0$ phase of FePt nanoparticles in the gas phase during ultrasonic-spray pyrolysis is first discussed in the present study. Without any post heat treatment, $L1_0$ phase of FePt nanoparticles appeared at the temperature above $900^{\circ}C$ in the gas phase synthesis. X-ray diffractometry (XRD) and transmission electron microscopy (TEM) studies revealed that FePt nanoparticles less than 10 nm in size contained small volume of $L1_0$ fct phase. However, in other samples obtained at the temperature below $900^{\circ}C$, iron oxide phase co-existed and no evidence of phase transformation was found. Thus, it is anticipated that the time of flight of particles required for crystallization and phase transformation was extended according to the increase of the collision rate. Finally, magnetic properties represented by coercivity and saturation magnetization and functional groups on the particle surface were discussed based on VSM and FT-IR results.

• Journal of Soil and Groundwater Environment
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• v.26 no.3
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• pp.14-24
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• 2021

Aquifer thermal energy storage (ATES) system uses groundwater thermal energy for cooling and heating of buildings, and it is also often utilized to provide warm water to crops and plants for the purpose of enhancing agricultural yields. This study investigated the potential influences of a ATES system on the geochemical properties of groundwater by simulating the variation of hydrochemistry and saturation index of groundwater during ATES operation. The test bed was installed at an agricultural field, which is mainly composed of an groundwater-rich alluvial plain. The simulation results showed no significant precipitation of mineral phases such as manganese-iron oxide, carbonate and sulfate around the ATES test bed, as well as no debasement of other important water quality parameters. The implementation of ATES system in the study area was appropriate and effective for utilizing the thermal energy of groundwater for agricultural use.

• Nuclear Engineering and Technology
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• v.54 no.4
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• pp.1343-1354
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• 2022

Experiments were performed to measure the critical heat flux (CHF) on a vertical surface abutting a coarse packed bed of spherical particles. This geometry is representative of a CANDU reactor calandria tubesheet facing the end shield cavity during the in-vessel retention (IVR) phase of a severe accident. Deionized light water was used as the working fluid. Low carbon steel shielding balls with diameters ranging from 6.4 to 12.7 mm were used, allowing for the development of an empirical correlation of CHF as a function of shielding ball diameter. Previously published data is used to develop a more comprehensive empirical correlation accounting for the impacts of both shielding ball diameter and heating surface height. Tests using borosilicate shielding balls demonstrated that the dependence of CHF on shielding ball thermal conductivity is insignificant. The deposition of iron oxide particles transported from shielding balls to the heating surface is verified to increase CHF non-trivially. The results presented in this paper improve the state of the knowledge base permitting quantitative prediction of CHF in the CANDU end shield, refining our ability to assess the feasibility of IVR. The findings clarify the mechanisms governing CHF in this scenario, permitting identification of potential future research directions.