• 한국물환경학회지
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• 제20권5호
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• pp.512-519
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• 2004

Hybrid barriers using reduction and immobilization were tested to remediate the groundwater contaminated with multi-pollutants in this study. Iron filings and HDTMA(hexadecyltrimethylammonium)-bentonite were simulated in columns to assess the performance of hybrid barriers for remediation of trichloroethylene(TCE)-contaminated water. TCE reduction rate for the mixture of iron filings and HDTMA-bentonite was about 7 times higher than that for iron filings, only suggesting the reduction of TCE was accelerated when HDTMA-bentonite was mixed with iron filings. TCE reduction rate for the two layers of iron and HDTMA-bentonite was nearly similar to that for iron filings alone, but the partition coefficient($K_d$) for the two layers was 4.5 times higher than for that iron filings only. TCE was immobilized in the first layer with HDTMA-bentonite, and then dechlorinated in the second layer with iron filings. HDTMA-bentonite may contribute to the increase in TCE concentration on iron surface so that more TCE can be reduced. Also, TCE removal in the hybrid barriers was not affected by chromate and naphthalene while the reduction rate of TCE with the co-existing contaminants by iron filings was significantly decreased. Significant TCE removal in this research indicates that the proposed hybrid barrier system has the potential to become the effective remediation alternative during the occurrence of oil shock. Also, if subsurface environments are contaminated with multi-pollutants that contain non-reducible compounds as well as reducible compounds such as TCE, the conventional reactive barriers cannot be applied to this subsurface environment, while the proposed hybrid system can be applied successfully.

• Journal of Magnetics
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• 제15권4호
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• pp.179-184
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• 2010

We have investigated the effects of post annealing on iron oxide nanoparticles synthesized by the novel hydrothermal synthesis method with the $FeSO_4{\cdot}7H_2O$. To investigate the post annealing effect, the as-synthesized iron oxide nanoparticles were annealed at different temperatures in a vacuum chamber. The morphological, structural and magnetic properties of the iron oxide nanoparticles were investigated with high resolution X-ray powder diffraction (XRD), high resolution transmission electron microscopy (HRTEM), Mossbauer spectroscopy, and vibrating sample magnetometer analysis. According to the XRD and HRTEM analysis results, as-synthesized iron oxide nanoparticles were only magnetite ($Fe_3O_4$) phase with face-centered cubic structure but post annealed iron oxide nanoparticles at $700^{\circ}C$ were mainly magnetite phase with trivial maghemite ($\gamma-Fe_2O_3$) phase which was induced in the post annealing treatment. The crystallinity of the iron oxide nanoparticles is enhanced by the post annealing treatment. The particle size of the as-synthesized iron oxide nanoparticles was about 5 nm and the particle shape was almost spherical. But the particle size of the post annealed iron oxide nanoparticles at $700^{\circ}C$ was around 25 nm and the particle shape was spherical and irregular. The as-synthesized iron oxide nanoparticles showed superparamagnetic behavior, but post annealed iron oxide nanoparticles at $700^{\circ}C$ did not show superparamagnetic behavior due to the increase of particle size by post annealing treatment. The saturation of magnetization of the as-synthesized nanoparticles, post annealed nanoparticles at $500^{\circ}C$, and post annealed nanoparticles at $700^{\circ}C$ was found to be 3.7 emu/g, 6.1 emu/g, and 7.5 emu/g, respectively. The much smaller saturation magnetization value than one of bulk magnetite can be attributed to spin disorder and/or spin canting, spin pinning at the nanoparticle surface.

• 한국주조공학회지
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• 제31권2호
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• pp.66-70
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• 2011

Hot dip aluminizing (HDA) is widely used in industry for improving corrosion resistance of material. The formation of intermetallic compound layers during the contact between dissimilar materials at high temperature is common phenomenon. Generally, intermetallic compound layers of $Fe_2Al_5$ and $FeAl_3$ are formed at the Al alloy and Fe substrate interface. In case of cast iron, high contact angle of graphite existed in the matrix inhibits the formation of intermetallic compound layer, which carry with it the disadvantage of a reduced reaction area and mechanical properties. In present work, the process for the removal of graphite existed on the surface of specimen has been investigated. And also HDA was proceeded at $800^{\circ}C$ for 3 minutes in aluminum alloy melt. The efficiency of graphite removal was increased with the reduction of particle size in sanding process. Graphite appears to be present both in the region of melting followed by re-solidification and in the intermetallic compound layer, which could be attributed to the fact that the surface of cast iron is melted down by the formation of low melting point phase with the diffusion of Al and Si to the cast iron. Intermetallic compound layer consisted of $Fe(Al,Si)_3$ and $Fe_2Al_5Si$, the layer formed at cast iron side contained lower amount of Si.

• Korean Chemical Engineering Research
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• 제46권6호
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• pp.1029-1038
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• 2008

전이금속 산화물의 전구체가 들어있는 합성모액을 수열 반응시켜 전이금속 산화물이 고정된 하이드로탈사이트를 제조하여 이들에 대한 이산화질소의 흡착 성질을 조사하였다. 전이금속 산화물의 분산도, 이산화질소의 흡착량 및 흡착상태를 XRD, SEM, XPS, 질소 흡착등온선, 중량식 흡착법, FT-IR, 승온탈착법으로 조사하였다. 전이금속 산화물은 주로 하이드로탈사이트의 표면에 분산 담지되었으며, 철과 니켈 산화물이 고정된 하이드로탈사이트에 이산화질소가 많이 흡장되었다. 철 산화물이 표면에 분산되어 담지되면 이산화질소의 흡장량이 많지만, 철 산화물이 지나치게 많이 담지되면 덩어리져서 표면의 염기점을 차폐하므로 이산화질소의 흡장량이 오히려 줄어들었다. 철 산화물의 고정량이 적절하면 하이드로탈사이트에서 이산화질소의 흡장세기는 약해지지만, 흡장량은 많아지고 수열 안정성이 증진되었다.

• 한국자동차공학회논문집
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• 제7권5호
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• pp.221-229
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• 1999

We examined the governing factors of fatigue limit in annealed and austempered ductile iron specimens machined micro hole(dia.<0.4mm) in rotary bending fatigue test. Also, the quantitative relationship between fatigue limit and maximum defect size in specimens was investigated. Artificial defect(micro-pit type, dia.<0.4mm) on specimen surface did not bring about an obvious reduction of fatigue limit in austempered ductile iton(ADI) as compared with annealed ductile iron. According to the investigation of ${\sqrt{area}}_c$ which is the critical defect size to crack initiation at artificial defect, ${\sqrt{area}}_c$ of ADI was larger than that of annealed ductile iron. This shows that the situation of crack initiation at artificial defect in ADI is more difficult in comparison with annealed ductile iron. Maximum defect size is one of the important parameters to predict fatigue limit. And, the quantitative relationship, between the fatigue limit ${\sigma}_{\omega}$ and the maximum defect size ${\sqrt{area}}_{max}$ can be expressed to ${\sigma}_{\omega}^n{\cdot}{\sqrt{area}}_{max}=C_2$ where, $C_2$ are constant. Moreover, it is possible to explain the difference in fatigue limit between, austempered and annealed ductile iron by introducing the parameter ${\delta}(=N_{sg}/N_{total})$in a plain spectimen.

• 대한안전경영과학회지
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• 제11권1호
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• pp.43-49
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• 2009

This study set three kinds of situation and observed the various states such as carbonization by experimenting damages by fire of electric iron. The results of this study are as follows: The fire did not occurred when the unpowered iron over mattress and cotton shirts was com busted completely by external flame because the temperature of surface of soleplate and mattress did not reach the minimum ignition energy and when the powered electric iron over mattress and cotton shirts was left for an hour with its temperature dial set to high because the temperature of combustibles did not reach the minimum ignition energy. The fire occurred when the electric iron in which the outer box, bi-metal switch, and temperature fuse were removed over mattress and cotton shirts was powered by through heater terminal, and then the electric iron, mattress, and cotton shirts were combusted by the fallen combustibles because the temperature of combustibles reached to the minimum ignition energy with the help of active transfer of heat.

• 보존과학회지
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• 제38권1호
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• pp.33-44
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• 2022

The study, iron-making process was examined through the scientific analysis of six by-products that were obtained during iron making at the Songdu-ri site in Jincheon. The total Fe content of the slags excavated from the Songdu-ri site was 36.29-54.61 wt%, whereas the deoxidation agent was 26.48-49.08 wt%. The compound analysis result indicated that fayalite and wüstite are the main compounds in slag. Furthermore, the microstructure analysis result confirmed the presence of fayalite and wüstite in the slag. It can be inferred from the flat shape in a bright matrix structure of the hammer scales that forging was performed in the latter stage. The Raman micro-spectroscopy results confirmed that the surface was hematite (Fe₂O₄), middle layer was magnetite (Fe₃O₄), and inner layer was wüstite (FeO). The presence of smelting and smithing slags, spheroid hammer scales, and flake hammer scales suggests that at the Songdu-ri site, iron-making process is carried out by division of labor into producing iron bloom through direct smelting, refining and forge welding, and ingot production.

• Journal of Advanced Marine Engineering and Technology
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• 제36권1호
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• pp.78-84
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• 2012

금형의 공정 과정에서 금형과 성형품 사이에서 발생하는 마찰로 인해 발생하는 금형의 마모가공차로 작용하여 성형 품질을 저하시킬 수 있다. 따라서 금형의 내마모성을 향상시키기 위해 질화나 침탄처리, 화염 및 고주파 표면처리 등의 방법들이 적용되어 왔다. 하지만 형상의 제한이나 제품의 변형 등과 같은 문제점을 수반하고 있기 때문에, 이러한 문제점을 해결할 수 있는 표면처리 방법으로써 레이저 표면처리 기술이 검토되고 있다. 따라서 본 연구에서는 고출력 다이오드 레이저를 이용, 금형재료용 주철의 표면처리를 시도하였다. 앞서 제1보와 제2보의 논문에서는 금형의 재료 및 형상의 차이에 따른 열처리 특성을 비교하였다면, 본 논문에서는 열처리 후 생성되는 경화부, 경계부위 및 모재의 조직적 차이를 분석하기 위해 광학 현미경 및 전자 현미경을 이용하여 미세조직을 관찰하고, EDS를 통해 조직의 상태를 파악하였다. 미세조직 관찰 결과, 경화부는 침상의 마르텐사이트 조직이 형성되어 있었다.

• 한국의사학회지
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• 제26권2호
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• pp.135-148
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• 2013

This study analyzed surface-chemical transitions in manufacturing process of traditional acupuncture as proposed method by Dongeuibogam. The manufacturing process of traditional acupuncture from a used iron for a long time was divided by primary medicinal herbs treatment, secondary medicinal herbs treatment and tertiary treatment using by dog meat. The traditional acupuncture research process was measured according to the characteristics and changes of the specimens at each processing step of the manufacturing process. The following devices were used to Surface analysis. Scanning electron microscopy (SEM), Energy Dispersive Spectrometer (EDS), X-ray diffraction analyzer (XRD). As a result, medicinal herbs removed impurities on the surface and raised the antibacterial effect in the manufacturing process of traditional acupuncture. Furthermore, the ingredients of medicinal herbs were coated on the surface of the iron. Dog meat influenced to prevent surface corrosion, reduce friction when the acupuncture was inserted. Although the process empirically obtained, a glimpse of the wisdom of our ancestors was revealed. These ancestral wisdom can be expected to apply today, when used in manufacturing process of a modern stainless steel acupuncture to compensate for the defective part.

• 보존과학회지
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• 제17권
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• pp.57-64
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• 2005

청평사 강선루 회전문 부근에서 출토된 조선시대 $16\~17$세기 철물과 철촉에 대한 금속조직학적으로 조사하기 위하여 유물에서 부식되지 않은 시편을 채취하여 마운트와 연마 및 부식을 시켜 금속조직을 관찰하고 비금속개재물부분은 SEM으로 관찰한 뒤 EDS로 분석하였다. 금속학적 조직조사와 SEM-EDS분석을 통하여 철물과 철촉은 고체저온환원법에 의한 순철에 가까운 괴련철 혹은 해면철을 이용하여 철을 생산하고, 단야로 같은 곳에서 침탄을 하여 탄소량을 높인 것으로 밝혀졌다. 또한 철물은 탄소량을 어느 정도 높인 다음 담금질과 열처리과정을 반복하여 철기의 강도를 인위적으로 많이 높이는 작업을 한 것으로 밝혀졌다. 이번 조사연구를 통하여 조선시대에도 괴련철을 소재로 하여 철을 생산하였다는 것을 알 수 있어 의미 있는 결과를 얻었다.