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Adsorption of Nitrogen Dioxide on Transition-Metal-Oxide-Incorporated Hydrotalcites  

Park, Ji Won (School of Applied Chemical Engineering, Chonnam National University)
Seo, Gon (Institute for Catalysis Research, Chonnam National University)
Publication Information
Korean Chemical Engineering Research / v.46, no.6, 2008 , pp. 1029-1038 More about this Journal
Abstract
Transition-metal-oxide-incorporated hydrotalcites were prepared by hydrothermal reaction of their synthetic mixtures containing precursors of transition metal oxides and their properties of nitrogen dioxide adsorption was investigated. The dispersion of transition metal oxides on the hydrotalcites and the amount and the state of nitrogen dioxide adsorbed on them were examined by using XRD, SEM, XPS, nitrogen adsorption, a gravimetric adsorption system, FT-IR spectroscopy and temperature programmed desorption techniques. Transition metal oxides were mainly incorporated on their surface and the incorporation of iron and nickel oxides to the hydrotalcites increased their adsorption amounts of nitrogen dioxide. The dispersion of iron oxide on the hydrotalcites was effective in increasing the amount of nitrogen dioxide adsorption, while too much amount of iron oxide incorporation reduced the amount of nitrogen dioxide adsorption due to masking of surface basic sites by agglomerated iron oxide. Although the incorporation of iron oxide to the hydrotalcites lowered the adsorption strength of nitrogen dioxide, the incorporation of it with a proper amount enhanced the amount of nitrogen dioxide adsorption and the stability against the hydrothermal treatment.
Keywords
Hydrotalcite; Transition Metal Oxide; Iron Oxide; Nitrogen Dioxide; Storage;
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