• Title/Summary/Keyword: Iron surface

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A Case Study of Monitored Natural Attenuation at the Petroleum Hydrocarbon Contaminated Site : II. Evaluation of Natural Attenuation by Groundwater Monitoring (유류오염부지에서 자연저감기법 적용 사례연구 II. 지하수모니터링에 의한 자연저감 평가)

  • Yun Jeong Ki;Lee Min Hyo;Lee Suk Young;Noh Hoe Jung;Kim Moon Soo;Lee Kang Kun;Yang Chang Sool
    • Journal of Soil and Groundwater Environment
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    • v.9 no.3
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    • pp.38-48
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    • 2004
  • Natural attenuation of petroleum hydrocarbon was investigated at an industrial complex about 45 Km away from Seoul. The three-years monitoring results indicated that the concentrations of DO, nitrate, and sulfate in the contaminated area were significantly lower than the background monitoring groundwater under the non-contaminated area. The results also showed a higher ferrous iron concentration, a lower redox potential, and a higher (neutral) pH in the contaminated groundwater, suggesting that biodegradation of TEX(Toluene, Ethylbenzene, Xylene) is the major on-going process in the contaminated area. Groundwater in the contaminated area is anaerobic, and sulfate reduction is the dominant terminal electron accepting process in the area. The total attenuation rate was about 0.0017∼0.0224day$^{-1}$ and the estimated first-order degradation rate constant(λ) was 0.0008∼0.0106day$^{-1}$ . However, the reduction of TEX concentration in the groundwater was resulted from not only biodegradation but also dilution and reaeration through recharge of uncotaminated surface and groundwater. The natural attenuation was, therefore, found to be an effective, on-going remedial process at the site.

Chemical weathering in King George Island, Antarctica

  • Jeong, Gi-Young
    • Proceedings of the Mineralogical Society of Korea Conference
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    • 2003.05a
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    • pp.66-66
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    • 2003
  • King George island, Antarctica, is mostly covered by ice sheet and glaciers, but the land area is focally exposed for several thousand years after deglaciation. For a mineralogical study of chemical weathering in the polar environment, glacial debris was sampled at the well-developed patterned ground which was formed by long periglaclal process. As fresh equivalents, recently exposed tills were sampled at the base of ice cliff of outlet glaciers and at the melting margin of ice cap together with fresh bedrock samples. Fresh tills are mostly composed of quartz, plagioclase, chlorite, and illite, but those derived from hydrothermal alteration zone contain smectite and illite-smectite. In bedrocks, chlorite was the major clay minerals in most samples with minor illite near hydrothermal alteration zone and interstratified chlorite-smectite in some samples. Smectite closely associated with eolian volcanic glass was assigned to alteration in their source region. Blocks with rough surface due to chemical disintegration showed weathering rinds of several millimeter thick. Comparision between inner fresh and outer altered zones did not show notable change in clay mineralogy except dissolution of calcite and some plagioclase. Most significant weathering was observed in the biotite flakes, eolian volcanic glass, sulfides, and carbonates in the debris. Biotite flakes derived from granodiorite were altered to hydrobiotite and vermiculite of yellow brown color. Minor epitactic kaolinite and gibbsite were formed in the cleaved flakes of weathered biotite. Pyrite was replaced by iron oxides. Calcite was congruently dissolved. Volcanic glass of basaltic andesite composition showed alteration rim of several micrometer thick or completely dissolved leaving mesh of plagioclase laths. In the alteration rim, Si, Na, Mg, and Ca were depleted, whereas Al, Ti, and Fe were relatively enriched. Mineralization of lichen and moss debris is of much interest. They are rich of A3 and Si roughly in the ratio of 2:1 to 3:1 typical of allophane. In some case, Fe and Ti are enriched in addition to Al and Si. Transmission electron microscopy of the samples rich of volcanic glass showed abundant amorphous aluminosilicates, which are interpreted as allophane. Chemical weathering in the King George Island is dominated by the leaching of primary phyllosilicates, carbonates, eolian volcanic glass, and minor sulfides. Authigenesls of clay minerals is less active. Absence of a positive evidence of significant authigenic smectite formation suggests that its contribution to the clay mineralogy of marine sediments are doubtful even near the maritime Antarctica undergoing a more rapid and intenser chemical weathering under more humid and milder climate.

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Control of Crowning Using Residual Stress induced by the Difference of Tehermal Expansion Between Ceramic and Carbon Steel in Ceramic Cam Follower (열팽창계수차에 기인된 잔류응력을 이용한 세라믹 캠 팔로우어의 크라우닝 제어)

  • Choe, Yeong-Min;Lee, Jae-Do;No, Gwang-Su
    • Korean Journal of Materials Research
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    • v.10 no.10
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    • pp.703-708
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    • 2000
  • As the engine design changes to get high efficiency and performance of commercial diesel engine, surface w wear of the earn follower becomes an important issue as applied load increasing at the contact face between cam follower and cam. We developed the ceramic cam follower made of sili$\infty$n nitride ceramic which was more wear resistant than the cast iron or sintered metal cam follower. Ceramic cam follower was made by direct brazing of thin ceramic disk to steel body using an active brazing alloy without the interlayer. In-situ crowning(R), resulted from the difference of thermal expansion coefficient between ceramic and carbon steel after direct brazing without any stress-relieving inter]ayer, could be controlled. When a earbon steel was heated above $A_{c1}$ point and then c$\infty$led, the expansion curve represented a hysteresis. Appropriate crowning was achieved below the $A_{c1}$ point(about $723^{\circ}C$) and crowning increased with brazing temperature exponentially above the $A_{c1}$ point. Optimum brazing temperature range was from 700 to $720^{\circ}C$. We developed successfully the ceramic cam follower having appropriate crowning and being inexpensive. Also we could successfully control the crowning of ceramic earn follower by hysteresis behavior of thermal expansion of earbon steel during direct brazing process.

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The Recycling of Sludge from Granite Stone Cutting and Polishing (화강암 석재 가공 슬러지의 재활용)

  • 이성오;국남표;임영빈;신방섭
    • Resources Recycling
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    • v.4 no.1
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    • pp.12-19
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    • 1995
  • This study was carried out to remove the iron and impurities usmg hydrocyclone and HGMS for recycling of sludge from the granite stone cutting and polishing industrγ in the basic of chemi떠1 analysis and minerallogical investigation. This sludge consist of 70.9% $SiO_2$ 13.6% $Al_2O_3$ and It also contained 2.52% of $Fe_2O_7$ and 0.29% of $TiO_2$, as a main impurities to decrease the whiteness. As the result of hydrocyclone experiment, It was very good condition that are 100~150 g/l of sludge amount, 2.0~ 2.5 mm of underflow nozzle size, and 1.2~1.6 kg/$\textrm{cm}^2$ of pressure for 85% sludge product with the $-37{\mu}\textrm{m}$ size. $Fe_2O_3$ and $TiO_2$, contents by treatment of HGMS were decreased with 0.65% and 0.07% each at 10,000 gauss of magnetic field strength, and addih$\upsilon$n of Sodium tripolyphosphate as a dispersant was effected to get low grade F Fe,Ol and TiO, concentrate. PhYSIcal properties of this stone sludge product were showed 58.5% of whiteness, 1 13.4% of firing shrinkage and 3.0812 $\textrm{m}^2$/g of specific surface area.

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Ameliorating Effects of Nokyongdaebo-tang on Experimental Subacute Hemorrhagic Anemia in Rats (녹용대보탕 열수 추출물의 실험적으로 유발된 랫트 아급성 출혈성 빈혈에 대한 효과)

  • Kim, Jung-Ah;Kim, Dong-Chul
    • The Journal of Korean Obstetrics and Gynecology
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    • v.30 no.3
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    • pp.1-19
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    • 2017
  • Objectives: The object of this study is to observe the possible ameliorating effects of Nokyongdaebo-tang (NYDBT) on the experimental subacute hemorrhagic anemia (SHA) in rats. Methods: In the present study, SHA in rats was induced by exsanguinations from orbital plexus, and ameliorating effects of NYDBT was observed based on the changes of body and hematopoietic organ (spleen, liver and femur) weights, red blood cell (RBC) related hematological values, smear cytology, histopathological changes and immunohistochemistrical analysis of hematopoietic stem cells in the femur bone marrow, liver and spleen. In addition, the gastrointestinal motility and the surface mucosa thicknesses of remnant fecal pellets in the colon lumen, mucosa thicknesses and the mucous producing cell numbers in the colonic mucosa were analyzed to observe the digestive disorders, especially on the constipation, the major discomfort problems in iron supplement. Results: SHA related abnormal anemic signs were markedly and dose-dependently inhibited by oral administration of NYDBT 500, 250 and 125 mg/kg in a condition of this experiment. In addition, no meaningful changes on the gastrointestinal motilities and mucous component on the colon and remnant feces were noticed in all three different dosages of NYDBT treated rats as compared with intact vehicle and SHA control rats in this study. Conclusions: It, therefore, is expected that NYDBT will be promising as a novel alternative hematopoietic and therapeutic agent for anemia.

Comparison of Membrane Degradation of PEMFC by Fenton Reaction and OCV Holding (Fenton 반응과 OCV Holding에 의한 PEMFC 고분자 전해질 막의 열화비교)

  • Oh, Sohyung;Kwag, Ahhyun;Lee, Daewoong;Lee, Mooseok;Lee, Donghoon;Park, Kwon-Pil
    • Korean Chemical Engineering Research
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    • v.57 no.6
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    • pp.768-773
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    • 2019
  • The Fenton reaction, which evaluates the electrochemical durability of polymer membranes of polymer electrolyte fuel cells (PEMFC), and the degradation of polymer membranes by OCV holding method are compared. The Fenton reaction is a method that can evaluate the chemical durability of the polymer membrane at outside the cell in a shorter time than the OCV Holding method. The Fenton reaction was carried out at 30% hydrogen peroxide, 10 ppm iron, and $80^{\circ}C$ for 24 hours. OCV Holding was driven at $90^{\circ}C$, 30% relative humidity and OCV for 168 hours. The Fenton reaction caused a lot of degradation inside the polymer membrane. On the other hand, in OCV Holding, the membrane thickness was thinned by the entire surface and internal degradation. The fluorine emission rate was more than 10 times higher than that of OCV Holding due to the Fenton reaction. The hydrogen permeation rate increased about 30% at 24 hours of Fenton reaction. At OCV Holding, hydrogen permeability decreased after 24 hours and then increased. As a whole, there was a difference in a membranes deteriorated by Fenton reaction and OCV Holding.

Convergence Comparison of Linear Oscillating Electric Machines (리니어 오실레이팅 전기기기의 비교 연구)

  • Jeong, Sung-In;Eom, Sang In
    • Journal of the Korea Convergence Society
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    • v.12 no.12
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    • pp.273-280
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    • 2021
  • This paper presents the results of study of linear oscillating electric machine; Cartesian, cylindrical type with permanent magnet, flux reversal, cylindrical reluctance, and transverse flux type. The focus of the work is the suggestion of the characteristics and design process of propose topology, respectively. First of all, there are five types of the proposed to this study on the basis of the existing literatures; Cartesian type, cylindrical type, flux reversal type, cylindrical reluctance type, and transverse flux type. All topology is achieved using equivalent magnetic circuit considering leakage elements as initial modeling. Cartesian type is investigated by number of phases and number of pole pairs using optimal process. A cylindrical type is described by number of phases and displacement of stroke. The flux reversal type is proposed based on the symmetrical and non symmetrical stator cores of the surface mounted PMs mover, and non slanted PMs and slanted PMs of the flux concentrating PMs mover. A cylindrical reluctance type is studied by the shape of mover teeth in geometric aspect to reduce force ripple and increase magnetic flux. A transverse flux type is considered by dividing the transverse flux electric excited and the transverse flux permanent magnet excited. It is significant that the study gives a design rules and features of linear oscillating electric machine.

Precise Deterioration Diagnosis and Restoration Stone Suggestion of Jungdong and Banjukdong Stone Aquariums in Gongju, Korea (공주 중동 및 반죽동 석조의 정밀 손상도 진단과 복원석재 제안)

  • Jo, Young Hoon;Lee, Myeong Seong;Choi, Gi Eun;Lee, Chan Hee
    • Korean Journal of Heritage: History & Science
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    • v.44 no.3
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    • pp.92-111
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    • 2011
  • This study focus on the restoration stone selection of break-out part based on material characteristics analysis and the conservational safety diagnosis using various nondestructive techniques for Jungdong and Banjukdong Stone Auariums. As a result, the original rocks of the stone aquariums body are porphyritic granodiorite with magnetite-series having igneous lineation, microcline phenocryst, veinlet and basic xenolith. As a result of the provenance presumption of the host rock, a rock around Gamgokri area in Nonsan City was identified the genetically same rock. Therefore, the rock is appropriate for restoration materials of the break-out part. The deterioration assessment showed that the stone aquariums were highly serious scaling, scale off and blackening. Particularly, the front face of Banjukdong stone aquarium needs reinforcement of structural crack (760mm) caused from igneous lineation of biotite. Blackening contaminants on the stone aquariums surface occurred by combining iron oxide, manganese oxide and clay mineral. Also, major factors of efflorescence contaminants were identified as calcite (Jungdong stone aquariums) and gypsum (Banjukdong stone aquariums). The physical characteristics of stone aquariums appeared that the original and new stone is third (moderately weathered) and second grade (slightly weathered), respectively. This study sets up an integrated conservation system from material analysis to restoration stone selection and conservational safety diagnosis of Jungdong and Banjukdong stone aquariums.

Study on the Casting Method and Manufacturing Process of Bronze Bells Excavated from the Hoeamsa Temple Site (회암사지 금탁(琴鐸)의 주조방법과 가공기술 연구)

  • Lee, Jae Sung;Baek, Ji Hye;Jeon, Ik Hwan;Park, Jang Sik
    • Korean Journal of Heritage: History & Science
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    • v.43 no.3
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    • pp.102-121
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    • 2010
  • Three bronze bells excavated from the Hoeamsa temple site were investigated for their microstructures and chemical compositions in an effort to understand the technology applied in fabrication, which may represent the related industry established in the early Joseon period. The result shows that the bells were cast from alloys of approximately 85% copper-8% tin-7% lead. The chemical analysis for ten trace elements shows that they were all kept below 0.3 weight %, suggesting that the alloys were made of relatively well-refined copper, tin and lead. The presence of sulfur and iron indicates that chalcopyrite or chalcocite may have been used in the smelting of copper. Evidence has been found that the bells were cast by pouring the liquid metal from the top of the sand molds that were set up in an upright position. No additional treatments, thermal or mechanical, other than a little grinding were applied upon the completion of casting. After the shaping process, a balancing plate was attached to the top of the bell using a steel connection ring. The connection assembly was then fixed to the main body by using molten bronze as a solder. The surface inscription was found carved using different techniques. The differences in the order of strokes and the calligraphic style indicate that the carving was carried out by more than one master. In the absence of documentary evidence on past bronze technology, the present bronze bells with known chronology, provenance and the main agent of production, prove to be a rare and valuable archaeological material for the understanding of the related technology in use in the early Joseon period.

Destruction and Improper Restoration of Cheomseongdae (경주첨성대의 파손과 잘못된 복구)

  • Chang, Hwal Sik
    • Korean Journal of Heritage: History & Science
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    • v.45 no.2
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    • pp.72-99
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    • 2012
  • Cheomseongdae, Korea's so-called "star-gazing tower" located in the former Silla Dynasty capital of Gyeongju, is generally believed to have maintained its original shape since its construction in 647. The stone structure was closely examined and measured by Gyeongju National Museum in 1962 and reexamined by Korean National Research Institute of Cultural Heritage in 2009. This research noted the following structural anomalies of Cheomseongdae. A corner of the top rectangle layer was broken diagonally in a form that can never be attributed to a natural cause. The four metal clamps under the top rectangle layer had been missing. Four grooves, with unknown usage, exist on the sides of the long rectangular stones projected out of the circular body at the second and third circular layers from the top. On the second circular layer from the top, there are three flat stones, less than a half as tall as their surrounding stones. The average height of the third circular layer from the top is only 23.5 cm, while the overall average of the entire 27 circular layers is 29.9cm. This research postulates that all these anomalies are due to prior destructions and improper restorations of the structure. The first destruction and restoration of Cheomsengdae was likely to have occurred before the mid 15th century. The damages might include a pavilion on the top of the structure and a stone with the name of the structure carved in. The Mongolian invasion in the 13th century was a most likely cause. After the restoration, the structure suffered at least another attack. The damages on the top layer and the missing iron clamps were due to the later attack. The grooves and flat stones were to house holding device that affixed certain objects to the outer surface of the circular body. The metal or stone objects might have faced upward at the four corners of Chemseongdae, bridging the gaps between the rectangle layers and circular layers. The current Chemseongdae lost at least the four affixed objects, four holding devices, and one flat stone.