• Title/Summary/Keyword: Iron saturation

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Impact of Amino-Acid Coating on the Synthesis and Characteristics of Iron-Oxide Nanoparticles (IONs)

  • Ebrahiminezhad, Alireza;Ghasemi, Younes;Rasoul-Amini, Sara;Barar, Jaleh;Davaran, Soodabeh
    • Bulletin of the Korean Chemical Society
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    • v.33 no.12
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    • pp.3957-3962
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    • 2012
  • Iron-oxide nanoparticles (IONs) with biocompatible coatings are the only nanostructural materials which have been approved by the FDA for clinical use. Common biocompatible coatings such as hydrocarbons, polymers, and silica have profound influences on critical characteristics of IONs. Recently, amino acids were introduced as a novel biocompatible coating. In the present study, the effects of amino acids on IONs synthesis and characteristics have been evaluated. Magnetite nanoparticles with L-arginine and L-lysine coatings were synthesised by a coprecipitation reaction in aqueous solvent and their characteristics were compared with naked magnetite nanoparticles. The results showed that amino acids can be a perfect coating for IONs and would increase particle stability without any significant effects on the critical properties of nanoparticles such as particle size and magnetization saturation value.

The Analysis of Operation Characteristics of Flux-Lock Type High-Tc Superconducting Fault Currents Limiter (자속 구속형 고온초전도 전류제한기의 동작특성 분석)

  • Park Chung-Ryul;Lim Sung-hun;Park Hyoung-Min;Lee Jong-Hwa;Ko Seokcheol;Choi Hyo-Sang;Han Byoung-Sung;Hyun Ok-Bae;Chung Dong-Chul
    • Proceedings of the KIEE Conference
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    • summer
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    • pp.1130-1132
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    • 2004
  • In this paper, we investigated the operational characteristics of the fault current limiting in the The flux-lock type high-Tc superconducting fault current limiter. The flux-lock type high-Tc superconducting fault current limiter was consisted of primary and secondary copper coils that flux was locked on iron core and YBCO thin film. The operational characteristic of a flux-lock type SFCL dependent on winding direction of coil 1 and coil 2, and the number of turns of coil 1 and coil 2, inductances of the coils, saturation in iron core, the properties of superconducting element etc. In this cases, we investigated the fault currents limiting characteristics of the flux-lock type SFCL when winding direction of coil 1 and coil 2 was subtractive polarity winding.

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Analysis of Hysteresis Characteristics of Flux-Lock Reactor (자속구속 리액터의 히스테리시스 특성 분석)

  • Lim, Sung-Hun;Choi, Hyo-Sang;Kang, Hyeong-Gon;Ko, Seok-Cheol;Lee, Jong-Hwa;Han, Byoung-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.255-258
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    • 2003
  • The hysteresis characteristics of flux-lock reactor, which is an essential component of flux-lock type superconducting fault current limiter (SFCL), was investigated. The hysteresis loss of iron core in flux-lock type SFCL does not happen due to its winding's structure especially in the normal state. From the equivalent circuit for the flux-lock type SFCL and the fault current limiting experiments, the hysteresis curves could be drawn. Through the hysteresis curves together with the fault current level due to the inductance ratio for the 1st and 2nd winding, the increase of the number of turns in the 2nd winding of the flux-lock type SFCL had a role to prevent the iron core from saturation.

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Influence Factor on Magnetization Property of Carbonyl Iron-based Magnetorheological Fluids

  • Wang, Daoming;Zi, Bin;Qian, Sen;Qian, Jun;Zeng, Yishan
    • Journal of Magnetics
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    • v.21 no.4
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    • pp.622-628
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    • 2016
  • Magnetization property is a critical factor for magnetorheological fluids (MRFs) to achieve the liquid-solid transition. The main focus of this study is on exploring the influence factors on magnetization properties of MRFs. In this paper, a theoretical analysis is performed to discuss the magnetization characteristics of MRFs firstly. Then, a method for the preparation of carbonyl iron-based MRFs is illustrated and five MRFs samples with various material parameters are prepared. It is succeeded by a series of experiments on testing the hysteresis loop and the magnetization curve of each sample and the influence factors are compared and analyzed. Experimental results indicate that there is basically no hysteresis phenomenon on MRFs which exhibits superparamagnetic behavior at room temperature. A surfactant coating on magnetic particles can slightly improve the MRFs magnetization. Additionally, the magnetic susceptibility and the saturation magnetization both increase with the particle concentration, whereas the influence of particle diameter is relatively very small. Moreover, as the temperature increases, the magnetization decreases and the declining rate accelerates gradually.

Acute methemoglobinemia after a normal diet (일상적인 음식 섭취 후 발생한 급성 메트헤모글로빈혈증)

  • Lee, Sung Kgun;Kang, Jeong Ho
    • Journal of Medicine and Life Science
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    • v.18 no.1
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    • pp.20-23
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    • 2021
  • Methemoglobin is generated by the oxidation of ferrous iron to ferric iron within a hemoglobin molecule. Methemoglobin is unable to bind and transport oxygen, resulting in methemoglobinemia, which can lead to fatal tissue hypoxia. The most common cause of methemoglobinemia is poisoning by oxidizing agents such as dapsone, benzocaine, and primaquine. However, methemoglobinemia can also be caused by normal dietary sources. We present two cases of methemoglobinemia that developed after a normal diet in two male patients. In this case report, the patients suddenly developed dyspnea and cyanosis after eating the same meal. They had no history of suspected poisoning, such as the use of drugs, exposure to chemicals, or gas inhalation. Their symptoms did not improve even after a high dose of oxygen was administered; further, an abnormal 'oxygen saturation gap' was observed. Because of CO-oximetry, the methemoglobin levels of the patients were 50.0% and 46.6%, respectively. We administered methylene blue (1 mg/kg), and the patients recovered completely without any complications. Emergency physicians should, therefore, be aware that methemoglobinemia can also be caused by normal dietary sources. In addition, if the source and route of contamination are unclear, an epidemiological investigation should be conducted.

Development of Hybrid Insulating Coating for Fe-based Soft Magnetic Powder (철계 연자성 분말용 하이브리드 절연 코팅막 개발)

  • Kim, Jungjoon;Kim, Sungyeom;Kim, Youngkyun;Jang, Taesuk;Kim, Hwi-jun;Kim, Youngjin;Choi, Hyunjoo
    • Journal of Powder Materials
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    • v.28 no.3
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    • pp.233-238
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    • 2021
  • Iron-based amorphous powder attracts increasing attention because of its excellent soft magnetic properties and low iron loss at high frequencies. The development of an insulating layer on the surface of the amorphous soft magnetic powder is important for minimizing the eddy current loss and enhancing the energy efficiency of high-frequency devices by further increasing the electrical resistivity of the cores. In this study, a hybrid insulating coating layer is investigated to compensate for the limitations of monolithic organic or inorganic coating layers. Fe2O3 nanoparticles are added to the flexible silicon-based epoxy layer to prevent magnetic dilution; in addition TiO2 nanoparticles are added to enhance the mechanical durability of the coating layer. In the hybrid coating layer with optimal composition, the decrease in magnetic permeability and saturation magnetization is suppressed.

Magnetic Mineral Identification in Meteorites (잔류자화비를 이용한 운석의 자성광물 판별)

  • Kim, In-Ho;Yu, Yong-Jae
    • Journal of the Mineralogical Society of Korea
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    • v.24 no.1
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    • pp.31-36
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    • 2011
  • Meteorites are extraterrestrial solid rock fragments that fell from the outer space. Investigating mineral magnetic properties of the Meteorites is essential in understanding the evolution of planets and asteroids in the Solar System. In particular, magnetic characterization of magnetic mineral can provide constraints on the progress of differentiation in ancient planetary bodies. In the present study, ratio of thermoremanent magnetization (TRM) over saturation isothermal remanent magnetization (SIRM) was applied to diagnose the magnetic minerals in meteorites and igneous rocks. Distinctive classification of TRM/SIRM suggests that kamacite, tetrataenite, magnetite, and (Cr,Ti)-rich iron oxide are responsible for the magnetization of H5 Richardton, LL6 St. Severin, ALH84001, and DaG476, respectively. The TRM/SIRM ratio could be an efficient tool in identifying magnetic minerals especially when rocks or meteorites contain unstable material under heating.

Assessment of The Above-Ground Carbon Stock and Soil Physico-Chemical Properties of an Arboretum within The University of Port Harcourt, Nigeria

  • Akhabue, Enimhien Faith;Chima, Uzoma Darlington;Eguakun, Funmilayo Sarah
    • Journal of Forest and Environmental Science
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    • v.37 no.3
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    • pp.193-205
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    • 2021
  • The importance of forests and trees in climate change mitigation and soil nutrient cycling cannot be overemphasized. This study assessed the above-ground carbon stock of two exotic and two indigenous tree species - Gmelina arborea, Tectona grandis, Khaya grandifoliola and Nauclea diderrichii and their litter impact on soil nutrient content of an arboretum within the University of Port Harcourt, Nigeria. Data were collected from equal sample plots from the four species' compartments. Tree growth variables including total height, diameter at breast height, crown height, crown diameter and merchantable height were measured for the estimation of above-ground carbon stock. Soil samples were collected from a depth of 0-30 cm from each compartment and analyzed for particle size distribution, organic carbon, total nitrogen, available phosphorus, exchangeable bases, exchangeable acidity, cation exchange capacity, base saturation, pH, Manganese, Iron, Copper and Zinc. Analysis of Variance (ANOVA) was used to test for significant difference (p<0.05) in the carbon contents of the four species and the soil nutrient contents of the different species' compartments. Pearson correlation was used to assess the relationships between the carbon contents, growth parameters and soil parameters. The highest and lowest carbon stock per hectare was observed for G. arborea (151.52 t.ha-1) and K. grandifoliola (45.45 t.ha-1) respectively. Cation exchange capacity and base saturation were highest and lowest for soil under G. arborea and K. grandifoliola respectively. The pH was highest and lowest for soil under G. arborea and T. grandis respectively. Carbon stock correlated positively with dbh, crown diameter, merchantable height and Zn and negatively with base saturation. The study revealed that G. arborea and N. diderrichii can effectively be used for reforestation and afforestation programmes aimed at climate change mitigation across Nigeria. Therefore, policies to encourage and enhance their planting should be encouraged.

Kinetic Characterization of an Iron-sulfur Containing Enzyme, L-serine Dehydratase from Mycobacterium tuberculosis H37Rv (Mycobacterium tuberculosis H37Rv로부터 유래된 철-황 함유 효소인 L-세린 탈수화효소의 동력학적 특성)

  • Han, Yu Jeong;Lee, Ki Seog
    • Journal of Life Science
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    • v.28 no.3
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    • pp.351-356
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    • 2018
  • L-Serine dehydratase (LSD) is an iron-sulfur containing enzyme that catalyzes the conversion of L-serine to pyruvate and ammonia. Among the bacterial amino acid dehydratases, it appears that only the L-serine specific enzymes utilize an iron-sulfur cluster at their catalytic site. Moreover, bacterial LSDs are classified into four types based on structural characteristics and domain arrangement. To date, only the LSD enzymes from a few bacterial strains have been studied, but more detailed investigations are required to understand the catalytic mechanism of various bacterial LSDs. In this study, LSD type II from Mycobacterium tuberculosis (MtLSD) H37Rv was expressed and purified to elucidate the biochemical and catalytic properties using the enzyme kinetic method. The L-serine saturation curve of MtLSD exhibited a typically sigmoid character, indicating an allosteric cooperativity. The values of $K_m$ and $k_{cat}$ were estimated to be $59.35{\pm}1.23mM$ and $18.12{\pm}0.20s^{-1}$, respectively. Moreover, the plot of initial velocity versus D-serine concentration at fixed L-serine concentrations showed a non-linear hyperbola decay shape and exhibited a competitive inhibition for D-serine with an apparent $K_i$ value of $30.46{\pm}5.93mM$ and with no change in the $k_{cat}$ value. These results provide insightful biochemical information regarding the catalytic properties and the substrate specificity of MtLSD.

The Effect of Vitamin B-2 and (or) Vitamin B-6 Deficiency on Hematologic Profile in Rats (Vitamin B-2와 (또는 ) Vitamin B-6 결핍이 흰쥐의 Hematologic Profile에 미치는 영향)

  • 유정열
    • Journal of Nutrition and Health
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    • v.22 no.3
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    • pp.167-174
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    • 1989
  • The purpose of this study was to determine if vitamin B-2 and vitamin B-6 deficiency affects hematologic profile in vivo. Rats were fed a vitamin B-2 deficient (-B2) diet or a vitamin B-6 deficient (- B6) diet or a combined vitamin B-2 and vitamin B-6 deficient (-B2-B6) diet or a control diet for 6 weeks. Hematocrit (Ht), hemoglobin (Hb), plasma iron (PI), transferrin saturation (TS) and liver iron concentration (LI) were compared. In -B2 rats vs. control rats, PI, TS and LI were significantly lower but Ht and Hb were not. In - B6 rats vs. control, Ht and Hb were significanty lower but LI was higher. The -B2-B6 rats had intermediate effects in Hb, PI, TS and LI and a decrease in Ht. The repletion with a contro diet for 2 weeks resulted in significant improvements in hematologic indices and LI in both - B2 rats and - B6 rats. This study suggests that the intakes of vitamin B-2 and vitamin B-6 are important for preventive and therap\ulcornereutic approaches to improve the hematologic status in nutritionally anemic groups.

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