• 제목/요약/키워드: Iron salt

검색결과 144건 처리시간 0.036초

강 구조물에 대한 폴리아닐린 함유도료의 방청특성 (Anti-Corrosion Characteristics of Steel Structures with Polyaniline Anti-Corrosive Coatings)

  • 송민경;공승대;오은하;윤철훈;김윤신;임호섭
    • 한국환경보건학회지
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    • 제36권3호
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    • pp.236-246
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    • 2010
  • In preparative anti-corrosive coating experiments, polyaniline was obtained by reacting an oxidizing agent with the monomer aniline. Further, the primer coating was prepared using a variety of widely-used materials such as urethane resin. For the top coating, epoxy resin and acrylic urethane resin were used. Characteristics of the coatings were assessed according to KS and ASTM specifications, and the structure of the polyaniline was characterized using FT-IR and TGA. For analysis of anti-corrosive properties in salt-spray experiments, measurements of the oxidation state of iron and surface atomic analysis were conducted using XPS and SEM-EDX. Unlike general anti-corrosive coatings which exhibit anti-corrosive effects only as a primer coating, the anti-corrosive coatings using polyaniline as the anti-corrosive pigment showed a marked synergistic effect with the top coatings. In other words, the top coatings not only produce a fine view effect, but also increase, through interaction with the primer coatings, the resistance to diffusion of corrosive factors from the external environment. It was also found that, unlike the heavy metal oxide-forming layer of the passive barrier alone, the polyaniline anti-corrosive pigment oxidized iron at the interface with the iron substrate to form a passive barrier in the oxidic layer, and itself formed a potential barrier layer with anti-corrosive factors from the external environment. Although the passive layer was damaged, the damaged area did not become completely oxidized iron; on the contrary, it showed a tendency to reduction. This can be interpreted such that a passive layer is formed again on the damaged area, and that at the same time there is a tendency to self-healing.

애기장대에서 activation tagging system을 이용한 새로운 고염 스트레스 반응 유전자의 동정 (Identification of Novel Salt Stress-responsive Genes Using the Activation Tagging System in Arabidopsis)

  • 석혜연;응웬부린;배형준;하지민;김하연;이선영;문용환
    • 생명과학회지
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    • 제28권9호
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    • pp.1030-1041
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    • 2018
  • 환경 스트레스는 식물의 성장을 저해하며 작물의 생산량을 감소시키는 주요 원인이다. 식물은 다양한 유전자의 발현 변화를 통해 스트레스에 대한 저항성을 나타낸다. 본 연구에서는 activation tagging system을 이용하여 기존에 밝혀지지 않은 새로운 고염 스트레스 반응 유전자들을 분리하였다. 애기장대의 발아 단계에서 고염 스트레스에 저항성을 보이는 9개의 activation tagging 라인을 선별하였다. 그 중 TAIL-PCR 방법을 이용하여 AT7508, AT7512, AT7527, AT7544, AT7548, AT7556의 6개 라인에서 T-DNA가 삽입된 위치를 확인하였으며 각 라인에서 T-DNA가 삽입된 주변 유전자의 발현을 RT-PCR로 분석하였는데 AT7508, AT7512, AT7527, AT7544, AT7556에서 각각 ClpC2/HSP93-III (At3g48870), plant thionin family (At2g20605), anti-muellerian hormone type-2 receptor (At3g50685), vacuolar iron transporter family protein (At4g27870), microtubule-associated protein (At5g16730)이 activation 된 것으로 밝혀졌다. 더불어 AT7548에서는 T-DNA가 삽입된 곳의 양쪽에 위치하는 두 유전자인 Arabinogalactan protein 13 (AGP13) (At4g26320)과 F-box/RNI-like/FBD-like domains-containing protein (At4g26340)이 모두 activation 되었다. Activation 된 7개 유전자는 기존에 고염 스트레스 저항성과 관련된 기능이 알려지지 않은 유전자로 본 연구를 통해 새롭게 고염 스트레스 반응에 대한 기능이 밝혀졌다. 7개의 activation된 유전자 중 ClpC2/HSP93-III, AGP13, F-box/RNI-like/FBD-like domains-containing protein의 3개 유전자는 고염 스트레스에 의해 발현이 증가하였다. 또한 AT7508과 AT7527, AT7544 라인은 발아 단계뿐만 아니라 유식물체 발달 과정에서도 고염 스트레스 저항성을 보여 activation tagging 라인의 선별 결과의 타당성을 뒷받침 하였다. 본 연구의 결과를 통해 activation tagging system이 새로운 스트레스 반응 유전자를 찾아낼 수 있는 유용한 기술임을 확인할 수 있었다.

Performance of fouled NF membrane as used for textile dyeing wastewater

  • Abdel-Fatah, Mona A.;Khater, E.M.H.;Hafez, A.I.;Shaaban, A.F.
    • Membrane and Water Treatment
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    • 제11권2호
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    • pp.111-121
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    • 2020
  • The fouling of Nanofiltration membrane (NF) was examined using wastewater containing reactive black dye RB5 of 1500 Pt/Co color concentrations with 16890 mg/l TDS collected from El-alamia Company for Dying and Weaving in Egypt. The NF-unit was operated at constant pressure of 10 bars, temperature of 25℃, and flowrate of 420 L/min. SEM, EDX, and FTIR were used for fouling characterization. Using the ROIFA-4 program, the total inorganic fouling load was 1.07 mM/kg present as 49.3% Carbonates, 10.1% Sulfates, 37.2% Silicates, 37.2% Phosphates, and 0.93% Iron oxides. The permeate flux, recovery, salt rejection and mass transfer coefficients of the dye molecules were reduced significantly after fouling. The results clearly demonstrate that the fouling had detrimental effect on membrane performance in dye removal, as indicated by a sharp decrease in permeate flux and dye recovery 68%. The dye mass transfer coefficient was dropped dramatically by 34%, and the salt permeability increased by 14%. In this study, all the properties of the membrane used and the fouling that caused its poor condition are identified. Another study was conducted to regeneration fouled membrane again by chemical methods in another article (Abdel-Fatah et al. 2017).

한국인(韓國人)의 식염(食鹽) 및 질소대사(窒素代謝)에 관(關)하여 (Studies on Sodium Chloride and Nitrogen Metabolism of the Korean)

  • 정순동;양일석
    • The Korean Journal of Physiology
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    • 제1권2호
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    • pp.193-197
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    • 1967
  • In order to study the daily metabolism of sodium chloride and of nitrogen, 24 hour urine samples were collected from 298 normal Korean males whose ages varied Iron 26 to 80 years old. The volume and the concentration of chloride and the total nitrogen were determine, along with the resting pulse and the blood pressure. The daily urine volume was maintained at approximately $1,000\;ml/m^2$ in all age groups while the chloride concentration was at approximately 230 mEq/l. Hence the daily urinary output of sodium chloride was estimated to be approximately 21 gm. On the other hand, the daily urinary output of total nitrogen amounted to approximately 10 gm. Theses findings are similar to those obtained earlier by Yi et al. (1966) in Korean subjects younger than 25 fears old, indicating that average Koreans live on low protein and high salt diets throughout their life. Despite a known correlation between the incidence of hypertension and the high salt intake, none of the these subjects employed in the present investigation showed any sign of hypertension.

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The Copper, Cobalt, Iron, Selenium and Zinc Status of Cattle in the Sanyati and Chinamhora Smallholder Grazing Areas of Zimbabwe

  • Mpofu, I.D.T.;Ndlovu, L.R.;Casey, N.H.
    • Asian-Australasian Journal of Animal Sciences
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    • 제12권4호
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    • pp.579-584
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    • 1999
  • The trace mineral status of cattle in the smallholder grazing areas of Sanyati and Chinamhora in Zimbabwe was evaluated during the rainy and dry seasons of 1994 and 1995. The evaluation was done in terms of mineral concentration in blood plasma. Plasma copper in calves, steers and cows in the dry season was; Sanyati: 0.55, 0.59, and 0.61; Chinamhora: 0.59, 0.58, and $0.60{\mu}g/ml$, respectively versus a normal of $0.65{\mu}g/ml$. In the rainy season, copper was deficient at both sites (averaging $0.56{\mu}g/ml$ and $0.59{\mu}g/ml$ at Sanyati and Chinamhora, respectively). Plasma selenium in the dry season was 0.017, 0.025, and $0.017{\mu}g/ml$ for calves, steers and cows, respectively at Sanyati versus a normal of $0.03{\mu}g/ml$ and therefore considered to be deficient. Iron, zinc and cobalt were found to be generally high and therefore unlikely to be deficient. Copper and selenium are recommended in salt licks in these environments.

Effects of Nutrient Levels on Cell Growth and Secondary Carotenoids Formation in the Freshwater Green Alga, Chlorococcum sp.

  • Liu, Bei-Hui;Haizhang, Dao;Lee, Yuan-Kun
    • Journal of Microbiology and Biotechnology
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    • 제10권2호
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    • pp.201-207
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    • 2000
  • The freshwater green alga Chlorococcum sp. grew on NH_4^{+},{\;}NO_3^{-}$, urea, yeast extract, and peptone as the nitrogen source showing similar pattens of growth and secondary carotenoid (SC) production. However, the most suitable nitrogen source for the induction fo SC was urea. The dffects of nutrient levels (urea, phosphate, sulfate, ferrous iron, and salt) on growth and SC production were stydied by varying the concentration of each nutrient in batch cultures. High biomass production was achieved in cultures containing 20-28 mM urea, 4.8-10 mM phosphate, 1.6 mM sulfate, 70 mM phosphate, 1.6 mM sulfate, 170 mM NACl, and $50{\;}\mu\textrm{M}$ iron. The optimum concentrations of nutrients for biomass and for the SC accumulation in biomass were evaluated and the two media for achieving high biomass production and SC production were thus developed. The extent to which each parameter to stimulate the formation of SC in the alga were varied and the potentially improned SC prodution by manipulating the nutrient levels in the modified media were descussed.

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수치료(水治療) 중 온천요법의 한의학적 문헌고찰 및 효능에 대한 연구 (A literature review and study on effect of Balneotherapy)

  • 김동건;허성규;김유진;허영진;공인표;한석훈;조영호;공경환;정수현;차윤엽
    • 한방안이비인후피부과학회지
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    • 제20권2호통권33호
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    • pp.132-141
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    • 2007
  • Objectives : The purpose of this study is to consider the definition, history, classification and clinical effect of balneotherapy. Methods : We researched oriental documents and recent sources of balneotherapy. Results and Conclusions : 1. Balneotherapy is medical cure method which uses physical chemistry effects of water. 2. Records of balneotherapy are seen in oriental documents such as Hwangjenaegyeong(黃帝內經), Sinnongbonchogyeong(神農本草經), Jaebyoungwonhuron(諸病源候論), Youmoonsachin(儒門事親), Bonchogangmok(本草綱目) and Donguibogam(東醫寶鑑) etc. 3. Spa can classify eleven types according to ingredient. The types were as following. Simple thermal spirng, Common salt spring, Sodium bicarbonated spring, Sulfate spring, Radioactive spring, Acid spring, Sulfur spring, Carbon dioxide spring, Iron spring, Alum spring & Sulfate-iron spring, Bicarbonatealkaline spring. 4. Physical, chemical and environmental effect of spa therapy have effectiveness on the chronic and we akness disease more than acute disease. And balneotherapy have more effectiveness on digestive disease, pulmonary disease, metabolic disease, circulatory disease, muscle skeletal disease and dermatologic disease than any other diseases.

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배지의 철이온과 pH 변화에 대한 인삼모상근의 생리적 반응 (Physiological Responses of Hairy Roots of Ginseng (Panax ginseng C.A. Meyer) to Iron Status and pH Change)

  • 양덕조;윤길영;김용해;양덕춘
    • 식물조직배양학회지
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    • 제27권1호
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    • pp.31-37
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    • 2000
  • 인삼 (Panax ginseng C.A. Meyer)의 뿌리로부터 유도한 모상근의 proton 방출은 철이온의 결핍 또는 nitrate나 ammonium이온에 의해 증가되었다. 철이온 결핍에 의한 수소이온 방출의 증가는 정단 조직에서 나타나는 반면에 nitrate와 ammonium 이온에 의한 수소이온 방출은 기저부위에서 높게 나타났다. 배지의 pH변화에 따른 무기이온의 흡수는 무기이온의 종류에 따라 다양한 양상을 나타냈다. $Ca^{2+}$, $Mg^{2+}$ 그리고 Fe$^{2+}$ 는 pH 4.8 에서 가장 높은 흡수를 나타냈으며, Mn$^{2+}$, $Zn^{2+}$ 그리고 Cu$^{2+}$ 는 pH 3.8에서 가장 높았다. HPLC를 이용한 유리당 및 ginsenoside분석에서, 인삼모상근 유리당 구성의 주성분은 sucrose, glucose 그리고 fructose 였으며, glucose와 fructose는 pH 6.8에서 sucrose는 pH 4.8 에서 함량이 가장 높았다. 반면에 ginsenosides와 phenolic compound의 함량은 MS 배지의 표준인 pH 5.8 에서 가장 높았다. pH 변화에 대한 인삼모상근의 이러한 생리적 반응은 인삼근의 적변유발과 관련된 무기이온의 mobilization 및 흡수기작의 구명을 위한 모델 시스템으로 이용할 수 있는 가능성을 제시하였다.

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해양용콘크리트의 초기강도 및 내염해 저항성 향상에 관한 실험적 연구 (An Experimental Study on the Improvement of Early Strength and Chloride Attack Resistance for Marine Concrete)

  • 이건호;김종백;배준영;서신석;조성현;노현승
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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    • pp.661-664
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    • 2008
  • 해양환경과 같이 특수한 환경에 위치한 구조물은 해수 및 염해 등에 의해 물리적 화학적 침식을받아 철근부식과 그 팽창압으로 인해 콘크리트 구조물의 성능저하가 가속화되고 있으며, 이러한 성능저하로 인해 콘크리트 구조물은 균열 박리되어 내구성이 현저히 저하된다. 이러한 염해대책으로는 염해침투를 억제하는 혼합시멘트를 사용하거나, 수화과정에서 염화물을 화학적으로 고정화 시키는 등의연구가 활발히 진행되고 있다. 따라서 본 연구에서는 고강도 혼합재가 첨가된 해양콘크리트의 특성을 검토하기 위하여 저발열 혼합시멘트에 고강도 혼합재(오메가2000)를 0, 5, 10, 15% 치환 첨가하여 해양콘크리트를 제조하였다. 제조한 해양콘크리트의 재령별 압축강도는 증가하는 경향을 나타내었으며, 재령에 따른 염소이온 침투저항성은 향상되는 것으로 나타났다.

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Investigation of the hydrogen production of the PACER fusion blanket integrated with Fe-Cl thermochemical water splitting cycle

  • Medine Ozkaya;Adem Acir;Senay Yalcin
    • Nuclear Engineering and Technology
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    • 제55권11호
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    • pp.4287-4294
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    • 2023
  • In order to meet the energy demand, energy production must be done continuously. Hydrogen seems to be the best alternative for this energy production, because it is both an environmentally friendly and renewable energy source. In this study, the hydrogen fuel production of the peaceful nuclear explosives (PACER) fusion blanket as the energy source integrated with Fe-Cl thermochemical water splitting cycle have been investigated. Firstly, neutronic analyzes of the PACER fusion blanket were performed. Necessary neutronic studies were performed in the Monte Carlo calculation method. Molten salt fuel has been considered mole-fractions of heavy metal salt (ThF4, UF4 and ThF4+UF4) by 2, 6 and 12 mol. % with Flibe as the main constituent. Secondly, potential of the hydrogen fuel production as a result of the neutronic evaluations of the PACER fusion blanket integrated with Fe-Cl thermochemical cycle have been performed. In these calculations, tritium breeding (TBR), energy multiplication factor (M), thermal power ratio (1 - 𝜓), total thermal power (Phpf) and mass flow rate of hydrogen (ṁH2) have been computed. As a results, the amount of the hydrogen production (ṁH2) have been obtained in the range of 232.24x106 kg/year and 345.79 x106 kg/year for the all mole-fractions of heavy metal salts using in the blanket.