• Title/Summary/Keyword: Iron(Fe)

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Investigation on Size Distribution of Tungsten-based Alloy Particles with Solvent Viscosity During Ultrasonic Ball Milling Process (초음파 볼밀링 공정에 의한 용매 점도 특성에 따른 텅스텐계 합금 분쇄 거동)

  • Ryu, KeunHyuk;So, HyeongSub;Yun, JiSeok;Kim, InHo;Lee, Kun-Jae
    • Journal of Powder Materials
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    • v.26 no.3
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    • pp.201-207
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    • 2019
  • Tungsten heavy alloys (W-Ni-Fe) play an important role in various industries because of their excellent mechanical properties, such as the excellent hardness of tungsten, low thermal expansion, corrosion resistance of nickel, and ductility of iron. In tungsten heavy alloys, tungsten nanoparticles allow the relatively low-temperature molding of high-melting-point tungsten and can improve densification. In this study, to improve the densification of tungsten heavy alloy, nanoparticles are manufactured by ultrasonic milling of metal oxide. The physical properties of the metal oxide and the solvent viscosity are selected as the main parameters. When the density is low and the Mohs hardness is high, the particle size distribution is relatively high. When the density is high and the Mohs hardness is low, the particle size distribution is relatively low. Additionally, the average particle size tends to decrease with increasing viscosity. Metal oxides prepared by ultrasonic milling in high-viscosity solvent show an average particle size of less than 300 nm based on the dynamic light scattering and scanning electron microscopy analysis. The effects of the physical properties of the metal oxide and the solvent viscosity on the pulverization are analyzed experimentally.

Physicochemical Properties of the Turmeric (Curcuma longa L.) in Jindo Korea (진도산 울금(Curcuma longa L.)의 이화학적 특성)

  • Oh, Da-Young;Kim, Han-Soo
    • Journal of Environmental Science International
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    • v.28 no.4
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    • pp.403-412
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    • 2019
  • Studies on the physicochemical properties of physiological activity substance in turmeric (Curcuma longa L.) were analyzed for the use as an functional food materialization. The proximate compositions in the vacuum freeze dried turmeric were carbohydrate 72.90%, moisture 5.74%, crude protein 10.02%, crude fat 4.67%, and crude ash 6.69%, respectively. The mineral contents of turmeric were calcium (Ca) $2,294.77mg\;kg^{-1}$, potassium (K) $28,780.54mg\;kg^{-1}$, magnesium (Mg) $2,826.90mg\;kg^{-1}$, sodium (Na) $1,826.58mg\;kg^{-1}$, iron (Fe) $190.94mg\;kg^{-1}$, and manganese (Mn) $620.16mg\;kg^{-1}$. The vitamin contents of turmeric were pantothenic acid 1.040 mg/100 g, riboflavin 0.166 mg/100 g, thiamin 0.148 mg/100 g, pyridoxine 0.010 mg/100 g, and calciferol 0.008 mg/100 g, respectively. Total amino acid contents in protein of turmeric were 7.66 g%, and major amino acids were aspartic acid 1.45 g%, glutamic acid 1.07 g%, leucine 0.71 g%, phenylalanine 0.47 g%, and arginine 0.46 g%, respectively. The amount of free amino acids of turmeric were 225.81 mg%, and major free amino acids were asparagine, aspartic acid, glutamic acid, serine, and alanine. Especially, in the case of asparagine, it was highest. The compositions of fatty acid were saturated fatty acid 45.09%, monoenes 8.62%, and polyenes 46.30%.

A Study on the Granulometry and Chemical Composition of Psudo-Gleized Soil in Jeongdongjin Area (정동진 의사글레이층의 입도와 화학 조성에 대한 연구)

  • Kim, Jong Yeon
    • Journal of The Geomorphological Association of Korea
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    • v.24 no.3
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    • pp.27-45
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    • 2017
  • At the upper part of terrace deposits at Jeongdongjin area, there is a structure in which reddish brown and grayish white layers laying horizontally. Previous studies have reported the existence of these structures within the deposits and suggested the theoretical background related to the formation process. However, the analysis of physical properties and chemical composition such as particle size, classification, etc. of the materials constituting the reddish brown and grayish white layers is scarcely done. In this study, the physico - chemical properties of gray - white and reddish brown beds are investigated. The mean grain size of the particles was less than $4{\varphi}$ in both layers and the reddish brown layer was more coarse. The results shows that the sorting of the grayish white layer is better. The chemical composition of both layers shows that the average concentration of $SiO_2$, $Al_2O_3$ and $K_2O$ of the grayish white layer was higher than those of the reddish brown layer. The concentration of $Fe_2O_3$ of reddish brown lyaer was 3 times higher than those of the grayish white layer. The degree of chemical weathering (CIA) is 90 or so in both the reddish brown and grayish white layers, indicating a significant level of chemical weathering. In conclusion, reddish brown layers had been formed by the processes related to the migration of iron and the migration of water that induced aggregation after the formation of sediments (psudo-gleization). In this study area, a vertical layer of grayish white which cuts off horizontal reddish brown and grayish white color was found. The vertical layer or wedge similar to a ice-wedge or columnar structure that in a cold environment, and there is a difference in shape and size. The vertical layer appears to have occurred three or more cycles. The vertical layers begin to form at a certain height within the outcrop and descend downwards, which of course is difficult to see as directing certain times.

Effects of an External Magnetic Field on the Magnetic Properties of Sputtered Magnetic Thin Films (스퍼터링 중 외부자기장이 자성박막의 자기적 특성에 미치는 영향)

  • Ahn, Hyun Tae;Lim, Sang Ho;Jee, Kwang Koo;Han, Jun Hyun
    • Korean Journal of Metals and Materials
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    • v.49 no.6
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    • pp.505-513
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    • 2011
  • A magnetic device which enables the application of a strong and uniform magnetic field to thin film during sputtering was designed for controlling the magnetic anisotropy using a three dimensional finite element method, and the effects of the external magnetic field on the magnetic properties of sputtered thin films were investigated. Both the intensity and the uniformity of the magnetic flux density in the sputter zone (50 mm ${\times}$50 mm) was dependent on not only the shape and size of the magnet device but also the magnitude of stray fields from the magnet. For the magnet device in which the distance between two magnets or two pure iron bars was 80-90 mm, the magnetic flux density along the direction normal to the external magnetic field direction was minimum. The two row magnets increased the magnetic flux density and uniformity along the external magnetic field direction. An Fe thin film sputtered using the optimized magnet device showed a higher remanence ratio than that fabricated under no external magnetic field.

Development of Amorphous Iron Based Coating Layer using High-velocity Oxygen Fuel (HVOF) Spraying (철계 비정질 분말을 활용한 초고속 용사 코팅층 개발)

  • Kim, Jungjoon;Kim, Song-Yi;Lee, Jong-Jae;Lee, Seok-Jae;Lim, Hyunkyu;Lee, Min-Ha;Kim, Hwi-Jun;Choi, Hyunjoo
    • Journal of Powder Materials
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    • v.28 no.6
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    • pp.483-490
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    • 2021
  • A new Fe-Cr-Mo-B-C amorphous alloy is designed, which offers high mechanical strength, corrosion resistance as well as high glass-forming ability and its gas-atomized amorphous powder is deposited on an ASTM A213-T91 steel substrate using the high-velocity oxygen fuel (HVOF) process. The hybrid coating layer, consisting of nanocrystalline and amorphous phases, exhibits strong bonding features with the substrate, without revealing significant pore formation. By the coating process, it is possible to obtain a dense structure in which pores are hardly observed not only inside the coating layer but also at the interface between the coating layer and the substrate. The coating layer exhibits good adhesive strength as well as good wear resistance, making it suitable for coating layers for biomass applications.

Effect of dietary salicylic acid supplementation on performance and blood metabolites of sows and their litters

  • Serge, Muhizi;Sungbo, Cho;Thanapal, Palanisamy;In Ho, Kim
    • Journal of Animal Science and Technology
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    • v.64 no.4
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    • pp.707-716
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    • 2022
  • The core intention to undertake this experiment for a period of 21 days is to evaluate the effect of salicylic acid (SA) supplemented diet on the performance and blood metabolites of sows and their litters. Sows weighing 208.5 ± 18.34kg and their neonates were used. From day 114 of gestation to 21st day of lactation(weaning), ten multiparous sows (n = 5/treatment) (Landrace × Yorkshire) were assigned randomly into one of two treatments: CON (basal diet) and TRT (CON + 0.05% SA). There was no significant difference in the body weight, backfat thickness, backfat loss, and body condition score in SA treated sows compared to sows fed the CON diet. However, the bodyweight of sow was dramatically reduced by an average of 16kg from farrowing to weaning time. The dietary inclusion of SA in the sow diet slightly improved the survival rate (p = 0.065) and showed a higher body weight (p = 0.009) in piglets. However, there was no significant difference in red blood cell, Fe, Hematocrit, and Hb concentrations between CON and TRT sows' groups, but the total iron-binding capacity (TIBC) was significantly reduced in sows from the TRT group compared with the CON group from the beginning to weaning. The outcome of this trial shows that dietary addition of SA on sows diet from early lactation could increase the birth weight and TIBC of neonates at the end of the trial.

Changes of Physical and Chemical Properties for Making Raw Materials and Reproductions According to Manufacturing Stages in Traditional Korean White Porcelain

  • Kim, Du Hyeon;Jeong, Ji Youn;Oh, Eun Jeong;Han, Min Su
    • Journal of Conservation Science
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    • v.38 no.4
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    • pp.301-313
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    • 2022
  • We made a Korean white porcelain or Joseon Baekja jar and based on the raw materials used and reproductions of each stage, we aimed to compare and analyze the physicochemical changes of the raw materials such as clay at each manufacturing stage, as well as identify the characteristics and correlations. Although the basic main components of clay and glaze material are similar, their texture becomes denser in the process of bisque firing pottery (Chobeol-pyeon) and glaze firing pottery (Jaebeol-pyeon), and we confirmed that in addition to the tendency of increasing vitrification, low-temperature minerals such as mica and illite gradually disappeared, while high-temperature minerals such as cristobalite were newly created. This phenomenon has also been verified by the rapid decrease in absorption rate while the change in specific gravity was small. In addition, the color was greatly affected by the firing atmosphere, and the yellow-red chromaticity of the raw materials was higher during bisque firing but showed a rapidly decreasing characteristic during glaze firing. The value of magnetic susceptibility, which is related to iron (Fe) component, showed a tendency to decrease in glaze firing pottery. CT images were confirmed as a method that can indirectly estimate the change in the material properties of the object step-by-step for the entire object. In conclusion, the study of manufacturing stages of reproduction can provide basic data for scientific research on the estimation of porcelain and pottery making technology and changes in raw materials.

Sources, Components, Structure, Catalytic Mechanism and Applications: a Critical Review on Nicotinate Dehydrogenase

  • Zhi Chen;Xiangjing Xu;Xin Ju;Lishi Yan;Liangzhi Li;Lin Yang
    • Journal of Microbiology and Biotechnology
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    • v.33 no.6
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    • pp.707-714
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    • 2023
  • Plant-derived insecticide-neonicotinoid insecticides (NIs) played a crucial role in the development of agriculture and food industry in recent years. Nevertheless, synthesis of these nitrogen-containing heterocyclic compounds with an effective and greener routing remains challenging especially to the notion raise of "green chemistry" and "atom economy". While bio-catalyzed methods mediated by nicotinate dehydrogenase (NDHase) then provide an alternative. The current review mainly focuses on the introduction of sources, components, structure, catalytic mechanism and applications of NDHase. Specifically, NDHase is known as nicotinic acid hydroxylase and the sources principally derived from phylum Proteobacteria. In addition, NDHase requires the participation of the electron respiratory chain system on the cell membrane. And the most important components of the electron respiratory chain are hydrogen carrier, which is mainly composed of iron-sulfur proteins (Fe-S), flavin dehydrogenase (FAD), molybdenum binding protein and cytochromes. Heterologous expression studies were hampered by the plasmid and host with high efficiency and currently only Pseudomonas entomophila L48 as well as Comamonas testosterone was successfully utilized for the expression of NDHase. Furthermore, it is speculated that the conjugate and inductive effects of the substituent group at position 3 of the substrate pyridine ring exerts a critical role in the hydroxylation reactions at position 6 concerning about the substrate molecular recognition mechanism. Finally, applications of NDHase are addressed in terms of pesticide industry and wastewater treatment. On conclusion, this critical review would not only deepen our understanding of the theory about NDHase, but also provides the guideline for future investigation of NDHase.

Evaluation of the Effect of Bank Protection Concrete Blocks on Water and Soil Environmental Impact (하천 호안 콘크리트 블록이 수질 및 토양환경에 미치는 영향평가)

  • Yoo Jae Hwan;Park Youn Shik;Shin Hyun Oh;Lee Goen Hee;Lee Bo Hyun;Cha Sang-Sun;Park Chan-Gi
    • Journal of The Korean Society of Agricultural Engineers
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    • v.65 no.1
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    • pp.51-59
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    • 2023
  • The study is to evaluate the effect of bank protection concrete block products to streams and soils. The effect on three types of bank protection concrete blocks was evaluated.. The first type was manufactured using fly ash, and the second and third type products used fine blast furnace slag powder. The laboratory and field Experiments test results showed the pHs of 9 or less. Also, any heavy metals were not detected in the heavy metal leaching tests. Although some iron (Fe) was partially detected, it still met the water quality standards. In addition, heavy metal was detected from all blocks by the US drinking water evaluation standards method. An on-site water quality and soil contamination tests were performed at the places that the blocks were implemented in practice. The test results showed that the application of the bank protection concrete block product did not lead to the water and soil quality degradation. Therefore, it was found that the hardened bank protection concrete block product did not elute harmful substances such as heavy metals that affect water and soil quality degradation.

The Effects of Drying Temperature on Chromate Treatment for Electroplated Zinc (전기 아연도금용 유색 크로메이트에 대한 건조 온도의 영향)

  • Su-Byung Jeon;Ji-Won Choi;Byung-Ki Son;Injoon Son
    • Journal of Surface Science and Engineering
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    • v.56 no.5
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    • pp.289-298
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    • 2023
  • In this study, the effect of drying temperature on characteristics of the trivalent chromate film on electroplated zinc was investigated. An zinc-electroplated iron specimen with a thickness of 5 ㎛ was used for chromate treatment. Chromate treatment was conducted in a solution diluted 10 times from a mixture of Cr(NO3)3·9H20 360 g/L, Co(NO3)2·6H2O 60 g/L, Na2SO4 60 g/L, NH4F·HF 25 g/L, and NaOH 20 g/L. The zinc electroplated specimen was treated using the chromate solution with pH 2.0 at 25 ℃ for 60 s. Subsequently, chromate-treated samples were dried in an electric furnace for 2h with temperature varied from 25 to 125 ℃. The corrosion rate increased with the increase in the drying temperature, and the surface morphology of the chromate-treated film was observed using FE-SEM. When the drying temperature changed, the color of the chromate film changed from green to yellow, and the thickness of the film changed from 362 to 241 nm, respectively. Additionally, corrosion resistance was evaluated via a salt spray test.