• Journal of Advanced Marine Engineering and Technology
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• v.32 no.5
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• pp.759-767
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• 2008

Bending deformation of an ionic polymer actuator(IPA) on applied low electric field across its thickness is dominated by electroosmosis of hydrated ions and self-diffusion of free water molecules. In the study by Popovic et al., two processes are assumed to occur sequentially in the way that fast electroosmosis is followed by self-diffusion and finite element formulation for the basic field equations are proposed. However the motions of hydrated ions and water molecules occur at the same time. In this study, those two processes are considered simultaneously and finite element formulation is conducted for the basic field equations governing electrochemical response of an IPA. Some numerical studies for IPA are carried out in order to show the validity of the present formulation.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.7 no.4
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• pp.24-30
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• 2008

The laminate IPMC actuator have been developed with a commercial Nafion film and platinum electrodes. Equivalent beam and equivalent bimorph beam models for IPMC(Ionic Polymer-Metal Composite) actuators are described. By using a beam equation with estimated physical properities and actuation displacements of a cantilevered IPMC actuator are estimated. And Finite element analysis(FEA) was done by ANSYS.

• Korean Journal of Soil Science and Fertilizer
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• v.38 no.5
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• pp.238-246
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• 2005

We conducted this investigation to observe competitive adsorption phenomena among the heavy metals onto the available sorption sites of soil particle surfaces in sandy clay loam and clay soil collected from Nonsan city, Chungnam and Yoosung, Daejeon in Korea, respectively. Polluted and contaminated soils can often contain more than one heavy metal species, resulting in competition for available sorption sites among heavy metals in soils due to complex competitive ion exchange and specific sorption mechanism. And the adsorption characteristics of the heavy metals were reported that the selectivity for the sorption sites was closely related with electropotential and electro negativity carried by the heavy metals. The heavy metals were treated as single, binary and ternary systems as bulk solution phase. Adsorption in multi-element system was different from single-element system as Cr, Pb and Cd. The adsorption isotherms showed the adsorption was increased with increasing equilibrium concentrations. For binary and ternary systems, the amount of adsorption at the same equilibrium concentration was influenced by the concentration of individual ionic species and valence carried by the respective heavy metal. Also we found that the adsorption isotherms of Cd and Pb selected in this experiment were closely related with electronegativity and ionic potential regardless number of heavy metals in solution, while the adsorption of Cr carried higher valance and lower electro negativity than Cd and Pb was higher than those of Cd and Pb, indicating that adsorption of Cr was influenced by ionic potential than by electronegativity. Therefore adsorption in multi-element system could be influenced by electronegativity and ionic potential and valance for the same valance metals and different valance, respectively. But it still needs further investigation with respect to ionic strength and activity in multi-element system to verify sorption characteristics and reaction processes of Cr, especially for ternary system in soils.

• Nuclear Engineering and Technology
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• v.54 no.5
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• pp.1616-1622
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• 2022

Selenium has been identified as an element of interest for the safety assessment of a deep geological repository (DGR) for used nuclear fuel. In Canada, groundwaters at DGR depths in sedimentary rocks have been observed to have a high ionic strength. This paper examines the sorption behavior of Se(-II) onto illite, MX-80 bentonite, Queenston shale, and argillaceous limestone in Na-Ca-Cl solutions of varying ionic strength (0.1-6 mol/kgw (m)) and across a pH range of 4-9. Little ionic strength dependence for Se(-II) sorption onto all solids was observed except that sorption at high ionic strength (6 m) was generally slightly lower than sorption at low ionic strength (0.1 m). Illite and MX-80 exhibited the expected results for anion sorption, while shale and limestone exhibited more constant sorption across the pH range tested. A non-electrostatic surface complexation model successfully predicted sorption of Se(-II) onto illite and MX-80 using the formation of an inner-sphere surface complex and an outer-sphere surface complex. Optimized values for the formation reactions of these surface species were proposed.

• Journal of Institute of Control, Robotics and Systems
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• v.10 no.11
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• pp.1012-1016
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• 2004

In the present paper, equivalent beam and equivalent bimorph beam models for IPMC(ionic Polymer-Metal Composite) actuators are described. Physical properties of an IPMC, such as Young's modulus and electro-mechanical coupling coefficient. are determined from the rule of mixture, bimorph beam equations, and measured force-displacement data of a cantilevered IPMC actuator. By using a beam equation with estimated physical properties, actuation displacements of a cantilevered IPMC actuator was calculated and a good agreement between the computed tip displacements and the measured data was observed. Finite element analysis(FEA) combined with the estimated physical properties was used to reproduce the force-displacement relationship of an IPMC actuator. Results from the FEA agreed well with the measure data. The proposed models might be used for modeling of IPMC actuators with complicated shapes and boundary conditions.

• Computers and Concrete
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• v.13 no.2
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• pp.149-171
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• 2014

This study presents the mathematical model for predicting chloride penetration into saturated concrete under non-isothermal condition. The model considers not only diffusion mechanism but also migration process of chloride ions and other chemical species in concrete pore solution such as sodium, potassium, and hydroxyl ions. The coupled multi-ionic transport in concrete is described by the Nernst-Planck equation associated with electro-neutrality condition. The coupling parameter taken into account the effect of temperature on ion diffusion obtained from available test data is proposed and explicitly incorporated in the governing equations. The coupled transport equations are solved using the finite element method. The numerical results are validated with available experimental data and the comparison shows a good agreement.

• Journal of Sensor Science and Technology
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• v.32 no.4
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• pp.252-256
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• 2023

A one-step method for nanoscale patterning of silver ionic ink on a substrate is developed using a microscale, elastic mold deformation. This method yields unique micro/nanoscale metallic structures that differ from those produced using the original molds. The linewidth of these metallic structures is significantly reduced (approximately 10 times) through the sidewall deformation of the original mold cavity on a thin liquid film, as verified by finite element analysis. The process facilitates the fabrication of various, isolated and complex micro/nanoscale metallic structures with negligible residual layers at low cost and high throughput. These structures can be utilized for various applications, including optoelectronics, wearable sensors, and metaverse-related devices. Our approach offers a promising tool for manipulation and fabrication of micro/nanoscale structures of various functional materials.

• Korean Journal of Soil Science and Fertilizer
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• v.34 no.3
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• pp.213-236
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• 2001

The ionic composition of soil solution is related to a nutrient uptake by plant. Many models for estimating ionic composition of solution have been developed, and most of them have been used for calculating a content of mineral and ionic species in a geochemical point of view. An approximation model considering both cation and anion in soil solution was developed. Variables such as pH, Eh, EC, cations(K, Ca, Mg. Na, Fe, Mn, Al, $NH_4{^+}$), anions(Si, S, P, CY, $NO_3{^-}$, $HCO_3{^-}$ and chemical equilibria of ionic species in soil solution were input into Excel sheet. The activities of soluble ion, ionpairs and complexes of input element were estimated by Newton-Raphson method using conditional equilibrium constant calculated by Davies equation and special models. Equilibrium contents of insoluble minerals and complexes were also calculated.

• Journal of Environmental Science International
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• v.30 no.6
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• pp.465-474
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• 2021

This research investigated the characteristics of fine particle concentration and ionic elements of PM_2.5 during sea breeze occurrences during summertime in Busan. The PM₁₀ and PM_2.5 concentrations of summertime sea breeze occurrence days in Busan were 46.5 ㎍/m³ and 34.9 ㎍/m³, respectively. The PM₁₀ and PM_2.5 concentrations of summertime non-sea breeze occurrence days in Busan were 25.3 ㎍/m³ and 14.3 ㎍/m³, respectively. The PM_2.5/PM₁₀ ratios of sea breeze occurrence days and non-sea breeze occurrence days were 0.74 and 0.55, respectively. The SO₄^2-, NH₄⁺, and NO₃^- concentrations in PM_2.5 of sea breeze occurrence days were 9.20 ㎍/m³, 4.26 ㎍/m³, and 3.18 ㎍/m³ respectively. The sulfur oxidation ratio (SOR) and nitrogen oxidation ratio (NOR) of sea breeze occurrence days were 0.33 and 0.05, respectively. These results indicated that understanding the fine particle concentration and ionic elements of PM_2.5 during sea breeze summertime conditions can provide insights useful for establishing a control strategy of urban air quality.

• Journal of Advanced Marine Engineering and Technology
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• v.34 no.3
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• pp.369-375
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• 2010

The two-dimensional finite element formulation for the basic field equations governing electrochemical responses of ionic conducting polymer-metal composite(IPMC) actuators is proposed in the present study. Biaxial deformation of a platinum plated Nafion actuator having 4 electrodes is dominated by electro-osmosis of hydrated ions and self-diffusion of free water molecules. Some numerical studies for IPMC actuators with electric field are carried out in order to show the validity of the proposed formulation and electric field analysis for the initial condition of total charge distribution are conducted using commercial code ANSYS/Emag.