• 한국정보통신학회논문지
• /
• 제10권1호
• /
• pp.111-116
• /
• 2006

본 연구에서는 비정질 실리콘 박막 트랜지스터를 스위칭소자로 포토센서를 구동 하는 방식의 이미지 센서를 구현하고자 한다. 먼저 PECVD(Plasma Enhanced Chemical Vapor Deposition) 진공 증착장비로 최적의 비정질실리콘 박막을 형성하고, 이 박막을 이용하여 스위칭소자인 박막트랜지스터와 광전변환소자인 광다이오드를 제조한다. 또한 이들을 결합하여 이미지 센서를 형성하고 그 특성 및 동작을 분석하고 최적의 동작특성을 이끌 수 있는 밀착이미지 센서를 제조한다. 제작한 이미지 센서를 측정한 결과 광전변환소자인 photodiode는 암전류의 경우 $\~10^{-l2}A$정도였으며, 광전류 $\~10^{-9}A$정도로서 Iphoto/Idark ${\ge}10^3$ 이상을 이루어 좋은 광전변환 특성을 갖고 있었다. 또한 a-Si:H TFT의 경우 Ioff ${\le}10^{-l2}A$, Ion ${\le}10^{-6}A$ 으로서 Ion/Ioff ${le}10^6$ 이상을 나타냈으며 Vth는 $2\~4$ volts였고, Id는 수 ${\mu}A$ 정도로 photodiode를 스위치하기에 충분한 전류-전압특성을 나타내고 있다. 이미지 센서 전체 동작 특성을 측정하기 위하여 photodiode의 ITO쪽에 -5volts의 역 bias를 가한 상태에서 TFT의 gate에 $70\;{\mu}sec$의 pulse를 가하여 photodiode에서 생성된 광전류 와 암전류를 측정하였다. 이렇게 하여 측정된 전압은 암상태에서 수십 mvolts이고, 광상태에서는 수백 mvolts로 나타나 우수한 이미지센서 특성을 갖고 있음을 확인하였다.

• 센서학회지
• /
• 제5권4호
• /
• pp.35-40
• /
• 1996

수소이온운반체로 HDBA(hexyldibenzylamine)나 HDPA(hexyldiphenylamine)을 이용하여 고분자막 pH 센서를 제작하였고, 온도 및 막의 두께 변화에 대한 전기화학적 특성을 연구하였다. HDPA를 이용한 센서는 수소이온에 대하여 선택적으로 감응하지 않았으며, HDBA를 이용한 센서는 pH 2 - pH 10 범위에서 수소이온에 대하여 선형적이고, 응답시간도 30 - 50초로 매우 빠르며, Nernstian 기울기는 53.6mV/pH을 나타내었다. pH 센서는 유리전극과 비교하여 알칼리금속과 알칼리토 금속이온에 대하여 방해를 적게 받았고, 재현성 및 안정성에 대한 편차는 2 - 4mV(${\pm}0.1mV$)로 우수하게 나타내었다.

• Bulletin of the Korean Chemical Society
• /
• 제25권10호
• /
• pp.1474-1476
• /
• 2004

A sodium ion- selective electrode based on dibenzopyridino-18-crown-6 as membrane carrier was successfully prepared. The electrode exhibits a Nernstian response for $Na^+$ ions within the concentration range of $1.0\;{\times}\;10^{-4}-1.0\;{\times}\;10^{-1}$ M. The response time of the sensor is 20 s. The sodium ion-selective electrode exhibited comparatively good selectivities with respect to alkali, alkaline earth and some transition metal ions.

• 한국분말재료학회지
• /
• 제30권4호
• /
• pp.310-317
• /
• 2023

Small-film-type ion sensors are garnering considerable interest in the fields of wearable healthcare and home-based monitoring systems. The performance of these sensors primarily relies on electrode capacitance, often employing nanocomposite materials composed of nano- and sub-micrometer particles. Traditional techniques for enhancing capacitance involve the creation of nanoparticles on film electrodes, which require cost-intensive and complex chemical synthesis processes, followed by additional coating optimization. In this study, we introduce a simple one-step electrochemical method for fabricating gold nanoparticles on a carbon nanotube (Au NP-CNT) electrode surface through cyclic voltammetry deposition. Furthermore, we assess the improvement in capacitance by distinguishing between the electrical double-layer capacitance and diffusion-controlled capacitance, thereby clarifying the principles underpinning the material design. The Au NP-CNT electrode maintains its stability and sensitivity for up to 50 d, signifying its potential for advanced ion sensing. Additionally, integration with a mobile wireless data system highlights the versatility of the sensor for health applications.

• Bulletin of the Korean Chemical Society
• /
• 제34권9호
• /
• pp.2577-2582
• /
• 2013

A novel stick-shaped portable sensing device featuring a microhole array interface between the polyvinylchloride-2-nitrophenyloctylether (PVC-NPOE) gel and water phase was developed for in-situ sensing of perchlorate ions in real water samples. Perchlorate sensitive sensing responses were obtained based on measuring the current changes with respect to the assisted transfer reaction of perchlorate ions by a perchlorate selective ligand namely, bis(dibenzoylmethanato)Ni(II) (Ni(DBM)2) across the polarized microhole array interface. Cyclic voltammetry was used to characterize the assisted transfer reaction of perchlorate ions by the $Ni(DBM)_2$ ligand when using the portable sensing device. The current response for the transfer of perchlorate anions by $Ni(DBM)_2$ across the micro-water/gel interface linearly increased as a function of the perchlorate ion concentration. The technique of differential pulse stripping voltammetry was also utilized to improve the sensitivity of the perchlorate anion detection down to 10 ppb. This was acquired by preconcentrating perchlorate anions in the gel layer by means of holding the ion transfer potential at 0 mV (vs. Ag/AgCl) for 30 s followed by stripping the complexed perchlorate ion with the ligand. The effect of various potential interfering anions on the perchlorate sensor was also investigated and showed an excellent selectivity over $Br^-$, $NO_2{^-}$, $NO_3{^-}$, $CO{_3}^{2^-}$, $CH_3COO^-$ and $SO{_4}^{2^-}$ ions. As a final demonstration, some regional water samples from the Sincheon river in Daegu city were analyzed and the data was verified with that of ion chromatography (IC) analysis from one of the Korean-certified water quality evaluation centers.

• 전기화학회지
• /
• 제5권4호
• /
• pp.212-215
• /
• 2002

A superoxide dismutase (SOD)-based superoxide ion $(O_2^-)$ sensor was fabricated by immobilizing SOD on a self-assembled monolayer (SAM) of 3-mercaptopropionic acid (MPA) which was prepared on a gold electrode. The SAM of MPA was found to function as an effective promoter for the electrode reaction of SOD. The amperometric response to $(O_2^-)$ was monitored at 300mV and -100mV vs. Ag/ Agel in 5mM phosphate buffer solution containing $KO_2$. The sensor was proved to have a high sensitivity, selectivity and short response time (<5 s) and negligible interference.

• EDISON SW 활용 경진대회 논문집
• /
• 제2회(2013년)
• /
• pp.77-88
• /
• 2013

The computational study on the fluoride ion binding with bis(bora)calix[4]arene has been performed using density functional theory and ONIOM model. The computed structure and fluorescent behavior of bis(bora)calix[4]arene was corresponded to experiment value. The binding energy for fluoride anion is computed to be 28.05kJ/mol in the chloroform solution. We also predicted that this sensing mechanism is only valid for fluoride ion in halogens. By analyzing molecular orbitals, binding with fluoride ion reduces energy differences between HOMO and LUMO, which leads to fluorescent sensing.

• Korean Chemical Engineering Research
• /
• 제61권3호
• /
• pp.463-471
• /
• 2023

Nitrogen-rich carbon dots (NDots) were synthesized by using uric acid as carbon and nitrogen sources. The as-synthesized NDots showed strong dual emissions at 420 nm and 510 nm with excitation at 350 nm and 460 nm, respectively. The physicochemical analyses such as X-ray photoelectron spectroscopy, Transmission electron microscopy and Fourier transform infrared spectroscopy were used to analyze the chemical, physical and morphological structures of NDots. The as-synthesized NDots exhibited wide linear range (0-100 µM) and very low detection limit (124 nM) in Ag⁺ ion sensing. In addition, Ag⁺ saturated NDots could be used as an EDTA sensor by the EDTA induced PL recovery.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
• /
• pp.846-850
• /
• 2003

Thin film $SnO_2$ Gas Sensor was fabricated by using ion beam sputtering and ultra thin film Pt catalyst of $45{\AA}$ was deposited on $SnO_2$ thin film. The effects of annealing temperature on the structural properies of $SnO_2$ were investigated using the X-ray diffraction. Using SEM, microstructures of thin film were investigated. The good gas sensitivity is shown when annealing condition is $650^{\circ}C$, 5hr and ultra thin film Pt catalyst thickness is $45{\AA}$.

• Bulletin of the Korean Chemical Society
• /
• 제34권10호
• /
• pp.3088-3092
• /
• 2013

A novel PVC membrane sensor for perindopril based on perindopril-phosphotungstate ion pair complex was prepared. The influence of membrane composition (i.e. percent of PVC, plasticizer, ion-pair complex, and kind of plasticizer), inner solution, pH of test solution and foreign cations on the electrode performance was investigated. The optimized membrane demonstrates Nernstian response ($30.9{\pm}1.0$ mV per decade) for perindopril cations over a wide linear range from $9.0{\times}10^{-7}$ to $1{\times}10^{-2}$ M at $25^{\circ}C$. The potentiometric response is independent of the pH in the range of 4.0-9.5. The proposed sensor has the advantages of easy preparation, fast response time. The selectivity coefficients indicate excellent selectivity for perindopril over many common cations (e.g., $Na^+$, $K^+$, $Mg^{2+}$, $Cu^{2+}$, $Ni^{2+}$, rhamnose, maltose, glycine and benzamide. The practical applications of this electrode was demonstrated by measuring the concentrations of perindopril in pure solutions and pharmaceutical preparations with satisfactory results.