• 제목/요약/키워드: Ion effect

검색결과 3,304건 처리시간 0.028초

혼화재 혼입 콘크리트의 염화물 침투저항성에 관한 실험적 연구 (Experimental Study on the Chloride Invasion Resistance Properties of Concrete Containing Mineral Admixtures)

  • 유재강;김동석;이상수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2003년도 학술.기술논문 발표회
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    • pp.43-48
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    • 2003
  • This paper investigate that the effect of the concrete containing mineral admixtures(pozzolanic materials such as fly-ash, ground granulated blast-furnace slag, silica fume and meta kaolin) on the resistance properties to chloride ion invasion. The purposed testing procedure was applied to the concrete added mineral admixtures for 3~4 replacement ratios under W/B ratios ranged from 0.40 to 0.55. For the electrical migration test, Tang and Nilsson's method was used to estimate the migration coefficient of chloride ion. As a results, the W/B ratios, kinds of admixture and replacement ratios, water curing periods had a great effect on the migration coefficient of chloride ion, and the optimal replacement ratios of admixture had a limitation for each admixtures. Also, the addition of mineral admixtures by mass(replacement of OPC) enhanced the resistance of the mixture to chloride penetration compared with the plain concrete. The amount of acid soluble chloride ions and water soluble chloride ions were varied with the kinds of mineral admixtures. The compressive strength was shown related to the migration coefficient of chloride ion, the compressive strength increased with the decreasing migration coefficient of chloride ion. Below the 50MPa, the variation of migration coefficient of concrete added mineral admixtures was bigger than plain concrete.

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혼화재 혼입 콘크리트의 염화물 침투저항성에 관한 실험적 연구 (Experimental Study on the Chloride Invasion Resistance Properties of Concrete Containing Mineral Admixtures)

  • 유재강;김동석;이상수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2003년도 학술.기술논문발표회
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    • pp.43-48
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    • 2003
  • This paper investigate that the effect of the concrete containing mineral admixtures(pozzaolanic materials such as fly-ash, ground granulated blast-furnace slag, silica fume and meta kaolin) on the resistance properties to chloride ion invasion. The purposed testing procedure was applied to the concrete added mineral admixtures for 3∼4 replacement ratios under W/B ratios ranged from 0.40 to 0.55. For the electrical migration test, Tang and Nilsson's method was used to estimate the migration coefficient of chloride ion. As a results, the W/B ratios, kinds of admixture and replacement ratios, water curing periods had a great effect on the migration coefficient of chloride ion, and the optimal replacement ratios of admixture had a limitation for each admixtures. Also, the addition of mineral admixtures by mass(replacement of OPC) enhanced the resistance of the mixture to chloride penetration compared with the plain concrete. The amount of acid soluble chloride ions and water soluble chloride ions were varied with the kinds of mineral admixtures. The compressive strength was shown related to the migration coefficient of chloride ion, the compressive strength increased with the decreasing migration coefficient of chloride ion. Below the 50MPa, the variation of migration coefficient of concrete added mineral admixtures was bigger than plain concrete.

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XPS STUDY ON THE EFFECT OF LOW-ENERGY ELECTRON IRRADIATION ON DNA DAMAGE BY Fe3+ ION

  • Noh, Hyung-Ah;Park, Yeun-Soo;Cho, Hyuck
    • Journal of Radiation Protection and Research
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    • 제40권2호
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    • pp.87-91
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    • 2015
  • We have employed X-ray photoelectron spectroscopy (XPS) technique to examine the combined effects of low-energy electron (LEE) irradiation and $Fe^{3+}$ ion on DNA damage. pBR322 plasmid DNA extracted from E. coli ER2420 was used for preparing DNA-$Fe^{3+}$ sample. The C1s XPS spectra were scanned for LEE-irradiated and LEE-unirradiated samples and then curve-fitted. For the samples with LEE irradiation only or with Fe ion only, no significant changes from pure DNA samples were observed - a single effect of either $Fe^{3+}$ ion or LEE irradiation did not cause a significant damage. However, when these two components were combined, the DNA damage was increased quite significantly, compared to the sum of DNA damages caused by $Fe^{3+}$ ion and by LEE irradiation independently. This observation is consistent with our previous results [Radiat. Res. 177, 775 (2012)] which was done using gel-electrophoresis technique. Partial interpretation of the observed spectrum peaks was also attempted.

Review of the Existing Relative Biological Effectiveness Models for Carbon Ion Beam Therapy

  • Kim, Yejin;Kim, Jinsung;Cho, Seungryong
    • 한국의학물리학회지:의학물리
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    • 제31권1호
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    • pp.1-7
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    • 2020
  • Hadron therapy, such as carbon and helium ions, is increasingly coming to the fore for the treatment of cancers. Such hadron therapy has several advantages over conventional radiotherapy using photons and electrons physically and clinically. These advantages are due to the different physical and biological characteristics of heavy ions including high linear energy transfer and Bragg peak, which lead to the reduced exit dose, lower normal tissue complication probability and the increased relative biological effectiveness (RBE). Despite the promising prospects on the carbon ion radiation therapy, it is in dispute with which bio-mathematical models to calculate the carbon ion RBE. The two most widely used models are local effect model and microdosimetric kinetic model, which are actively utilized in Europe and Japan respectively. Such selection on the RBE model is a crucial issue in that the dose prescription for planning differs according to the models. In this study, we aim to (i) introduce the concept of RBE, (ii) clarify the determinants of RBE, and (iii) compare the existing RBE models for carbon ion therapy.

Effect of LiCoO2 Cathode Density and Thickness on Electrochemical Performance of Lithium-Ion Batteries

  • Choi, Jaecheol;Son, Bongki;Ryou, Myung-Hyun;Kim, Sang Hern;Ko, Jang Myoun;Lee, Yong Min
    • Journal of Electrochemical Science and Technology
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    • 제4권1호
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    • pp.27-33
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    • 2013
  • The consequences of electrode density and thickness for electrochemical performance of lithium-ion cells are investigated using 2032-type coin half cells. While the cathode composition is maintained by 90:5:5 (wt.%) with $LiCoO_2$ active material, Super-P electric conductor and polyvinylidene fluoride polymeric binder, its density and thickness are independently controlled to 20, 35, 50 um and 1.5, 2.0, 2.5, 3.0, 3.5 g $cm^{-3}$, respectively, which are based on commercial lithium-ion battery cathode system. As the cathode thickness is increased in all densities, the rate capability and cycle life of lithium-ion cells become significantly worse. On the other hand, even though the cathode density shows similar behavior, its effect is not as high as the thickness in our experimental range. This trend is also investigated by cross-sectional morphology, porosity and electric conductivity of cathodes with different densities and thicknesses. This work suggests that the electrode density and thickness should be chosen properly and mentioned in detail in any kinds of research works.

Characteristics of a Titanium-oxide Layer Prepared by Plasma Electrolytic Oxidation for Hydrogen-ion Sensing

  • Lee, Do Kyung;Hwang, Deok Rok;Sohn, Young-Soo
    • 센서학회지
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    • 제28권2호
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    • pp.76-80
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    • 2019
  • The characteristics of a titanium oxide layer prepared using a plasma electrolytic oxidation (PEO) process were investigated, using an extended gate ion sensitive field effect transistor (EG-ISFET) to confirm the layer's capability to react with hydrogen ions. The surface morphology and element distribution of the PEO-processed titanium oxide were observed and analyzed using field-emission scanning-electron microscopy (FE-SEM) and energy-distribution spectroscopy (EDS). The titanium oxide prepared by the PEO process was utilized as a hydrogen-ion sensing membrane and an extended gate insulator. A commercially available n-channel enhancement MOS-FET (metal-oxide-semiconductor FET) played a role as a transducer. The responses of the PEO-processed titanium oxide to different pH solutions were analyzed. The output drain current was linearly related to the pH solutions in the range of pH 4 to pH 12. It was confirmed that the titanium-oxide layer prepared by the PEO process could feasibly be used as a hydrogen-ion-sensing membrane for EGFET measurements.

캘빈방전 효과를 이용한 초순수 및 전해이온수의 정전기 방전 연구 (A Study on Electrostatic Discharging in Ultrapure and Electrolyzed Waters Using Kelvin's Thunderstorm Effect)

  • 김형원;정윤원;최인식;최병선;최동현;유근걸
    • 반도체디스플레이기술학회지
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    • 제21권1호
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    • pp.5-11
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    • 2022
  • Despite the increasing importance of manufacturing and application R&D for ultrapure deionized water and electrolyzed ion water, various and systematic studies have not been conducted until now. In this study, the electrostatic discharge (ESD) behavior of electrolyzed ion water using a proton exchange membrane(PEM) was evaluated according to the type, flow rate, and bubble of electrolyzed ion water. In addition, by observing that Oxidation Reduction Potential (ORP) value returns to the unique value of electrolyzed ion water after electrostatic discharge, the possibility of two types of ions participating in electrostatic discharge ((H2O)n+ (assumed)) and ions for maintaining the characteristics of electrolyzed water could be inferred. In order to confirm the chemical structure and characteristics of the cations, in-depth research related to water molecular orbital energy or band gap should be followed.

지지막을 이용한 액막 추출기에 의한 합성해수 중의 $Sr^{2+}$ 이온 분리 (Separation of $Sr^{2+}$ Ion from Seawater by Liquid Membrane Permeator with Two Micro-Porous Films)

  • 주창식;이회근;정갑섭
    • 한국환경과학회지
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    • 제9권6호
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    • pp.517-522
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    • 2000
  • Separation of strontium ion from synthetic seawater in the contained liquid membrane permeator with two micro-porous films was performed. The permeator consisted of a liquid membrane and two cells for aqueous solutions. The liquid membrane consisted of $D_2EHPA(di-2-ethylhexy1-phosphoric acid)$ and DCH18C6 (dicyclohexano-18-crown-6),diluted to 30 vol% with kerosine and was trapped between two micro-porous hydrophilic films. This liquid membrane separated two aqueous solutions, one of which was synthetic seawater and the other of which was the stripping solutions consisting of 1mol/L $H_2SO_4$ solution. The effects of various operating parameters on the extraction rate and equilibrium extraction ratio of strontium ion from synthetic seawater were experimentally examined. The addition of DCH18C6 to the $D_2EHPA$ solution caused synergy effect on the extraction of strontium ion. The permeator extracted strontium ion from synthetic seawater effectively with high membrane life time.

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질소 이온주입법에 의한 BN 박막의 계면구조 개선 및 밀착력 향상 (Modification and adhesion improvement of BN interfacial layers by Post-N+ implantation)

  • 변응선;이성훈;이상로;이구현;한승희;이응직;윤재홍
    • 한국진공학회지
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    • 제8권2호
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    • pp.157-164
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    • 1999
  • The post ion implantation has been applied to modify early-grown BN layer and improve the adhesion of the BN films. The effect of ion implantation doses on microstructure and interlayer was investigated by FTIR and HRTEM. And the hardness and delamination life time of N+-implanted BN films were measured. With increasing the ion dose up to $5.0\times10^{15}\textrm{atoms/cm}^2$,the change of IR spectrum is observed. At $5.0\times10^{16}\textrm{atoms/cm}^2$, a drastic transition of cubic phase into hexagonal phase is detected. The change of microstructure of early-grown layers by ion implantation is confirmed using HRTEM. Both microhardness and delamination life time of BN films increase with ion dose. The modification model of early-grown BN layers is briefly discussed based on the displacement per atom and excess boron in the BN film induced by ion irradiation.

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Effect of Titanium-Ion on the Growth of Various Bacterial Species

  • Yu, Tae-Shick
    • Journal of Microbiology
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    • 제42권1호
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    • pp.47-50
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    • 2004
  • There are a number of studies that explain the metabolism and roles of metallic titanium and titanium-ion. One of the most intriguing results from these studies is the finding of metallic titanium having no bacteriostatic effects on oral bacterial species. In this research, the effects of titanium-ion on the growth of twenty-two bacterial species, some of which are commonly found in foods such as yoghurt, kimchi, and soy fermented products, were investigated. All but two bacteria, Escherichia coli and Pseudomonas aeruginosa appeared to be sensitive to titanium-ion. These two species were grown on 360 $\mu\textrm{g}$/$m\ell$ of titanium-ions, and they were found to be resistant to the titanium-ion. Both the wild-type and plasmid-cured E. coli showed good growth in a medium with 200 $\mu\textrm{g}$/$m\ell$ of titanium-ions. These results suggest that titanium-resistance was independent from the effects of the plasmid in E. coli.