• 제목/요약/키워드: Ion density

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원심분리기를 이용한 분말시료의 TEM용 시편 준비법 연구 (An Investigation of TEM Specimen Preparation Methods from Powders Using a Centrifuge)

  • 정종만;이영부;김윤중
    • Applied Microscopy
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    • 제29권1호
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    • pp.67-73
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    • 1999
  • 분말시료를 epoxy로 포매 (embedding)한 후 ion milling하는 방법으로 TEM 시편을 준비하는 경우에는 시료와 epoxy와의 milling정도의 차이 때문에 좋은 시편을 만들기 어렵다. 이러한 문제점을 극복하기 위해서 포매 물질에 대한 분말시료의 상대 밀도를 높여 주는 방법을 시도하였다. 일반적인 진공법보다는 원심분리기법을 이용하여 포매하는 것이 시료의 밀도를 높일 수 있었다. 또한, 비슷한 크기의 분말의 혼합보다는 서로 다른 크기의 분말을 혼합한 후 원심분리기를 이용하여 포매할 때, 큰 입자들 사이로 작은 입자들이 유입되면서 분말의 밀도가 더욱 높아지는 것을 알 수 있었다. 이렇게 준비된 시료는 ion milling정도의 차이에서 오는 문제점을 크게 줄일 수가 있어 TEM 관찰에 필요한 시편을 얻을 수 있었다. 원심분리기법은 마이크로미터 이하 크기의 구형, 판상 및 침상의 분말시료에서부터 TEM 시편을 준비하는 데에도 매우 효과적임이 드러났다.

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리튬 이온 전지용 리튬 코발트 산화물 양극에서의 삽입 전압과 리튬 이온 전도 (Intercalation Voltage and Lithium Ion Conduction in Lithium Cobalt Oxide Cathode for Lithium Ion Battery)

  • 김대현;김대희;서화일;김영철
    • 전기화학회지
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    • 제13권4호
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    • pp.290-294
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    • 2010
  • 본 연구는 밀도 범함수 이론을 이용하여 Li이온전지에 사용되는 Li코발트 산화물에서의 Li이온 삽입 전압과 전도에 관한 것이다. Li이온은 Li코발트 산화물 원자구조의 각 층을 1개씩 채우거나 한 층을 다 채우고 다음 층을 채울 수 있다. 평균 삽입 전압은 3.48V로 동일하나, 전자가 후자보다 더 유리하였다. 격자상수 c는 Li농도가 0.25보다 작을 때는 증가하였으나, 0.25보다 클 때는 감소하였다. Li농도가 증가하면, Li코발트 산화물에서의 Li이온 전도를 위한 에너지 장벽은 증가하였다. Li이온전지가 방전 중 출력 전압이 낮아지는 현상은 Li농도 증가에 따른 삽입 전압의 감소와 전도 에너지 장벽의 증가로 설명할 수 있었다.

Development and Testing of a Prototype Long Pulse Ion Source for the KSTAR Neutral Beam System

  • Chang Doo-Hee;Oh Byung-Hoon;Seo Chang-Seog
    • Nuclear Engineering and Technology
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    • 제36권4호
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    • pp.357-363
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    • 2004
  • A prototype long pulse ion source was developed, and the beam extraction experiments of the ion source were carried out at the Neutral Beam Test Stand (NBTS) of the Korea Superconducting Tokamak Advanced Research (KSTAR). The ion source consists of a magnetic bucket plasma generator, with multi-pole cusp fields, and a set of tetrode accelerators with circular apertures. Design requirements for the ion source were a 120kV/65A deuterium beam and a 300 s pulse length. Arc discharges of the plasma generator were controlled by using the emission-limited mode, in turn controlled by the applied heating voltage of the cathode filaments. Stable and efficient arc plasmas with a maximum arc power of 100 kW were produced using the constant power mode operation of an arc power supply. A maximum ion density of $8.3{\times}10^{11}\;cm^{-3}$ was obtained by using electrostatic probes, and an optimum arc efficiency of 0.46 A/kW was estimated. The accelerating and decelerating voltages were applied repeatedly, using the re-triggering mode operation of the high voltage switches during a beam pulse, when beam disruptions occurred. The decelerating voltage was always applied prior to the accelerating voltage, to suppress effectively the back-streaming electrons produced at the time of an initial beam formation, by the pre-programmed fast-switch control system. A maximum beam power of 0.9 MW (i.e. $70\;kV{\times}12.5\;A$) with hydrogen was measured for a pulse duration of 0.8 s. Optimum beam perveance, deduced from the ratio of the gradient grid current to the total beam current, was $0.7\;{\mu}perv$. Stable beams for a long pulse duration of $5{\sim}10\;s$ were tested at low accelerating voltages.

이온빔 조사 각도와 에너지강도에 의한 수직 배향막의 특성 분석 (Characteristic Analysis of Vertical Alignment by Ion-beam Irradiation Angle and Energy Density)

  • 강동훈;오병윤;김병용;한진우;김영환;옥철호;한정민;이상극;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.398-398
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    • 2007
  • The Liquid Crystal (LC) alignment uniformity is very important in LC devices. The alignment mechanism of LC molecules on a rubbed polyimide (PI) surface is very important for both LC fundamental research and application. So, Generally a rubbing method to align LC has been widely used to mass-produce LCD panels. But because rubbing method is contact method between rubbing fabric and indium-tin-oxide glass or flexible substrate, rubbing method has some defects, such as the electrode charges and the creation of contaminating particles. Thus we strongly recommend a non-contact alignment technique for getting rid of some defects of rubbing method. Most recently, the LC aligning capabilities achieved by ion-beam exposure on the organic and nonorganic thin film surface have been reported successfully. In this research, we studied the tilt angle generation and electro-optical performances for a NLC on homeotropic polyimide surfaces with ion-beam exposure. The LC aligning capabilities of a nematic liquid crystal (NLC) on a homeotropic PI surface using a new ion-beam method were studied. On the homeotropic PI surface, the tilt angle of the NLC by exposure ion-beam had a tendency to decrease as increased ion-beam energy density. And, on the homeotropic PI surface, the alignment character of the NLC with respect to ion-beam energy was good. And we achieved satisfactory result for EO character.

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Calculation on the Ion Flow Field under HVDC Transmission Lines Considering Wind Effects

  • Wu, Jing;Gao, Sheng;Liu, Yuxiao
    • Journal of Electrical Engineering and Technology
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    • 제10권5호
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    • pp.2077-2082
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    • 2015
  • Based on Deutsch assumption, a calculation method on the electric field over the ground surface under HVDC transmission lines in the wind is proposed. Analyzing the wind effects on the electric field and the space charge density the existing method based on Deutsch assumption is improved through adding the wind speed to the ion flow field equations. The programming details are illustrated. The calculation results at zero wind speed are compared with available data to validate the code program. Then the ionized fields which resulted from corona of ±800kV HVDC lines are analyzed. Both the electric field and the current density on the ground level are computed under different wind direction and speed. The computation results are in good agreement with measurements. The presented method and code program can be used to rapidly predict and evaluate the wind effects in HVDC transmission engineering.

리튬 이온 커패시터에서 마이크로파 조사에 의한 팽창 흑연의 전기화학적 특성 (Electrochemical Characteristics of Expanded Graphite by Microwave Irradiation in Lithium Ion Battery)

  • Seol, Sun-hwa;Park, Soo-gil;KIM, Han-Ju;Kim, Hong-il
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2014년도 추계학술대회 논문집
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    • pp.167-167
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    • 2014
  • Graphite is used as a negative electrode active material of Lithium ion capacitor (LIC). At the cathod, electrostatic reaction of EDLC is a very high reaction rate compared to a oxidaion reduction reaction. When the graphite was expanded that the length between the sheet, the intercalation of lithium ions is smoothed. And thus, the power density increases. By measuring the XRD, it was confirmed that the increase in interlayer spacing of graphite. And by measuring an electrochemical reactionin Lithium Ion Battery (LIB), it was confirmed the tendency of power density is improved.

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Simulation of a Dually Excited Capacitively Coupled RF Plasma

  • Kim, Heon-Chang;Sul, Yong-Tae;Park, Sung-Jin
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.I
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    • pp.513-514
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    • 2005
  • In plasma processing reactors, it is common practice to control plasma density and ion bombardment energy by manipulating excitation voltage and frequency. In this paper, a dually excited capacitively coupled rf plasma reactor is self-consistently simulated with a three moment model. Effects of phase differences between primary and secondary voltage waves, simultaneously modulated at various combination of commensurate frequencies, on plasma properties are investigated. The simulation results show that plasma potential and density as well as primary self-dc bias are nearly unaffected by the phase lag between the primary and the secondary voltage waves. The results also show that, with the secondary frequency substantially lower than the primary frequency, secondary self-dc bias remains constant regardless of the phase lag. As the secondary frequency approaches to the primary frequency, however, the secondary self-dc bias becomes greatly altered by the phase lag, and so does the ion bombardment energy at the secondary electrode. These results demonstrate that ion bombardment energy can be more carefully controlled through plasma simulation.

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Effects of Phase Difference between Voltage loaves Applied to Primary and Secondary Electrodes in Dual Radio Frequency Plasma Chamber

  • Kim, Heon-Chang
    • 반도체디스플레이기술학회지
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    • 제4권2호
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    • pp.11-14
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    • 2005
  • In plasma processing reactors, it is common practice to control plasma density and ion bombardment energy by manipulating excitation voltage and frequency. In this paper, a dually excited capacitively coupled rf plasma reactor is self-consistently simulated with a three moment model. Effects of phase differences between primary and secondary voltage waves, simultaneously modulated at various combinations of commensurate frequencies, on plasma properties are investigated. The simulation results show that plasma potential and density as well as primary self-dc bias are nearly unaffected by the phase lag between the primary and the secondary voltage waves. The results also show that, with the secondary frequency substantially lower than the primary frequency, secondary self·do bias remains constant regardless of the phase lag. As the secondary frequency approaches to the primary frequency, however, the secondary self-dc bias becomes greatly altered by the phase lag, and so does the ion bombardment energy at the secondary electrode. These results demonstrate that ion bombardment energy can be more carefully controlled through plasma simulation.

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Quantum chemical investigations on bis(bora)calix[4]arene: a fluorescent fluoride sensor

  • Jin, Jae Hyeok;Lee, Yoon Sup
    • EDISON SW 활용 경진대회 논문집
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    • 제2회(2013년)
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    • pp.77-88
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    • 2013
  • The computational study on the fluoride ion binding with bis(bora)calix[4]arene has been performed using density functional theory and ONIOM model. The computed structure and fluorescent behavior of bis(bora)calix[4]arene was corresponded to experiment value. The binding energy for fluoride anion is computed to be 28.05kJ/mol in the chloroform solution. We also predicted that this sensing mechanism is only valid for fluoride ion in halogens. By analyzing molecular orbitals, binding with fluoride ion reduces energy differences between HOMO and LUMO, which leads to fluorescent sensing.

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Investigation of the Driving Frequency Effect on the RF-Driven Atmospheric Pressure Micro Dielectric Barrier Discharges

  • Bae, Hyowon;Lee, Jung Yeol;Lee, Hae June
    • Applied Science and Convergence Technology
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    • 제26권4호
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    • pp.74-78
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    • 2017
  • The discharge characteristics of the radio frequency (RF) surface dielectric barrier discharge have been simulated for the investigation of the ratio of the ion transit time to the RF period. From one-dimensional particle-in-cell (PIC) simulation for a planar dielectric barrier discharge (DBD), it was observed that the high-frequency driving voltage confines the ions in the plasma because of a shorter RF period than the ion transit time. For two-dimensional surface dielectric barrier discharges, a fluid simulation is performed to investigate the characteristics of RF discharges from 1 MHz to 40 MHz. The ratio of the peak density to the average density decreases with the increasing frequency, and the spatiotemporal discharge patterns change abruptly with the change in the ratio of ion transit time to the RF period.