• Title/Summary/Keyword: Ion components

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Tunable Dielectric Properties and Curie Temperature with BST Thick Films (BST 후막의 가변 유전특성과 큐리온도에 관한 연구)

  • Kim In-Sung;Song Jae-Sung;Min Bok-Ki;Jeon So-Hyun
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.8
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    • pp.392-398
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    • 2006
  • The properties of tunable dielectric materials on RF frequency band are important high tunability and low loss for RF variable devices, variable capacitor, phased array antenna and other components application. Various composite of BST(barium strontium titanate) ratio combined with other non-electrical active oxide ceramics have been formulated for such uses. We present the tunable properties and Curie temperature on BST thick films. The grain growth of the weight ratio of $BaTiO_3$ increased. This can be explained by the substitute $Sr^{2+}$ ion for $Ba^{2+}$ ion in the $BaTiO_3$ system. The Curie temperature was shifted to lower temperature with increasing $SrTiO_3$in the $BaTiO_3-SrTiO_3$ system, because of decreasing the lattice constant. Also, the dielectric constant, tunability and K-factor of $(Ba_xSr_{1-x})TiO_3$ at over the Curie temperature decreased, at over the $60^{\circ}C$ fixation, maximum dielectric constant at Curie temperature and hence sharper phase transformation occurred at Curie temperature. The result were interpreted as a process of internal stress relaxation resulting form the increase of $90^{\circ}$ domains induced the BST. As a result, It is concluded that over the Curie temperature, frequency response and DC field effect for the tunable properties of BST thick film are suppressed by the transition broadening. For the application of tunable devices, that the curie temperature was investigated to be increased.

Seasonal Variations of Acdity and Chemicstry of Precipitation in Iksan Area (익산지역 강수의 계절별 산성도와 화학성상)

  • 강공언;오인교;김희강
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.4
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    • pp.393-402
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    • 1999
  • Precipitation samples were collected by the wet-only sampling method in Iksan in the northwest of Chonbuk from March 1995 to February 1997. These samples were analyzed for the concentration of ion components, in addition to pH and electrical conductivity. The annual mean pH of precipitation was 4.8 and the seasonal trend of pH was shown to be low in Fall and Winter(4.5), middle-ranged in Spring(4.7) and high in Summer(5.0). The frequency of pH below 5.6 was about 71%. The seasonal pattern of pH frequency was found to be different in each season. In the case of the pH less than 5.0, the frequency was higher in Spring, Fall and Winter than in Summer, especially higher in Fall than in other seasons. The concentrations of analysed ions showed a pronounced seasonal pattern. However, major ion species for all seasons were $NH^+_4,;Ca^{2+};and;Na^+$ among cations and $SO^{2-}_4,;Cl^-;and;NO^-_3$ among anions. The major acidifying species appeared to be $nss-SO^{2-}_4;and;NO^-_3$, and the main bases responsible for the neutralization of precipitation acidity were $nss-Ca^{2+};and;NH^+_4$. The potential acidity of precipitation, pAi, was found to be between 3.0 and 5.0 for total samples, while the measured pH was approximately between 3.9 and 7.8. The seasonal trend of pAi showed a decreasing order: Summer (4.3), Winter(4.0), Spring and Fall(3.8). During the Fall, both pAi and pH were especially very low, which indicated that during this period the potential acidity of precipitation was high but the neutralizing capacity was low. For Spring, pAi was very low but pH was slightly high. This was likely due to the large amount of $CaCO_3$ in the soil particles transported over a long range from the Chinese continent that were incorporated into the precipitation, and then neutralized the acidifying species with its high concentraton.

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Model-Based Analysis of the $ZrO_2$ Etching Mechanism in Inductively Coupled $BCl_3$/Ar and $BCl_3/CHF_3$/Ar Plasmas

  • Kim, Man-Su;Min, Nam-Ki;Yun, Sun-Jin;Lee, Hyun-Woo;Efremov, Alexander M.;Kwon, Kwang-Ho
    • ETRI Journal
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    • v.30 no.3
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    • pp.383-393
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    • 2008
  • The etching mechanism of $ZrO_2$ thin films and etch selectivity over some materials in both $BCl_3$/Ar and $BCl_3/CHF_3$/Ar plasmas are investigated using a combination of experimental and modeling methods. To obtain the data on plasma composition and fluxes of active species, global (0-dimensional) plasma models are developed with Langmuir probe diagnostics data. In $BCl_3$/Ar plasma, changes in gas mixing ratio result in non-linear changes of both densities and fluxes for Cl, $BCl_2$, and ${BCl_2}^+$. In this work, it is shown that the non-monotonic behavior of the $ZrO_2$ etch rate as a function of the $BCl_3$/Ar mixing ratio could be related to the ion-assisted etch mechanism and the ion-flux-limited etch regime. The addition of up to 33% $CHF_3$ to the $BCl_3$-rich $BCl_3$Ar plasma does not influence the $ZrO_2$ etch rate, but it non-monotonically changes the etch rates of both Si and $SiO_2$. The last effect can probably be associated with the corresponding behavior of the F atom density.

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Concentration Characteristics of Airborne Hexavalent Chromium in the Industrial Area (산업단지 대기 중 6가 크롬 농도 특성에 관한 연구)

  • Kang, Byung-Wook;Han, Jin-Seok;Lee, Min-Do;Lee, Hak-Sung;Kim, Jong-Ho;Son, Eun-Seong;Baek, Sung-Ok
    • Journal of Korean Society for Atmospheric Environment
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    • v.25 no.3
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    • pp.179-187
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    • 2009
  • This paper describes the field evaluation of a sampling and analytical method for the quantity of airborne hexavalent chromium ($Cr^{6+}$) in the industrial areas, such as Sihwa and Banwol. Ambient measurements were performed by using the cellulose filter during the four seasons (October 2006 to June 2007). The determination of hexavalent chromium was carried out by ion chromatography. Performance validations, including method detection limit, relative standard deviation, and recovery percent, were also investigated. The mean concentrations of $Cr^{6+}$ in Sihwa and Banwol were 0.767 and 0.796 $ng/m^3$, respectively, which are similar to those of other foreign industrial areas. The seasonal variations of $Cr^{6+}$ levels were not quite different, which implies that the chromium was continuously emitted from the industrial sources throughout the year. The concentration variations between total chromium and $Cr^{6+}$ have also shown the similar pattern, suggesting that these components originate from the same sources. The concentration of $Cr^{6+}$ was found to be 0.7 to 2.4% of the total chromium. From these results, the approach using the cellulose filter may be suitable to collect $Cr^{6+}$ in the ambient air.

Analysis of Influence of Environmental Conditions on Ganoderic Acid Content: in Ganoderma lucidum Using Orthogonal Design

  • Li Na;Liu Xiao Hua;Zhou Jie;Li Yu Xiang;Zhao Ming Wen
    • Journal of Microbiology and Biotechnology
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    • v.16 no.12
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    • pp.1940-1946
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    • 2006
  • The influence of environmental conditions on the ganoderic acid (GA) content in the fungus Ganoderma lucidum was investigated using a one-factor-at-a-time design and orthogonal design. Among the various medium components examined, sucrose, soybean powder or peptone, ferrous sulfate, and pH 6.0 were the most suitable carbon source (factor A), nitrogen source (factor B), mineral source (factor C), and initial pH (factor D), respectively, for the GA content in the one-factor-at-a-time design. According to the orthogonal design, the order of effect for the four factors on the GA content was A>C>D>B. The best level of factor A was $A_2$ (sucrose) with a value of +0.34 mg/100 mg DW. The optimal treatment combination was $A_2B_1C_3D_1$ with which the GA content reached up to 2.63$\pm$0.011 mg/100 mg DW. The interactions between the mineral ion and the nitrogen source, and the mineral ion and the pH were both highly significant (P<0.01). The highest interaction effect was ($B_2{\times}D_2$) with a value of +0.19 mg/100 mg DW, which was higher than the level effect value for $B_2$ (peptone) and D$_2$ (pH 5.0). Therefore, the results proved that interactions between factors cannot be ignored. The results also indicated the importance of the interactions between the factors, which may help to understand the metabolic pathway leading to triterpene biosynthesis and the expression and regulation of the key enzymes involved.

Production of Monoclonal Antibody to Polychlorinated Biphenyl Induced Cytochrome P-450 LMII in Rat Liver (Polychlorinated Biphenyl에 의한 백서간 Cytochrome P-$450_{LMII}$에 대한 Monoclonal Antibody 생성에 관한 연구)

  • Kim, Jung-Hye;Kim, Jae-Ryong;Lee, Ki-Yung
    • Journal of Yeungnam Medical Science
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    • v.3 no.1
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    • pp.103-110
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    • 1986
  • Cytochrome P-450(CP-450) is one of the three components of the liver microsomal enzyme system which hydroxylates fatty acids, hydrocarbons and a variety of drugs and other foreign compounds. Female Balb/c mice were immunized with purified polychlorinated bipheny(PCB)-induced CP-450 LMII. The spleen cells derived from immunized mice were fused with $SP^2$ myeloma cells using polyethylene glycol(PEG 3500). The hybrid cells were selected by hypoxanthine-aminopterine and thymidine(HAT) medium and the culture fluid were screened by enzyme-linked immunosorbent assay to CP450 LMII. The hybrid cess(${\times}10^7$) were innoculated into intraperitoneal cavity of Balb/c mice for the purpose of production of ascitic fluids. Monoclonal antibody(Mab) was purified from ascitic fluid by DEAE cellulose ion exchange chromatography and $I^{125}$-labeled Mab was also confirmed by autoradiography and SDS-polyacrylamide gel electrophoresis (MW : 55,000 and 110,000).

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Comparison of methods for proanthocyanidin extraction from pine (Pinus densiflora) needles and biological activities of the extracts

  • Kim, Nam-Young;Jang, Min-Kyung;Lee, Dong-Geun;Yu, Ki-Hwan;Jang, Hye-Ji;Kim, Mi-Hyang;Kim, Sung-Gu;Yoo, Byung-Hong;Lee, Sang-Hyeon
    • Nutrition Research and Practice
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    • v.4 no.1
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    • pp.16-22
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    • 2010
  • Flavonoids are known to be effective scavengers of free radicals. In particular, proanthocyanidins are flavonoids that possess cardiovascular protection, antioxidative activities, and immunomodulatory activities. Here, we evaluated proanthocyanidin contents in the total polyphenolic compounds of pine needle extracts prepared by hot water, ethanol, hexane, hot water-hexane (HWH), and hot water-ethanol (HWE). Analysis of each extract indicated that the ethanol extract contained the highest proanthocyanidin concentration. The HWH and hexane extracts also contained relatively high concentrations of proanthocyanidin. On the other hand, proanthocyanidin content analyses out of the total polyphenolic compounds indicated that the HWH extract contained the highest content. These results suggest that HWH extraction is a suitable method to obtain an extract with a high level of pure proanthocyanidins and a relatively high yield. The HWH extract possessed superior activity in diverse antioxidative analyses such as 2,2-diphenyl-1-picrylhydrazyl (DPPH), ferrous ion chelating (FIC), and ferric-ion reducing power (FRAP) assays. In addition, upon assessing the effects of the pine needle extracts on macrophages (Raw 264.7 cell), the HWH extract exhibited the highest activity. In this study, we discerned an efficient extraction method to achieve relatively pure proanthocyanidins from pine needles and evaluated the biological functions of the resulting extract, which could potentially be used for its efficacious components in functional food products.

Relationship between Cholesterol and Oxidative Potential from Meat Cooking (고기구이 초미세먼지 내 콜레스테롤 및 산화 잠재력과의 관계)

  • Lee, Yongmin;Kim, Eunyoung;Ryu, Chunho;Oh, Sea-Ho;Joo, Hungsoo;Bae, Min-Suk
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.5
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    • pp.639-650
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    • 2018
  • Identification of the major sources contributing to PM is of importance in order to understand their quantitative contributions to atmosphere. In the viewpoint of the meat cooking in Korea, only a few analyses of organic molecular markers have been conducted due to analytical difficulties. In this study, ten different parts of meat (i.e., blade shoulder, belly, and arm shoulder of pork; ribeye roll, top blade muscle, and short plate of beef; leg quarter, breast, and wing of chicken; duck; mackerel) were pyrolyzed to generate the cooked PM using an electronic heating plate. Generated PM were collected by the pyrolysis sampling system to identify total carbon (TC) using a carbon analyzer and cholesterol using a Liquid chromatography tandem-mass spectrometry (LC-MSMS) based on fragmentor voltage (FV), precursor ion, collision energy, product ion. In addition, oxydative potential (OP) analysis using dithiothreitol (DTT) method were discussed to investigate the toxicity relates. Highly correlated pairwise scatterplots between the cholesterol and TC indicate that oxydative potential was highly associated with different parts of meat. This study provides insight into the meat cooking components of PM, which could be drivers of the oxidative potential relates.

A Study on the Metallic and Ion Elements by Fine Particle and Effects of Vessels Exhaust Emission in Busan City (부산지역의 미세먼지 중 중금속 및 이온성분과 선박배출가스의 영향에 관한 연구)

  • Lee, Seung-Won;Son, Yi-Seul;Kim, Jung-Kwon
    • Journal of Environmental Science International
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    • v.20 no.1
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    • pp.147-153
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    • 2011
  • The objectives of this study were to investigate the seasonal characteristics of metallic and ion elements of $PM_{10}$(Particulate matter with aerodynamic diameter ${\leq}10\;{\mu}m$) and the effects of vessels exhaust emission from ships harboring in Busan City. The $PM_{10}$ samples were collected from January 2010 to October 2010 at Dongsam-dong(coastal area), in Busan City. The particulate matters were analyzed for major water soluble ionic components and metals. The ranges of the $PM_{10}$ mass concentrations were from 29.8 ${\mu}g/m^3$ to 47.0 ${\mu}g/m^3$ in Dongsam-dong. The $PM_{10}$ mass concentrations in Dongsam-dong are very similar to Gwangbok-dong during same sampling periods. These results were understood by the effects of the shipping source emitted from ships anchoraging and running. The concentrations of water-soluble ions and metals in the $PM_{10}$ had a level of as high as the order of $SO_4^{2-}$>$NO_3^-$>$Cl^-$ and $NH_4^+$>$Na^+$>$Ca^{2+}$>$K^+$>$Mg^{2+}$, respectively. The correlation coefficients($R^2$) for $SO_4^{2-}/PM_{10}$ and $NH_4^+/PM_{10}$ of were 0.7446 and 0.7784, respectively, and it showed the high correlation with each other.

Determination of Lipid A Profile of Gram-Negative Bacteria from Arctic Soils Using Mass Spectrometric Approaches (질량분석 시스템을 이용한 극지 토양 유래 신규 미생물의 지질 A 화학적 구조 분석)

  • Hwang, Cheol-hwan;Park, Han-Gyu;Kim, Yun-Gon
    • KSBB Journal
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    • v.31 no.4
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    • pp.263-269
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    • 2016
  • For decades, the microorganisms in arctic soils have been newly discovered according to the climate change and global warming. In this study, the chemical structure of a lipid A molecule from Pseudomonas sp. strain PAMC 28615 which was newly discovered from arctic soils was characterized by mass spectrometric approaches such as matrix-assisted laser desorption/ionization time-of-flight (MALDI-TOF) and MALDI multi-stage tandem mass spectrometry (MS). First, lipopolysaccharide (LPS) from Pseudomonas sp. strain PAMC 28615 was extracted and subsequently hydrolyzed to obtain the lipid A. The parent ion peak at m/z 1632 was determined by MALDI-TOF MS, which also can validate our lipid A purification method. For detailed structural determination, we performed the multiple-stage tandem mass analysis ($MS^4$) of the parent ion, and subsequently the abundant fragment ions in each MS stage are tested. The fragment ions in each MS stage were produced from the loss of phosphate groups and fatty acyl groups, which could be used to confirm the composition or the position of the lipid A components. Consequently, the mass spectrometry-based lipid A profiling method could provide the detail chemical structure of lipid A from the Pseudomonas sp. strain PAMC 28615 as an arctic bacterium from the frozen arctic soil.