• Title/Summary/Keyword: Ion Composition

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Preparation and Characterization of Water-Soluble Glass through Melting Process (I) : Dissolution Characteristics, Bactericidal Effects and Cytotoxicity (용융법에 의한 수용성 유리의 제조 및 특성 (I) : 용해 특성, 살균 효과 및 세포 독성)

  • 조종호;이용근;최세영;신철수;김경남
    • Journal of the Korean Ceramic Society
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    • v.32 no.10
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    • pp.1093-1102
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    • 1995
  • Water-soluble phosphate glasses containing Ag or Cu ion were prepared through melting process. Then the powdered glass samples were dissolved in D.I. water at room temperature with changing the dissolution time. In terms with the glass composition, dissolution characteristics, bactericidal effects and cytotoxicities were investigated. Dissolved amounts increased uniformly with dissolution time, and the dissolution rate was higher for ternary glass than for binary glass and with less metal oxide amount. And the dissolution rate of the glass with Ag ion was higher than that with Cu ion, and the bactericidal effect of the glass with Ag ion was also greater. Solution with more than 25 ppm of Ag was observed to have strong cytotoxicity to L929, and solutions of lower Ag concentration or with Cu seemed to have little cytotoxicity.

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Evaluation of 0ff-gas Characteristics in Vitrification Process of ion-Exchange Resin

  • Park, S. C.;Kim, H. S.;K. H. Yang;C. H. Yun;T. W. Hwang;S. W. Shin
    • Nuclear Engineering and Technology
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    • v.33 no.1
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    • pp.83-92
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    • 2001
  • The properties of off-gas generated from vitrification process of ion-exchange resin were characterized. Theoretical composition and flow rate of the off-gas were calculated based on chemical composition of resin and it's burning condition inside CCM. The calculated off-gas flow rate was 67.9Nm$^3$/h at the burning rate of 40kg/h. And the composition of off-gas was avaluated as $CO_2$(41.4%), steam(40.0%), $O_2$(13.3%), NO(3.6%), and SO$_2$(1.6%) in order. Then, actual flow rate and composition of off-gas were measured during pilot-scale demonstration tests and the results were compared with theoretical values. The actual flow rate of off-gas was about 1.6 times higher than theoretical one. The difference between theoretical and actual flow rates was caused by the in-leakage of air to the system, and the in-leakage rate was evaluated as 36.3Nm$^3$/h. Because of continuous change in the combustion parameters inside CCM, during demonstration tests, the concentration of toxic gases showed wide fluctuation. However, the concentration of CO, a barometer of incompleteness of combustion inside CCM, was stabilized soon. The result showed quasi-equilibrium state was achieved two hours after feeding of resin.

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A Study on the Transition Characteristics of Precipitation Components in Dangjin and Anmyon-do Area (唐津과 安眠島地域 降水 成分의 變化特性에 關한 硏究)

  • Chung, Jin-Do;Lee, Choun-Ho
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.5
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    • pp.593-601
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    • 2004
  • In this study, we are going to compare the chemical composition of the precipitation that falls in the Dangjin and Anmyon-do areas by analyzing the water soluble components (anion and cation). We also examined the effects of seasonal change and regional difference in those data sets. The [$NO_3\;^- \;+\;SO_4\;^{2-}$] at 49.2${\mu}$eq/l is 67% of the total anion of 73.1${\mu}$eq/l, while that of [$NH_4\;^+\;+\;Ca^{2+}$] at 37.7${\mu}$eq/l is 62% of the cation in Dangjin area. Also, the [$NO_3\;^-\;+\;SO_4\;^{2-}$] concentration of 151.8 (${\mu}$eq/l) is 62% for the total anion of 143.5 (${\mu}$eq/l), and the [$NH_4\;^+\;+\;Ca^{2+}$] concentration of 119.7 (${\mu}$eq/l) is 47% for the cation of 254.3 (${\mu}$eq/l) in Anmyon-do area. The ion composition ratio is shown for the order by 22% of $SO_4\;^{2-}$, 20.8% of $NH_4\;^+$ and 15.4% of $Cl^-$ that is the sum of 58.7% for the total ion composition in Dangjin area, and is the order by 33.8% of $NH_4\;^+$, 16.3% of $SO_4\;^{2-}$ and 11.1% of $Cl^-$ in Anmyon-do area. Furthermore, We predicted that even areas which were previously clean will get acid rain if there is large scale construction there or nearby.

Investigation of Ge2Sb2Te5 Etching Damage by Halogen Plasmas (할로겐 플라즈마에 의한 Ge2Sb2Te5 식각 데미지 연구)

  • Jang, Yun Chang;Yoo, Chan Young;Ryu, Sangwon;Kwon, Ji Won;Kim, Gon Ho
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.4
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    • pp.35-39
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    • 2019
  • Effect of Ge2Sb2Te5 (GST) chalcogen composition on plasma induced damage was investigated by using Ar ions and F radicals. Experiments were carried out with three different modes; the physical etching, the chemical etching, and the ion-enhanced chemical etching mode. For the physical etching by Ar ions, the sputtering yield was obtained according to ion bombarding energy and there was no change in GST composition ratio. In the plasma mode, the lowest etch rate was measured at the same applied power and there was also no plasma induced damage. In the ion-enhanced chemical etching conditions irradiated with high energy ions and F halogen radicals, the GST composition ratio was changed according to the density of F radicals, resulting in higher roughness of the etched surface. The change of GST composition ratio in halogen plasma is caused by the volatility difference of GST-halogen compounds with high energy ions over than the activation energy of surface reactions.

Acrylic Polymer Composition Suitable for Ion Delivery and Selective Detection of Proton, and Hydroxyl and Cu(II) Ions (이온 이동에 적합한 아크릴고분자 박막의 조성과 수소이온, 수산화이온, 구리이온의 선택적 검출)

  • Lee, Dahye;Woo, Heejung;Do, Jung Yun
    • Polymer(Korea)
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    • v.38 no.6
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    • pp.801-808
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    • 2014
  • Ion diffusion and chemical binding to acrylic polymer were investigated in a solid film. The composition of acrylic monomers containing amino group and carboxylic acid was adjusted for rapid ion migration in the film. p-Methylred (PMR) and phenolphthalein derivatives were optically sensitive to the concentration of proton and hydroxyl anion, respectively and verified the ion migration through the film layers. A rapid proton migration was observed in the film of a high amino content. On the other hand, $OH^-$ migration occurred rapidly in a high content of carboxylic acid group. The proton migration occurred through the internal layer as well as surface layer of a film and was reversible during 50 repetition examination. Copper(II) ion migration was examined with a Rhodamine-containing polymer film. The light absorption and emission spectra of a Rhodamine-Cu complex showed the key contribution of carboxylic acid group to the Cu(II) migration in a film.

The Influence of Oxygen on Czochralski Growth of Oxide Single Crystals

  • D. S. Chung;Park, B. H.
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.06a
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    • pp.179-181
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    • 1997
  • When grown the oxide single crystal including Li-ion, optimum oxygen condition is needed. Color and crack are caused in single crystal according too the change in the condition of the oxygen. LiTaO₃ crystals grown from off-composition of congruent melt composition under oxygen deficieny condition didn't generate any crack. LiNbO₃. LiTaO₃ crystals grown from congruent melt composition under optimum oxygen condition caused pale yellow color or colorless with no crack. Color gradually became colorless and generated cracks according to Oxygen excess.

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Strategy for Prevention of Weakly Flocculating Characters in Bottom Brewing Yeast Strains

  • Cheong, Chul;Wackerbauer, Karl;Kang, Soon-Ah
    • Food Science and Biotechnology
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    • v.17 no.3
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    • pp.558-563
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    • 2008
  • To prevent weakly flocculating characters of bottom brewing yeast during first fermentation, various technical investigations were carried out using strain of Saccharomyces cerevisiae. It appeared that the propagation at $10^{\circ}C$ promoted the molecular structure and biochemical composition of cell wall in favor of flocculation. The yeast grown at $20^{\circ}C$ by addition of zinc ion also had a stimulating effect on flocculation behavior during first fermentation cycle. The zinc ion did not influence directly on the changes of cell wall in favor of stronger flocculence. The increased fermentation activity of yeast due to addition zinc ion was rather responsible for the intensified flocculation capacity. It was concluded that the weakly flocculating characters of bottom brewing yeast during first fermentation can be solved by using yeast propagated at $10^{\circ}C$ or by means of yeast by addition of zinc ion during propagation.

Voltammetric Determination of Ag(I) ion using Carbon Paste Electrode Modified with $Ph_2O_2S_3$ ($Ph_2O_2S_3$로 변성된 탄소반죽전극에 의한 Ag(I) 이온의 전압-전류법적 정량)

  • Lee, Ihn Chong
    • Analytical Science and Technology
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    • v.12 no.2
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    • pp.171-175
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    • 1999
  • Carbon paste electrodes, modified with podands containing more than two sulfur atoms, have been employed for the voltammetric determination of Ag(I) ion from aqueous solution. The voltammetric response was characterized with respect to paste composition, preconcentration method, kind of anion, variation of pH, Ag(I) ion concentration, and possible interferences. Linear calibration curves were obtained for Ag(I) ion concentration ranging from $1.0{\times}10^{-6}$ to $9.0{\times}10^{-5}M$, and detection limit was $5.0{\times}10^{-7}M$.

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Voltammetric Determination of Ag(I) ion with Carbon Paste Electrode Modified with Macrocyclic Ligand Containing Oxygen and Nitrogen as Ligating Atoms (주게원자로 산소와 질소를 포함하는 거대고리 리간드로 변성된 탄소반죽전극에 의한 Ag(I) 이온의 전압-전류법적 정량)

  • Lee, Ihn Chong
    • Analytical Science and Technology
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    • v.15 no.1
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    • pp.91-95
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    • 2002
  • Carbon paste electrodes, modified with 5,6,14,15-dibenzo-1,4-dioxa-8,12-diazacyclopentadeca-5,14-diene containing different ligating atoms of oxygen and nitrogen, have been employed for the voltammetric determination of Ag(I) ion from aqueous solution. The voltammetric response was characterized with respect to paste composition, preconcentration method, kind of anion, variation of pH, Ag(I) ion concentration, and possible interferences. Linear calibration curves were obtained for Ag(I) ion concentration ranging from $3.0{\times}10^{-6}M$ to $8.0{\times}10^{-5}M$, and detection limit was $8.5{\times}10^{-7}M$.