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http://dx.doi.org/10.7317/pk.2014.38.6.801

Acrylic Polymer Composition Suitable for Ion Delivery and Selective Detection of Proton, and Hydroxyl and Cu(II) Ions  

Lee, Dahye (Department of Chemistry Education, Pusan National University)
Woo, Heejung (Department of Chemistry Education, Pusan National University)
Do, Jung Yun (Department of Chemistry Education, Pusan National University)
Publication Information
Polymer(Korea) / v.38, no.6, 2014 , pp. 801-808 More about this Journal
Abstract
Ion diffusion and chemical binding to acrylic polymer were investigated in a solid film. The composition of acrylic monomers containing amino group and carboxylic acid was adjusted for rapid ion migration in the film. p-Methylred (PMR) and phenolphthalein derivatives were optically sensitive to the concentration of proton and hydroxyl anion, respectively and verified the ion migration through the film layers. A rapid proton migration was observed in the film of a high amino content. On the other hand, $OH^-$ migration occurred rapidly in a high content of carboxylic acid group. The proton migration occurred through the internal layer as well as surface layer of a film and was reversible during 50 repetition examination. Copper(II) ion migration was examined with a Rhodamine-containing polymer film. The light absorption and emission spectra of a Rhodamine-Cu complex showed the key contribution of carboxylic acid group to the Cu(II) migration in a film.
Keywords
proton transfer in polymer film; UV-polymerizaion; p-methylred; rhodamine; copper(II) ion detection;
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