• Title/Summary/Keyword: Interphase design

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Effect of Interphase Modulus and Nanofiller Agglomeration on the Tensile Modulus of Graphite Nanoplatelets and Carbon Nanotube Reinforced Polypropylene Nanocomposites

  • Karevan, Mehdi;Pucha, Raghuram V.;Bhuiyan, Md.A.;Kalaitzidou, Kyriaki
    • Carbon letters
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    • v.11 no.4
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    • pp.325-331
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    • 2010
  • This study investigates the effect of filler content (wt%), presence of interphase and agglomerates on the effective Young's modulus of polypropylene (PP) based nanocomposites reinforced with exfoliated graphite nanoplatelets ($xGnP^{TM}$) and carbon nanotubes (CNTs). The Young's modulus of the composites is determined using tensile testing based on ASTM D638. The reinforcement/polymer interphase is characterized in terms of width and mechanical properties using atomic force microscopy which is also used to investigate the presence and size of agglomerates. It is found that the interphase has an average width of ~30 nm and modulus in the range of 5 to 12 GPa. The Halpin-Tsai micromechanical model is modified to account for the effect of interphase and filler agglomerates and the model predictions for the effective modulus of the composites are compared to the experimental data. The presented results highlight the need of considering various experimentally observed filler characteristics such as agglomerate size and aspect ratio and presence and properties of interphase in the micromechanical models in order to develop better design tools to fabricate multifunctional polymer nanocomposites with engineered properties.

A Modular UPS Design with an Active Multiple Interphase Reactor and Double PLL Control (능동 다중인터페이스 리액터와 Double PLL제어를 이용한 Modular UPS 설계)

  • 박인덕;정상식;안형회;김시경
    • The Transactions of the Korean Institute of Power Electronics
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    • v.6 no.6
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    • pp.489-497
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    • 2001
  • The proposed dobule phase locked loop and active multiple interphase reactor are used to eliminate the circular current and the voltage ripples caused by the system parameter unbalance of parallel connected UPSs. In this paper, digital controller for the dobule PLL and active interphase reactor is implemented with ADSP21061 as an aspect of functional convenience.

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Harmonic Reduction of Parallel-Connected Thyristor Rectifiers with an Active Interphase Reactor

  • Choi, Sewan;Oh, Junyong;Kim, Kiyong
    • Proceedings of the KIPE Conference
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    • 1998.10a
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    • pp.276-280
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    • 1998
  • This paper proposes a harmonic a harmonic reduction technique of the parallel-connected twelve-pulse thyristor rectifiers. The proposed system is an improvement over the diode rectifier system with an active interphase reactor [2]. In this scheme, a low KVA (0.15 Po (PU) ) active current source injects a triangular current into an interphase reactor of a twelve-pulse thyristor rectifier along the phase delay angle. The current injection results in near sinusoidal input current with less than 1% THD. Detailed analysis of the proposed scheme along scheme along with design equations is illustrated. Simulation results verify the concept.

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Research Progress in SiC-Based Ceramic Matrix Composites

  • Dong, Shaoming;Wang, Zhen;Zhou, Haijun;Kan, Yan-Mei;Zhang, Xiangyu;Ding, Yusheng;Gao, Le;Wu, Bin;Hu, Jianbao
    • Journal of the Korean Ceramic Society
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    • v.49 no.4
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    • pp.295-300
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    • 2012
  • SiC-based ceramic matrix composites show many advantages over their monolithic ceramic counterparts, which makes them potential candidates for applications in various fields. Depending strongly on the chemical composition and microstructure of the fiber reinforcement, matrix as well as the fiber/matrix interphase in the material, the properties of ceramic matrix composites(CMCs) are highly tailorable. In this paper, the latest progresses in the interphase design, matrix modification and fiber reinforcement decoration of CMCs are reviewed, their effects on the properties of the CMCs are introduced.

Numerical Analysis of Plume Characteristics and Liquid Circulation in Gas Injection Through a Porous Plug

  • Choi, Choeng-Ryul;Kim, Chang-Nyung
    • Journal of Mechanical Science and Technology
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    • v.14 no.12
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    • pp.1365-1375
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    • 2000
  • Two phase flows have been numerically calculated to analyze plume characteristics and liquid circulation in gas injection through a porous plug. The Eulerian approach has been for formulation of both the continuous and dispersed phases. The turbulence in the liquid phase has been modeled using the standard $textsc{k}$-$\varepsilon$ turbulence model. The interphase friction coefficient has been calculated using correlations available in the literature. The turbulent dispersion of the phase has been modeled by the "dispersion Prand시 number". The predicted mean flows is compared well with the experimental data. The plume region area and the axial velocities are increased with the gas flow rate and with the decrease in the inlet area. The turbulent intensity also shows the same trend. Also, the space-averaged turbulent kinetic energy for various gas flow rates and inlet areas has been obtained. The results are of interest in the design and operation of a wide variety of materials and chemical processing operations.

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Solid-Electrolyte Interphase in the Spinel Cathode Exposed to Carbonate Electrolyte in Li-Ion Battery Application: An ab-initio Study

  • Choe, Dae-Hyeon;Gang, Jun-Hui;Han, Byeong-Chan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.169-169
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    • 2017
  • Due to key roles for the electrochemical stability and charge capacity the solid-electrolyte interphase (SEI) has been extensively studied in anodes of a Li-ion battery cell. There is, however, few of investigation for cathodes. Using first-principles based calculations we describe atomic-level process of the SEI layer formation at the interface of a carbonate electrolyte and $LiMn_2O_4$ spinel cathode. Furthermore, using beyond the conventional density functional theory (DFT+U) calculations we examine the work function of the cathode and frontier orbitals of the electrolyte. Based on the results we propose that proton transfer at the interface is an essential mechanism initiating the SEI layer formation in the $LiMn_2O_4$. Our results can guide a design concept for stable and high capacity Li-ion battery cell through screening an optimum electrolyte fine-tuned energy band alignment for a given cathode.

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A Modular U.P.S Design with Multiple Interphase Reactor and Double PLL Control (다중인터페이스 리액터와 Double PLL제어를 이용한 Modular U.P.S 설계)

  • Park In-Duck;Jeung Sang-Sik;Kim Si-Kyung
    • Proceedings of the KIPE Conference
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    • 2001.07a
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    • pp.506-509
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    • 2001
  • A high power U.P.S system utilizing the parallel connection of low power U.P.S is developed. For the purpose of elimination the circular current between U.P.S.s, a digital circuit is employed. Furthermore a double phase synchronization and an interphase reactor are used to eliminate the circular current and the voltage ripples caused by the system parameter unbalances of parall connected U.P.S.s. The digital controller is implemented with ADSP21061 as aspect of a functional convenience.

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First-principles Study on the Formation of Solid-Electrolyte Interphase on the LiMn2O4 Cathode in Li-Ion Batteries (제일원리 전산모사를 통한 리튬 이온 전지의 LiMn2O4 전극-전해질 계면 반응 분석)

  • Choe, Dae-Hyeon;Gang, Jun-Hui;Han, Byeong-Chan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.97-97
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    • 2016
  • Development of advanced Li-ion battery cells with high durability is critical for safe operation, especially in applications to electric vehicles and portable electronic devices. Understanding fundamental mechanism on the formation of a solid-electrolyte interphase (SEI) layer, which plays a substantial role in the electrochemical stability of the Li-ion battery, in a cathode was rarely reported unlike in an anode. Using first-principles density functional theory (DFT) calculations and ab-initio molecular dynamic (AIMD) simulations we demonstrate atomic-level process on the generation of the SEI layer at the interface of a carbonate-based electrolyte and a spinel $LiMn_2O_4$ cathode. To accomplish the object we calculate the energy band alignment between the work function of the cathode and frontier orbitals of the electrolyte. We figure out that a proton abstraction from the carbonate-based electrolyte is a critical step for the initiation of an SEI layer formation. Our results can provide a design concept for stable Li-ion batteries by optimizing electrolytes to form proper SEI layers.

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A Study on the Prediction of Elastoplastic Behavior of Carbon Nanotube/Polymer Composites (계면 결합력과 나노튜브의 응집에 따른 나노튜브/고분자 복합재의 탄소성 거동 예측에 대한 연구)

  • Yang, Seunghwa;Yu, Suyoung;Ryu, Junghyun;Cho, Maenghyo
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.26 no.6
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    • pp.423-430
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    • 2013
  • In this research, a paramteric study to account for the effect of interfacial strength and nanotube agglomeration on the elastoplastic behavior of carbon nanotube reinforced polypropylene composites is performed. At first, the elastoplastic behavior of nanocomposites is predicted from molecular dynamics(MD) simulations. By combining the MD simulation results with the nonlinear micromechanics model based on the Mori-Tanaka model, a two-step domain decomposition method is applied to inversely identify the elastoplastic behavior of adsorption interphase zone inside nanocomposites. In nonlinear micromechanics model, the secant moduli method combined with field fluctuation method is used to predict the elastoplastic behavior of nanocomposites. To account for the imperfect material interface between nanotube and matrix polymer, displacement discontinuity condition is applied to the micromechanics model. Using the elastoplastic behavior of the adsorption interphase zone obtained from the present study, stress-strain relation of nanocomposites at various interfacial bonding condition and local nanotube agglomeration is predicted from nonlinear micromechanics model with and without the adsorption interphase zone. As a result, it has been found that local nanotube agglomeration is the most important design factor to maximize reinforcing effect of nanotube in elastic and plastic behavior.

Chromosome Analysis in Clinical Samples by Chromosome Diagnostic System Using Fluorescence in Situ Hybridization (국산 Fluorescence in Situ Hybridization 시스템을 이용한 다양한 검체에서의 염색체 분석)

  • Moon, Shin-Yong;Pang, Myung-Geol;Oh, Sun-Kyung;Ryu, Buom-Yong;Hwang, Do-Yeong;Jung, Byeong-Jun;Choe, Jin;Sohn, Cherl;Chang, Jun-Keun;Kim, Jong-Won;Kim, Seok-Hyun;Choi, Young-Min
    • Clinical and Experimental Reproductive Medicine
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    • v.24 no.3
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    • pp.335-340
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    • 1997
  • Fluorescence in situ hybridization (FISH) techniques allow the enumeration of chromosome abnormalities and from a great potential for many clinical applications. In order to produce quantitative and reproducible results, expensive tools such as a cooled CCD camera and a computer software are required. We have developed a Chromosome Image Processing System (Chips) using FISH that allows the detection and mapping of the genetic aberrations. The aim of our study, therefore, is to evaluate the capabilities of our original system using a black-and-white video camera. As a model system, three repetitive DNA probes (D18Z1, DXZ1, and DYZ3) were hybridized to variety different clinical samples such as human metaphase spreads and interphase nuclei obtained from uncultured peripheral blood lymphocytes, uncultured amniocytes, and germ cells. The visualization of the FISH signals was performed using our system for image acquisition and pseudocoloring. FISH images were obtained by combining images from each of probes and DAPI counterstain captured separately. Using our original system, the aberrations of single or multiple chromosomes in a single hybridization experiment using chromosomes and interphase nuclei from a variety of cell types, including lymphocytes, amniocytes, sperm, and biopsied blastomeres, were enabled to evaluate. There were no differences in the image quality in accordance with FISH method, fluorochrome types, or different clinical samples. Always bright signals were detected using our system. Our system also yielded constant results. Our Chips would permit a level of performance of FISH analysis on metaphase chromosomes and interphase nuclei with unparalleled capabilities. Thus, it would be useful for clinical purposes.

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