• Title/Summary/Keyword: Internal Layer

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Bi-layer Electrolyte for Preventing Solid Oxide Fuel Cell Stack Degradation (고체산화물 연료전지 스택 열화 방지를 위한 전해질 기술)

  • Park, Mi Young;Bae, Hongyeul;Lim, Hyung-Tae
    • Journal of the Korean Ceramic Society
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    • v.51 no.4
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    • pp.289-294
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    • 2014
  • The stability of a solid oxide fuel cell (SOFC) stack is strongly dependent on the magnitude and profile of the internal chemical potential of the solid electrolyte. If the internal partial pressure is too high, the electrolyte can be delaminated from the electrodes. The formation of high internal pressure is attributed to a negative cell voltage, and this phenomenon can occur in a bad cell (with higher resistance) in a stack. This fact implies that the internal chemical potential plays an important role in determining the lifetime of a stack. In the present work, we fabricate planar type anode-supported cells ($25cm^2$) with a bi-layer electrolyte (with locally increased electronic conduction at the anode side) to prevent high internal pressure, and we test the fabricated cells under a negative voltage condition. The results indicate that the addition of electronic conduction in the electrolyte can effectively depress internal pressure and improve the cell stability.

DEM analysis of the anisotropy effects on the failure mechanism of the layered concretes' specimens with internal notches

  • Jinwei Fu;Vahab Sarfarazi;Hadi Haeri;Mohammad Fatehi Marji
    • Computers and Concrete
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    • v.33 no.6
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    • pp.659-670
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    • 2024
  • The mechanical behaviour of layered concrete samples containing an internal crack was numerically studied by modelling the geo-mechanical specimens in the particle flow code in two dimensions (PFC2D). The numerical modelling software was calibrated with the experimental results of the Brazilian tensile strengths gained from the laboratory disc-type specimens. Then, the samples with the bedding layers and internal notch were numerically simulated with PFC2D under uniaxial compressive loading. In each specimen, the layers' thickness was 10 mm but the layer's inclination angle was changed to 0°, 30°, 60°, 90°, 120° and 150°. Of course, the layers'interfaces are considered to have very low strengths. The internal notch was kept at 3 cm in length however, its inclination angle was changed to 0°, 40°, 60° and 90°. Therefore, a total, of 24 numerical models were made to study the failure mechanism of the layered concrete samples. Considering these results, it has been concluded that the inclination angles of both internal crack and bedding layers affect the failure mechanism and uniaxial compressive strength of the concrete.

Fitting accuracy of ceramic veneered Co-Cr crowns produced by different manufacturing processes

  • von Maltzahn, Nadine Freifrau;Bernhard, Florian;Kohorst, Philipp
    • The Journal of Advanced Prosthodontics
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    • v.12 no.2
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    • pp.100-106
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    • 2020
  • PURPOSE. The purpose of this in vitro study was to evaluate the fitting accuracy of single crowns made from a novel presintered Co-Cr alloy prepared with a computer-aided design and computer-aided manufacturing (CAD/CAM) technique, as compared with crowns manufactured by other digital and the conventional casting technique. Additionally, the influence of oxide layer on the fitting accuracy of specimens was tested. MATERIALS AND METHODS. A total of 40 test specimens made from Co-Cr alloy were investigated according to the fitting accuracy using a replica technique. Four different methods processing different materials were used for the manufacture of the crown copings (milling of presintered (Ceramill Sintron-group_cer_sin) or rigid alloy (Tizian NEM-group_ti_nem), selective laser melting (Ceramill NPL-group_cer_npl), and casting (Girobond NB-group_gir_nb)). The specimens were adapted to a resin model and the outer surfaces were airborne-particle abraded with aluminum oxide. After the veneering process, the fitting accuracy (absolute marginal discrepancy and internal gap) was evaluated by the replica technique in 2 steps, before removing the oxide layer from the intaglio surface of the crowns, and after removing the layer with aluminum oxide airborne-particle abrasion. Statistical analysis was performed by multifactorial analysis of variance (ANOVA) (α=.05). RESULTS. Mean absolute marginal discrepancy ranged between 20 ㎛ (group_cer_npl for specimens of Ceramill NPL) and 43 ㎛ (group_cer_sin for crowns of Ceramill Sintron) with the oxide layer and between 19 ㎛ and 28 ㎛ without the oxide layer. The internal gap varied between 33 ㎛ (group_ti_nem for test samples of Tizian NEM) and 75 ㎛ (group_gir_nb for the base material Girobond NB) with the oxide layer and between 30 ㎛ and 76 ㎛ without the oxide layer. The absolute marginal discrepancy and the internal gap were significantly influenced by the fabrication method used (P<.05). CONCLUSION. Different manufacturing techniques had a significant influence on the fitting accuracy of single crowns made from Co-Cr alloys. However, all tested crowns showed a clinically acceptable absolute marginal discrepancy and internal gap with and without oxide layer and could be recommended under clinical considerations. Especially, the new system Ceramill Sintron showed acceptable values of fitting accuracy so it can be suggested in routine clinical work.

Evolution of Wind Storm over Coastal Complex Terrain (연안복합지형에서 바람폭풍의 진화)

  • Choi, Hyo;Seo, Jang-Won;Nam, Jae-Cheol
    • Journal of Environmental Science International
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    • v.11 no.9
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    • pp.865-880
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    • 2002
  • As prevailing synoptic scale westerly wind blowing over high steep Mt. Taegulyang in the west of Kangnung coastal city toward the Sea of Japan became downslope wind and easterly upslope wind combined with both valley wind and sea breeze(valley-sea breeze) also blew from the sea toward the top of the mountain, two different kinds of wind regimes confronted each other in the mid of eastern slope of the mountain and further downward motion of downlsope wind along the eastern slope of the mountain should be prohibited by the upslope wind. Then, the upslope wind away from the eastern slope of the mountain went up to 1700m height over the ground, becoming an easterly return flow in the upper level of the sea. Two kinds of circulations were detected with a small one in the coastal sea and a large one from the coast toward the open sea. Convective boundary layer was developed with a thickness of about 1km over the ground in the upwind side of the mountain in the west, while a thickness of thermal internal boundary layer(TIBL) form the coast along the eastern slope of the mountain was only confined to less than 200m. After sunset, under no prohibition of upslope wind, westerly downslope wind blew from the top of the mountain toward the coastal basin and the downslope wind should be intensified by both mountain wind and land breeze(mountain-land breeze) induced by nighttime radiative cooling of the ground surfaces, resulting in the formation of downslope wind storm. The wind storm caused the development of internal gravity waves with hydraulic jump motion bounding up toward the upper level of the sea in the coastal plain and relatively moderate wind on the sea.

Development of multi-cell flows in the three-layered configuration of oxide layer and their influence on the reactor vessel heating

  • Bae, Ji-Won;Chung, Bum-Jin
    • Nuclear Engineering and Technology
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    • v.51 no.4
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    • pp.996-1007
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    • 2019
  • We investigated the influence of the aspect ratio (H/R) of the oxide layer on the reactor vessel heating in three-layer configuration. Based on the analogy between heat and mass transfers, we performed mass transfer experiments to achieve high Rayleigh numbers ranging from $6.70{\times}10^{10}$ to $7.84{\times}10^{12}$. Two-dimensional (2-D) semi-circular apparatuses having the internal heat source were used whose surfaces of top, bottom and side simulate the interfaces of the oxide layer with the light metal layer, the heavy metal layer, and the reactor vessel, respectively. Multi-cell flow pattern was identified when the H/R was reduced to 0.47 or less, which promoted the downward heat transfer from the oxide layer and possibly mitigated the focusing effect at the upper metallic layer. The top boundary condition greatly affected the natural convection of the oxide layer due to the presence of secondary flows underneath the cold light metal layer.

The Effect of Quantum Well Structure on the Characteristics of GaN-based Light-Emitting Diode (양자 우물 구조가 GaN 기반 LED 특성에 미치는 영향)

  • Lee, Jae-Hyun;Yeom, Keesoo
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2012.10a
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    • pp.251-254
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    • 2012
  • In this paper, the output characteristics of GaN-based LED considering quantum well structure are analyzed. The basic structure of the LED consists of active region of GaN barrier and InGaN quantum well between AlGaN EBL(Electron Blocking Layer) and AlGaN HBL(Hole Blocking Layer) on GaN buffer layer. The output power, internal quantum efficiency characteristics of LED active region considering thickness of quantum well, number of quantum well and doping of barrier are analyzed using ISE-TCAD.

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Laboratory Experiment of Two-layered fluid in a Rotating Cylindrical container (원통형 이층유체의 회전반 실험)

  • 나정열;최진영
    • 한국해양학회지
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    • v.28 no.1
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    • pp.17-23
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    • 1993
  • A right cylindrical tank with sloping bottom and top (${\beta}-effect$) is filled with two-layered fluid and is put on the rotating table. External fluid of same density as the lower-layer fluid is continuously injected to drive the lower-layer current. By minimizing the interfacial stress between two layers the motion in the lower-layer deformed the shape of interface such that the upper-layer adjust itself to the variations of the interface in terms of its direction of flow patterns .The most significant parameter is the internal Froude Number($F_1$) and when $F_1$ is greater than 6 two-cellular circulation of the upper-layer changes its direction, there by creates a separation of Western boundary current. The separation position moves to the most northward when $F_1$ equals to 6.

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Characteristics of MEMS Probe Tip with Multi-Rhodium Layer (이중 로듐 층을 갖는 멤스 프로브 팁의 특성)

  • Park, Dong-Gun;Park, Yong-Joon;Lim, Seul-Ki;Kim, Il;Shin, Sang-Hun;Cho, Hyun-Chul;Park, Seung-Pil;Kim, Dong-Won
    • Journal of the Korean institute of surface engineering
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    • v.45 no.2
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    • pp.81-88
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    • 2012
  • Probe tip, which should have not only superior electrical characteristics but also good abrasion resistance for numerous contacts with semiconductor pads to confirm their availability, is essential for MEMS probe card. To obtain good durability of probe tip, it needs thick and crack-free rhodium layer on the tip. However, when the rhodium thickness deposited by electroplating increased, unwanted cracks by high internal stress led to serious problem of MEMS probe tip. This article reported the method of thick Rh deposition with Au buffer layer on the probe tip to overcome the problem of high internal stress and studied mechanical and electrical properties of that. MEMS probe tip with double-Rh layer had good contact resistance and durability during long term touch downs.

The added carbon effect on residual stress in ion-nitriding (ION질화에 있어 첨가 탄소량이 잔류응력에 미치는 영향)

  • 김희송;강명순
    • Journal of the korean Society of Automotive Engineers
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    • v.4 no.2
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    • pp.35-46
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    • 1982
  • This paper deals with residual stress characteristics of ion-nitrided metal which is primarilly concerned with the effects of added carbon content in gas atmosphere. A small optimal amount of carbon content in gas atmosphere increase compound layer thickness, as well as to increase diffusion layer thickness and hardness. The residual stress and deflection of the specimens was measured in various elevated temperature at the surface of ion-nitrided metal and the internal stress distribution was calculated. It is found that compressive residual stress at the compound layer is largest at the compound layer, and decreases as the depth from the surface increases.

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Simulation of the tensile behaviour of layered anisotropy rocks consisting internal notch

  • Sarfarazi, Vahab;Haeri, Hadi;Ebneabbasi, P.;Bagheri, Kourosh
    • Structural Engineering and Mechanics
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    • v.69 no.1
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    • pp.51-67
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    • 2019
  • In this paper, the anisotropy of tensile behaviours of layered rocks consisting internal notch has been investigated using particle flow code. For this purpose, firstly calibration of PFC2D was performed using Brazilian tensile strength. Secondly Brazilian test models consisting bedding layer was simulated numerically. Thickness of layers was 10 mm and layered angularity was $90^{\circ}$, $75^{\circ}$, $60^{\circ}$, $45^{\circ}$, $30^{\circ}$, $15^{\circ}$ and $0^{\circ}$. The strength of bedding interface was too high. Each model was consisted of one internal notch. Notch length is 1 cm, 2 cm and 4 cm and notch angularities are $60^{\circ}$, $45^{\circ}$, $30^{\circ}$, $15^{\circ}$ and $0^{\circ}$. Totally, 90 model were tested. The results show that failure pattern was affected by notch orientation and notch length. It's to be noted that layer angle has not any effect on the failure pattern. Also, Brazilian tensile strength is affected by notch orientation and notch length.