• Title/Summary/Keyword: Internal Diameter

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Synthesis, morphology and electrochemical applications of iron oxide based nanocomposites

  • Letti, Camila J.;Costa, Karla A.G.;Gross, Marcos A.;Paterno, Leonardo G.;Pereira-da-Silva, Marcelo A.;Morais, Paulo C.;Soler, Maria A.G.
    • Advances in nano research
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    • v.5 no.3
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    • pp.215-230
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    • 2017
  • The development of hybrid systems comprising nanoparticles and polymers is an opening pathway for engineering nanocomposites exhibiting outstanding mechanical, optical, electrical, and magnetic properties. Among inorganic counterpart, iron oxide nanoparticles (IONP) exhibit high magnetization, controllable surface chemistry, spintronic properties, and biological compatibility. These characteristics enable them as a platform for biomedical applications and building blocks for bottom-up approaches, such as the layer-by-layer (LbL). In this regard, the present study is addressed to investigate IONP synthesised through co-precipitation route (average diameter around 7 nm), with either positive or negative surface charges, LbL assembled with sodium sulfonated polystyrene (PSS) or polyaniline (PANI). The surface and internal morphologies, and electrochemical properties of these nanocomposites were probed with atomic force microscopy, UV-vis and Raman spectroscopy, scanning electron microscopy, cross-sectional transmission electron microscopy, and electrochemical measurements. The nanocomposites display a globular morphology with IONP densely packed while surface dressed by polyelectrolytes. The investigation of the effect of thermal annealing (300 up to $600^{\circ}C$) on the oxidation process of IONP assembled with PSS was performed using Raman spectroscopy. Our findings showed that PSS protects IONP from oxidation/phase transformation to hematite up to $400^{\circ}C$. The electrochemical performance of nanocomposite comprising IONP and PANI were investigated in $0.5mol{\times}L^{-1}$ $Na_2SO_4$ electrolyte solution by cyclic voltammetry and chronopotentiometry. Our findings indicate this structure as promising candidate for potential application as electrodes for supercapacitors.

Fabrication Technology of Turbo Charger Housing for Riser Minimizing by Fusion S/W Application and its Experimental Investigation (압탕 최소화를 위한 터보차저하우징의 융합 S/W 응용 제조기술 및 실험적 검증)

  • Lee, Hak-Chul;Seo, Pan-Ki;Jin, Chul-Kyu;Seo, Hyung-Yoon;Kang, Chung-Gil
    • Journal of Korea Foundry Society
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    • v.37 no.1
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    • pp.1-13
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    • 2017
  • The purpose of this study is to increase the part recovery rate (to more than 70%) during the casting of a ductile cast iron turbo charger housing using a heater around the riser. Before creating a casting mold, various runner and riser systems were designed and analyzed with a casting simulation analysis tool. The design variables were the heater temperature, top insulation, riser location, riser diameter and the riser shape. During the feeding from the riser to the part, the reverse model was better than the forward model. When heating the riser (above $600^{\circ}C$), solidification of the riser was delayed and the feeding effect was suitable compared to that without heating. At a higher heating temperature, less solidification shrinkage and porosity were noted inside the part. On the basis of a casting simulation, eight molds were fabricated and casting experiments were conducted. According to the experimental conditions, external and internal defects were analyzed and mechanical properties were tested. The ultimate tensile strength and elongation outcome were correspondingly more than 540MPa and 5% after a heat treatment. In addition, a maximum part recovery rate of 86% was achieved in this study.

Preparation and Evaluation of Bupivacaine Microspheres by a Solvent Evaporation Method (용매증발법에 의한 부피바카인 microsphere의 제조 및 평가)

  • Kwak, Son-Hyok;Hwang, Sung-Joo;Lee, Byung-Chul
    • YAKHAK HOEJI
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    • v.44 no.6
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    • pp.511-520
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    • 2000
  • Various bupivacaine-loaded microspheres were prepared from poly (d,l-lactide) (PLA) or poly (d,l-lactic-co-glycolide) (PLGA) by a solvent evaporation method for the sustained release of drug. PLA and PLGA microspheres were prepared by w/o/w and w/o/o multiple emulsion solvent evaporation, respectively. The effects of process conditions such as emulsification speed, emulsifier type, emulsifier concentration and internal/external phase ratio on the characteristics of microspheres were investigated. The prepared microspheres were characterized for their drug loading, size distribution, surface morphology and release kinetics. Drug loading efficiency was higher in the microspheres prepared by w/o/o multiple emulsion than that by w/o/w multiple emulsion method, because the solubility of bupivacaine HCI was decreased in oil phase compared with water phase. The prepared microspheres had an average diameter between 1 and $2\;{\mu}M$ in all conditions of two methods. In morphology studies the PLA microspheres showed an irregular shape and smooth surface, but PLGA microspheres had a spherical shape and smooth surface. The release pattern of the drug from microspheres was evaluated on the basis of the burst effect and the extent of the release after 24h. The in vitro release of bupivacaine HCl from microspheres showed a large initial burst release and $60{\sim}80%$ release within one day in all conditions of two methods. The extents of the burst release against PLA and PLGA microspheres were $30{\sim}50%$ and $50{\sim}80%$ within 20min, respectively. This burst release seems to be due to the smaller size of microspheres and the solubility of drug in water.

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Numerical Analysis on Heat Transfer Characteristics of a Heat Pipe Type Solar Thermal Receiver Depending on End Wall Angle Variation (고온 히트파이프식 태양열 흡수기의 후벽 각도 변화에 따른 열전달 특성의 수치해석)

  • Park, Young-Hark;Jung, Eui-Guk;Boo, Joon-Hong;Kang, Yong-Heack
    • 한국태양에너지학회:학술대회논문집
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    • 2008.11a
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    • pp.226-231
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    • 2008
  • The heat transfer characteristics of a solar high-temperature receiver with heat pipes was investigated by numerical simulation. The concentration ratio of the solar receiver ranges 1000 and the concentrated heat is required to be transported to a certain distance for specific applications. This study deals with internal geometry variation of a solar receiver incorporating high-temperature heat pipe. The isothermal characteristics in the receiver section is of major concern. The diameter of the solar thermal receiver was 120 mm and the length was 400 mm. The angle of receiver end wall was varied between $0^{\circ}$ and $45^{\circ}$. The wall thickness of the heat pipe channel was 4mm and 48 axial channels of the same dimensions were attached to the outer wall of the receiver with even spacing in the circumferential direction. The channels are changed to high-temperature sodium heat pipes. Commercial softwares were employed to deal with the radiative heat transfer inside the receiver cavity and the conduction heat transfer along the channels. The numerical results are compared and analyzed from the view Point of high-temperature solar receiver.

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The Experimental Reconstruction of the Trachea with A Heavy Marlex Mesh and Pericardium (Heavy Marlex Mesh 와 심낭편을 이용한 기관재건술의 실험적 연구)

  • 왕영필;이홍균
    • Journal of Chest Surgery
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    • v.10 no.1
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    • pp.7-17
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    • 1977
  • The increasing frequency of post-tracheostomy stenosis parallels the increase in the incidence of tracheostomy. The development of stenosis of trachea following the operation of tracheal tumor or tracheostomy is a very serious complication. The continuing need for an adequate tracheal substitute has not been answered, despite the necessities of excision and reconstruction of the trachea to keep for effective ventilation. Experimental tracheal reconstuction, with a prosthesis of heavy Marlex mesh and pericardium, _ vas performed in twelve dogs. Five to six tracheal ring circumferential defects were created and were bridged with heavy Marlex mesh fashioned into a tube of suitable diameter. Group A: A prepared cylinder of Marlex mesh was anastomosed outside the cut ends of the trachea. Group B: The external surface of the prepared cylinder of Marlex mesh was completely covered with suitably sized patch of pericardium and overlapped all margin of the Marlex mesh by 2 to 3 mm in each direction. Group C: The internal surface of the prepared cylinder of Marlex mesh was covered with suitably sized patch of pericardium and overlapped all margin of the Marlex mesh by 2 to 3 mm in each direction. The results of this exepriment were as follow: 1. In group A and B, the graft was well bridged with new granulation and fibrous tissue, and the lumen of trachea kept good patency for effective ventilation.. The interstices of Marlex became uniformly infiltrated with young well vasculated connective tissue. Epithelization has not yet occurred at 4 weeks in each group, but there were evidences of new growing mucosa at grafted site in 6 weeks. The remainder of the prosthesis was completely covered with glistening epithelium and the underlying fibrous tissue became more matured with little inflammation. These findings were more striking in group B than group A. 2. In group C, the covered pericardium was necrotized with stenosis of the lumen of grafted site due to poor blood supply.

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Evaluation of Structural Behavior of Connections in Precast Arch Structures (프리캐스트 아치구조의 이음부 구조 거동 평가)

  • Shim, Chang Su;Kim, Dong Chan;Choi, Dae;Jin, Kyung Seok
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.36 no.5
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    • pp.747-756
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    • 2016
  • In this paper, a connection details for precast arch structures was proposed. Experiments were performed to evaluate structural performance of the loop connection details satisfying current design requirements and of alternative details for improvement of constructability. Precast arch specimens considering the current design requirements showed higher structural capacity than a cast-in-place arch specimen. Crack width at the connection of arch crown showed smaller value than 0.2 mm due to increased compression force by the applied vertical load. Strengthening by wire-mesh at notch area of the connection improved initial crack control capability. Connection detail with couplers and headed bars showed similar capacity to the reference specimen. The alternative details to improve constructability of reinforcements can be used without decreasing structural performance. Specimens with smaller internal diameter of mandrel and shorter loop splicing than the current design codes showed worse behavior in terms of crack width control.

Development of 3 D.O.F parallel robot's simulator for education

  • Yoo, Jae-Myung;Kim, John-Hyeong;Park, Dong-Jin
    • 제어로봇시스템학회:학술대회논문집
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    • 2005.06a
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    • pp.2290-2295
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    • 2005
  • In this paper, it is developed simulator system of 3 D.O.F parallel robot for educate of expertness. This simulator system is composed of three parts ? 3 D.O.F parallel robot, controller (hardware) and software. First, basic structure of the robot is 3 active rotary actuator that small geared step motor with fixed base. An input-link is connected to this actuator, and this input-link can connect two ball joints. Thus, two couplers can be connected to the input-link as a pair. An end-plate, which is jointed by a ball joint, can be connected to the opposite side of the coupler. A sub-link is produced and installed to the internal spring, and then this sub-link is connected to the upper and bottom side of the coupler in order to prevent a certain bending or deformation of the two couplers. The robot has the maximum diameter of 230 mm, 10 kg of weight (include the table), and maximum height of 300 mm. Hardware for control of the robot is composed of computer, micro controller, pulse generator, and motor driver. The PC used in the controller sends commands to the controller, and transform signals input by the user to the coordinate value of the robot by substituting it into equations of kinematics and inverse kinematics. A controller transfer the coordinate value calculated in the PC to a pulse generator by transforming it into signals. A pulse generator analyzes commands, which include the information received from the micro controller. A motor driver transfer the pulse received from the pulse generator to a step motor, and protects against the over-load of the motor Finally, software is a learning purposed control program, which presents the principle of a robot operation and actual implementation. The benefit of this program is that easy for a novice to use. Developed robot simulator system can be practically applied to understand the principle of parallel mechanism, motors, sensor, and various other parts.

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Manufacture & Launch of Small PE/$LN_2O$ Hybrid Rocket with 50 kgf Thrust Level (추력 50 kgf 급 PE/$LN_2O$ 소형 하이브리드 로켓 제작 및 시험발사)

  • Kim, Hyeon-Woo;Jeon, Min-Ho;Oh, Ji-Sung;Han, See-Hee;Kang, Min-Seok;Jang, Hyoung-Gui;Kim, Hee-Yong;Bae, Tae-Hyun;Lee, Sun-Jae;Kim, Jin-Kon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.507-510
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    • 2009
  • The small size of hybrid rocket using PE-$LN_2O$ was designed, constructed and launched for a development basic technology of Hybrid rocket vehicle. The hybrid engine ignition system was designed with valve system using external actuator and confirmed working without any fault. To design fuel grain an internal ballistics design was carried out, and to estimate rockets flight path an external ballistics analysis was carried out. So the rocket was designed and constructed, and the launch test proves that hybrid rocket's design was suitable. The hybrid rocket(weight : 9kg, diameter : 110 mm, height : 1.7 m) was launched successfully. But parachute was deployed on mid-flight and the mission could not finish its purposed flight. Some of problems were found in this activity but next launch vehicle will be improved.

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Detection of a mollicute-like organism in kuruma shrimp, Penaeus japonicus (보리새우(Penaeus japonicus)에 감염된 Mollicute-like Organism)

  • Choi, Dong-Lim;Sohn, Sang-Gyu;Park, Myoung-Ae;Heo, Moon-Soo;Renault, Tristan
    • Journal of fish pathology
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    • v.9 no.1
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    • pp.33-40
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    • 1996
  • A filamentous form of mollicute-like bacterium was detected during a routine health survey of wild adult kuruma shrimp Penaeus japonicus. The kuruma shrimp were native to Japan and were imported to Korea. The histology showed no pathological changes. Transmission electron microscopy revealed extensive infections of hepatopancreatic epithelial cell by a pleomorphic, filamentous intracellular bacterium. The filamentous bacterium was of about 60 nm in diameter and 300 nm to more than $1{\mu}m$ in length. Teh morphology of bacteria were filamentous and branched with terminal blebs, or knobs, on the branches. They lacked the cell wall, and were bounded by the plasma membrane. They contained typical prokaryotic ribosomes and fibrillar DNA-like strands. No additional internal structure has been observed. They are considered to be mollicutes, based upon the morphological appearance and upon the cellular location.

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A finite element stress analysis on the supporting bone and abutment screw by tightening torque of dental implant abutment screw (치과용 임플란트 지대주나사의 조임체결력에 따른 지지골과 지대주나사의 유한요소법 응력 분석)

  • Lee, Myung-Kon
    • Journal of Technologic Dentistry
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    • v.42 no.2
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    • pp.99-105
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    • 2020
  • Purpose: A study analysed the stress distribution of abutment screw and supporting bone of fixture by the tightening torque force of the abutment screw within clinical treatment situation for the stability of the dental implant prosthesis. Methods: The finite element analysis was targeted to the mandibular molar crown model, and the implant was internal type 4.0 mm diameter, 10.0 mm length fixture and abutment screw and supporting bone. The occlusal surface was modeled in 4 cusps and loaded 100 N to the buccal cusps. The connection between the abutment and the fixture was achieved by combining three abutment tightening torque forces of 20, 25, and 30 Ncm. Results: The results showed that the maximum stress value of the supporting bone was found in the buccal cortical bone region of the fixture in all models. The von Mises stress value of each model showed 184.5 MPa at the 20 Ncm model, 195.3 MPa in the 25 Ncm model, and 216.5 MPa in the 30 Ncm model. The contact stress between the abutment and the abutment screw showed the stress value in the 20 Ncm model was 201.2 MPa, and the 245.5 MPa in the 25 Ncm model and 314.0 MPa in the 30 Ncm model. Conclusion: The increase of tightening force within the clinical range of the abutment screw of the implant dental prosthesis was found to have no problem with the stability of the supporting bone and the abutment screw.