• Title/Summary/Keyword: Interfacial energy

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Interfacial Engineering Strategies for Third-Generation Photovoltaics (차세대 태양전지의 계면 개질 전략)

  • Lim, Hunhee;Choi, Min-Jae;Jung, Yeon Sik
    • Current Photovoltaic Research
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    • v.4 no.3
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    • pp.98-107
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    • 2016
  • Third-generation photovoltaics are of low cost based on solution processes and are targeting a high efficiency. To meet the commercial demand, however, significant improvements of both efficiency and stability are required. In this sense, interfacial engineering can be useful key to solve these issues because trap sites and interfacial energy barrier and/or chemical instability at organic/organic and organic/inorganic interfaces are critical factors of efficiency and stability degradation. Here, we thoroughly review the interfacial engineering strategies applicable to three representative third-generation photovoltaics - organic, perovskite, colloidal quantum dot solar cell devices.

Interfacial Boundary Estimation in Stratified Flow of Two Immiscible Liquids Using Hybrid-type Fourier Series

  • Kim, Bong Seok;Choi, Bong-Yeol;Kim, Kyung Youn
    • Journal of IKEEE
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    • v.18 no.4
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    • pp.463-470
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    • 2014
  • In stratified flows of two immiscible liquids, due to the vibration in a pipe, the shape of the interface is not always periodic and it causes the different end points of the interfacial boundary. In this case the performance is not good. To solve this, in this paper, the hybrid-type Fourier series is proposed, which consists of both the polynomial and the trigonometric terms. Under the stationary interfacial boundary during acquiring a full set of voltage data, the performance of the proposed method is evaluated through the numerical experiments. The results show that the proposed method performs better than the conventional Fourier series in estimating the interfacial boundary.

Interfacial bonding Energy between Laser Surface Treated HA layer and Ti alloy (레이저 표면처리에 의한 수산화아파타이트 코팅된 타이타니움합금 경계면의 결합에너지)

  • Moon, D.S.;Kim, Y.K.;Nam, S.Y.;Cho, H.S.;Huh, E.J.;Kim, S.Y.;Lee, J.H.
    • Proceedings of the KOSOMBE Conference
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    • v.1997 no.05
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    • pp.35-38
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    • 1997
  • The interfacial bonding energy between laser surface treated HA layer and Ti alloy substrate was investigated using a mechanical push-out tester. The initial slope of shear-stress and reduced displacement curves, maximum interfacial bond strength and bonding energy were calculated from results of the push-out test. The calculated initial slpoes are 38 MPa for the Ti alloy(A), 65 MPa for the sandblast finished specimen(B), 95 MPa for the HA plasma spray coated specimen and 49 MPa for the laser surface treated specimen(D). The maximum interfacial bonding strength are 3 MPa for the A, 19 MPa for the B, 20 MPa for the C, 10 MPa for the D. The interfacial bonding energies are $3.3\times10^{-9}J/mm^2$ for the A, $15.5\times10^{-9}J/mm^2$ for the B, $15.6\times10^{-9}J/mm^2$ for the C and $18.3\times10^{-9}J/mm^2$ for the D. Microscopic observation shows that the breaking of the laser treated specimen had been occured through the boundary between HA layer and polymer resin, but the untreated specimen had been occured through the inside of HA coating layer.

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A stress-function variational approach toward CFRP -concrete interfacial stresses in bonded joints

  • Samadvand, Hojjat;Dehestani, Mehdi
    • Advances in concrete construction
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    • v.9 no.1
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    • pp.43-54
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    • 2020
  • This paper presents an innovative stress-function variational approach in formulating the interfacial shear and normal stresses in an externally bonded concrete joint using carbon fiber-reinforced plastic (CFRP) plies. The joint is subjected to surface traction loadings applied at both ends of the concrete substrate layer. By introducing two interfacial shear and normal stress functions on the CFRP-concrete interface, based on Euler-Bernoulli beam idea and static stress equations of equilibrium, the entire stress fields of the joint were determined. The complementary strain energy was minimized in order to solve the governing equation of the joint. This yields an ordinary differential equation from which the interfacial normal and shear stresses were proposed explicitly, satisfying all the multiple traction boundary conditions. Lamination theory for composite materials was also employed to obtain the interfacial stresses. The proposed approach was validated by the analytic models in the literature as well as through a comprehensive computational code generated by the authors. Furthermore, a numerical verification was carried out via the finite element software ABAQUS. In the end, a scaling analysis was conducted to analyze the interfacial stress field dependence of the joint upon effective issues using the devised code.

Capillary Bundle Model for the Estimation of Air-water Interfacial Area and the Gas-filled Pore Size Distribution in Unsaturated Soil (모세관 모델을 이용한 불포화토양의 물-가스 접촉면적 및 가스공극 크기분포의 계산 및 검증)

  • Kim, Heonki
    • Journal of Soil and Groundwater Environment
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    • v.26 no.1
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    • pp.1-7
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    • 2021
  • Air-water interfacial area is of great importance for the analysis of contaminant mass transfer processes occurring in the soil systems. Capillary bundle model has been proposed to estimate the specific air-water interfacial areas in unsaturated soils. In this study, the measured air-water interfacial areas of a soil (loam) using the gaseous interfacial tracer technique were compared to those from capillary bundle model. The measured values converged to the specific solid surface area (7.6×104 ㎠/㎤) of the soil. However, the simulated air-water interfacial areas based on the capillary bundle model deviated significantly from those measured. The simulated values were substantially over-estimated at low end of the water content range, whereas the model under-estimated the air-water interfacial area for the most of the water content range. This under-estimation is considered to be caused by the nature of the capillary bundle model that replaces the soil pores with a bundle of glass capillaries and thus no surface roughness at the inner surface of the capillaries is taken into account for the estimation of the air-water interfacial area with the capillary bundle model. Subsequently, appropriate correction is necessary for the capillary bundle model to estimate the air-water interfacial area in soils. Since the soil-moisture release curve data is the basis of the capillary bundle model, the model can be of use due to its simplicity, while the gaseous tracer technique requires complicated experimental equipment followed by moment analysis of the breakthrough curves. The size distribution profile of the pores filled with gas estimated by the water retention curve was found to be similar to that of particle size at different size range. The shifted distribution of gas-filled pores toward smaller size side compared to the particle size distribution was also found.

Effect of Post-annealing on the Interfacial adhesion Energy of Cu thin Film and ALD Ru Diffusion Barrier Layer (후속 열처리에 따른 Cu 박막과 ALD Ru 확산방지층의 계면접착에너지 평가)

  • Jeong, Minsu;Lee, Hyeonchul;Bae, Byung-Hyun;Son, Kirak;Kim, Gahui;Lee, Seung-Joon;Kim, Soo-Hyun;Park, Young-Bae
    • Journal of the Microelectronics and Packaging Society
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    • v.25 no.3
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    • pp.7-12
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    • 2018
  • The effects of Ru deposition temperature and post-annealing conditions on the interfacial adhesion energies of atomic layer deposited (ALD) Ru diffusion barrier layer and Cu thin films for the advanced Cu interconnects applications were systematically investigated. The initial interfacial adhesion energies were 8.55, 9.37, $8.96J/m^2$ for the sample deposited at 225, 270, and $310^{\circ}C$, respectively, which are closely related to the similar microstructures and resistivities of Ru films for ALD Ru deposition temperature variations. And the interfacial adhesion energies showed the relatively stable high values over $7.59J/m^2$ until 250h during post-annealing at $200^{\circ}C$, while dramatically decreased to $1.40J/m^2$ after 500 h. The X-ray photoelectron spectroscopy Cu 2p peak separation analysis showed that there exists good correlation between the interfacial adhesion energy and the interfacial CuO formation. Therefore, ALD Ru seems to be a promising diffusion barrier candidate with reliable interfacial reliability for advanced Cu interconnects.

AN EXPERIMENTAL STUDY OF THE INTERFACIAL FRICTION FACTOR FOR COUNTERCURRENT STRATIFIED AIR-WATER FLOW IN NEARLY HORIZONTAL AND INCLINED PIPES

  • Yu, Seon-Oh;Kim, Yang-Seok;Chun, Moon-Hyun;Sung, Chang-Kyung;Park, Sang-Doug;Lee, Byung-Ryung;Sohn, Yong-Soo
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05b
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    • pp.247-253
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    • 1996
  • The Interfacial friction factor for the countercurrent stratified air-wafer flow has been experimentally investigated in nearly horizontal and inclined pipes. The presence of the hydraulic jump may significantly affect both the flow pattern and the interfacial friction factor. The measured values of f$_{i}$ in nearly horizontal and two inclined pipes are of the same order of magnitude but the dependencies of the air and water velocities are slightly different.t.

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A penny-shaped interfacial crack between piezoelectric layer and elastic half-space

  • Ren, J.H.;Li, Y.S.;Wang, W.
    • Structural Engineering and Mechanics
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    • v.52 no.1
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    • pp.1-17
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    • 2014
  • An interfacial penny-shaped crack between piezoelectric layer and elastic half-space subjected to mechanical and electric loads is investigated. Using Hankel transform technique, the mixed boundary value problem is reduced to a system of singular integral equations. The integral equations are further reduced to a system of algebraic equations with the aid of Jacobi polynomials. The stress intensity factor and energy release rate are determined. Numerical results reveal the effects of electric loadings and material parameters of composite on crack propagation and growth. The results seem useful for design of the piezoelectric composite structures and devices of high performance.