• 제목/요약/키워드: Instrumental Analysis Method

검색결과 200건 처리시간 0.024초

Characteristic Impact Odorants of Changpo (Acorus calamus var. angustatus Bess) Root Essential Oil

  • Choi, Hyang-Sook
    • Food Science and Biotechnology
    • /
    • 제14권4호
    • /
    • pp.450-455
    • /
    • 2005
  • This study was conducted to determine firstly the composition of the essential oil from fresh changpo (Acorus calamus var. angustatus Bess) roots quantitatively and qualitatively by use of two internal standards, and secondly volatile compounds which are primarily responsible for the aroma of changpo roots. Simultaneous steam distillation and extraction method was used for essential oil extraction, and aroma extract dilution analysis (AEDA) and sniffing test by gas chromatography/olfactometry (GC/O) were used to detect the characteristic impact odorants. According to the instrumental analysis of changpo root essential oil, cis, trans-famesol (47.56 mg/kg of fresh wt), octanoic acid (23.73 mg/kg of fresh wt), trans-2-dodecenal (20.28 mg/kg of fresh wt) and trans, trans-farnesol (13.81 mg/kg of fresh wt) were the most abundant compounds. Geranyl acetate, trans-nerolidol and trans, trans-farnesyl acetate were evaluated as the characteristic impact odorants of changpo roots from results of AEDA and sniffing test. Especially, geranyl acetate was considered as the most similar odor component to changpo roots by organoleptic evaluation with GC/O.

A Study on the Characterization on Some Semiconuctor Materials by Neutron Activation Analysis. Characterization of Semiconductor Silicon

  • 이철;권오천;김호근;이종두;정구순
    • Bulletin of the Korean Chemical Society
    • /
    • 제10권1호
    • /
    • pp.30-32
    • /
    • 1989
  • Traces of nine elements, gold, arsenic, cobalt, chromium, copper, europium, hafnium, sodium and antimony in commercially available silicon crystals were determined by the instrumental neutron activation analysis using the single comparator method. The values of the concentrations of these elements in both single and polycrystals were found to decrease significantly to a low limiting level by simply washing and etching surface contaminants having been introduced during various steps of sample preparation and irradiation. However, the chromium levels in polycrystals were not easily decreased, these depending upon the cutting tools employed. The Sb-doped content in each semiconductor has been compared with the associated quantities such as the concentration and the conductivity range given by the sample donor. Uncertainty in the sodium analysis due to the fission neutron reaction by silicon itself was discussed.

Overestimation of Radioactivity Concentration of Difficult-To-Measure Radionuclides in Scaling Factor Methodology

  • Park, Junghwan;Kim, Tae-Hyeong;Lee, Jeongmook;Kim, Junhyuck;Kim, Jong-Yun;Lim, Sang Ho
    • 방사성폐기물학회지
    • /
    • 제19권3호
    • /
    • pp.367-386
    • /
    • 2021
  • The overestimation and underestimation of the radioactivity concentration of difficult-to-measure radionuclides can occur during the implementation of the scaling factor (SF) method because of the uncertainties associated with sampling, radiochemical analysis, and application of SFs. Strict regulations ensure that the SF method as an indirect method does not underestimate the radioactivity of nuclear wastes; however, there are no clear regulatory guidelines regarding the overestimation. This has been leading to the misuse of the SF methodology by stakeholders such as waste disposal licensees and regulatory bodies. Previous studies have reported instances of overestimation in statistical implementation of the SF methodology. The analysis of the two most popular linear models of the SF methodology showed that severe overestimation may occur and radioactivity concentration data must be dealt with care. Since one major source of overestimation is the use of minimum detectable activity (MDA) values as true activity values, a comparative study of instrumental techniques that could reduce the MDAs was also conducted. Thermal ionization mass spectrometry was recommended as a suitable candidate for the trace level analysis of long-lived beta-emitters such as iodine-129. Additionally, the current status of the United States and Korea was reviewed from the perspective of overestimation.

소셜네트워크게임의 성공요소분석 : 팜빌 게임을 중심으로 (An Analysis for Success Factors of Social Network Game Towards Farmville Game)

  • 김종찬;송승근
    • 한국정보통신학회논문지
    • /
    • 제14권11호
    • /
    • pp.2586-2592
    • /
    • 2010
  • 최근 소셜네트워크게임은 지인과의 관계에 중점을 두면서 여성 유저들과 40대 이상의 고연령층 유저들을 게임 시장으로 끌어내는 등 이용자층 확대에 큰 기여를 하고 있다. 그래서 소셜네트워크게임에 대한 관심과 산업적 확산이 폭발적인 데 반하여 소셜네트워크게임에 대한 학술적인 연구가 미흡하다. 본 연구는 게임전문가와의 심층면담을 통해 최근 성공한 소셜네트워크게임의 성공요인을 살펴보고 이에 대한 개발 지침을 마련하는데 목적이 있다. 소셜네트워크게임 가운데 상업적으로 성공하고 최고의 이용자 수를 갖고 있는 대표적인 게임인 팝벌을 대상으로 핵심 성공요인을 고찰하였다. 그 결과 사회적 교류, 간단한 인터페이스, 비동기 방식, 도구적 합리성 요인이 도출되었다. 본 연구결과를 통해 성공적인 소셜네트워게임을 개발하기 위한 지침으로 활용 될 것으로 기대된다.

주파수영역에서의 가속도 기록 보정 (Correction of Accelerogram in Frequency Domain)

  • 박창호;이동근
    • 대한토목학회논문집
    • /
    • 제12권4호
    • /
    • pp.71-79
    • /
    • 1992
  • 지진에 관한 지반가속도 기록이나 동적실험에서 계측된 가속도 기록에는, 가속도계의 응답특성, A/D변환기의 성능 및 수치화 과정, 그리고 기록계의 특성 등으로 여러 가지 오차가 포함된다. 이들 오차들은 데이터 해석이나 동적해석시 왜곡된 결과를 유발시킨다. 본 연구에서는 가속도 기록에 포함된 오차를 효율적으로 보정하는 방법을 제안하였다. 제안된 오차보정방법은 다음과 같이 4단계로 나뉘어 진행된다; 1) 보간법을 이용하여 보정에 적절한 데이터를 만든다, 2) 저주파와 고주파 성분이 주를 이루는 수치화 오차를 band-pass필터를 이용하여 제거한다, 3) 가속도계의 특성으로 인한 오차들을 보정한다, 4) 보정된 기록을 적분하여 속도와 변위를 얻는다. 현재 band-pass 필터로는 FIR필터나 IIR필터가 주로 이용되고 있는 데 초기데이터의 왜곡, 위상의 변화, 계산량의 과다와 같은 문제점들을 가지고 있다. 제안된 오차보정방법은 이들 필터의 여러 문제점을 개선하였으며, Fourier 변환의 특성을 이용하여 미분과 적분을 수행함으로써 가속도계의 특성으로 인한 오차의 보정과 속도 및 변위 계산의 정확성을 높였다.

  • PDF

Parametric study on multichannel analysis of surface waves-based nondestructive debonding detection for steel-concrete composite structures

  • Hongbing Chen;Shiyu Gan;Yuanyuan Li;Jiajin Zeng;Xin Nie
    • Steel and Composite Structures
    • /
    • 제50권1호
    • /
    • pp.89-105
    • /
    • 2024
  • Multichannel analysis of surface waves (MASW) method has exhibited broad application prospects in the nondestructive detection of interfacial debonding in steel-concrete composite structures (SCCS). However, due to the structural diversity of SCCS and the high stealthiness of interfacial debonding defects, the feasibility of MASW method needs to be investigated in depth. In this study, synthetic parametric study on MASW nondestructive debonding detection for SCCSs is performed. The aim is to quantitatively analyze influential factors with respect to structural composition of SCCS and MASW measurement mode. First, stress wave composition and propagation process in SCCS are studied utilizing 2D numerical simulation. For structural composition in SCCS, the thickness variation of steel plate, concrete core, and debonding defects are discussed. To determine the most appropriate sensor arrangement for MASW measurement, the effects of spacing and number of observation points, along with distances between excitation points, nearest boundary, as well as the first observation point, are analyzed individually. The influence of signal type and frequency of transient excitation on dispersion figures from forwarding analysis is studied to determine the most suitable excitation signal. The findings from this study can provide important theoretical guidance for MASW-based interfacial debonding detection for SCCS. Furthermore, they can be instrumental in optimizing both the sensor layout design and signal choice for experimental validation.

의류제품에 대한 소비자만족 형성과정 -소비자관여, 제품성과, 소비감정을 중심으로- (Consumer Satisfaction Formation Process of Clothing -Based on Consumer Involvement, Product Performance, and Consumption Emotion-)

  • 김지영;박재옥
    • 한국의류학회지
    • /
    • 제26권5호
    • /
    • pp.663-674
    • /
    • 2002
  • The objectives of this study were 1) to ascertain whether there was a difference in product performance (expressive or instrumental), which consumer recognized after using, related to consumer involvement toward clothing, 2) to clarify the effect of product performance on consumption emotion(positive or negative), 3) to investigate the effect of consumption emotion on satisfaction, and 4) to find out whether product performance had a direct effect on satisfaction toward product. The study was conducted in three steps. Through the two steps, measurement instruments were developed. At the last step, judgement sampling method were utilized to collect the data and subjects were 614 university students. Confirmatory factor analysis and structural equation model analysis were used to analyze the data. The results were as follows: 1) Consumer involvement had an effect on product performances but it was related to the expressive product performance more than to the instrumental product performance. 2) Product performance had positive influence on positive consumption emotion, while it had negative influence on negative consumption emotion. The results revealed that there were significant relationships between product performance and consumption emotion. 3) Positive consumption emotion had a positive effect on consumer satisfaction, on the other hand negative consumption emotion had a negative effect on consumer satisfaction. 4) Although the direct effects of product performances on satisfaction were larger than the indirect effects, product performance was greatly influential in consumption emotion and consumption emotion was strongly related to consumer satisfaction. Therefore, consumption emotion is an important determinant variable in the process of consumer satisfaction.

냉각 제습에 의한 음식물 쓰레기 처리장치 악취제거에 관한 실험적 연구 (A Study on an experimental basis a use deodorize stink of food-waste in order to cooling dehumidification)

  • 박일수;김재돌
    • 동력기계공학회지
    • /
    • 제12권1호
    • /
    • pp.35-40
    • /
    • 2008
  • This paper presents an effective cooling dehumidification method to remove odorous gas from food-wastes. The odorous gases, such as Styrene, Ammonia, Hydrogen sulfide and Acetaldehyde, are produced in environments where temperature is $50\sim80^{\circ}C$ and humidity is $40\sim70%$. Under such conditions, experiments are performed reiteratively using experiment equipments. The effect of the cooling dehumidification is measured via measuring instrument, and this research is focused on improving efficiency. The effect of cooling dehumidification using measuring instrument is validated. At $80^{\circ}C$, four type of gases that was mentioned previously showed generally better cooling efficiency with a good result for a component concentration. Among them, hydrogen sulfide gas demonstrated the highest reduction of 50%.

  • PDF

Neutron Activation Analysis of Korean Clays and Pottery

  • 이철;권오천;김낙배
    • Bulletin of the Korean Chemical Society
    • /
    • 제6권4호
    • /
    • pp.241-246
    • /
    • 1985
  • Twenty trace elements were determined in 250 Korean potsherds and 5 clay samples by instrumental NAA. In the absence of identified samples of known origin, the potsherds were classified by a hierarchical centroid sorting method to construct a dendrogram. From this dendrogram 61 well-defined samples were selected to form 8 subclasses and five elements such as Cr, Cs, Sm, Sc and Th were supposed to be the main contributors for the classification. The 61 samples along with 5 clay samples were reclassified by means of minimal spanning tree as well as the hierarchical centroid sorting method by using 5 elements selected. As the results, the potsherds of certain classes defined in this work could be taken as a basis for latter identification and served as batches of identified species.

Simultaneous quantitative analysis of four isothiazolinones and 3-iodo-2-propynyl butyl carbamate in hygienic consumer products

  • Heo, Jin Ju;Kim, Un-Jung;Oh, Jeong-Eun
    • Environmental Engineering Research
    • /
    • 제24권1호
    • /
    • pp.137-143
    • /
    • 2019
  • In this study, extraction, clean-up and instrumental analytical conditions were optimized for identifying and quantifying methyl-, chloromethylbenzi-, octyl- isothiazolinone (MIT, CMIT, BIT, OIT) and 3-iodo-2-propynyl butyl carbamate (IPBC), widely used biocidal active ingredients in human hygiene consumer products. Accuracy of the developed ultrasonic assisted extraction method followed by HPLC/MS analysis for four isothiazolinones and IPBC ranged between 60.4% and 113% in various types of consumer product samples. Method detection limits ranged 0.011-0.034 mg/kg for wet wipes, 0.57-1.5 mg/kg for liquid detergent and 0.58-1.6 mg/kg for powder detergent. Wet wipes, powder and liquid detergents collected from local market in Korea were analyzed to demonstrate the applicability of the developed method. Even after the regulation of those compounds in wet wipes, CMIT, MIT and IPBC were still frequently detected from complementary wet wipes without brand labels which were distributed to customers at local retail shops and restaurants. The maximum observed concentrations of MIT and CMIT found in those complementary wet wipes were 70.2 mg/kg and 11.3 mg/kg, respectively.