• Journal of Korea Foundry Society
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• v.33 no.4
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• pp.147-156
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• 2013

The effects of core materials on the microstructure and mechanical properties of Al casting products have been investigated. The Al casting samples and cylinder head were fabricated by using organic and inorganic binder core respectively, and their microstructure and mechanical properties were evaluated. The Al casting samples fabricated by using inorganic core showed the better mechanical properties such as tensile strength and elongation than those of the Al casting samples fabricated by using organic core. That's because the Al casting samples contained small amount of pore defects and had fine microstructure compared with the Al casting samples fabricated by using organic core. Also, the use of inorganic core effectively reduced harmful gas emission and pollution.

• Environmental Analysis Health and Toxicology
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• v.17 no.4
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• pp.333-339
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• 2002

Yellow sand (YS) storms were observed about ten times in the Korean peninsula during March and April in 2002. Twenty four hour fine particle (PM$\_$2.5/) samples were collected onto the 47 mm Teflon - coated quartz filters over 9 days during and after the events using the MiniVol Portable Air Sampler at a flow rate of 5 liters per minute. The highest PM$\_$2.5/ concentration measured during the YS period was 289 $\mu\textrm{g}$/㎥, which is 13 times higher than the lowest of the values for the samples collected during the non-yellow sand period. The filter samples were analyzed for inorganic ions using the IC, AAS and Autoanalyzer, and for metals using the ICP-MS. The results showed that the concentrations of some inorganic ions (e.g., Ca$\^$2+/ and SO$_4$$\^$2-/) and metals (e.g., Fe, Mn) of soil origin were elevated during the yellow sand events.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.34 no.3
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• pp.193-201
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• 2024

Objectives: Paints contain various types of metal substances. However, our review of MSDS (Material Safety Data Sheets) for paints found that their components were often kept secret or exact content information was otherwise not provided. We analyzed the metal elements in various inorganic pigment-based paints available in South Korea in this study and checked whether they contain hazardous metal substances as defined by the Occupational Safety and Health Acts. We investigated issues of health hazard classification related to the metal elements. The study is intended to contribute to strengthening the management of hazardous substances by suggesting improvements to MSDS. Methods: We randomly selected 19 samples that were predicted to contain hazardous inorganic pigments after reviewing MSDS among paints currently in use. The samples were analyzed using XRF (X-ray Fluorescence spectrometry), ICP_OES (Inductively Coupled Plasma-Optical Emission Spectroscopy) and SP-ICP-MS (Single Particle-ICP-Mass Spectroscopy). Results: The most common elements in the samples were Al (aluminum), Fe (iron), Ti (titanium), Ca (calcium), and Si (silica). One sample contained more lead than allowed by the limits. There were ten samples that could potentially contain nanoforms, seven samples that contained titanium dioxide, and six samples that contained complex inorganic color pigments (CICPs). Conclusions: Inorganic pigments in paints should be evaluated for hazards separately from other metallic compounds and reflected in the MSDS because they have different characteristics than other metallic compounds. These include particle size, crystal structure, and complex substances. The results of this study can be helpful for determining whether a paint contains sufficient hazardous metal compounds to affect its classification, and it can be a guideline for improving MSDS through comparative review and rationalization with the manufacturer's MSDS. This would make it possible to contribute to the management of chemical substances in the workplace through the proper MSDS disclosure of paints.

• 전기의세계
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• v.18 no.2
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• pp.15-20
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• 1969

The main focus of this paper is on the study of the .gamma. ray irradiation effect upon the electrical properties of a B-kind insulator which is one of the inorganic insulators. The mica is so typical of the B kind insulators as to be selected for a sample. DC, AC, and Impulse voltage is applied to the variable .gamma. ray irradiated dose samples with the constant time duration and the time variable samples with the .gamma. ray irradiated dose. The dielectric breakdown voltage and dielectric constant are measured from the samples and we get the experimental data that the dielectric breakown voltage variations are relatively large, but the dielectric constants are almost constant. The above conclusion is useful for the selection and application of the inorganic insulators under the irradiation effects, and we expect that the conclusion can apply to not only B-kind insulators but also the inorganic insulators.

• Analytical Science and Technology
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• v.6 no.3
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• pp.297-305
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• 1993

Generally, it is difficult to analyze cast iron samples with spark discharge emission spectrometry since the content of carbon in these samples is high as a few percent. The cast iron samples were analyzed with the developed glow discharge emission spectrometer composed of glow discharge emission source and polychromator. The discharge condition of glow discharge lamp(GDL) has been optimized by variation of Ar gas pressure, discharge voltage and discharge time. Under the optimum conditions obtained in this work, relationships between the measured emission intensities and concentration of two types of cast iron standard samples(BAS, LECO) were investigated. Most of elements(Mn, Si, P, S etc.) showed the good linearity in one calibration curve. And the carbon showed slightly the systematic difference according to the type of standard samples.

• Journal of environmental and Sanitary engineering
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• v.19 no.1
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• pp.8-16
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• 2004

Ground water samples were collected from residential, green" industrial, landfill and mining area and analyzed for 23 inorganics from March to October in 2002. The results are as follows; 1. The detection frequencies of inorganic materials such as As, Ba, B, Mo, Ca, Mg, Al, Cu, Fe, Mn, Zn, Na, K were 7.2∼77.1% which showed that these inorganics were detected in many ground waters. 2. The detection frequencies of 7 inorganics(Cd, Cr, Ph, Se, Sb, Be, Tl) were commonly low at ranging from 0.42 to 2.5%. These inorganics were contained in ground water partially. 3. Three inorganics such as Hg, Ni, Ag were not detected in any ground-water samples. 4. Compared to the other areas, ground water samples from landfill area contained greater concentration in many inorgainics and then showed higher levels in industral, residential, mining and green area in order. 5. Compared to noted concentrations of bottled water, inorganic minerals including Ca, Mg, Na, K related to taste were fluent in target samples. The results showed that the average concentrations of Mg, Na, K were 4.0 mg/l, 14.7 mg/l, 1.5 mg/l respectively. 6. The concentrations of inorganics such as Sb, Ba, Mo, Be, Tl, K in some ground water samples exceeded the water quality standards of WHO, the US and UK. Especially, Ba, Mo, K also showed relatively high detection frequencies so these inorganics need to be considered as analytes in Korea Drinking Water Regulation in further study.

• Analytical Science and Technology
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• v.9 no.3
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• pp.253-261
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• 1996

Analytical method for the determination of trace germanium in inorganic matrices by differential pulse polarography(DPP) was studied. The reduction peak of germanium(IV) in perchloric acid solution containing 1, 2, 3-trihydroxy benzene appeared at -0.45V(vs. Ag/AgCl) and the peak current for germanium complex varied linearly with concentration variation. Factors affecting sensitivity and precision for germanium quantification were studied and detection limit under the investigated parameters was 1ng/ml. Inorganic samples were decomposed by fusion with potassium pyrosulfate. Serious interferences of Se(IV), Pb(II), As(III) for the determination of germanium were discussed. Interferences of these elements could be avoided by extraction of germanium from decomposed matrices by $CCl_4$ in 10M HCl solution. The germanium contents of inorganic samples(Pb bf. dust, Cu bf. dust, gneiss, Cu anode slime) were determined by the above method.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.31 no.1
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• pp.22-30
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• 2021

Objectives: The objectives of this study were to develop a quality control protocol of inorganic acids using ion chromatograph and to evaluate analytical proficiency of the legally designated agencies. Methods: This study prepared inorganic acid samples by injecting three anion certified solutions (chloride, nitrate, and sulfate) on the quartz filters. To investigate the storage stability and concentration consistency of the samples, 240 samples for each anion were tested at weeks 0, 2, 4, 8, 12, and 16 while storing at 4℃ and 25℃. To evaluate analytical proficiency, two separate testings were administrated for six skilled analysts and 46 analysts affiliated with legally designated agencies. Results: Average recoveries of the three ions after 16 weeks of storage were fairly high (over 95%). In addition, average recoveries (chloride = 97%, nitrate = 96%, and sulfate = 103%) after 16 weeks of storage at low temperate were relatively higher than those (94%, 93%, and 98%) at room temperature. The coefficients of variation (CV) for the three ions were less than 5% except for the sulfate sample at 5.56 ㎍ (CV = 12.4%). The average ratios of the concentration values analyzed by the legally designated agencies to the injected concentrations were close to 1. However, their CVs were relatively greater (chloride ≤ 49%, nitrate ≤ 14%, and sulfate ≤ 28%), which implies a need for quality control. Conclusions: The quality control protocol used in this study for the three inorganic acids can be utilized in the quality control for ion chromatography.

• Journal of environmental and Sanitary engineering
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• v.20 no.1 s.55
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• pp.55-63
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• 2005

Ground water samples of 275 were collected from Gapyeong county which it contained six-eup and myeon and analyzed for 12 mineral inorganics extending from March to October in 2004. Among the inorganics, Calcium, Magnesium, Sodium, Potassium, Copper and Zinc had more than $70\%$ of detection frequencies, which coincided with essential inorganics required by the human body. The average values of inorganic contents by sampling sites were insignificant. Fluorine contents of 8 samples, $2.9\%$ of 275 samples, exceeded KDWR, and it was considered to be affected by a base rock being made up granite and gneiss because there were not polluting sources around. It is necessary to find out relation between geological characteristics and mineral inorganics in ground water through the further investigation. Compared to noted concentrations of bottled water, inorganic minerals including Calcium, magnesium, Sodium and Potassium related to taste were fluent double in target samples and those average concentrations were 14.80, 3.80, 7.60, and $2.31\cal{mg/L}$ respectively.

• Analytical Science and Technology
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• v.8 no.4
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• pp.835-841
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• 1995

The quantitation of inorganic anions in various drinking waters were investigated using capillary electrophoresis(CE) and the results were compared with ion chromatography(IC). With CE, in contrast to IC, was demonstrated rapid analysis, good efficiency, a low detection limit and the low comsumption of a solvent and samples. CE analysis was used 5 mM sodium chromate(pH 8.0) containing 20 mM tetraalkylammoniumbromide at -25kV applied voltage with indirect UV detection at 254 nm. This results in exceedingly short analysis time within 3 min. with efficiencies approaching 200,000 theoretical plates. The coefficients of variants of migration time are less than 0.8% and those of peak area are less than 2.3%. Detection limits for quantitative determination were 300 ppb-50 ppm level. These optimum conditions are applicable to various samples without pretreatment.