• 대한금속재료학회지
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• 제47권8호
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• pp.516-521
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• 2009

In this study we report a rapid synthesis of nanoporous organo-functional silica (OFS) with unimodal and bimodal pore structures encompassing pores ranging from meso-to macroscale. The problems of tediousness and high production cost in the conventional syntheses are overcome by co-condensation of an inexpensive inorganic precursor, sodium silicate with an organosilane containing trimethyl groups. The insitu covalent anchoring of the non-polar trimethyl groups to the inner pore walls prohibits irreversible shrinkage of the wet-gel during microwave drying at ambient pressure and thus larger size pores (from ca. 20 to ca. 100 nm) can be retained in the dried silica. The drying process of the silylated wet-gels at an ambient pressure can be greatly accelerated upon microwave exposure instead of drying in an oven or furnace. Using this approach, anoporous and superhydrophobic silicas showing a wide variation in texture and morphology can be readily synthesized in roughly two hours. The effects of various sol-gel parameters solely on the textural properties of the organo-functional silica (OFS) have been investigated and discussed.

• 폴리머
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• 제28권5호
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• pp.391-396
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• 2004

기존의 에폭시/실리카 나노복합재료의 제조 방법에서 나타나는 문제점인 경화 반응 중의 휘발성 부산물 생성에 의한 미세기공 형성 및 치수 불안전성 등을 극복하고자 Si-N 전구체를 사용한 새로운 방법을 제안하고자 한다. 실리카 전구체로 부산물이 형성되지 않는 메틸트리페닐실란 (MTPS)을 합성하고 이를 이용하여 솔-젤 반응과 에폭시 경화 반응이 병행되는 동시 복합화 반응을 통하여 무기상의 고른 분산상태를 지닌 에폭시/실리카 나노복합재료를 제조하였으며, 이로부터 뛰어난 투명성뿐 아니라 기계적 물성과 열적특성에서 탁월한 물성의 증가를 얻을 수 있었다.

• 한국재료학회지
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• 제23권2호
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• pp.143-148
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• 2013

Well-distributed $SnO_2$-Sn-$Ag_3Sn$ nanoparticles embedded in carbon nanofibers were fabricated using a co-electrospinning method, which is set up with two coaxial capillaries. Their formation mechanisms were successfully demonstrated. The structural, morphological, and chemical compositional properties were investigated by field-emission scanning electron spectroscopy (FESEM), bright-field transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). In particular, to obtain well-distributed $SnO_2$ and Sn and $Ag_3Sn$ nanoparticles in carbon nanofibers, the relative molar ratios of the Ag precursor to the Sn precursor including 7 wt% polyacrylonitrile (PAN) were controlled at 0.1, 0.2, and 0.3. The FESEM, bright-field TEM, XRD, and XPS results show that the nanoparticles consisting of $SnO_2$-Sn-$Ag_3Sn$ phases were in the range of ~4 nm-6 nm for sample A, ~5 nm-15 nm for sample B, ~9 nm-22 nm for sample C. In particular, for sample A, the nanoparticles were uniformly grown in the carbon nanofibers. Furthermore, when the amount of the Ag precursor and the Sn precursor was increased, the inorganic nanofibers consisting of the $SnO_2$-Sn-$Ag_3Sn$ nanoparticles were formed due to the decreased amount of the carbon nanofibers. Thus, well-distributed nanoparticles embedded in the carbon nanofibers were successfully synthesized at the optimum molar ratio (0.1) of the Ag precursor to the Sn precursor after calcination of $800^{\circ}C$.

• 대한전자공학회논문지
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• 제27권8호
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• pp.1250-1254
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• 1990

The cordierite (MgO, SiO2, Al2O3) is of great interest for microelectronic packaging of integrated circuits. Its main advantages are low dielectric constant and low thermal expansion. The cordierite precursor is obtained by sol-gel synthesis using organic and inorganic compounds. The obtained cordierite precursor is an amorphous state at about 900\ulcorner. Green and fired cordierite samples were studied by SEM. Microanalysis X and TEM for microscopic properties. The fired cordierite shows forte diminution of Mg in comparison with its value at volume and the deficit of Mg compensates by sugmentation of Al and Si \ulcornercordierite and \ulcornercordierite are present near the surface (< 100) and small quantities of magnesium aluminate (MgAl2O4)is presented spinnel phase.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.365.2-365.2
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• 2014

Nickel sulfide (NiS) has been utilized in optoelectronic applications, such as transformation-toughening agent for materials used in semiconductor applications, catalysts, and cathodic materials in rechargeable lithium batteries. Recently, high quality nickel sulfide thin films have been explored using ALD/CVD technique. Suitable precursors are needed to deposit thin films of inorganic materials. However, nickel sulfide precursors available for ALD/CVD process are very limited to nickel complexes with dithiocarbamate and alkanethiolate ligands. Therefore, it is essential to prepare novel nickel sulfide suitable for ALD/CVD precesses. Herein we report on the synthesis and characterization of new nickel sulfide complex with designed aminothiolate ligand. Furthermore thin films of NiS have been prepared on silicon oxide substrates by spin coating nickel precursor 10 wt% in THF. The novel complex has been characterized by means of 1H-NMR, elemental analysis, thermogravimetric analysis (TGA), X-ray Diffraction (XRD) and scanning electron microscope (SEM).

• The Korean Journal of Ceramics
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• 제6권3호
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• pp.245-249
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• 2000

Consolidation of amorphous powders is emerging as a route for synthesis of high strength composite materials. Diffusion processes necessary for consolidation are expected to be more rapid in amorphous state(SRO) than in the crystalline state(LRO). A new synthesis technique of exploiting polymeric ceramic precursors(polysilazane and polyborosilazane) is derived for Si$_3$N$_4$/SiC and boron-modified nanocomposites for extremely high temperature applications up to 200$0^{\circ}C$. The characterization methods include thermal analysis of DTA, and XRD, NMR, TEM, after pyrolysis, as a function of time and temperature.

• 한국세라믹학회지
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• 제39권4호
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• pp.336-340
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• 2002

Pure and nano-sized $TiO_2$ and $CaTiO_3$ powders were fabricated by a polymeric steric entrapment route and planetary milling process. An ethylene glycol was used as a polymeric carrier for the preparation of organic-inorganic precursors. Titanium isopropoxide and calcium nitrate were dissolved in liquid-type ethylene glycol without any precipitation. At the optimum amount of the polymer, the metal cations were dispersed in solution and a homogeneous polymeric network was formed. The dried precursor ceramic gels were turned to porous powders through calcination process. The porous powders were crystallized at low temperatures and the crystalline powders were planetary milled to nano size.

• Bulletin of the Korean Chemical Society
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• 제28권12호
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• pp.2333-2337
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• 2007

Nanoporous TiO2 and ZrO2 thin films were spin-coated using a surfactant-templated approach from Pluronic P123 (EO20PO70EO20) as the templating agent, titanium alkoxide (Ti(OC4H9)4) as the inorganic precursor, and butanol as a the solvent. The control of the electronic structure of TiO2 is crucial for its various applications. We found that the band gap of the hybrid nanoporous thin films can be easily tuned by adding an acetylacetonestabilized Zr(OC4H9)4 precursor to the precursor solution of Ti(OC4H9)4. Pores with a diameter of 5 nm-10 nm were randomly dispersed and partially connected to each other inside the films. TiO2 and ZrO2 thin films have an anatase structure and tetragonal structure, respectively, while the TiO2-ZrO2 hybrid film exhibited no crystallinity. The refractive index was significantly changed by varying the atomic ratio of titanium to zirconium. The band gap for the nanoporous TiO2 was estimated to 3.43 eV and that for the TiO2-ZrO2 hybrid film was 3.61 eV.

• 한국재료학회지
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• 제6권2호
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• pp.182-187
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• 1996

물과 에탄올의 혼합용액에 HCI을 촉매로하여 금속알콕사이드의 가수분해로부터 코오디어라이트 분말을 제조하였다. 이때 HCI/precursor 몰비로써 촉매의 양을 조절하였다. 건조분말 중의 용매를 제거하기위해 80$0^{\circ}C$에서 3시간 하소처리하였다. 이들 하소된 분말에 대하여 시차열분석과 X-선회절분석을 행한 결과-92$0^{\circ}C$에서 $\mu$-cordierite, -103$0^{\circ}C$에서 $\alpha$-cordierite 결정상의 생성을 확인하였다. 또한, 하소분말을 가압성형한 후 130$0^{\circ}C$에서 4시간 열처리한 결과 HCI양에 따라 기공율 19.45-25.45%, 부피비중 2.06-1.70g/㎤, 유전상수 1.38-3.38 범위의 소결체를 얻었다. HCI양이 증가할수록 기공율은 증가한 반면에 비유전상수와 부피비중은 감소하였다.

• 한국광학회지
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• 제11권4호
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• pp.255-260
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• 2000

유기 금속화합물을 출발물질로 이용하는 졸-겔 방법으로 균열이 없는 유기-무기 복합 실리카 박막을 제작하였으며, 코팅방법, 조성비, prebake, postbake 온도 등의 제작조건에 따른 박막의 두께 및 굴절률의 변화를 체계적으로 조사하여 재현성 있는 제작조건을 확립하였다. 특히 광개시제를 첨가하였을 때 자외선 노광량에 따른 광학적 성질변화를 세 가지 광개시제에 대하여 측정, 비교하였다. 또한 졸-겔 박막으로 다중모드 간섭을 이용한 광 파워 분배기를 제작하여 광소자로의 응용 가능성을 살펴보았다.