• 제목/요약/키워드: Inorganic polymer

검색결과 494건 처리시간 0.033초

무기폴리머계 모르타르의 결합재 Si/Al 몰비 변화에 따른 물리적 특성 (An Experimental Study on the Physical Properties with Changes to Si/Al Mol Ratio of Inorganic Polymer Mortar Binder)

  • 최해영;박동철
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
    • /
    • pp.749-752
    • /
    • 2008
  • 본 연구에서는 시멘트 결합재를 사용하는 모르타르의 성능개선을 위한 방법으로 무기폴리머 결합재를 사용한 모르타르에 있어서 무기폴리머 결합재의 Si/Al 몰비에 따른 물리적 특성변화를 확인하고자 하였다. 무기폴리머 결합재는 주성분이 Si와 Al로 구성되어 있으며 이 성분들의 혼합비에 따라 물리적, 화학적 성능에 있어서 큰 차이가 나타나는 것으로 알려져 있다. 따라서 Si와 Al의 혼합 구성비에 따른 모르타르의 물리적 성능에 대한 영향연구에 관한 기초 근거자료를 재공하고자 평가를 실시하였다. 그 결과, 무기폴리머 결합재의 Si/Al 몰비가 증가할수록 조기강도는 증가하나 급격한 반응으로 작업성이 저하되며 28일 재령 확인결과 Si/Al 몰비가 2.61 이상인 경우에 수축현상이 심해지는 것으로 확인되었다. 그리고 무기폴리머 결합재의 Si/Al 몰비가 $2.43{\sim}2.61$ 범위내인 경우 상용 폴리머 시멘트 모르타르와 비교시 압축강도가 재령7일차에는 32% 이상 증가하는 것을 확인하였으며 재령 28일차에는 12% 이상 증가하는 것을 확인하였다.

  • PDF

열전도성 입자를 활용한 시트용 점착제의 점착 특성과 방열특성 연구 (Comparative Analysis of Heat Sink and Adhesion Properties of Thermal Conductive Particles for Sheet Adhesive)

  • 김영수;박상하;최정우;공이성;윤관한;민병길;이승한
    • 한국염색가공학회지
    • /
    • 제28권1호
    • /
    • pp.48-56
    • /
    • 2016
  • Improvement of heat sink technology related to the continuous implementation performance and extension of device-life in circumstance of easy heating and more compact space has been becoming more important issue as multi-functional integration and miniaturization trend of electronic gadgets and products has been generalized. In this study, it purposed to minimize of decline of the heat diffusivity by gluing polymer through compounding of inorganic particles which have thermal conductive properties. We used NH-9300 as base resin and used inorganic fillers such as silicon carbide(SiC), aluminum nitride(AlN), and boron nitride(BN) to improve heat diffusivity. After making film which was made from 100 part of acrylic resin mixed hardener(1.0 part more or less) with inorganic particles. The film was matured at $80^{\circ}C$ for 24h. Diffusivity were tested according to sorts of particles and density of particles as well as size and structure of particle to improve the effect of heat sink in view of morphology assessing diffusivity by LFA(Netzsch/LFA 447 Nano Flash) and adhesion strength by UTM(Universal Testing Machine). The correlation between diffusivity of pure inorganic particles and composite as well as the relation between density and morphology of inorganic particles has been studied. The study related morphology showed that globular type had superior diffusivity at low density of 25% but on the contarary globular type was inferior to non-globular type at high density of 80%.

탄소나노튜브 강화 나노복합재료의 연구현황 (Research Status on the Carbon Nanotube Reinforced Nanocomposite)

  • 차승일;김경태;이경호;모찬빈;홍순형
    • 한국복합재료학회:학술대회논문집
    • /
    • 한국복합재료학회 2003년도 추계학술발표대회 논문집
    • /
    • pp.25-28
    • /
    • 2003
  • Carbon nanotubes(CNTs), since their first discovery, have been considered as new promising materials in various fields of applications including field emission displays, memory devices, electrodes, NEMS constituents, hydrogen storages and reinforcements in composites due to their extra-ordinary properties. The carbon nanotube reinforced nanocomposites have attracted attention owing to their outstanding mechanical and electrical properties and are expected to overcome the limit of conventional materials. Various application areas are possible for carbon nanotube reinforced nanocomposites through the functionalization of carbon nanotubes. Carbon nanotube reinforced polymer matrix nanocomposites have been fabricated by liquid phase process including surface functionalization and dispersion of CNTs within organic solvent. In case of carbon nanotube reinforced polymer matrix nanocomposites, the mechanical strength and electrical conducting can be improved by more than an order of magnitude. The carbon nanotube reinforced polymer matrix nanocomposites can be applied to high strength polymers, conductive polymers, optical limiters and EMI materials. In spite of successful development of carbon nanotube reinforced polymer matrix nanocomposites, the researches on carbon nanotube reinforced inorganic matrix nanocomposites show limitations due to a difficulty in homogeneous distribution of carbon nanotubes within inorganic matrix. Therefore, the enhancement of carbon nanotube reinforced inorganic nanocomposites is under investigation to maximize the excellent properties of carbon nanotubes. To overcome the current limitations, novel processes, including intensive milling process, sol-gel process, in-situ process and spark plasma sintering of nanocomposite powders are being investigated. In this presentation, current research status on carbon nanotube reinforced nanocomposites with various matrices are reviewed.

  • PDF

Polymer-directed Crystallization of Sibutramine using Cellulose Derivatives

  • Bae, Ha-Rim;Lee, Hye-Seung;Lee, Min-Kyung;Lee, Jong-Hwi
    • Journal of Pharmaceutical Investigation
    • /
    • 제41권1호
    • /
    • pp.45-50
    • /
    • 2011
  • Nonclassical pathway of crystallization has been utilized to modify the properties and morphologies of inorganic and organic/inorganic materials. In here, the polymer-directed crystallization method has been applied to the pharmaceutical active ingredient to assess the applicability for as a particle engineering tool. The polymer-directed crystallization was successful to modifying the crystal size, habit and morphology, but it was not effective to discover the novel polymorphs of Sibutramine (SB). SB was selected as a model drug and polyacrylic acid (PAA), polyethylene imine (PEI) and chitosan (CHI) were added as a crystallization pathway modifier. SB was crystallized via drowning crystallization using methanol or ethanol as a solvent and water as a non-solvent. The significant interactions between polymer and the drug were confirmed by measuring the solubility of the drug in presence of polymer during the crystallization. The crystal forms of SB are characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and optical microscope (OM). The polymer-directed crystallization seems to be able to modify the crystal properties of pharmaceutical active ingredient, which is critical in determining the bioavailability, processability, and stability.

Interfacial Layers for High Efficiency Polymer Solar Cells

  • Kim, Youn-Su;Choi, Ha-Na;Son, Seon-Kyoung;Kim, Ta-Hee;Kim, Bong-Soo;Kim, Kyung-Kon
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
    • /
    • pp.74-74
    • /
    • 2011
  • Polymer solar cells utilize bulk heterojunction (BHJ) type photo-active layer in which the electron donating polymer and electron accepting C60 derivatives are mixed together. In the BHJ system the electron donating polymer and electron accepting C60 derivatives are blended. The blended system causes charge recombination at the interface between the BHJ active layer and electrode. To reduce the charge recombination at the interface, it is needed to use an interlayer that can selectively transfer electrons or holes. We have developed solution processable wide band gap inorganic interfacial layers for polymer solar cells. The effect of interlayers on the performance of polymer solar cell was investigated for various types of conjugated polymers. We have found that inorganic interfacial layers enhanced the solar cell efficiency through the reduction of charge recombination at the interface between active layer and electrode. Furthermore, the stability of the polymer solar cell using the interlayer was significantly improved. The efficiency of 6.5% was obtained from the PTB7:PCBM70 based solar cells utilizing $TiO_2$nanoparticles as an interlayers.

  • PDF

Nano Patterning Functional Polymers Using Nano-imprint Technique

  • 권현근;이규태
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
    • /
    • pp.430.2-430.2
    • /
    • 2014
  • Previous studies to enhance optical properties of opto-electronic devices involve patterning of inorganic materials. Patterning of inorganic material usually encompasses vacuum process that hinders productivity and increases cost. In this research, we successfully formed nano patterns with polymer matrix and fabricated photonic crystals. This process is anticipated to increase the performance of opto-electronic devices without any vacuum process. Moreover, nano imprint technology reduces cost and bolsters productivity.

  • PDF

The use of ZrO2 as an electron-injecting layer in hybrid metal-oxide/polymer light-emitting diodes

  • Tokmoldin, Nurlan;Bradley, Donal D.C.;Haque, Saif
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
    • /
    • pp.779-780
    • /
    • 2009
  • New inverted architecture of a hybrid inorganic-organic light-emitting diode, utilizing ZrO2 electron-injecting layer, is presented. The thickness of the ZrO2, as well as the annealing of the light-emitting polymer, is found critical to obtain good performance. A range of light-emitting polymers is shown to operate efficiently in the proposed architecture.

  • PDF

Gate dielectric based on organic-inorganic hybrid polymer in organic thin-film transistors

  • Lee, Seong-Hui;Jeong, Sun-Ho;Moon, Joo-Ho
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
    • /
    • pp.727-729
    • /
    • 2007
  • Inorganic-organic hybrid polymer provides various advantages including low-temperature process, high dielectric constant and direct photo-patterning. The hybrid dielectric was synthesized by the sol-gel process in which an acid-catalyzed solution of Si alkoxide and Zr alkoxide was used as a precursor. The electrical performance of transistors with hybrid dielectric was investigated.

  • PDF

자기치유 공학재료: II. 무기재료 (Self-healing Engineering Materials: II. Inorganic Materials)

  • 김민희;강동은;윤지환;최은지;심상은;윤주호;김일
    • 청정기술
    • /
    • 제17권2호
    • /
    • pp.85-96
    • /
    • 2011
  • 자기치유재료란 장기간 사용에 의한 기계적 충격에 의해 발생된 손상을 치료할 수 있는 능력을 발휘하도록 구조적, 화학적으로 개질시킨 스마트 재료의 하나이다. 사용에 손상이 일어난 부위를 본질적으로 치유할 수 있는 재료(고분자, 세라믹, 금속 등)를 사용함으로써 부품의 수명을 길게 할 수 있고, 장기간 사용에 의한 분해로 야기되는 효율의 감소를 막을 수 있으며, 재료의 파괴에 의한 비용지출을 막을 수 있어 여러 산업 공정의 생산단가를 낮출 수 있다. 최근 차량용 자기치유 페인트가 가능하다는 니싼의 발표 이후 재료의 자기치유능력에 대한 관심이 고조되고 있다. 본 총설에서는 앞서 발표한 자기치유 유기재료에 이어 금속, 세라믹, 콘크리트 등 무기 재료의 자기치유방법에 대해서 알아보고, 향후의 방향을 제시하고자 한다.