• Title/Summary/Keyword: Inorganic Salt

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Watertightness and Crack Reduction Property of Concrete added Fluosilicate Salt Based Inorganic Compound for Watertight Concrete (수밀 콘크리트용 규불화염계 무기 조성물을 첨가한 콘크리트 수밀성 및 균열저감 특성)

  • Kim Da-Su;Khil Bae-Su;Choi Se-Jin;Park Min-Yong;Lee Seong-Yeon;Yeo Byung-Chul
    • Proceedings of the Korean Institute of Building Construction Conference
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    • v.y2004m10
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    • pp.33-38
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    • 2004
  • This study was performed to know watertightness and reduction effect and crack occurred by hydration heat, restraint of multiplication of hydration heat, through mechanical test, strength test and crack control test using fluosilicate salt based inorganic compound made from by-product during phosphoric acid manufacturing process. Mix proportions for experiment were modulated at 0.45 of water to cement ratio and $0.5-2.0\%$ of adding ratio of fluosilicate salt based inorganic compound. Evaluation for watertightness of concrete was carried out permeability, absorption test and porosity analysis. Effect of crack reduction was evaluated by length, drying shrinkage as well as stress change of hardened concrete at unrestraint/restraint state and also elucidated crack pattern on the concrete surface. It is ascertained that characteristics of crack resistance and watertightness for concrete was improved by an adequate addition of fluosilicate salt based inorganic compound.

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Durability and Crack Control of Concrete Using Fluosilicates Based Composite (규불화염계 복합 조성물을 혼입한 콘크리트의 균열제어 및 내구성)

  • Yun, Hyun-Do;Yang, Il-Seung;Kim, Do-Su;Khil, Bae-Su;Han, Seung-Gu
    • Journal of the Korea Concrete Institute
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    • v.18 no.1 s.91
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    • pp.57-64
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    • 2006
  • The crack presented in concrete structures causes a structural defect, the durability decrease, and external damages etc. Therefore, it is necessary to improve durability through the effort to control the crack. Fluosilicic acid($H_2SiF_6$) is recovered as aqueous solution which absorbs $SiF_4$ produced from the manufacturing of industrial-graded $H_3PO_4$ or HF. Generally, fluosilicates prepared by the reaction between $H_2SiF_6$ and metal salts. Addition of fluosilicates to cement endows odd properties through unique chemical reaction with the fresh and hardened cement. Mix proportions for experiment were modulated at 0.45 of water to cement ratio and $0.0{\sim}2.0%$ of adding ratio of fluosilicate salt based inorganic compound. To evaluate correlation of concrete strength and adding ratio of fluosilicate salt based inorganic compound, the tests were performed about design strength(21, 24, 27 MPa) with 0.5% of adding ratio of fluosilicate salt based inorganic compound. Applications of fluosilicate salt based inorganic compound to reduce cracks resulted from plastic and drying shrinkage, to improve durability are presented in this paper. Durability was evaluated as neutralization, chloride ion penetration depth, freezing thawing resistant tests and weight loss according reinforcement corrosion. It is ascertained that the concrete added fluosilicate salt based inorganic compound showed m ability to reduce the total area and maximum crack width significantly as compared non-added concrete. In addition, the durability of concrete improved because of resistance to crack and watertightness by packing role of fluosilicate salt based inorganic compound obtained and pozzolanic reaction of soluble $SiO_2$ than non-added concrete.

Experimental Study on Physical Properties and Water Absorption Resistance Evaluation of Cement Mortar Incorporating Inorganic Metal Salt-based Water Repellent Powder (무기물 금속염계 발수분체를 혼입한 시멘트 모르타르의 물리적 특성 및 수분흡수저항성에 대한 실험적 연구)

  • Lee, Won Geun;Yoon, Chang Bok
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.609-616
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    • 2021
  • In this experimental, water-repellent powder, which is a metal salt-based inorganic substance, and natural zeolite powder, which is a pozzolan-based material, were mixed into cement mortar, and their physical properties and resistance to moisture were confirmed. It was confirmed that the test specimen using natural zeolite at the same time had excellent resistance in the water permeation test and the chloride penetration test as compared with the test specimen in which the inorganic metal salt-based water-repellent powder was mixed alone. When a metal salt-based water-repellent powder is used, it cannot be uniformly dispersed inside water due to its insoluble property, and is limited to the surface. When used at the same time as natural zeolite, the setting time at the initial stage of hydration is fast due to the pozzolan reaction, and the water-repellent powder adheres to the porous of the natural zeolite and is evenly distributed inside the test specimen to generate some water resistance.

Intercalation of Functional Organic Molecules with Pharmaceutical, Cosmeceutical and Nutraceutical Functions into Layered Double Hydroxides and Zinc Basic Salts

  • Hwang, Seong Ho;Han, Yang Su;Choe, Jin Ho
    • Bulletin of the Korean Chemical Society
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    • v.22 no.9
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    • pp.1019-1022
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    • 2001
  • Negatively charged functional organic molecules such as retinoic acid, ascorbic acid, indole acetic acid, citric acid, salicylic acid, acidic dye (indigo carmine, Food Blue 1) are intercalatively encapsulated by zinc basic salt (hydrozincite) and layered double hydroxide. Such functional organic-inorganic nanohybrids are realized via coprecipitation reaction involving simultaneous formation of layered inorganic lattice and intercalation of anionic species. The heterostructural nature of these nanohybrids, their particle morphology and textural characterizations are mainly discussed on the basis of Powder X-ray Diffraction and Field Emission Scanning Electron Microscopy results.

Inorganic Salts which effect on IDOD Value (IDOD에 영향(影響)을 주는 환원성호기물에 관(關)한 연구(硏究))

  • Kim, Hang-Joon
    • Journal of Preventive Medicine and Public Health
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    • v.11 no.1
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    • pp.83-85
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    • 1978
  • IDOD (Immediate Dissolved Oxygen Demand) is a value of the oxygen demand after 15 minute of inoculation by inorganic reducing salts. Industrial development and urban enlargement are bringing water pollution deeply, and industrial waste waters are the source of the inorganic reducing salts. Author investigated the IDOD value change according to the inorganic salts and gained the following results: 1. IDOD value influenced by $Na_{2}SO_3$ is 81.4 ppm. 2. Generally sulfur compounds are highly effecting on IDOD. 3. The nitrite salt had little influence on IDOD.

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Distribution and Cyclings of Nutrients in Phragmites communis Communities of a Coastal Salt Marsh (해안염습지 갈대 군락의 무기영양소 순환과 분배)

  • 민병미
    • Journal of Plant Biology
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    • v.26 no.1
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    • pp.17-32
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    • 1983
  • The aboveground production, nutrient distribution and nutrient cyclings were compared between two Phragmites communis communities growing in the different salt contents of soil in a coastal salt marsh. Inorganic nutrient contents of soil for plant growth were greater at the low salt stand than at the high salt stand except for sodium(Na). Maximum aboveground biomass of the plant at the low and the high salt stands were 2,533 and 1,719 g dw/$m^2$, respectively, in August. Seasonal changes of nutrient content of biomass in dry weight decreased with growth except for Na. Nutrient contents in biomass per unit land area increased continuously as biomass increases, although the amount of potassium(K) reached the maximum content in July and thereafter decreased. Vertical distributions of total nitrogen(T-N) and phosphorus(P) increased with plant height, but Na showed the reverse trend. That of K was similar to the patterns for T-N and P in the leaves, and to the pattern of Na in the stems. The Na was greatly accumulated in underground biomass but transported scarcely to aboveground. At the low and the high salt stands, the ratios of the inorganic nutrients contained in the plant were 100 : 66 for T-N, 100 : 61 for P, 100 : 62 for K and 100 : 97 for Na. the ratios of the amounts of nutrients retrieved to soil were 100 : 242 for T-N, 100 : 408 for P, 100 : 127 for K and 100 : 269 for Na, respectively. Turnover times of the T-N, P, K and Na in the communities were 56, 1, 15 and 174 years at the low salt stand, and 75, 2, 24 and 323 years at the high salt stand, respectively. In nutrient cyclings, all of the nutrients retrieving to soil were less than uptake by plant. Among the nutrient, especially P is expected to be exhausted from soil, sooner or later, because of the harvest by men.

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Effect of Inorganic Salt Additives on Formation of Phase-Inversion Polyethersulfone Ultrafiltration Membrane (상변환 Polyethersulfone 한외여과막 제조시 무기염 첨가 효과)

  • 김민정;이상덕;염경호
    • Membrane Journal
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    • v.12 no.2
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    • pp.75-89
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    • 2002
  • The effect of addition of inorganic salts in polyethersulfone (PES) polymer solution on the membrane formation and ultrafiltartion performance was studied through the thermodynamic and kinetic properties of casting solution. To control the thermodynamic and kinetic properties of casting solution, various inorganic salts $[CaC1_2, LiCl, LiClO_4, ZnC1_2 $and Mg(ClO_4)_2]$ were added in the PES/NMP solution. Variation of membrane morphology and performance of the resulting membranes with change of the salt type and content added in tasting solution were discussed using viscosity, coagulation value, light transmittance measurement, overall membrane porosity, ultrafiltration experiment and cross-sectional SEM image. For all kind of inorganic salts, according as increase of the salt content in casting solution, viscosity is increased, coagulation value becomes lower, top layer thickness below the skin surface is increased, bovine serum albumin(BSA) rejection decreased and pure water flux is increased except $CaC1_2$ and LiCl. In case of $CaC1_2$ and LiCl, it is found that when the salt content is increased, the formation of macrovoids is suppressed and the precipitation rate becomes slow while instantaneous demixing of precipitation type is maintained. However, in case of $LiClO_4$ and $Mg(ClO_4)_2,$ it is found that precipitation rate becomes faster.

Heat Transfer Characteristics of High Temperature molten salt storage for Solar Thermal Power Generation (태양열 발전을 위한 고온 축열 물질의 열전달 특성)

  • Aiming, Mao;KIm, Ki-Man;Han, Gui-Young;Seo, Tae-Beom;Kang, Yong-Heack
    • Journal of the Korean Solar Energy Society
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    • v.27 no.3
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    • pp.63-69
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    • 2007
  • The heat transfer characteristics of inorganic salt for high temperature heat storage material of solar power system were examined. The inorganic salts employed in this study was a mixture of $NaNO_3$ and $KNO_3$ and the operating temperature range was determined by measuring the melting temperature with DSC and by measuring the thermal decomposition temperature with TGA. The heat transfer characteristics was qualitatively obtained in terms of temperature profiles of salt in the tanks during the heat storage and heat release process as a function of steam flow rates, steam inlet temperature and the inlet position of steam. The effects of steam flow rates and inlet temperature of steam were experimentally determined and the effect of natural convection was observed due to significant density difference with temperature.

Liquid-Liquid Extraction for Recovery of Paclitaxel from Plant Cell Cultures by Adding Inorganic Salts (식물세포배양으로부터 파클리탁셀 회수를 위한 무기염이 첨가된 액-액 추출)

  • Ha, Geon-Soo;Kim, Jin-Hyun
    • Korean Chemical Engineering Research
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    • v.54 no.1
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    • pp.135-139
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    • 2016
  • We developed a liquid-liquid extraction method using an inorganic salt to dramatically improve the recovery efficiency of the anticancer agent paclitaxel from plant cell cultures. As a result of liquid-liquid extraction using a diverse types of inorganic salt (NaCl, KCl, $K_2HPO_4$, $NaH_2PO_4$, $NaH_2PO_4{\cdot}2H_2O$), NaCl gave the highest yield (~96%) and lowest partition coefficient (0.053) of paclitaxel. The optimal NaCl/solvent ratio, methylene chloride/MeOH ratio, and pure paclitaxel content for liquid-liquid extraction using NaCl were 1% (w/v), 26% (v/v), and 0.066% (w/v), respectively. Under the optimal conditions developed in the present method, most of the paclitaxel (~96%) was recovered from biomass by a single extraction step. In addition, this method facilitated 3-fold higher recovery efficiency of paclitaxel in a shorter extraction number than the conventional liquid-liquid extraction method.

Analysis of Quality Characteristics of Regional Traditional and Commercial Soybean Pastes (Doenjang) (지역별 전통된장과 개량된장의 품질특성)

  • Park, Sun-Young;Kim, Seulki;Hong, Sang-pil;Lim, Sang-Dong
    • Korean journal of food and cookery science
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    • v.32 no.6
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    • pp.686-695
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    • 2016
  • Purpose: This study aimed to investigate the quality characteristics of traditional and commercial soybean pastes (Doenjang) for development of traditional soybean pastes. Methods: Proximate compositions, amino acid nitrogen contents, pH, acidity, salt contents, chromaticity, viable bacteria and inorganic substance contents of nineteen traditional and three commercial Doenjang were investigated. Results: Analysis of proximate compositions indicated a significant difference between samples. In moisture content, D10 did not meet the standard of food codex. The contents of moisture, fat, protein and ash were slightly higher in traditional than commercial Doenjang. However, the carbohydrate content was 2-fold higher in commercial than traditional, and thus, the calories were also higher. The amino nitrogen content was lower in commercial than traditional Doenjang. pH, acidity and salt contents of Doenjang were pH 4.67-6.15, 1.53-3.29%, and 9.01-18.78%, respectively. pH and acidity showed no significant differences between traditional and commercial Doenjang, however, salt contents were significantly higher in traditional than commercial Doenjang. In case of chromaticity, the averages of L, a, b values were higher in traditional Doenjang. In microbiological analysis, total bacteria counts were higher in traditional than commercial Doenjang. The number of Bacillus cereus in D12 and D19 exceeded the standard of food codex. Staphylococcus aureust was undetected in all samples. The number of fungi varied widely between samples, with no detection in five traditional and all commercial Doenjang. Results of inorganic substance analysis indicated that contents of inorganic substances in Doenjang were in order of Na, K, Mg and Ca. Overall, Na content was higher in traditional Doenjang. Contents of inorganic substances showed wide variations in traditional Doenjang. Conclusion: For the development of traditional Doenjang, quality standardization and ensuring safety are considered necessary.