• Title/Summary/Keyword: Injection barrier

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Dependance on Metal Electrode of Poly(3-hexylthiophene) EL Device (Poly(3-hexylthiophene) 발광소자의 금속전극 의존성)

  • 서부완;김주승;김형곤;이경섭;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.162-165
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    • 2000
  • To investigate the effect of metal electrode in electroluminescent[EL] devices, we fabricated EL devices of ITO/P3HT/Al, ITO/P3HT/LiF/Al and ITO/P3HT/Mg:In structure. In current-voltage-light power characteristics, turn-on voltage of EL devices using LiF insulating layer and Mg:In(2.8V) metal electrode is lower than EL device using Al(4.2V). Besides the external quantum efficiency is improved also. The reason is related to carrier mobility and carrier injection, which would affect the hole-electron balance. In the device with Al electrode, holes injected from indium-tin-oxide[ITO] to poly(3-hexylthiophene)[P3HT] might reach the Al electrode without interacting with injected electrons, because the electron injection efficiency was very low for this electrode. Besides oxidation of the Al electrode is likely due to holes reaching the cathode without meeting injected electrons. Another possible reason for the higher EL efficiency may be the insulating layer playing the role of a tunneling barrier for holes to the Al electrode. In all EL devices, the orange-red light was clearly visible in a dark room. Maximum peak wavelength of EL spectrum emitted at 640nm in accordance with photon energy 1.9eV

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Schottky Barrier Free Contacts in Graphene/MoS2 Field-Effect-Transistor

  • Qiu, Dongri;Kim, Eun Kyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.209.2-209.2
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    • 2015
  • Two dimensional layered materials, such as transition metal dichalcogenides (TMDs) family have been attracted significant attention due to novel physical and chemical properties. Among them, molybdenum disulfide ($MoS_2$) has novel physical phenomena such as absence of dangling bonds, lack of inversion symmetry, valley degrees of freedom. Previous studies have shown that the interface of metal/$MoS_2$ contacts significantly affects device performance due to presence of a scalable Schottky barrier height at their interface, resulting voltage drops and restricting carrier injection. In this study, we report a new device structure by using few-layer graphene as the bottom interconnections, in order to offer Schottky barrier free contact to bi-layer $MoS_2$. The fabrication of process start with mechanically exfoliates bulk graphite that served as the source/drain electrodes. The semiconducting $MoS_2$ flake was deposited onto a $SiO_2$ (280 nm-thick)/Si substrate in which graphene electrodes were pre-deposited. To evaluate the barrier height of contact, we employed thermionic-emission theory to describe our experimental findings. We demonstrate that, the Schottky barrier height dramatically decreases from 300 to 0 meV as function of gate voltages, and further becomes negative values. Our findings suggested that, few-layer graphene could be able to realize ohmic contact and to provide new opportunities in ohmic formations.

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Artificial Injection to Control Saltwater Intrusion in Groundwater-Numerical Study on a Vertical Cross Section (지하수 해수쐐기 제어를 위한 인공주입-연직 2차원 단면 수치실험)

  • Hong, Sung-Hoon;Shi, Lei;Cui, Lei;Park, Nam-Sik
    • The Journal of Engineering Geology
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    • v.19 no.2
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    • pp.131-138
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    • 2009
  • A simulation-optimization model is developed for development of groundwater and control of a saltwater wedge for protecting over-exploiting freshwater pumping wells. To achieve the goal an objective function is developed for three types of wells: freshwater pumping, freshwater injection and saltwater pumping. Integrity of groundwater environment is accounted for by including three indices. Illustrative cross-sectional examples show that both types of barriers can protect freshwater pumping wells from saltwater intrusion. A barrier well operating at the same rate located anywhere within a certain reach can protect a pumping well. However, the location of the reach appears to contradict the common practice of barrier placements. Consideration of the groundwater environment yields a unique optimal location for barrier wells.

Effect of the Surface Roughness of Electrode on the Charge Injection at the Pentacene/Electrode Interface (전극 표면의 거칠기가 펜터신/전극 경계면의 전류-전압 특성에 주는 영향)

  • Kim, Woo-Young;Jeon, D.
    • Journal of the Korean Vacuum Society
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    • v.20 no.2
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    • pp.93-99
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    • 2011
  • We investigated how the surface roughness of electrode affects the charge injection at the pentacene/Au interface. After depositing Au film on the Si substrate by sputtering, we annealed the sample to control the Au surface roughness. Pentacene and Au top electrode were subsequently deposited to complete the sample. The nucleation density of pentacene was slightly higher on the rougher Au electrode, but surface morphologies of thick pentacene films were similar on both the as-prepared and the roughened Au electrodes. The current-voltage curves obtained from the Au/pentacene/Au structure measured as a function of temperature indicated that the interface barrier was higher for the rougher Au bottom-electrode. We propose that the higher barrier was caused by the lower work function of rougher electrode surface and the higher trap density at the interface.

Degradation characteristics and upgrading biodegradability of phenol by dielectric barrier discharge plasma using catalyst (촉매 물질을 적용한 유전체 장벽 방전 플라즈마의 페놀 분해 특성 및 생분해도 향상)

  • Shin, Gwanwoo;Choi, Seungkyu;Kim, Jinsu;Weon, Kyoungja;Lee, Sangill
    • Journal of Korean Society of Water and Wastewater
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    • v.34 no.1
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    • pp.75-83
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    • 2020
  • This study investigated the degradation characteristics and biodegradability of phenol, refractory organic matters, by injecting MgO and CaO-known to be catalyst materials for the ozonation process-into a Dielectric Barrier Discharge (DBD) plasma. MgO and CaO were injected at 0, 0.5, 1.0, and 2 g/L, and the pH was not adjusted separately to examine the optimal injection amounts of MgO and CaO. When MgO and CaO were injected, the phenol decomposition rate was increased, and the reaction time was found to decrease by 2.1 to 2.6 times. In addition, during CaO injection, intermediate products combined with Ca2+ to cause precipitation, which increased the COD (chemical oxygen demand) removal rate by approximately 2.4 times. The biodegradability of plasma treated water increased with increase in the phenol decomposition rate and increased as the amount of the generated intermediate products increased. The biodegradability was the highest in the plasma reaction with MgO injection as compared to when the DBD plasma pH was adjusted. Thus, it was found that a DBD plasma can degrade non-biodegradable phenols and increase biodegradability.

Effect of Insamyangyoung-tang on the TEWL of High Dose Steroid Injected Hairless Mice (인참양영탕(人參養榮湯)이 장기간 고용량 스테로이드 투여 hairless mice의 피부장벽에 미치는 영향)

  • Nam, Hae-Jeong;Kim, Yoon-Bum
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • v.21 no.2
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    • pp.19-27
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    • 2008
  • Objective : The side effect of prolonged use of topical corticosteroids to skin is well-known. Moreover, resent studies have shown that prolonged use of systemic corticosteroids also negatively impacts skin barrier function. Corticosteroids have a major role in the practical management of many variable conditions. So, it is important to find the drug or the method which could protect the skin from the damage caused by corticosteroids. At former study, we investigated that Insamyangyoung-tang has some effect on skin barrier function of DNCB induced contact dermatitis hairless mice. So, this study was performed to research the effect of Insamyangyoung-tang on the TEWL with high dose steroid injected hairless mice. Method : Hairless mice were divided into 4 groups ; Control group, Group A, Group B and Group C. All groups were injected triamcinolone O.4mg for 10 times. Control group was medicated distilled water during the experimental period. Group A was medicated distilled water for 5 days before the $1^{st}$ injection day, and then medicated Insamyangyoung-tang extract during the experimental period. Group B was medicated Insamyangyoung-tang extract for 5 days before the $1^{st}$ injection day, and then medicated distilled water during the experimental period. Group C was medicated Insamyangyoung-tang extract for 5 days before the $1^{st}$ injection day, and then medicated Insamyangyoung-tang extract during the experimental period. TEWL of each group was measured for 5 times. After the $10^{th}$ injection, the tissue sample was made and the damage of epithelial cell was examined. Statistical significance was set at p<0.05 by using non parametric methods and repeated-anova.. Results : Group C showed significant effect on TEWL change of hairless mice evoked by triamcinolone injection. Group A and Group B also showed some effect, but there was no statistical significance.

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Effects of injection route, volume and concentration of mannitol on blood-brain barrier disruption (Mannitol의 주입 경로와 양 및 농도가 혈-뇌 장벽 손상에 미치는 효과)

  • Cha, Myeoung-Hoon;Lee, Kyu-Hong;Lee, Chul-Hyun;Chung, Myung-Ae;Sohn, Jin-Hun;Cheong, Chae-Joon;Lee, Bae-Hwan
    • Science of Emotion and Sensibility
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    • v.11 no.4
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    • pp.565-574
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    • 2008
  • Functions of human brain including sensibility and emotion may be affected by drugs mediated by the blood-brain barrier (BBB). The present study was performed to evaluate whether injection route, volume and concentration of mannitol could alter the degree of disruption of the BBB. Under urethane anesthesia, female Sprague-Dawley rats were infused with 20% mannitol into the right internal carotid artery (ICA). In the other group, intravenous injection of mannitol through the femoral vein was performed. Evans blue(EB) dye was used as a marker of BBB disruption. When mannitol was injected via the ICA, the content of EB dye in the ipsilateral hemisphere was markedly increased. However, the content of EB in the brain was not increased when mannitol was injected via the femoral vein, even though the volume or concentration of mannitol was increased. These results suggest that the BBB was disrupted only through ICA injection route and this may provide a useful strategy for transient opening of the BBB to control the functions of human brain.

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Alkali & Alkaline-Earth Metal Sources for OLED Devices

  • Tominetti, S.;Cattaneo, L.;Longoni, G.;Bonucci, A.;Toia, L.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1763-1768
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    • 2006
  • Low work function alkali metals and alkaline earths successfully lower the electron injection barrier and increase electron injection into the organic layer in OLED displays, but their implementation is not easy. AlkaMax technology can ensure the required metal evaporation rate in a fast, homogeneous and easily controllable way.

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Study of OLEDs to Improve Carrier Injection Efficiency (캐리어 주입효율 향상을 위한 유기 발광 다이오드 연구)

  • Park, Jin-U;Im, Jong-Tae;O, Jong-Sik;Kim, Seong-Hui;Yeom, Geun-Yeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.169-169
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    • 2012
  • Molybdeum oxide-doped 4,4',4"-tris(2-naphthyl(phenyl)amino)tri- phenylamine (2-TNATA) layer 의 도핑농도가 75%일 때 OLED 소자의 성능이 향상되었다. Hole transport layer (HTL) 로 사용된 MOOX-doped 2-TNATA layer는 hole-injection barrier height를 낮추어서 효율적인 홀주입특성을 보였다. 그러나 도핑농도가 75%이하일 때는 소자 특성이 나빠짐을 알 수 있었다.

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Bio-barrier Formation by Biomass Injection into Soil (미생물 토양 주입을 통한 Bio-barrier 형성)

  • Kim, Geon-Ha;Song, Youngwoo;Gu, Dongyoung
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.5
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    • pp.927-938
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    • 2000
  • When microorganism is injected into porous medium such as soils along with appropriate substrate and nutrients, biomass retained in the soil pore. Soil pore size and shape are varied from the initial condition as a result of biofilm formation, which make hydraulic conductivity reduced. In this research, hydraulic conductivity reduction was measured after microorganism are inoculated and cultured with synthetic substrates and nutrients. Biomass-soil mixture was evaluated its applicability to the field condition as an alternative liner material in landfill by measuring hydraulic conductivity change after repetitive freeze-thaw cycles. Resistance of biofilm to chemical solution and degree of biodegradation were measured through column test.

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