• Journal of the Korean Institute of Gas
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• v.17 no.1
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• pp.56-66
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• 2013

The gas production plants supply the inert gas to production plants for maintaining safe operation and also supply combustible, flammable, explosive and toxic gases as functions of basic materials needed for producing chemical goods. In addition, gas plants need to be safe and reliable operation because they are operated under high temperature, high pressure, cryogenic and catalytic reactions. As these plants have a complex process in operation, there has been a risk that major industrial accidents such as a fire, explosion and toxic gas released, also risks of asphyxiations by inert gases and burns caused by high temperature and cryogenic substances. This study is to carry out the semi quantitative risk assesment method which is the generic risk analysis (GRA). This method is applied to air separation unit(ASU) to identify its initial risk, safety barriers, residual risk and elements important for safety(EIS). The result of this study, suggested the management tools and procedures of implementation for EIS management.

• Journal of Energy Engineering
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• v.6 no.1
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• pp.77-86
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• 1997

In this study, numerical computations were performed to scrutinize the effect of the size of coal particles on reactive flow fields and concentration distribution of product gases for five cases with four different particle sizes (40 $\mu\textrm{m}$, 60 $\mu\textrm{m}$, 100 $\mu\textrm{m}$, 120 $\mu\textrm{m}$, 140 $\mu\textrm{m}$) in an axisymmetric cylindrical coal gasifier in which Alaska Usibelli subbituminous coals were gasified. Predictions showed that coal particle size affected the concentration distribution of product gases. When coals of 100 $\mu\textrm{m}$ were gasified, the maximum average concentrations of major products, H$_2$and CO, were predicted at the exit of the gasifier. The average mole fractions of CO and H, were shown to be 0.62, and 0.16 (dry basis, inert free), respectively. The cold gas efficiency of 83% was also predicted for the same particle size of 100 $\mu\textrm{m}$.

• Transactions on Electrical and Electronic Materials
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• v.13 no.3
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• pp.157-161
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• 2012

In this study, we investigated the etching characteristics of ITO thin films and the effects of inert gases added to $Cl_2/BCl_3$ inductivity coupled plasma. The maximum etch rate of ITO thin film was 130.0 nm/min upon the addition of Ar (6 sccm) to the $Cl_2/BCl_3$ (4:16 sccm) plasma, which was higher than that with He or $N_2$ added to the plasma. The ion bombardment by $Ar^+$ sputtering was due to the relatively low volatility of the by-products formed in the $Cl_2/BCl_3$ (4:16 sccm) plasma. The surface of the etched ITO thin film was characterized by x-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM). From the XPS results, it is concluded that the proper addition of Ar and He to the $Cl_2/BCl_3$ plasma removes carbon and by-products from the surface of the etched ITO thin film.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2002.05a
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• pp.21-29
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• 2002

With regard to the personnel safety and other safety when the gas suppressants are discharged into the area where occupants exist, the short term and long term effects to the health of people are discussed mainly with the Carbon dioxide agent and Halon Replacement agents system. To gain the benefits of CO2 extinguishing systems while minimizing risk to people serious attention must be given to personnel safety in the design, installation, and maintenance of CO2 systems. Training of personnel is essential. A major factor in the use of a clean agent fire suppressant in a normally occupied area is toxicity. While all halocarbon agents are tested for long-term health hazards, the primary endpoint is acute or short-term exposure, The primary acute toxicity effects of the halocarbon agents described here are anesthesia and cardiac sensitization. For inert gases, the primary physiological concern is reduced oxygen concentration.

• Transactions of the Korean Society of Automotive Engineers
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• v.9 no.4
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• pp.1-9
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• 2001

The soot yield has been studied by a premixed propane-oxygen-inert gas combustion in a specially designed disk-type constant-volume combustion chamber to investigate the effects of pressure, temperature and turbulence on soot formation. Premixtures are simultaneously ignited by eight spark plugs located on the circumference of chamber at 45 degree intervals in order to observe the soot formation under high pressures. The eight flames converged compress the end gases to a high pressure. The laser schlieren and direct flame photographs for observation field with 10 mm in diameter are taken to examine into the behaviors of flame front and gas flow in laminar and turbulent combustion. The soot volume fraction in the chamber center during the final stage of combustion at the highest pressure is measured by the in situ laser extinction technique and simultaneously the corresponding burnt gas temperature by the two-color pyrometry method. The pressure and temperature during soot formation are changed by varying the initial charge pressure and the volume fraction of inert gas compositions, respectively. It is found that the soot yield increases with dropping temperature and rising pressure at constant equivalence ratio, and that the soot yield of turbulent combustion decreases in comparison with that of laminar combustion because the burnt gas temperature increases with the drop of heat loss.

• International Journal of Automotive Technology
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• v.7 no.4
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• pp.391-397
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• 2006

The soot yield has been studied by a premixed propane-oxygen-inert gas combustion in a specially designed disk-type constant-volume combustion chamber to investigate the effect of pressure, temperature and turbulence on soot formation. Premixtures are simultaneously ignited by eight spark plugs located on the circumference of chamber at 45 degrees intervals in order to observe the soot formation under high temperature and high pressure. The eight converged flames compress the end gases to a high pressure. The laser schlieren and direct flame photographs with observation area of 10 mm in diameter are taken to examine the behaviors of flame front and gas flow in laminar and turbulent combustion. The soot volume fraction in the chamber center during the final stage of combustion at the highest pressure is measured by the in-situ laser extinction technique and simultaneously the corresponding burnt gas temperature by the two-color pyrometry method. The changes of pressure and temperature during soot formation are controlled by varying the initial charging pressure and the volume fraction of inert gas compositions, respectively. It is found that the soot yield increases with dropping the temperature and raising the pressure at a constant equivalence ratio, and the soot yield in turbulent combustion decreases as compared with that in laminar combustion because the burnt gas temperature increases with the drop of heat loss for laminar combustion.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.27 no.3
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• pp.144-157
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• 2022

Noble gases, which are chemically inert and behave conservatively in marine environments, have been used as tracers of physical processes such as air-sea gas exchange, mixing of water masses, and distribution of glacial meltwater in the ocean. For precise measurements of Ne, Ar, and Kr, we developed a mass spectrometric system consisting of a quadrupole mass spectrometer (QMS), a high vacuum preparation line, an activated charcoal cryogenic trap (ACC), and a set of isotope standard gases. The high vacuum line consists of three sections: (1) a sample extraction section that extracts the dissolved gases in the sample and mixes them with the standard gases, (2) a gas preparation section that removes reactive gases using getters and separates the noble gases according to their evaporation points with the ACC, and (3) a gas analysis section that measures concentrations of each noble gas. The ACC attached to the gas preparation section markedly lowered the partial pressures of Ar and CO₂ in the QMS, which resulted in a reduced uncertainty of Ne isotope analysis. The isotope standard gases were prepared by mixing ²²Ne, ³⁶Ar, and ⁸⁶Kr. The amounts of each element in the mixed standard gases were determined by the reverse isotope dilution method with repeated measurements of the atmosphere. The analytical system achieved precisions for Ne, Ar, and Kr concentrations of 0.7%, 0.7%, and 0.4%, respectively. The accuracies confirmed by the analyses of air-equilibrated water were 0.5%, 1.0%, and 1.7% for Ne, Ar, and Kr, respectively.

• Journal of the Korean Society for Precision Engineering
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• v.22 no.6 s.171
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• pp.168-174
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• 2005

Nowadays, the companies use polymer materials for many purposes fur they have many advantages. The costs of these materials take up too high a proportion of the overall cost of products that use these materials as their major material. It is advantage for polymer industries to reduce these costs. The microcellular foaming process was developed in the early 1980s to solve this problem and proved to be quite successful. Microcellular foaming process uses inert gases such as $CO_2,\;N_2$. As these gases solve into polymer matrices, many properties are changed. The microcellular foaming process makes the glass transition temperature of polymers to low, and diminish the residual stress of polymer matrices. Besides, the microcellular foaming process has several merits, impact strength elevation, thermal insulation, noise insulation, and raw material saving etc. In previous research, many facts of microcellular foaming process are founded its characteristics. But previous researcher found the characteristics of microcellular foaming process with pure gas, for example $CO_2,\;N_2$ and so on, they did not found the characteristics of microcellular foaming process with one more gases. If one more gases inlet the resin, the characteristics of microcellular foaming process is changed very amazingly. In this paper, discuss on the characteristics of microcellular foaming process wi th gas cocktail about cell morphology.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.4 s.175
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• pp.824-829
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• 2000

The industries use polymer materials for many purposes because they have many merits. But these materials' costs take up too much proportion in overall cost of products that use these materials as their major material. So it is very economical for polymer industries to reduce these costs. Microcellular foaming process appeared in 1980's to solve this problem and it proved to be quite successful. This process uses inert gases such as CO2, N2. As these gases are dissolved into polymer matrices. many properties are changed. Glass transition temperature is one of these properties. DSC, DMA are devices that measures this temperature, but these are not sufficient to measure the temperature of polymer containing gas. In this paper, we devised a new tester that uses magnetism. We used this device to acquire data of the change of glass transition temperature and made Cha-Yoon model that can predict the change of glass transition temperature. Using this model, the change of this temperature can be estimated as a function of weight gain of gas. Cha-Yoon model proved that Chow's model is inappropriate to predict the change of glass transition temperature of polymer matrices containing gas.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2004.10a
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• pp.491-495
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• 2004

The industries use polymer materials for many purposes for they have many merits. The costs of these materials take up too great a proportion of the overall cost of products that use these materials as their major material. It is advantage for polymer industries to reduce these costs. The microcellular foaming process was developed in the early 1980s to solve this problem and proved to be quite successful. Microcellular foaming process uses inert gases such as $CO_2$, $N_2$. As these gases solve into polymer matrices, many properties are changed. The microcellular foaming process makes the glass transition temperature of polymers to low, and diminish the residual stress of polymer matrices. Besides, the microcellular foaming process has several merits, impact strength elevation, thermal insulation, noise insulation, and raw material saving etc. This characteristic of microcellular foaming process has influenced by cell morphology. The cell morphology means cell size and cell density. The cell morphology has influenced by many factors. The examples of factor are pressure drop rate, foaming temperature, foaming time, saturation pressure, saturation time etc. Among their factors, pressure drop rate is the most important factor for cell morphology in microcellular foaming injection molding process. This paper describes about the cell morphology change in accordance with the pressure drop rate of microcellular foaming injection molding process.