• Title/Summary/Keyword: Industrial metal waste

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Solubility and Yield Characteristics of KCl in Cement By-Pass Dust (시멘트 바이패스 더스트에 존재하는 염화칼륨의 용해 및 수득 특성)

  • Yun, Youngmin;Jeong, Jaehyun;Chu, Yongsik
    • Resources Recycling
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    • v.25 no.3
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    • pp.43-48
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    • 2016
  • Cement manufacturing plant uses various kinds of industrial/municipal waste. The waste contains considerable amount of potassium, chlorine and small amount of heavy metal. Many researches were performed to fabricate valuable resources from the waste. In this study, various methods, which dissolves and crystallizes potassium/chlorine to extract potassium chloride, were experimented. Especially amount of water, slurry temperature, and stirring time were controlled. Then kind of heavy metal and content of potassium chloride were analyzed. The yield of potassium chloride increased, as the amount of water for slurry increased but it increased slightly, when the water content was over 200%. The yield tended to increase, when the temperature of slurry was over a certain point. The yield did not increase in case of over 10 minutes stirring time. The kind and content of heavy metal in potassium chloride were various according to stirring time. The main heavy metals were Pb, Cu, and $Cr^{6+}$.

Development Status for Commercialization of Spent Nuclear Fuel Transportation and Dry Storage System Technology (사용후핵연료 수송/저장시스템 상용화 기술개발 경과)

  • Baeg, Chang-Yeal;Cho, Chun-Hyung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.2
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    • pp.271-279
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    • 2018
  • During the seven years from 2009 to 2016, PWR SNF (spent nuclear fuel) transportation and storage systems suitable for domestic conditions were developed by the government to cope with the saturation of wet storage capacity in NPPs. One of the developed systems is a multipurpose metal cask applicable for transportation/storage; the other is a concrete cask dedicated to storage. Efficient cask technologies were secured utilizing the characteristics and experience of relevant industrial, academic and research institutes. Technological independence was also achieved through several patent registrations of research outcomes. To prepare for a rapid increase of demand in the near future, technology transfer of secured patents and technologies to the domestic industry was carried out twice in the years of 2016 and 2017.

Physicochemical Properties of Landfill Mined Wastes from Old Landfill Site (불량 매립지에서 굴착된 폐기물의 물리화학적 특성평가)

  • 남궁완;이노섭;박준석;인병훈
    • Journal of Environmental Health Sciences
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    • v.28 no.2
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    • pp.99-108
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    • 2002
  • This study was carried out to evaluate the Physicochemical characteristics of mined waste(separated waste and soil) and to predict environmental effect of an old landfill site located at north of Seoul. Municipal solid waster(MSW) had been disposed of at the old landfill site used in this study for about 2 years(1990-1992). The old landfill site selected for this study had accepted mainly municipal solid waste. The landfill-mined waste contained separated waste (40.9%) and soil(59.1%) by wet weight basis. The separated waste consisted of combustible(91.0%) and non-combustible(9.0%). The combustible waste was mainly non-biodegradable plastics. The low heating value of the separated combustible waste, which is calculated by Dulong's equation, was as high as 3,470kcal/kg. According to the Korean Extraction Procedure, separated waste and soil were proved to be not hazardous. The total content of heavy metal in the separated waste and soil met standard of California State, USA. Therefore the separated waste may be relandfilled at a sanitary landfill site and/or burned up at an incinerator, and the separated old soil may be used ad landfill cover-soil at a sanitary landfill site. Water quality of two streams was grade IV, of which water could be used as industrial and agricultural water. The streams near the landfill site might not be contaminated by leachate from the old landfill site. It was estimated that organic matter in the old landfill site would not be actively biodegraded within a short period of time.

Standardization Status of Rare Earth Elements Recycling in ISO TC 298 (ISO TC 298에서의 희토류 재활용 관련 국제 표준화 현황)

  • Lee, Mi Hye;Song, Yosep;On, Ji Sun;Yoon, Seung Hwan;Han, Munhwan;Kim, Bum Sung;Kim, Taek-soo;Lee, Bin
    • Journal of Powder Materials
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    • v.29 no.2
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    • pp.159-165
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    • 2022
  • Rare earth elements, which are important components of motors, are in high demand and thus constantly get more expensive. This tendency is driven by the growth of the electric vehicle market, as well as environmental issues associated with rare-earth metal manufacturing. TC 298 of the ISO manages standardization in the areas of rare-earth recycling, measurement, and sustainability. Korea, a resource-poor country, is working on international standardization projects that focus on recycling and encouraging the domestic adoption of international standards. ITU-T has previously issued recommendations regarding the recycling of rare-earth metals from e-waste. ISO TC 298 expands on the previous recommendations and standards for promoting the recycling industry. Recycling-related rare earth standards and drafts covered by ISO TC 298, as well as Korea's strategies, are reviewed and discussed in this article.

RESEARCH PAPERS : REMOVAL EFFICIENCY OF THE POLLUTANTS BY MULTILAYERED METAL TREATED CARBON FILTER

  • Oh, Won-Chun;Lee, Ho-Jin;Bae, Jang-Soon
    • Environmental Engineering Research
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    • v.9 no.5
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    • pp.193-200
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    • 2004
  • A study of the treatment of piggery wastes using a multilayered metal-activated carbon system followed by carbon bed filtration was carried out at bench scale. From the physicochemical properties obtained from samples treated with aqueous solutions containing metallic ions such as Ag$^+$, Cu$^{2+}$, Na$^{-}$, K$^+$ and Mn$^{2+}$, main inspections are subjected to isothem shape, pore distribution with micropore, SEM and EDX. Multilayered metal-activated carbons were contacted to waste water to inwestigate the simultaneous catalytic effect for the COD, BOD, T-N and T-P removal. From these removal performance was achieved. The high efficiency of the multilayered metal-activated carbon bed, satisfactory removal performance was achieved. The high efficiency of the multilayered metal-activated carbon bed was derermined by the properties of this material for trapping, catalytic effect and adsorption of organic solid particles.

Recovery of Nitric acid and Copper from Plating Waste of Automobile Wheel (자동차 휠 도금박리폐액으로부터 질산 및 구리의 회수)

  • Ha, Yonghwang;Gang, Ryun-Ji;Son, Seong-Ho;Lee, Wonsik;Ahn, Jong-Gwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.11
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    • pp.6015-6022
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    • 2013
  • It has been known that there are large amount of nitric acid and valuable metals, copper in the plating waste solution of automobile wheel. As nitric acid and valuable metals are high price and toxic, they should be recovered for economics and environment. Plating waste was extracted with TBP diluted with kerosene. The concentration of nitric acid in aqueous phase was analyzed by titration method by NaOH solution (0.1~1.0N) and the amount of metals by ICP-MS and ICP-AES. The concentration of copper in plating waste were 76,850 mg/L. The concentration of nitric acid in plating waste was 1.02 M. After three step extraction was performed with 50% TBP, each organic phase was stripped three times with distilled water to obtain 48.1% of nitric acid. Purity of final nitric acid was over 99.9% by ICP analysis. After recovery of nitric acid, copper was extracted with various solvent extractors like PC 88A, D2EPHA, LIX 84 and ISE 106. Among these extractors, 92% of copper was recovered by ISE 106 after 1st extraction and 30% $H_2SO_4$ stripping. Copper ion was reduced with $N_2H_4$ to make metal powders, respectively.

A Study of the Bottom Ash as Environmentally Grouting Materials (Bottom Ash를 이용한 그라우팅재의 환경적 연구)

  • Doh, Young-Gon;Kwon, Hyuk-Doo;Lee, Song
    • Journal of the Korean Geotechnical Society
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    • v.22 no.11
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    • pp.5-11
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    • 2006
  • The purpose of this study was to examine the proper mixing ratio of ordinary portland cement and Bottom Ash to recycle the Bottom Ash, which is an industrial waste. After the evaluation, the compressive strength and durability were assessed using the mixture of completely weathered soil (Hwangto), weathered granite soil, and Bentonite. Then environmental friendliness of this mixed material was examined through heavy metal leaching method. It was found out that proper mixing ratio is 6:4, and that the 6% mixture quantity of completely weathered soil (Hwangto), weathered granite soil, and Bentonite is the most effective for compressive strength and durability It was also found out through heavy metal leaching method that the Bottom Ash could be below the standard of the Clean Water Law.

The Environmental Safety Evaluation on Heavy Metal Leaching of Deteriorated Concrete under Severe Conditions (가혹한 조건에서 열화된 콘크리트의 중금속 용출에 대한 환경 안전성 평가)

  • Choi, Yun-Wang;Oh, Sung-Rok;Park, Man-Seok;Kim, Sang-Chel;Jung, Sang-Hwa
    • Journal of the Korea Concrete Institute
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    • v.25 no.5
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    • pp.539-546
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    • 2013
  • Cement industry in 1997 began to use industrial waste in cement factory for purpose of resource recycling. However recently, environmental hazard of the cement in accordance with recycling of industrial waste have been raised a problem by contamination around the cement factory and heavy metal leaching in cement. In particular, the presence of $Cr^{6+}$ in cement has become a critical issue, the studies for minimizing of $Cr^{6+}$ in cement have been performed. But, in domestic, most of the research on heavy metal leaching was carried out from the perspective of the cement. Environmental safety assessment in terms of concrete is needed because cement is used to the concrete material. Therefore, this paper was evaluated heavy metals leaching of deteriorated concrete by severe conditions. test result showed that $Cr^{6+}$ were not detected from all the variables.

Systematic investigation of heavy metals from MSWI fly ash and bottom ash samples

  • Ramakrishna., CH;Thriveni., T;Ahn, Ji Whan
    • Journal of Energy Engineering
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    • v.26 no.4
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    • pp.35-44
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    • 2017
  • Disposal of municipal solid waste has become a major problem in many countries around the world. As landfill space for the disposal of ash from Municipal Solid Waste Incineration (MSWI) becomes scarce, numerous reports and researches address the various environmental issues about the municipal solid waste incineration waste management and other particulate matters with the range of 10 ~ 2.5. Although in many developing and industrialization countries landfill with the disposal of municipal solid waste, open incineration has become a common practice. Large municipal waste incinerators are major industrial facilities and have the potential to be significant sources of environmental pollution. Despite the significant volume reduction from incineration, waste recycling is important to ensuring the future welfare of mankind. The main goal of the present work is the physical and chemical characterization of the local incineration bottom ash towards its eventual re-utilization. In this paper, we reported the studies on physical and chemical characteristics of municipal solid waste incineration (MSWI) fly ash and bottom ash containing particulate matter whose particulate sizes are lower than $PM_{10}$, $PM_{2.5}$ and heavy metal were investigated.

Study on Bio-H2 Production from Synthetic Food Waste and Activated Sludge from Industrial Waste Water Processes using Dark-fermentation (산업공정의 폐수처리에서 발생된 폐활성슬러지 및 인공음식폐기물을 이용한 생물학적 수소생성에 관한 연구)

  • Kim, Tae-Hyeong;Kim, Mi-Hyung;Lee, Myoung-Joo;Hwang, Sun-Jin;Eom, Hyoung-Choon
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.6
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    • pp.703-712
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    • 2010
  • This study performed to extract operation factors of major organic wastes, which were food wastes and waste activated sludge generated in industries in order to use them as a substrate for bio-H2 production. According to the results of experimental analysis for hydrogen production capacity by various organic concentrations, the hydrogen production yield was the highest at 80 g/L, and the efficiency was improved by the pretreatment of waste activated sludge (acid treatment, alkali treatment). Hydrogen production efficiency was improved by mixing food wastes and waste activated sludge if waste activated sludge was below than 30%, however, it was decreased when it was more than 50%. The impacts of heavy metals on the hydrogen production shows that the inhibition level depends on the concentration of Cr, Zn, and Cu, Fe was able to enhance the hydrogen production.