• Applied Chemistry for Engineering
• /
• v.33 no.3
• /
• pp.309-314
• /
• 2022

Carbon dots (CDs) are few nanometer-sized carbon-based nanoparticles and emerging candidate materials in various fields such as biosensors and bioimaging due to their excellent optical properties and high biocompatibility. However, most CDs, emitting blue light, have limited their application in biomedical fields due to the low penetration of short-wavelength lights into the biological system. Therefore, there has been enormous need to develop long-wavelength emitting CDs. In this study, red-emitting CDs were successfully synthesized through the hydrothermal reaction of p-phenylenediamine with hydrochloric acid. In addition, the effect of the amount of hydrochloric acid on the formation of carbon dots, resulting in the variation of the chemical structures of CDs, were investigated, which was confirmed with the intensive structural analyses using infrared and X-ray photoelectron spectroscopy. It was found that the chemical structure of CDs governed their optical properties and quantum yield. Therefore, this study provides an insight into the role of acid in forming red-emitting CDs as the optimal probe for biomedical application.

• The Journal of Korean Institute of Communications and Information Sciences
• /
• v.17 no.3
• /
• pp.213-224
• /
• 1992

An encoding technique based on region splitting and vector quantization is proposed for the lower level Laplacian pyramid images. The lower level Laplacian pyramid images have lower variance than higher levels but a great influence on compression ration due to large spatial area. And so from data compression viewpoint, we subdivide them with variance thresholding into two regions such as one called : flat region” and the other “edge region”, and encode the flat region with its mean value and the edge region as vector quantization method. The edge region can be reproduced faithfully and significant improvement on compression ratio can be accomplished with a little degradation of PSNR in spite of the effect of large flat region since the codebook used is generated from the edge region only on from the entire image including the flat region. It can be verified by computer simulation results that proposed method is more efficient in compression ratio and processing time than the conventional encoding technique of vector quantization.

• 한국신재생에너지학회:학술대회논문집
• /
• 2007.11a
• /
• pp.318-321
• /
• 2007

CdSe nanoparticles were prepared by chemical solution methods using $CdCl_2{\cdot}4H_2O$ (or $Cd(NO_3)_ 2{\cdot}4H_2O$) and $Na_2SeSO_3$. The characteristics of CdSe nanoparticles were controlled by the react ion time, reaction temperature and reaction method as well as the surfactants. Cetyltrimethyl ammonium bromide(CTAB) was used as a capping agent to control the chemical reactions in aqueous solution. Polyvinylalcohol(PVA) was used as a templet in sono-chemical method. CdSe nanoparticles synthesized in aqueous solution showed homogeneous size distribution with relatively stable surface. CdSe nanoparticles synthesized in non-aqueous solution containing diethanolamine(DEA) showed the structure transformation from cubic to hexagonal as the reduction temperature increased from 80 to $160^{\circ}C$. Core shell CdSe was synthesized by sono-chemical method. Characteristics of CdSe nanoparticles were analyzed using transmission electron microscopy(TEM), x-ray photoelectron spectroscopy(XPS), x-ray diffraction(XRD), UV-Vis absorption spectra, fourier transform infrared spectroscopy(FT-IR) and photoluminescence spectra spectroscopy(PL). This paper presents simple routes to prepare CdSe nanoparticles for solar cell applications.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.35 no.1
• /
• pp.93-97
• /
• 2022

We report highly efficient quantum dot light-emitting diodes (QLEDs) with TiO₂ nanoparticles (NPs) as an alternative electron transport layer (ETL) and poly (methyl methacrylate) (PMMA) as an insulating layer. TiO₂ NPs were applied as ETLs of inverted structured QLEDs and the effect of the addition of PMMA between ETL and emission layer (EML) on device characteristics was studied in detail. A thin PMMA layer supported to make the charge balance in the EML of QLEDs due to its insulating property, which limits electron injection effectively. Green QLEDs with a PMMA layer produced the maximum luminance of 112,488 cd/m² and a current efficiency of 25.92 cd/A. We expect the extended application of TiO₂ NPs as the electron transport layer in inverted structured QLEDs device in the near future.

• Journal of Korean Philosophical Society
• /
• v.126
• /
• pp.79-108
• /
• 2013

Is the development of linguistic competence due to the learning process or the maturational process? According to Piaget, its development is a genuine learning process involving authentic constructions with gradual disclosure of new possibilities. But According to Chomsky, the acquisition of linguistic competence is due to a genetically conditioned maturational process. So it merely involves the actualization of a set of possibilities existing from the beginning Consequently, Piaget supposes that interaction with the environment plays a shaping role, while Chomsky allows it to have a mere triggering role. In broad respective, Chomsky supposes the rationalism that knowledge is largely inborn, while Piaget in the constructivist position which strives to find a middle course between radical rationalism and radical empiricism. In the one hand, an ultra-rationalistic concept such as 'fixed nucleus' supposed by Chomsky is, in my eye, nor plausible. In the other hand, if Piagetian constructivism is to be sustained, it must be sustained independently of its dubious biological fundament, and merely as a developmental psychological theory. In one word, we need to synthesize Piagetian cognitive approach and Chomskian syntactical, in order to explain exactly the source of human linguistic competence.

• Journal of the Korea Institute of Information Security & Cryptology
• /
• v.28 no.5
• /
• pp.1089-1098
• /
• 2018

As the development of quantum computers becomes visible, the researches on post-quantum cryptography to alternate the present cryptography system have actively pursued. To substitute RSA and Elliptic Curve Cryptosystem, post-quantum cryptography must also consider side channel resistance in implementation. In this paper, we propose a side channel analysis on NTRU, based on the implementation made public in the NIST standardization. Unlike the previous analysis which exploits a thousands of traces, the proposed attack can recover the private key using a single power consumption trace. Our attack not only reduces the complexity of the attack but also gives more possibility to analyze a practical public key cryptosystem. Furthermore, we suggested the countermeasure against our attacks. Our countermeasure is much more efficient than existing implementation.

• Journal of Powder Materials
• /
• v.29 no.5
• /
• pp.370-375
• /
• 2022

Cu-doped ZnSe quantum dots were successfully synthesized in an aqueous solution using an internal doping method. The effects of ligand type, CuSe synthesis temperature, and heating time on Cu-doped ZnSe synthesis were systematically investigated. Of MPA, GSH, TGA, and NAC used as ligands, MPA was the optimal ligand as determined by PL spectrum analysis. In addition, the emission wavelength was found to depend on the synthesis temperature of the internal doping core of CuSe. As the temperature increased, the doping of Cu²⁺ was enhanced, and the emission wavelength band was redshifted; accordingly, the emission peaks moved from blue to green (up to 550 nm). Thus, the synthesis of Cu:ZnSe using internal doping in aqueous solutions is a potential method for ecomanufacturing of color-tuned ZnSe quantum dots for display applications.

• Journal of KIISE:Software and Applications
• /
• v.27 no.4
• /
• pp.422-431
• /
• 2000

This paper proposes a new codebook generation method, called a PCA-Based VQ, that incorporates the PCA (Principal Component Analysis) technique into VQ (Vector Quantization) codebook design. The PCA technique reduces the data dimensions by transforming input image vectors into the feature vectors. The cluster of feature vectors in the transformed domain is bisectioned into two subclusters by an optimally chosen partitioning hyperplane. We expedite the searching of the optimal partitioning hyperplane that is the most time consuming process by considering that (1) the optimal partitioning hyperplane is perpendicular to the first principal axis of the feature vectors, (2) it is located on the equilibrium point of the left and right cluster's distortions, and (3) the left and right cluster's distortions can be adjusted incrementally. This principal axis bisectioning is successively performed on the cluster whose difference of distortion between before and after bisection is the maximum among the existing clusters until the total distortion of clusters becomes as small as the desired level. Simulation results show that the proposed PCA-based VQ method is promising because its reconstruction performance is as good as that of the SOFM (Self-Organizing Feature Maps) method and its codebook generation is as fast as that of the K-means method.

• Journal of Sensor Science and Technology
• /
• v.31 no.2
• /
• pp.125-130
• /
• 2022

We describe the importance of zinc oxide nanoparticle (ZnO NP) concentration in the enhancement of electrical properties in a lead sulfide quantum dot (PbS QD)-based shortwave infrared (SWIR) photodetector. ZnO NPs were synthesized using the sol-gel method. The concentration of the ZnO NPs was controlled as 20, 30 and 40 mg/mL in this study. Note that the ZnO NPs layer is commonly used as an electron transport layer in PbS QDs SWIR photodetectors. The photo-to-dark ratio, which is an important parameter of a photodetector, was intensively examined to evaluate the electrical performance. The 20 mg/mL condition of ZnO NPs exhibited the highest photo-to-dark ratio value of 5 at -1 V, compared with 1.8 and 0.4 for 30 mg/mL and 40 mg/mL, respectively. This resulted because the electron mobility decreased when the concentration of ZnO NPs was higher than the optimized value. Based on our results, the concentration of ZnO NPs was observed to play an important role in the electrical performance of the PbS QDs SWIR photodetector.

• The Journal of the Acoustical Society of Korea
• /
• v.19 no.1
• /
• pp.97-102
• /
• 2000

Subband coding is to divide the signal frequency band into a set of uncorrelated frequency bands by filtering and then to encode each of these subbands using a bit allocation rationale matched to the signal energy in that subband. The actual coding of the subband signal can be done using waveform encoding techniques such as PCM, DPCM and vector quantizer(VQ) in order to obtain higher data compression. Most researchers have focused on the error in the quantizer, but not on the overall reconstruction error and its dependence on the filter bank. This paper provides a thorough analysis of subband codecs and further development of optimum filter bank design using vector quantizer. We compute the mean squared reconstruction error(MSE) which depends on N the number of entries in each code book, k the length of each code word, and on the filter bank coefficients. We form this MSE measure in terms of the equivalent quantization model and find the optimum FIR filter coefficients for each channel in the M-band structure for a given bit rate, given filter length, and given input signal correlation model. Specific design examples are worked out for 4-tap filter in 2-band paraunitary filter bank structure. These optimum paraunitary filter coefficients are obtained by using Monte Carlo simulation. We expect that the results of this work could be contributed to study on the optimum design of subband codecs using vector quantizer.