• Journal of the Korean institute of surface engineering
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• v.53 no.5
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• pp.241-248
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• 2020

The change of the deposition behavior of diamond through a pretreatment process of the base metal prior to diamond deposition using HFCVD was investigated. To improve the specific surface area of the base material, sanding was performed using sandblasting first, and chemical etching treatment was performed to further improve the uniform specific surface area. Chemical etching was performed by immersing the base material in HCl solutions with various etching time. Thereafter, seeding was performed by immersing the sanded and etched base material in a diamond seeding solution. Diamond deposition according to all pretreatment conditions was performed under the same conditions. Methane was used as the carbon source and hydrogen was used as the reaction gas. The most optimal conditions were found by analyzing the improvement of the specific surface area and uniformity, and the optimal diamond seeding solution concentration and immersion time were also obtained for the diamond particle seeding method. As a result, the sandblasted base material was immersed in 20% HCl for 60 minutes at 100 ℃ and chemically etched, and then immersed in a diamond seeding solution of 5 g/L and seeded using ultrasonic waves for 30 minutes. It was possible to obtain optimized economical diamond film growth rates.

• Resources Recycling
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• v.4 no.1
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• pp.31-37
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• 1995

This study was to investigate the effects oi agitation speed, pulp concentration, ion concentration ill the slurry solution, printed area of the waste newspaper, immerwng time and the temperature on the defiberation process for the waste newspaper. The defikration efficiency at 50% is twice that of 16%. The efficiency is improved as two times according to elevate the agtation speed as two times in the range of 200-2WO r.p.m.. Defiberation with NaOH 1X10-'M solution has higher efficiency than that of NaOH 1 x 1 0 - M solution as 3 times at the conditions of 16%, 1200 r.p.m, and 1% pulp concentration The temperature of immersing salut~on aifects on the efficiency more than immersing time does. Increasing the printed area of newspaper decreases the velocity of defiberation. The alkaline solution is effective to defiberate and the defiberation efficiency at the same dosage of alkalinity is in the order a1 NaOH) KOH) Na,SiO, ) Na,CO, ) Ca(OH)2.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2001.11a
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• pp.98-104
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• 2001

Recently, the researches on the prevention of marine oil pollution being strengthened. Sludge oils were unavoidably produced in ship's operations, therefore it is necessary to manage the sludge oils inside the ship itself with the view to prevent marine oil pollution from ship. The present study deals with the ultrasonic breaking systems that recycle the sludge oil from ships into usable oil to be burnt. At the first instanceexperimental studies were carried out to investigate the homogenizing effect of the marine oils and the erosion aspect of horn disc by repeated vibration of ultrasonic transducer. The erosion damages for horn disc SS41 steel with weight loss rate and the irradiation time to max. erosion rate were examined according to the variation of the transducer amplitude, the oil temperature and the immersing depth of horn disc. As the result of it, the erosion aspects of horn disk were varied with oil environments and testing time.

• Proceedings of the KIEE Conference
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• 1996.07c
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• pp.1450-1452
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• 1996

In order to optimize the characteristics of gate insulator for FED(field emission device), we investigated the effect of wet-etching process on the gate insulator for fabrication of FED. We used the general three types of etchants for fabrication of the metal tip FEA(field emitter array), they are MO and oxide etchants to form the gate hole, and Al etchant to remove the release layer. In the result of the breakdown field of the insulator by the measure of the current-voltage characteristics, the breakdown field of insulator for immersing in oxide etchant was rapidly lowering with increasing etching time, but that for immersing in Al etchant was slow lowering. Also, in comparing cleaning with non-cleaning samples, the breakdown field of the cleaning samples was higher than that of non-cleaning samples.

• Journal of Korean Society for Quality Management
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• v.32 no.4
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• pp.196-207
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• 2004

TDR(Tear Down & Redesign)means that renounce the past resolutely, from a white paper condition, let's change directions. That is, let's redesign from the basic of the establishment of the construction process. Through the switchover the conception, innovate totally the whole existing processes. TDR is the best core innovation activity. The ultimate aim of the TDR activity induces the employees to do more productive business and obtain excellent results in the future by solving the problems, which are the nonproductive business in the business process on the objective view, the business that customers don't recognize the value, the same old practice of business, and the unsettled business from the restriction of resources. By organizing the related to workers of those business, they can solve the problems for 3-4months by full time working This paper inquires what are the obstruction factors on the process of executing TDR activity. Through the search of the reformation plan for the improvement of immersion degree, it presents some methods to be successful business.

• Journal of the Korean Ceramic Society
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• v.34 no.2
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• pp.171-174
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• 1997

It was experimentally identified, for the first time, that oxygen phonons play an important role in the low temperature degradation(tetragonallongrightarrowmonoclinic phase transformation) of yttria stabilized tetragonal zir-conia polycrystals (Y-TZP). The degradation accompanied by immersing the samples in the boiling water were markedly reduced by substituting of 18O for 16O in Y-TZP. This was attributed to the heavier mass of 18O which leads to the smaller probability to find oxygen atoms beyond certain critical displacements.

• Journal of the Korean Society of Marine Environment & Safety
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• v.7 no.3
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• pp.75-84
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• 2001

Ultrasonic vibrator is an equipment which atomizes and homogenizes the oils by breaking the oil particles with ultrasonic vibration cavity, and possibly improves the properties. There are various parameters on the effect of ultrasonic irradiation. Especially, this study intended to investigate the matrix structure of sludge oils and the erosion damages for horn disc SS41 according to the variation of the oil temperature and the immersing depth of horn disc. Sludge oils were irradiated with ultrasonic vibration and then observed the aspects of the change of oil particles. From these, the recycling feasibility of sludge oil for useable oil to be burnt was determined. The erosion damages for horn disc SS41 were examined with weight loss, weight loss rate and the irradiation time to max. erosion rate. These data will be useful to the development of ultrasonic breaking systems to recycle sludge oil and to consider a countermeasure for the prevention of erosion damages.

• Bulletin of the Korean Chemical Society
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• v.17 no.4
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• pp.342-347
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• 1996

Voltammetric determination of phenol derivatives, such as phenol, o-, m-, and p-cresols was studied with a β-Cyclodextrin (β-CD) modified-carbon paste electrode composing of the graphite powder and Nujol oil. Phenol derivatives were chemically deposited via the complex formation with β-CD by immersing the CME into a sample solution. The resulting surfaces were characterized with cyclic and differential pulse voltammetry. Treating the CME with 1 M nitric acid for five sec after a measurement could regenerate the electrode surface. Linear sweep and differential pulse voltammograms were recorded for the above system to optimize the experimental parameters for analysing the phenol derivatives. In this case, the detection limit for phenols was 5.0×10-7M for 25 min of the deposition time with differential pulse voltammetry. The relative standard deviation was ±5.2% of 3.0×10-6M (four repetitions). The interference effect of the following organic compounds was also investigated; Bezoic acid, hippuric acid, o-, m-, and p-methylhippuric acid. Adding the organic compounds into the sample solution reduces the peak current of the phenols to about 25%.

• Carbon letters
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• v.12 no.4
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• pp.243-248
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• 2011

Two different types of graphite, such as flake graphite (FG) and spherical graphite (SG), were used as anode materials for a lithium-ion secondary battery in order to investigate their electrochemical performance. The FG particles were prepared by pulverizing natural graphite with a planetary mill. The SG particles were treated by immersing them in acid solutions or mixing them with various carbon additives. With a longer milling time, the particle size of the FG decreased. Since smaller particles allow more exposure of the edge planes toward the electrolyte, it could be possible for the FG anodes with longer milling time to deliver high reversible capacity; however, their initial efficiency was found to have decreased. The initial efficiency of SG anodes with acid treatments was about 90%, showing an over 20% higher value than that of FG anodes. With acid treatment, the discharge rate capability and the initial efficiency improved slightly. The electrochemical properties of the SG anodes improved slightly with carbon additives such as acetylene black (AB), Super P, Ketjen black, and carbon nanotubes. Furthermore, the cyclability was much improved due to the effect of the conductive bridge made by carbon additives such as AB and Super P.

• Transactions on Electrical and Electronic Materials
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• v.13 no.2
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• pp.78-84
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• 2012

An in-situ optical monitoring method for real-time process monitoring of electrochemical copper deposition (CED) is presented. Process variables to be controlled in achieving desired process results are numerous in the CED process, and the importance of the chemical bath conditions cannot be overemphasized for a successful process. Conventional monitoring of the chemical solution for CED relies on the pH value of the solution, electrical voltage level for the reduction of metal cations, and gravity measurement by immersing sensors into a plating bath. We propose a nonintrusive optical monitoring technique using three types of optical sensors such as chromatic sensors and UV/VIS spectroscopy sensors as potential candidates as a feasible optical monitoring method. By monitoring the color of the plating solution in the bath, we revealed that optically acquired information is strongly related to the thickness of the deposited copper on the wafers, and that the chromatic information is inversely proportional to the ratio of $Cu$ (111) and {$Cu$ (111)+$Cu$ (200)}, which can used to measure the quality of the chemical solution for electrochemical copper deposition in advanced interconnection technology.