• Korean Chemical Engineering Research
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• v.57 no.6
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• pp.790-803
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• 2019

The dioctyl terephthalic acid (DOTP) process produces plastic plasticizers by esterification of terephthalic acid with powder in the form of octanol. In this study, the dust explosion characteristics of terephthalic acid directly injected into the manhole in the form of powder in the presence of flammable solvent or vapor in the reactor of this process were investigated. Dust particle size and particle size distribution dust characteristics were investigated, and pyrolysis characteristics of dust were investigated to estimate fire and explosion characteristics and ignition temperature. Also, the minimum ignition energy experiment was performed to evaluate the explosion sensitivity. As a result, the average particle size of terephthalic acid powder was $143.433{\mu}m$. From the thermal analysis carried out under these particle size and particle size distribution conditions, the ignition temperature of the dust was about $253^{\circ}C$. The lower explosive limit (LEL) of the terephthalic acid was determined to be $50g/m^3$. The minimum ignition energy (MIE) for explosion sensitivity is (10 < MIE < 300) mJ, and the estimated minimum ignition energy (Es) based on the ignition probability is 210 mJ. The maximum explosion pressure ($P_{max}$) and the maximum explosion pressure rise rate $({\frac{dP}{dt}})_{max}$ of terephthalic acid dust were 7.1 bar and 511 bar/s, respectively. The dust explosion index (Kst) was 139 mbar/s, corresponding to the dust explosion grade St 1.

• Journal of the Korean Society of Safety
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• v.39 no.2
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• pp.1-8
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• 2024

Unwanted effects of electrostatic phenomena occur in various industries. Electrostatic problems originating from the human body in flammable atmospheres in the industry are especially concerning. A substantial volume of experimental data on the electrostatic charging voltages created on the human body owing to the rubbing of apparel were generated and reviewed during this study. The data were reviewed to determine whether the resultant charging levels of the human body are hazardous in flammable atmospheres. This study was conducted under several conditions, such as different fiber types used in apparel, shoe types, and relative humidities (RHs). The following conclusions were drawn in this study. ① The electrostatic charging levels of the human body owing to the rubbing of apparel increase with the increase in the surface resistances of apparel; however, the electrostatic charging levels may be different depending on the condition of the cloth surface. ② The discharging energy of 1.98-18.5 [mJ] from the human body exceeds the minimum ignition energy of most flammable materials, when removing an overcoat made of polyester, cotton and wool under severe conditions such as wearing height-raising shoes for men. ③ When removing antistatic apparel, the maximum discharging energy of 0.128 mJ from the human body is dangerous if the minimum ignition energy of the flammable material is between 10^-5-10^-4 [J] Grade; however, a minimum ignition energy of 10^-3 J Grade of the flammable material is considered safe. ④ While wearing antistatic shoes, the electrostatic charging voltage generated in the human body when removing an overcoat is 30 V; therefore, wearing such shoes is a suitable countermeasure when handling flammable materials. However, the antistatic abilities of shoes reduce when thick socks are worn. ⑤ As RH increases, the electrostatic charging levels of the human body decrease. ⑥ The electrostatic charging levels of the human body from removing a cotton overcoat can ignite the majority of flammable materials when RH is less than 30% under severe conditions such as wearing height-raising shoes for men.

• Journal of the Korean Society of Safety
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• v.25 no.5
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• pp.22-26
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• 2010

The ignitability(minimum ignition energy, MIE) of a suspended dust clouds is very important aspect of technical safety indices. This paper reported the experimental results dealing with the influence of discharge circuit on the MIE of a suspended dust clouds. The movement of a suspended dust clouds was also observed with the high speed camera. The Hartmann vertical-tube apparatus(MIKE-3) described in the international standard of IEC and Polypropylene (PP, 50% volume-average, D50: $761{\mu}m$) resin powders were used in this experiment. The following results were obtained: (1) the MIE of a suspended PP powder depended markedly on the discharge circuit; in other words, when a resistor was connected in series with the discharge sparking circuit(RC), the lowest value(31mJ) of MIE was obtained for a suspended PP powder comparison with the other circuits(C circuit; 370mJ or LC circuit; 71mJ). (2) the discharge duration time is more important than other factors with regard to MIE of a suspended PP powder.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.10
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• pp.1393-1400
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• 2003

Ignition of hydrogen and oxygen in the "third limit" is theoretically investigated in the stagnation point flow with activation energy asymptotics. With the steady-state approximations of H, OH, O and HO$_2$, a two-step reduced kinetic mechanism is derived for the regime lower than the crossover temperature T$_{c}$ at which the rates of production and consumption of all radicals are equal. Appropriate scaling of Damkohler number successfully provides the explicit relationship between pressure, temperature and strain rate at ignition. It is shown that, compared with those for the counterflow, ignition temperatures for the stagnation point flow are considerably increased with increasing the system pressure. This is because ignition in the "third limit" is characterized by the production of reduction of $H_2O$$_2$, which is reduced by wall effect. Strain rate substantially affects ignition temperature because key reaction rates of $H_2O$$_2$ are comparably with its transport rate, while the mixture temperature and the hydrogen composition do not significantly affect ignition temperature.e.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.05a
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• pp.138-141
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• 2010

A study to reduce the ignition peak pressure of gas generator for the missile launching system was accomplished. The igniter, as the energy release device for igniting the propellant, is aimed at simultaneous ignition of bundled 3-layered propellant grain without unstable burning. In case of our gas generator which must use the double-base propellant with low ignition property, the fast ignition of propellant and reduction of initial peak pressure should be required for the satisfaction of ejection velocity and acceleration condition. By applying MTV ignition charge for the igniter of gas generator, we accomplished all system performance requirements.

• Fire Science and Engineering
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• v.18 no.1
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• pp.1-6
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• 2004

In the reutilization process using limonene, the organic solvent to reduce volume of EPS, the AIT was measured with the variation of concentration and volume of mixture, in order to present the fund-mental data on the fire hazard assessment of limonene - EPS mixture at storage and handling. And ignition zone was compared with non-ignition zone. The equation related to AIT, activation energy and ignition delay time, used by the most scientific basis for predicting AIT values, was suggested using linear regression analysis as ln t = 0.704/T-5.819. And the equation related to concentration of mixture and AIT was also suggested to predict ignition hazard of combustible mixture using nonlinear regression analysis as $T_m/=248.32+69.27X+172.60X^2$. It enabled to predict ignition temperature according to variation of ignition delay time and concentration of mixture by the suggested equations.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2007.04a
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• pp.349-352
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• 2007

In this paper, we describe the modeling of ablation based laser applications for innovative use in the military In the laser ignition system, a metal confinement is ablated with the high intensity pulsed energy, triggering a thermal ignition of the confined high explosives. The constitutive equations for the laser source, deformation of metals, and explosion of energetic materials are described.

• Transactions of the Korean Society of Mechanical Engineers
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• v.10 no.4
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• pp.471-476
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• 1986

본 연구에서는 구모양의 석탄가루나 곡식가루등 비금속성 고체입자가 압축파 (shock wave)에 의해 생성된 고온의 기체속에 놓여있을때 일어나는 점화현상을 활성 화에너지(activation energy)가 큰 경우의 접합 점근법을 이용 해석하였다. 이렇게 하여 얻어진 석탄입자에 대한 점화지연시간을 실험치와 비교 이의 타당성을 입증하였 다.

• Transactions of the Korean Society of Mechanical Engineers
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• v.6 no.2
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• pp.133-139
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• 1982

One of factors that affect combustion in the cylinder of the engine is to keep a greater energy in the ignition system to minimize pollutant emissions and to increase its performance of the low temperature. This paper reviews theoretically the state and input variables of the ignition system from the state transition equation. Effects on characteristics of the system such as primary current, secondary available voltage and spark duration by reducing the pre-resistance from 3.5 to 0 ohm in 12V system is experimentally investigated when the ignition coil has a primary resistance of 1.5 ohms ad the dwell angle of the breaker point is 43.2 degrees (0.75 radian). Advantages and limitations for using the low resistance of the primary circuit are also presented to optimize the performance of the ignition system with the breaker point.

• Transactions of the Korean Society of Automotive Engineers
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• v.4 no.2
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• pp.147-157
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• 1996

Natural gas is gaining more attraction as a future fuel in particular both for environmental protection and energy conservation. In order to bring about more widespread use of gaseous engines, the technology capable of achieving output and efficiency performance equivalent to that of diesel engines needs to be developed. In the present paper, the requirements of the pilot torch from pre-chamber for ensuring ignition and promoting combustion are discussed by means of taking high-speed flame photography and system can run with leaner mixture of various fuels comparing to the electric plug ignition system cause the ignition delay period ignited with the torch and the combustion period are very short in spite of changing A/F of gaseous fuels in the main chamber. However, the suitable piston-cavity design for the use of lower-hydrocarbon fuels such as propane and butane must be discussed increasingly in the mear future.