• Title/Summary/Keyword: Ignition Delay time

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Measurement and Prediction of Autoignition Temperature of n-Butanol+p-Xylene Mixture (노말부탄올과 파라자일렌 혼합물의 최소자연발화온도 측정 및 예측)

  • Ha, Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.20 no.5
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    • pp.1-8
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    • 2016
  • The autoignition temperature (AIT) of a substance is the lowest temperature at which the vapor ignites spontaneously from the heat of the environment. The AIT is important index for the safe handling of flammable liquids which constitute the solvent mixtures in the process. This study measured the AITs of n-butanol+p-xylene mixture by using ASTM E659 apparatus. The AITs of n-butanol and p-xylene which constituted binary system were $340^{\circ}C$ and $557^{\circ}C$, respectively. The experimental AITs of n-butanol+p-xylene mixture were a good agreement with the calculated AITs by the proposed equations with a few A.A.D.(average absolute deviation).

On-orbit Thermal Control of MEMS Based Solid Thruster by Using Micro-igniter (MEMS 기반 고체 추력기의 마이크로 점화기를 이용한 궤도 열제어)

  • Ha, Heon-Woo;Kang, Soo-Jin;Jo, Mun-Shin;Oh, Hyun-Ung
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.42 no.9
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    • pp.802-808
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    • 2014
  • MEMS based solid propellant thruster researched for the purpose of an academic research will be verified at space environment through CubeSat program. For this, the temperature of the MEMS thruster should be within allowable operating temperature range by proper thermal control to prevent the ignition failure caused by ignition time delay and to guarantee the structural safety of the MEMS thruster in the low temperature. In this study, we proposed an effective thermal control strategy, that is to use micro-igniter as a heater and temperature sensor for active thermal control instead of using additional heater. The effectiveness of the strategy has been verified through on-orbit thermal analysis of CubeSats with MEMS thruster.

Effect of Hydrogen Addition on Autoignited Methane Lifted Flames (자발화된 메탄 부상화염에 대한 수소 첨가의 영향)

  • Choi, Byung-Chul;Chung, Suk-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.1
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    • pp.75-81
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    • 2012
  • Autoignited lifted flames in laminar jets with hydrogen-enriched methane fuels have been investigated experimentally in heated coflow air. The results showed that the autoignited lifted flame of the methane/hydrogen mixture, which had an initial temperature over 920 K, the threshold temperature for autoignition in methane jets, exhibited features typical of either a tribrachial edge or mild combustion depending on fuel mole fraction and the liftoff height increased with jet velocity. The liftoff height in the hydrogen-assisted autoignition regime was dependent on the square of the adiabatic ignition delay time for the addition of small amounts of hydrogen, as was the case for pure methane jets. When the initial temperature was below 920 K, where the methane fuel did not show autoignition behavior, the flame was autoignited by the addition of hydrogen, which is an ignition improver. The liftoff height demonstrated a unique feature in that it decreased nonlinearly as the jet velocity increased. The differential diffusion of hydrogen is expected to play a crucial role in the decrease in the liftoff height with increasing jet velocity.

Aging of Solid Fuels Composed of Zr and ZrNi Part 1: Thermal/Chemical/Spectroscopic Analysis (Zr과 ZrNi로 구성된 고체연료의 노화 연구 Part 1: 열/화학/분광학적 분석)

  • Han, Byungheon;Ryu, Jihoon;Yang, Junho;Oh, Juyoung;Gnanaprakash, K.;Yoh, Jai-ick
    • Journal of the Korean Society of Propulsion Engineers
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    • v.24 no.2
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    • pp.1-13
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    • 2020
  • The characterization of aging of the pyrotechnic device is conducted thermally, chemically, and spectroscopically. The device is comprised of two parts: (i) igniter composed of Zr and (ii) pyrotechnic delay composed of ZrNi alloy. The thermally induced chemical reaction is identified through Differential Scanning Calorimetry (DSC) and Thermogravimetry Analysis (TGA). The peak deconvolution of the themo-chemical data is used to estimate the enthalpy change of each metallic fuel component. Laser Induced Breakdown Spectroscopy (LIBS) and X-ray Photoelectron Spectroscopy (XPS) are used for chemical species analysis. The decomposition of oxidants by moisture significantly affected the fuel aging, and the formation of oxide film and metal oxide on the fuel surface gave rise to the thermal energy decrease.

Measurement of Autoignition Temperature of Propionic Acid and 3-Hexanone System (Propionic acid와 3-Hexanone 계의 최소자연발화온도의 측정)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.28 no.4
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    • pp.44-49
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    • 2014
  • The autoignition temperaturs (AIT) of solvent mixture is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AIT and ignition delay time for Propionic acid and 3-Hexanone system by using ASTM E659 apparatus. The AITs of Propionic acid and 3-Hexanone which constituted binary system were $511^{\circ}C$ and $425^{\circ}C$, respectively. The experimental AIT of Propionic acid and 3-Hexanone system were a good agreement with the calculated AIT by the proposed equations with a few average absolute deviation (A.A.D.). And Propionic acid and 3-Hexanone system was shown the minimum autoignition temperature behavior (MAITB).

Experimental Investigation of Entrainment of Ambient Gases into Diesel Spray (디이젤 噴霧 周圍氣體의 엔트레인먼트에 관한 實驗的 硏究)

  • 하종률;김봉곤
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.12 no.3
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    • pp.534-540
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    • 1988
  • A study on the mixing process of fuel with ambient gas is necessary to verify combustion process of a diesel engine, especially the mechanism of its ignition delay. In this study, a single shot of diesel spray was injected through either a constant pressure injection system and bypass type injection system. Measurements were made on the flow characteristics of ambient gas and its time history using a hot wire anemometer and a high speed camera. The gas flow direction was determined by a smoke tracer method. (1) The ambient gas of spray flows away at the stagnation part where static pressure value is positive and flows in at the penetration part of a negative value with the steady entrainment length of 0.7. (2) The steady entertainment velocity around the spray in creases from the nozzle tip to the downstream, has the maximum value at the mixing boundary part, and represents zero at the stagnation boundary part after which the stream flows reversely at the stagnation part.

Combustion Characteristics of Emulsified C-heavy Oil in Constant Volume Combustion with High Temperature and Pressure (고온.고압의 정적연소에서 C-중유 에멀젼 연료의 연소특성)

  • Yoo, Dong-Hoon;Nishida, Osami;Fujita, Hirotsugu;Lim, Jae-Keun
    • Journal of Advanced Marine Engineering and Technology
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    • v.34 no.2
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    • pp.243-249
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    • 2010
  • The improvement of fuel economy and the reduction of diesel exhaust PM(Particulate Matter) and $NO_X$ have been successfully achieved by supplying diesel engines with emulsified diesel oil. However, combustion analysis of emulsified C-heavy oil is difficult because the combustion characteristics of emulsified C-heavy oil compared to other fuels have a special form. Therefore, these experimental researches have analyzed the combustion characteristics of emulsified C-heavy oil in a chamber with high pressure and temperature. The pressure and the rate of heat releases in a combustion chamber was decreased with increasing the water content and the ignition delay time was increased with increasing the water percent.

Measurement and Prediction of Fire and Explosion Characteristics of n-Butylacetate (초산부틸의 화재 및 폭발 특성치 측정 및 예측)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.32 no.5
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    • pp.25-31
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    • 2017
  • The flash point, explosion limits, autoignition temperature(AIT) are important combustible properties which need special concern in the chemical safety process that handle hazardous substances. For the evaluation of the flammable properties of n-butylacetate, this study was investigated the explosion limits of n-butylacetate in the reference data. The flash points, fire points and AIT by the ignition delay time of n-butylacetate were experimented. The lower flash points of n-butylacetate by using the Setaflash and Pensky-Martens closed-cup testers were $24^{\circ}C$ and $26^{\circ}C$, respectively. The flash points of n-butylacetate using the Tag and Cleveland open cup testers are measured $31^{\circ}C$ and $40^{\circ}C$, respectively. And the fire points of n-butylacetate by the Tag and Cleveland open cup testers were measured $32^{\circ}C$ and $41^{\circ}C$. The AIT of n-butylacetate measured by the ASTM 659E tester was measured as $411^{\circ}C$. The lower explosion limit of lower flash point $24^{\circ}C$, which was measured by the Setaflash tester, was calculated to be 1.40 vol%. Also, the upper explosion limit of upper flash point $67^{\circ}C$ the Setaflash tester was calculated to be 12.5 vol%.

Prediction of Autoignition Temperature of n-Decane and sec-Butanol Mixture (n-Decane과 sec-Butanol 혼합물의 최소자연발화온도의 예측)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.26 no.3
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    • pp.85-90
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    • 2012
  • The autoignition temperature (AIT) of a material is the lowest temperature at which the material will spontaneously ignite. The AIT is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs of n-Decane+sec-Butanol system by using ASTM E659 apparatus. The AITs of n-Decane and sec-Butanol which constituted binary system were $212^{\circ}C$ and $447^{\circ}C$, respectively. The experimental AITs of n-Decane+sec-Butanol system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D. (average absolute deviation).

Spray Penetrations of Dimethyl Ether (DME) and Diesel for the Variation of Injection Rate (분사율 변화에 따른 Dimethyl Ether (DME)와 디젤의 분무도달거리)

  • Choi, Wook;Lee, Ju-Kwang;Bae, Choong-Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.6
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    • pp.16-22
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    • 2004
  • Dimethyl Ether (DME) has been considered as one of the most attractive alternative fuels for a compression ignition engine. The major advantage of DME-fuelled engine is a great potential for soot-free combustion without sacrificing an inherent high thermal efficiency of diesel engine, despite a necessity for modification of the conventional fuel injection system. An experimental study on DME and conventional diesel sprays was conducted by employing a common-rail type fuel injection system with a 5-holes sac type nozzle, including a constant volume vessel pressurized with nitrogen gas. The injection rates of DME and diesel fuel were recorded with the Bosch type injection rate meter. The injection delay of DME was shorter than that of diesel fuel. The measured injection rates of DME and diesel fuel were correlated with spray penetrations. The prediction method of spray penetration was established using the injection rates, which was verified with the Dent's penetration model and found to agree well for DME case.