• Fire Science and Engineering
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• v.25 no.6
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• pp.14-20
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• 2011

It is very difficult for fire investigators to analyze the fire debris in fire scene to figure out the reason of fire. ASTM E 1618 method with Gas Chromatoghraphy-Mass Spectrometry was used to analyze the ignitable liquid residues in fire debris prepared in our laboratory. According to fire cases, sample handling procedure methods and fire debris store time, different total ion chromatograms were obtained. We wish the study will be helpful to fire investigators to figure out the reason of fire.

• Fire Science and Engineering
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• v.27 no.2
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• pp.70-74
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• 2013

It is very important for the collected samples at fire scenes to be properly preserved for laboratory analysis. Preserving abilities of four type containers, metal cans, glass jars, zipper and heat sealed polymer bags, with the five ignitable liquids (toluene, n-octane, o-xylene, n-decane and n-hexadecane) were examined with gas chromatography-mass spectrometry. The glass jars with Teflon (PTFE) liner were the best ability to prevent the evaporation of the ignitable liquids.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2010.10a
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• pp.148-151
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• 2010

화재증거물 속의 인화성물질을 분석하는 기술은 현재 다양한 추출 및 농축법을 활용한다. 본 연구에서는 Tenax TA를 이용하여 화재증거물 속의 인화성물질을 농축한 후 자동열탈착 장비를 사용하여 Tenax TA관 속에 농축되어 있는 인화성물질을 자동열탈착시켜 GC로 보낸 후 MS 분석하는 기술을 소개한다. 이러한 전처리과정을 사용하여, 화재증거물속의 인화성물질(경유, 등유 등)을 분석하였는데, 물로 화재증거물을 물을 이용하여 소화하여도, 시간이 오래지난 화재증거물이라도 열탈착 장비를 이용한 분석은 경유, 등유등을 확인하는데 유용하였다.

• Journal of the Korean Institute of Gas
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• v.20 no.6
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• pp.31-36
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• 2016

The flash point is one of the most important indicators of the flammability of liquid solutions. The flash point is the lowest temperature at which there is enough concentration of flammable vapor to form an ignitable mixture with air. In this study the flash points of ternary liquid solutions, n-nonane+n-decane+n-dodecane system, were measured using Seta flash closed cup tester. The measured values were compared with the calculated values using Raoult's law and empirical equation. The calculated data by empirical equation described the measured values more effectively than those calculated by Raoult's law.

• Journal of the Korean Society of Propulsion Engineers
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• v.17 no.4
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• pp.1-9
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• 2013

An active anti-ship missile decoy system was designed conceptually to analyze propulsion system requirements and feasibility to use a liquid bi-propellant rocket engine. Overall mass, size, and shape were assumed referring to specifications of Nulka which was developed by US and Australia in 1990s. The propulsion system was assumed to be a 1,000 N-class $H_2O_2$/kerosene rocket engine with a pressurized feed system. A three-degree-of-freedom optimal trajectory was calculated based on the assumptions, and mass budget was designed from the calculation results. It was found that the requirements for the propulsion system is that it shall be operated more than 100 sec; it shall be re-ignitable; it shall have a throttle capability of a range from 35% to 100% when the maximum thrust at sea level is 1,000 N.

• Journal of the Korean Institute of Gas
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• v.19 no.3
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• pp.18-24
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• 2015

The flash point is one of the most important indicators of the flammabiliy of liquid solutions. The flash point is the lowest temperature at which there is enough concentration of flammable vapor to form an ignitable mixture with air. In this study the flash points of binary flammable solutions, 2-propanol+propionic acid and n-hexanol+formic acid systems, were measured using Seta flash closed cup tester. Particularly n-hexanol+formic acid system exhibited minimum flash point behavior. The measured values were compared with the calculated values using Raoult's law and optimization method. The calculated data by optimization method described the measured values more effectively than those calculated by Raoult's law.

• Fire Science and Engineering
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• v.20 no.3 s.63
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• pp.29-34
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• 2006

The flash and fire point are the most important combustible properties used to determine the potential for the fire and explosion hazards of flammable material. The flash point is defined as the lowest temperature at which a flammable liquid gives off sufficient vapor to form an ignitable mixture with air near its surface or within a vessel. The fire point is the temperature of the flammable liquid at which there will be flaming combustion, sustained 5 seconds in response to the pilot flame. In this study, the flash points and fire points were measured to present raw data of the flammable risk assessment for acids, using Pensky-Martens Closed Cup(C.C.) apparatus (ASTM-D93) and Tag Open-cup (O.C.) apparatus(ASTM D 1310-86). The measured fire points were compared with the estimated values based on 1.11 times stoichiometric concentration. The values calculated by the proposed equation were in good agreement with measured values.

• Journal of the Korean Institute of Gas
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• v.17 no.6
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• pp.67-72
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• 2013

The flash point is the lowest temperature at which there is enough concentration of flammable vapor to form an ignitable mixture with air. The flash point is a major physical property used to analyse the fire and explosion hazards of a flammable liquid solution. The flash point data for pure components are easily available in several literature. But the flash points of the flammable binary solutions appear to be scarce in the literature. The objective of this study is to measure and estimate the flash point of acetic acid-formic acid system. Cleveland open cup tester was used to measure the flash point. The experimental data were compared with the values estimated by the Raoult's law and the optimization methods based on van Laar and Wilson equations. As a result, the estmated values by optimization methods were found to be better than those based on the Raoult's law.

• Fire Science and Engineering
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• v.24 no.3
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• pp.52-57
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• 2010

Fire protection countermeasure were considered on the straw thatched roof and wooden structure. For the fire resistant treatment, rice straw was soaked in the fire resistant liquid with different soaking time. After treatment, some rice straw sample was washed with water then the rice straws were tested to check the fire resistance performance. And the wood was soaked in the fire resistant liquid at an atmospheric pressure, vacuum-pressure condition and painted with brush on the surface. To analyse the fire resistant performance of rice straw, ignition delay time was measured under the radiant heat flux of cone heater. And the fire resistant performance of wood samples were tested with 45 degree fire resistant test apparatus and cone heater. Based on the cone heater test, the rice straw which most easily ignitable material shows the longer ignition delay time than not treated ones and even in the water washed straw show a longer ignition delay time than not treated ones. And fire resistant treated woods of vacuum-pressure treated sample showed the most excellent performance on fire resistance. And the fire resistant treated by brush and soaking showed a longer ignition delay time than not treated ones. From this experiment, it was found that a fire resistant treatment of rice straw and wood of the house can be protected from the fire spread.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.11
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• pp.1005-1013
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• 2010

This study was conducted to assess the spray control of flash boiling with mixed fuel in consideration of HCCI (Homogeneous Charge Compression Ignition) engine condition. Mixed fuel existing in two phase regions can control the process of mixture formation under low temperature and density by using the spray resulting from flash boiling which is able to induce rapid evaporation of fuel spray as well as the evaporation of high boiling point component. Because HCCI engine injects the fuel early under ambient conditions, it can facilitate the chemical control of ignition combustion and physical control such as breakup and atomization of liquid fuel by flash boiling of mixed fuel which consists of highly ignitable light oil and highly volatile gasoline. This study was conducted by performing video processing after selected composition and molar fraction of the mixed fuel as major parameters and photographed Schlieren image and Mie scattered light corresponding to the flash boiling phenomenon of the fuel spray that was injected inside a constant volume vessel. It was found that flash boiling causes significant changes in the spray structure under relatively low temperature and density. Thus, we analyzed that the flash boiling spray can be used for HCCI combustion by controlling the mixture formation at the early fuel injection timing.