• Bulletin of the Korean Chemical Society
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• v.30 no.1
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• pp.153-156
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• 2009

Low temperature methane steam reforming to produce $H_2$ for fuel cells has been calculated thermodynamically considering both heat loss of the reformer and unreacted $H_2$ in fuel cell stack. According to the thermodynamic equilibrium analysis, it is possible to operate methane steam reforming at low temperatures. A scheme for the low temperature methane steam reforming to produce $H_2$ for fuel cells by burning both unconverted $CH_4$ and $H_2$ to supply the heat for steam methane reforming has been proposed. The calculated value of the heat balance temperature is strongly dependent upon the amount of unreacted $H_2$ and heat loss of the reformer. If unreacted $H_2$ increases, less methane is required because unreacted $H_2$ can be burned to supply the heat. As a consequence, it is suitable to increase the reaction temperature for getting higher $CH_4$ conversion and more $H_2$ for fuel cell stack. If heat loss increases from the reformer, it is necessary to supply more heat for the endothermic methane steam reforming reaction from burning unconverted $CH_4$, resulting in decreasing the reforming temperature. Experimentally, it has been confirmed that low temperature methane steam reforming is possible with stable activity.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.58 no.1
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• pp.35-41
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• 2009

This paper proposes a stand alone type single-phase fuel cells micro-source with a voltage sag compensator for compensating the ac output voltage variations (sag or swell) of micro-source. The proposed micro-source is consist of a PEM(polymer electrolyte membrane) fuel cells simulator, a full bridge de converter, a 60Hz PWM(pulse width modulation) VSI(voltage source inverter), and a voltage sag compensator. Voltage sag compensator is similar to the configuration of hybrid series active power filter, and it is directly connected to micro-source through the injection transformer. Compensation algorithm of a voltage sag compensator adopts a single phase p-q theory. Effectiveness of the proposed the system is verified by the PSIM(power electronics simulation tool) simulation in the steady state and transient state which the proposed system is able to simultaneously compensate the harmonic current and source voltage sag or swell.

• Journal of Electrochemical Science and Technology
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• v.13 no.2
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• pp.167-176
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• 2022

Electrochemical impedance spectroscopy (EIS) is a unique non-destructive technique employed to analyze various devices in different energy storage applications. It characterizes materials and interfaces for their properties in heterogeneous systems employing equivalent circuits as models. So far, it has been used to analyze the performance of various photovoltaic cells, fuel cells, batteries, and other energy storage devices, through equivalent circuit designing. This review highlights the diverse applications of EIS in fuel cells and specific parameters affecting its performance. A particular emphasis has been laid on the challenges faced by this technique and their possible solutions.

• Journal of the Korean Ceramic Society
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• v.42 no.12 s.283
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• pp.777-786
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• 2005

The Solid Oxide Fuel Cell (SOFC) is an electrochemical device to convert chemical energy of a fuel into electricity at temperatures from about 600 to $1000^{\circ}C$. The SOFC offers certain advantages over lower temperature fuel cells, notably its ability to use CO as a fuel rather than being poisoned by it, and high grade exhaust heat for combined heat and power, or combined cycle gas turbine applications. This paper reviews the operating principle, materials for different cell and stack components, cell designs, and applications of SOFCs. Among all designs of Solid Oxide Fuel Cells (SOFCs), the most progress has been achieved with the tubular design. However, the electrical resistance of tubular SOFCs is high, and specific power output $(W/cm^2)$ and volumetric power density $(W/cm^3)$ low. Planar SOFCs, in contrast, are capable of achieving very high power densities.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.60-61
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• 2006

New Energy and Industrial Technology Development Organization (NEDO) promotes R&D that individual private sector enterprises can not undertake by themselves. To do this, it utilizes an extensive network that supports cooperation between industries, universities, and public research organizations. NEDO's government-funded R&D budget for FY2005 totals approximately 148.8 billion yen. Fuel cells and hydrogen technology development project is one of NEDO's emphasizing projects. The budget size was ${\yen}$20.8 billion, corresponding to about 60% of annual expenditure of Japanese government for fuel cells in FY2005. These projects consist of 8 programs as follows.

• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.27-30
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• 2007

This study considers the feasibility of the concentration control of the methanol solution by oscillating flow in the anode channel of passive type Direct Methanol Fuel Cells(DMFC). DMFC stack performance is largely influenced by the fuel concentration. If the fuel concentration is either lower than 0.5M or more than 2M, its performance deteriorates seriously because of the fuel starvation or the fuel crossover. In this respect the optimization of the fuel concentration is crucially important to maximize the DMFC stack performance. In this work, the effects of oscillating actuation in the fuel supply are studied to control the fuel concentration. Two important nondimensional parameters are introduced, each of which represents either the oscillating frequency or the oscillating amplitude. It is shown how these factors affect the stack performance and the efficiency of the DMFC stack.

• Journal of the Korean Ceramic Society
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• v.52 no.5
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• pp.308-314
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• 2015

The electrochemical performance and Cr poisoning behavior of $La_{1-x}Ba_xCo_{0.9}Fe_{0.1}O_{3-{\delta}}$ (LBCF, x = 0.3, 0.4, 0.5) and $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_{3-{\delta}}$ (LSCF) cathodes were investigated for solid oxide fuel cells (SOFCs). The polarization resistance of the LBCF/GDC/LBCF symmetrical cell was found to decrease with increasing Ba content (x value). This phenomenon might be associated with the high oxygen vacancy concentration in the LBCF sample, with x = 0.5. In addition, there was no chromium poisoning in the LBCF cathode. On the other hand, the polarization resistance of the LSCF cathode was found to significantly increase after exposure to gaseous chromium species; it appears that this result stemmed from the formation of $SrCrO_4$ phase. Therefore, it can be expected that LBCF can be a durable potential cathode material for intermediate-temperature solid oxide fuel cells (IT-SOFC).

• Journal of Powder Materials
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• v.27 no.1
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• pp.63-71
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• 2020

It is necessary to fabricate uniformly dispersed nanoscale catalyst materials with high activity and long-term stability for polymer electrolyte membrane fuel cells with excellent electrochemical characteristics of the oxygen reduction reaction and hydrogen oxidation reaction. Platinum is known as the best noble metal catalyst for polymer electrolyte membrane fuel cells because of its excellent catalytic activity. However, given that Pt is expensive, considerable efforts have been made to reduce the amount of Pt loading for both anode and cathode catalysts. Meanwhile, the atomic layer deposition (ALD) method shows excellent uniformity and precise particle size controllability over the three-dimensional structure. The research progress on noble metal ALD, such as Pt, Ru, Pd, and various metal alloys, is presented in this review. ALD technology enables the development of polymer electrolyte membrane fuel cells with excellent reactivity and durability.

• Transactions of the Korean hydrogen and new energy society
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• v.32 no.4
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• pp.245-255
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• 2021

Various studies about metallic bipolar plates have been conducted to improve fuel cell performance through flow field design optimization. These research works have been mainly focused on fuel cells for vehicle, but not fuel cells for building. In order to reduce the price and volume of fuel cell stacks for building, it is necessary to apply a metallic flow field, In this study, for a metallic flow field applied to a fuel cell for building, the effect of a change in the flow field shape on the performance of a polymer electrolyte membrane fuel cell was confirmed using a model and experiments with a down-sizing single cell. As a result, the flow field using a metal foam outperforms the channel type flow field because it has higher internal differential pressure and higher reactants velocity in gas diffusion layer, resulting in higher water removal and higher oxygen concentration in the catalyst layer than the channel type flow field. This study is expected to contribute to providing basic data for selecting the optimal flow field for the full stack of polymer electrolyte membrane fuel cells for buildings.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.87.2-87.2
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• 2011

Many type of fuel cell stacks have been developed to improve the efficiency of reactants usage. The cascade type fuel cell stack using dead end operation is able to attain above 99% usage of hydrogen and oxygen. It is sectionalized to several parts and the residual reactants which are used previous parts would be supplied again to next parts which have less number of cells in dead end operation stack. The oversupply of reactants which is usually 120%~150% of the theoretical amount to generate current for preventing the flooding effect could be provided to each part except the last one. The final section which is called monitoring cells is supposed to be supplied insufficient the fuel or oxidant that would have some accumulated inert gas from former parts. It makes some voltage drop in the part and the fresh reactants must be supplied to the part for recovering it by venting the residual gas. So the usage of fuel and oxidant is depend on the time and frequency of opening valves for venting of residual gas and it is important to optimize the vent logic for achieving higher usage of hydrogen and oxygen. In this research, many experiments are performed to find optimal condition by evaluating the effect of time and frequency under several power conditions using over 100kW class fuel cell module. And the characteristics of the monitoring cells are studied to know the proper cell voltage which decide the condition of opening the vent valve for stable performance of the cascade type fuel cell module.