• Title/Summary/Keyword: IR spectra

Search Result 849, Processing Time 0.025 seconds

MODELS FOR THE IRAS LOW RESOLUTION SPECTRA OF OH/IR STARS

  • Lee, Sung-Min;Suh, Kyung-Won
    • Journal of Astronomy and Space Sciences
    • /
    • v.15 no.2
    • /
    • pp.291-295
    • /
    • 1998
  • We investigate models for the IRAS LRS)Low Resolution Spectra) of OH/IR stars. OH/IR stars often show the silicate features at 9.7 ${mu}m$ and $18{mu}m$ in the spectra obtained by the IRAS LRS as well as remarkably red values in the IRAS photometric colors such as [60]-[25] and [25]-[12]. We compare the radiative transfer model results with observed spectral energy distributions (SEDs) of the stars including IRAS PSC(Point Source Catalog), IRAS LRS and ground based observational data.

  • PDF

Calibrating the stellar velocity dispersion in near-IR

  • Kang, Wol-Rang;Woo, Jong-Hak
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.36 no.1
    • /
    • pp.52.2-52.2
    • /
    • 2011
  • The correlation between black hole mass and galaxy stellar velocity dispersion gives an important clue on the black hole growth and galaxy evolution. In the case of AGN, however, it is extremely difficult to measure stellar velocity dispersions in the optical spectra since AGN continuum dilutes stellar absorption features. In contrast, stellar velocity dispersions of active galaxies can be measured in the near-IR, where AGN-to-star flux ratio is much smaller, particularly with the laser-guide-star adaptive optics. However, it is crucial to test whether the stellar velocity dispersion measured from the near-IR spectra is consistent with that measured from the optical spectra. Using the TripleSpec at the Palomar 5-m Telescope, we obtained high quality spectra ranging from 1 to 2.4 micron for a sample of 35 nearby galaxies, for which dynamical black hole masses and optical stellar velocity dispersion measurements are available, in order to calibrate the stellar velocity dispersion in the near-IR. In this poster, we present the initial results based on 10 galaxies, with the stellar velocity dispersion measured in the H-band.

  • PDF

Identification of a Radical Decomposition Pathway(s) of Polycyclic Aromatic Hydrocarbon by the Vibrational Frequency Calculations with DFT Method (DFT법에 의한 진동 운동 진동수 계산을 통한 다고리 방향족 탄화수소의 라디칼 분해 경로 동정)

  • Lee, Byung-Dae;Ha, Kwanga;Lee, Min-Joo
    • Journal of the Korean Chemical Society
    • /
    • v.62 no.5
    • /
    • pp.344-351
    • /
    • 2018
  • The IR spectra of gaseous phenanthrene, phenathrenols, phenanthrenyl radicals, and hydroxylphenanthrene radicals have been obtained using the BLYP/6-311++G(d,p) method. A comparison of these spectra shows that the measurements of IR spectra can be valuable to identify the reaction pathway(s) of the phenanthrene decomposition reaction by ${\cdot}OH$. We have found that the H atom abstraction reaction process can be easily identifiable from the $650-850cm^{-1}$ (CH out-of-plane bending) region and the ${\cdot}OH$ addition reaction process from the CH stretching and bending modes region of IR spectra. In addition, the calculated IR spectra of all five phenanthren-n-ols (n = 1, 2, 3, 4, 9) have also given in this work.

Defining the $M_{BH}-sigma_*$ relation using the uniformly measured stellar velocity dispersions in the near-IR

  • Kang, Wol-Rang;Woo, Jong-Hak
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.36 no.2
    • /
    • pp.62.2-62.2
    • /
    • 2011
  • The correlation between black hole mass and stellar velocity dispersion provides an important clue on the black hole growth and galaxy evolution. In the case of AGN, however, it is extremely difficult to measure stellar velocity dispersions in the optical since AGN continuum dilutes stellar absorption features. In contrast, stellar velocity dispersions of active galaxies can be measured in the near-IR, where AGN-to-star flux ratio is much smaller. Expecting that more stellar velocity dispersion measurements will be available using future near-IR facilities, it is crucial to test whether the stellar velocity dispersions measured from the near-IR spectra are consistent with those measured from the optical spectra. For a sample of 35 nearby galaxies, for which optical stellar velocity dispersion measurements and dynamical black hole masses are available, we obtained high quality H-band spectra, using the TripleSpec at the Palomar 5-m Telescope, in order to calibrate the stellar velocity dispersions and define the $M_{BH}-sigma_*$ relation in the near-IR. Based on the spatially resolved kinematics, we correct for the rotation component and determine the luminosity-weighted stellar velocity dispersion of the spheroid component in each galaxy. In this presentation, we will show the comparison between optical and near-IR stellar velocity dispersion measurements and define the $M_{BH}-sigma_*$ relation based on uniformly measured stellar velocity dispersion in the near-IR.

  • PDF

PROPERTIES OF OH/IR STARS WITH THE IRAS LRS SPECTRA

  • CHEN P. S.;KWOK S.
    • Journal of The Korean Astronomical Society
    • /
    • v.29 no.spc1
    • /
    • pp.257-258
    • /
    • 1996
  • 1607 OH/IR stars associated with IRAS sources are assembled and the IRAS LRS spectra of 980 OH/IR stars are examined in this paper. The nature of the circumstellar dust for these sources is classified. The distributions of these subgroups of OH/IR stars in the IRAS color-color diagram and the period-color diagram are interpreted with their evolutionary status. The Galactic and the velocity distributions of these subgroups of OH/IR stars are also presented. The correlations among the expanding velocities of the envelopes, colors, periods and the pumping efficiencies for subgroups of OH/IR stars are investigated to outline the evolutionary status of OH/IR stars.

  • PDF

Characterazation of Butyldithiodiacetic Acid, Benzmethyldithiodiacetic Acid and Cyclohexyldithiodiacetic Acid used Infrared Spectra in Aqueous Solution (수용액상에서 Infrared Spectra를 이용한 Butyldithiodiacetic Acid, Benzmethyldithiodiacetic Acid, Cyclohexyldithiodiacetic Acid의 특성에 관한 연구)

  • Doh, Kiel Myung;Kim, Ill Chool;Choi, Bo Yong
    • Journal of the Korean Chemical Society
    • /
    • v.39 no.3
    • /
    • pp.213-217
    • /
    • 1995
  • Infrared Spectra of aqueous solution of BUDDA(Butyldithiodiacetic acid), BMDDA(Benzmethyldithiodiacetic acid), and CHDDA(Cyclohexyldithiodiacetic acid) are reported at various pH values. On the basis of the antisymmetric stretching bands of the ionized and un-ionized carboxyl group, the structures of the free-ligand are inferred. An approach to the study of these structures are compared with the results of potentiometric titration curve and IR Spectra studies.

  • PDF

Calibrating high-z QSO masses using near-IR and optical spectra

  • Kim, Phuong Thi;Woo, Jong-Hak
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.36 no.1
    • /
    • pp.48.2-48.2
    • /
    • 2011
  • Using the newly commissioned Fiber-Multi-Object-Spectrograph at the Subaru telescope, we obtained near-IR spectra of a sample of 19 AGNs at 0.6 < z < 2.6, selected from the NOAO Deep Wide-Field Survey (NDWFS) Bootes field, in order to calibrate high-z black hole mass (MBH) estimators. MBHs are generally determined through the kinematics of ionized gas clouds around the black hole assuming virial equilibrium. The velocity profiles of $H{\beta}/H{\alpha}$, MgII and CIV are used to infer the gas kinematics of low-z, mid-z, and high-z quasars, respectively. However, the MBH based on MgII and CIV is not very well calibrated. We compare the $H{\alpha}$ - based MBH estimates from the new FMOS near-IR spectra, with the MgII-based MBH estimates from our existing optical spectra, and investigate the systematic differences.

  • PDF

A Study on the Characteristics of Humic Materials Extracted from Plant Residues (composts) -II. Oxygen-containing Functional Groups and Infrared (IR) Spectra of Fulvic Acid Fractions (식물성(植物性) 유기물질(有機物質)의 부숙과정중(腐熟過程中) 부식특성(腐植特性)에 관(關)한 연구(硏究) -II. Fulv 산중(酸中)에 함유(含有)되어 있는 효소함유작용기(酵素含有作用基)와 적외선(赤外線) spectrum)

  • Kim, Jeong-Je;Shin, Young-Oh
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.20 no.4
    • /
    • pp.341-349
    • /
    • 1987
  • Fulvic acids extracted from seven plant materials were tested. The IR spectra and the data obtained from chemical analyses in terms of oxygen-containing functional groups complemented one another. Selected samples covered straws of grain crops (rice, barley, wheat and rye), hay of wild grass, and leaves of trees (deciduous and coniferous). 1. No significant variation in IR spectra of fulvic acids was observed among samples taken from different plant residues and at different stages of humification. 2. Oxygen-containing functional goups, such as carboxyls, phenolics, alcoholics, carbonyls, and quinones were identified on IR spectra and confirmed by chemical analyses. 3. The acidity of fulvic acids was directly related with the content of carboxyl groups. 4. Alcoholic hydroxyl groups predominated over phenolic hydroxyls. 5. The major part of fulvic acid structure appeared to be strongly aliphatic in many respects of chemical characteristics.

  • PDF

On the UV and IR Spectra of Dioxane Lignin from Bamboo Culm (죽재(竹材) Dioxane Lignin의 UV, IR Spectrum에 대하여)

  • Moon, Chang-Kuck;Jo, Jong-Soo
    • Journal of the Korean Wood Science and Technology
    • /
    • v.15 no.4
    • /
    • pp.26-31
    • /
    • 1987
  • The ultraviolet and infrared spectra of dioxane lignin from bamboo were investigated. 1. Spectrum curve type considerably resembled that of wood lignin. There were 3 absorption peak positions at 210nm(max. peak), at 260-270nm(shallow mini. peak), at 280nm(lower max. peak) as in the wood lignin spectra. 2. The lower minimum peak near at 280 nm is the typical peak of lignin. This peak does not exist exactly at 280 nm but from 282nm to 285nm in this bamboo UV spectra. The absorption intensities are equal in this region and the peak is not sharp. 3. The absorption band of aromatic nucleus is near at wave number $1550cm^{-1}$ in the IR spectra of bamboo lignin. The intensity at about 1040-$1130cm^{-1}$ and at about 1230-$1275cm^{-1}$ were similar in the hardwood lignin but reverse to that of softwood lignin spectrum.

  • PDF

Vasorelaxation Study and Tri-Step Infrared Spectroscopy Analysis of Malaysian Local Herbs

  • Ch'ng, Yung Sing;Tan, Chu Shan;Loh, Yean Chun;Ahmad, Mariam;Asmawi, Mohd. Zaini;Yam, Mun Fei
    • Journal of Pharmacopuncture
    • /
    • v.19 no.2
    • /
    • pp.145-154
    • /
    • 2016
  • Objectives: The aim of this paper is to investigate the activities of Malaysian local herbs (Clinacanthus nutans Lindau, Strobilanthes crispus, Murdannia bracteata, Elephantopus scaber Linn., Pereskia bleo, Pereskia grandifolia Haw., Vernonia amygdalina, and Swietenia macrophylla King) for anti-hypertensive and vasorelaxant activity. An infrared (IR) macro-fingerprinting technique consisting of conventional fourier transform IR (FTIR), second-derivative IR (SD-IR), and two-dimensional correlation IR (2D-correlation IR) analyses were used to determine the main constituents and the fingerprints of the Malaysian local herbs. Methods: The herbs were collected, ground into powder form, and then macerated by using three different solvents: distilled water, 50% ethanol, and 95% ethanol, respectively. The potentials of the extracts produced from these herbs for use as vasorelaxants were determined. Additionally, the fingerprints of these herbs were analyzed by using FTIR spectra, SD-IR spectra, and 2D-correlation IR spectra in order to identify their main constituents and to provide useful information for future pharmacodynamics studies. Results: Swietenia macrophylla King has the highest potential in terms of vasorelaxant activity, followed by Vernonia amygdalina, Pereskia bleo, Strobilanthes crispus, Elephantopus scaber Linn., Pereskia grandifolia Haw., Clinacanthus nutans Lindau, and Murdannia bracteata. The tri-step IR macro-fingerprint of the herbs revealed that most of them contained proteins. Pereskia bleo and Pereskia grandifolia Haw. were found to contain calcium oxalate while Swietenia macrophylla King was found to contain large amounts of flavonoids. Conclusion: The flavonoid content of the herbs affects their vasorelaxant activity, and the tri-step IR macro-fingerprint method can be used as an analytical tool to determine the activity of a herbal medicine in terms of its vasorelaxant effect.