• 제목/요약/키워드: IR spectra

검색결과 848건 처리시간 0.026초

MODELS FOR THE IRAS LOW RESOLUTION SPECTRA OF OH/IR STARS

  • Lee, Sung-Min;Suh, Kyung-Won
    • Journal of Astronomy and Space Sciences
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    • 제15권2호
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    • pp.291-295
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    • 1998
  • We investigate models for the IRAS LRS)Low Resolution Spectra) of OH/IR stars. OH/IR stars often show the silicate features at 9.7 ${mu}m$ and $18{mu}m$ in the spectra obtained by the IRAS LRS as well as remarkably red values in the IRAS photometric colors such as [60]-[25] and [25]-[12]. We compare the radiative transfer model results with observed spectral energy distributions (SEDs) of the stars including IRAS PSC(Point Source Catalog), IRAS LRS and ground based observational data.

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Calibrating the stellar velocity dispersion in near-IR

  • 강월랑;우종학
    • 천문학회보
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    • 제36권1호
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    • pp.52.2-52.2
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    • 2011
  • The correlation between black hole mass and galaxy stellar velocity dispersion gives an important clue on the black hole growth and galaxy evolution. In the case of AGN, however, it is extremely difficult to measure stellar velocity dispersions in the optical spectra since AGN continuum dilutes stellar absorption features. In contrast, stellar velocity dispersions of active galaxies can be measured in the near-IR, where AGN-to-star flux ratio is much smaller, particularly with the laser-guide-star adaptive optics. However, it is crucial to test whether the stellar velocity dispersion measured from the near-IR spectra is consistent with that measured from the optical spectra. Using the TripleSpec at the Palomar 5-m Telescope, we obtained high quality spectra ranging from 1 to 2.4 micron for a sample of 35 nearby galaxies, for which dynamical black hole masses and optical stellar velocity dispersion measurements are available, in order to calibrate the stellar velocity dispersion in the near-IR. In this poster, we present the initial results based on 10 galaxies, with the stellar velocity dispersion measured in the H-band.

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DFT법에 의한 진동 운동 진동수 계산을 통한 다고리 방향족 탄화수소의 라디칼 분해 경로 동정 (Identification of a Radical Decomposition Pathway(s) of Polycyclic Aromatic Hydrocarbon by the Vibrational Frequency Calculations with DFT Method)

  • 이병대;하광아;이민주
    • 대한화학회지
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    • 제62권5호
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    • pp.344-351
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    • 2018
  • 이 연구에서는 기체 상태 페난트렌, 페난트렌올, 페난트레닐 라디칼, 하이드록실 페난트렌 라디칼에 대한 IR 스펙트럼을 BLYP/6-311++G(d,p)법을 사용하여 얻었다. 이 스펙트럼들을 비교함으로써 ${\cdot}OH$에 의한 페난트렌의 분해 반응 경로를 동정하는데 IR 스펙트럼 측정이 유용하게 사용될 수 있음을 볼 수 있었다. IR 스펙트럼에서 H 원자 제거 과정은 CH의 out-of-plane 굽힘 진동 영역인 $650{\sim}850cm^{-1}$, ${\cdot}OH$ 첨가 과정은 CH 신축 및 굽힘 진동 영역에서 용이하게 확인 할 수 있음을 알 수 있었다. 또한 5종의 페난트렌-n-올 (n = 1, 2, 3, 4, 9) 모두에 대하여 얻어진 IR 스펙트럼 역시 여기에 주어졌다.

Defining the $M_{BH}-sigma_*$ relation using the uniformly measured stellar velocity dispersions in the near-IR

  • 강월랑;우종학
    • 천문학회보
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    • 제36권2호
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    • pp.62.2-62.2
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    • 2011
  • The correlation between black hole mass and stellar velocity dispersion provides an important clue on the black hole growth and galaxy evolution. In the case of AGN, however, it is extremely difficult to measure stellar velocity dispersions in the optical since AGN continuum dilutes stellar absorption features. In contrast, stellar velocity dispersions of active galaxies can be measured in the near-IR, where AGN-to-star flux ratio is much smaller. Expecting that more stellar velocity dispersion measurements will be available using future near-IR facilities, it is crucial to test whether the stellar velocity dispersions measured from the near-IR spectra are consistent with those measured from the optical spectra. For a sample of 35 nearby galaxies, for which optical stellar velocity dispersion measurements and dynamical black hole masses are available, we obtained high quality H-band spectra, using the TripleSpec at the Palomar 5-m Telescope, in order to calibrate the stellar velocity dispersions and define the $M_{BH}-sigma_*$ relation in the near-IR. Based on the spatially resolved kinematics, we correct for the rotation component and determine the luminosity-weighted stellar velocity dispersion of the spheroid component in each galaxy. In this presentation, we will show the comparison between optical and near-IR stellar velocity dispersion measurements and define the $M_{BH}-sigma_*$ relation based on uniformly measured stellar velocity dispersion in the near-IR.

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PROPERTIES OF OH/IR STARS WITH THE IRAS LRS SPECTRA

  • CHEN P. S.;KWOK S.
    • 천문학회지
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    • 제29권spc1호
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    • pp.257-258
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    • 1996
  • 1607 OH/IR stars associated with IRAS sources are assembled and the IRAS LRS spectra of 980 OH/IR stars are examined in this paper. The nature of the circumstellar dust for these sources is classified. The distributions of these subgroups of OH/IR stars in the IRAS color-color diagram and the period-color diagram are interpreted with their evolutionary status. The Galactic and the velocity distributions of these subgroups of OH/IR stars are also presented. The correlations among the expanding velocities of the envelopes, colors, periods and the pumping efficiencies for subgroups of OH/IR stars are investigated to outline the evolutionary status of OH/IR stars.

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수용액상에서 Infrared Spectra를 이용한 Butyldithiodiacetic Acid, Benzmethyldithiodiacetic Acid, Cyclohexyldithiodiacetic Acid의 특성에 관한 연구 (Characterazation of Butyldithiodiacetic Acid, Benzmethyldithiodiacetic Acid and Cyclohexyldithiodiacetic Acid used Infrared Spectra in Aqueous Solution)

  • 도길명;김일출;최보용
    • 대한화학회지
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    • 제39권3호
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    • pp.213-217
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    • 1995
  • 수용액상에서 BUDDA(Butyldithiodiacetic acid), BMDDA(Benzmethyldithiodiac-etic acid), CHDDA(Cyclohexyldithiodiacetic acid)의 IR 스펙트라는 다양한 pH값에서 보고되어진다. 이온화된 carboxyl group과 비이온화된 carboxyl group의 비대칭 신축진동 흡수띠 차이를 이용하여 free-ligand의 구조를 추정한다. 또한 이들 연구의 접근은 리간드의 IR 스펙트라와 전위차 적정법을 이용하여 얻어진 $pk_a$값을 비교함으로서 설명된다.

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Calibrating high-z QSO masses using near-IR and optical spectra

  • 김치푸옹;우종학
    • 천문학회보
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    • 제36권1호
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    • pp.48.2-48.2
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    • 2011
  • Using the newly commissioned Fiber-Multi-Object-Spectrograph at the Subaru telescope, we obtained near-IR spectra of a sample of 19 AGNs at 0.6 < z < 2.6, selected from the NOAO Deep Wide-Field Survey (NDWFS) Bootes field, in order to calibrate high-z black hole mass (MBH) estimators. MBHs are generally determined through the kinematics of ionized gas clouds around the black hole assuming virial equilibrium. The velocity profiles of $H{\beta}/H{\alpha}$, MgII and CIV are used to infer the gas kinematics of low-z, mid-z, and high-z quasars, respectively. However, the MBH based on MgII and CIV is not very well calibrated. We compare the $H{\alpha}$ - based MBH estimates from the new FMOS near-IR spectra, with the MgII-based MBH estimates from our existing optical spectra, and investigate the systematic differences.

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식물성(植物性) 유기물질(有機物質)의 부숙과정중(腐熟過程中) 부식특성(腐植特性)에 관(關)한 연구(硏究) -II. Fulv 산중(酸中)에 함유(含有)되어 있는 효소함유작용기(酵素含有作用基)와 적외선(赤外線) spectrum (A Study on the Characteristics of Humic Materials Extracted from Plant Residues (composts) -II. Oxygen-containing Functional Groups and Infrared (IR) Spectra of Fulvic Acid Fractions)

  • 김정제;신영오
    • 한국토양비료학회지
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    • 제20권4호
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    • pp.341-349
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    • 1987
  • 7종(種)의 식물성(植物性) 유기물(有機物)을 부숙(腐熟)시키면서 경시적(經時的)으로 시료(試料)를 채취(採取)한 후 Fulv산(酸)을 추출정제(抽出精製)하여 IR spectrum의 특성(特性)과 산소함유작용기(酸素含有作用基)의 함량(含量)을 정량(定量)하여 얻은 결과(結果)는 다음과 같다. 1. 식물체(植物體)의 종류(種類)와 부숙기간(腐熟期間)이 상이(相異)한 시료(試料)에서 추출(抽出)한 Fulv산(酸)의 IR spectrum은 큰 차이(差異)가 없었다. 2. 산소함유작용기(酸素含有作用基) 즉(卽) Carboxyl 기(基), Phenol 기(基), Alcohol 기(基), Carbonyl 기(基), 그리고 Quiuone기(基) 등(等)이 IR spectrum 상(上)에 나타났으며 화학분석결과(化學分析結果)에도 검출(檢出)되었다. 3. Fulv산중(酸中) Total Acidity와 Carboxyl 기(基)의 함량간(含量間)에는 유의상관(有意相關)이 있었다. 4. Alcoholic hydroxyl 기(基)가 Phenolic hydroxyl 기(基)보다 훨씬 많았다. 5. Fulv산(酸) 구조(構造)의 주요부분(主要部分)은 화학적(化學的)인 특성상(特性上)으로 볼때 여러면에서 Aliphatic 성(性)이 매우 강(强)했다.

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죽재(竹材) Dioxane Lignin의 UV, IR Spectrum에 대하여 (On the UV and IR Spectra of Dioxane Lignin from Bamboo Culm)

  • 문창국;조종수
    • Journal of the Korean Wood Science and Technology
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    • 제15권4호
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    • pp.26-31
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    • 1987
  • 맹종죽, 왕대, 솜대 Dioxane Lignin의 UV, IR spectrum의 특징(特徵)을 조사(調査)하여 본 바, 그 결과(給果)를 요약하면 다음과 같다. 1. UV spectrum에 있어서는 일반적(一般的)인 Lignin spectrum과 같이 Maximum peak, Shallow minium peak, Minimum peak의 3개소(個所)를 보였는데 Max. peak는 210nm 부근(附近), Shallow peak는 260-270nm에, Minimum peak는 280nm부근(附近)에 있었다. 2. 280nm부근(附近)의 Minimum peak는 Lignin이 갖는 특징적(特徵的)인 peak로서 일반(一般) 침엽수재(針棄樹材) Lignin이나 활엽수(闊葉樹) Lignin과는 달리 282-285nm에서 흡광도(吸光度)가 꼭 같아 아주 완만한 peak 를 보여 주었다. 3. IR spectrum에 있어서는 방향핵(芳香核) 흡수대(吸收帶)는 $1550cm^{-1}$ 부근(附近)에 있고 1040-$1130cm^{-1}$부근(附近)과 1230-$1275cm^{-1}$에서의 Spectrum 형태(形態)는 활엽수(闊葉樹)에 가깝고 침엽수재(針葉樹材) Lignin의 spectrum과는 상반되는 모습을 보여 주었다.

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Vasorelaxation Study and Tri-Step Infrared Spectroscopy Analysis of Malaysian Local Herbs

  • Ch'ng, Yung Sing;Tan, Chu Shan;Loh, Yean Chun;Ahmad, Mariam;Asmawi, Mohd. Zaini;Yam, Mun Fei
    • 대한약침학회지
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    • 제19권2호
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    • pp.145-154
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    • 2016
  • Objectives: The aim of this paper is to investigate the activities of Malaysian local herbs (Clinacanthus nutans Lindau, Strobilanthes crispus, Murdannia bracteata, Elephantopus scaber Linn., Pereskia bleo, Pereskia grandifolia Haw., Vernonia amygdalina, and Swietenia macrophylla King) for anti-hypertensive and vasorelaxant activity. An infrared (IR) macro-fingerprinting technique consisting of conventional fourier transform IR (FTIR), second-derivative IR (SD-IR), and two-dimensional correlation IR (2D-correlation IR) analyses were used to determine the main constituents and the fingerprints of the Malaysian local herbs. Methods: The herbs were collected, ground into powder form, and then macerated by using three different solvents: distilled water, 50% ethanol, and 95% ethanol, respectively. The potentials of the extracts produced from these herbs for use as vasorelaxants were determined. Additionally, the fingerprints of these herbs were analyzed by using FTIR spectra, SD-IR spectra, and 2D-correlation IR spectra in order to identify their main constituents and to provide useful information for future pharmacodynamics studies. Results: Swietenia macrophylla King has the highest potential in terms of vasorelaxant activity, followed by Vernonia amygdalina, Pereskia bleo, Strobilanthes crispus, Elephantopus scaber Linn., Pereskia grandifolia Haw., Clinacanthus nutans Lindau, and Murdannia bracteata. The tri-step IR macro-fingerprint of the herbs revealed that most of them contained proteins. Pereskia bleo and Pereskia grandifolia Haw. were found to contain calcium oxalate while Swietenia macrophylla King was found to contain large amounts of flavonoids. Conclusion: The flavonoid content of the herbs affects their vasorelaxant activity, and the tri-step IR macro-fingerprint method can be used as an analytical tool to determine the activity of a herbal medicine in terms of its vasorelaxant effect.