• 제목/요약/키워드: IEM

검색결과 89건 처리시간 0.034초

이온교환막을 통한 이온분리에 대한 총설 (A Review Based on Ion Separation by Ion Exchange Membrane)

  • 살센벡 아샐;라즈쿠마 파텔
    • 멤브레인
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    • 제32권4호
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    • pp.209-217
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    • 2022
  • 이온교환막(IEM)은 다양한 종류의 단가이온과 다가이온을 분리하기 위해 사용되는 막의 한 종류로, 배터리, 연료전지, 염화물-알칼리 공정 등에 사용된다. 이온교환막을 통한 막분리는 전기 구동력을 기반으로 한 녹색 분리 방식이며, 해수 담수화와 수처리 분야에서 떠오르는 방식이다. 전기투석(ED)은 양이온과 음이온이 이온교환막을 따라 선택적으로 이동하는 기술이다. 음이온 교환막(AEM)은 전기투석의 중요한 구성 요소 중 하나이며, 공정 효율을 향상시키는 데 상당한 역할을 한다. 이온교환막에 가교결합을 도입하면 자유 부피의 감소로 인해 이온 선택 분리 성능이 향상된다. 역삼투(RO) 공정을 통한 해수 담수화 시 RO 농축수에 용해된 염이 다량 존재한다. 따라서 1가 양이온 선택막으로 구성된 전기투석 공정은 오염을 줄이고 막 플럭스를 개선한다. 이 검토는 전기투석, 음이온 교환막, 그리고 양이온 교환막의 세 부분으로 나뉜다.

이온 교환 공정에 의한 귀중한 수산화 리튬의 회수: 리뷰 (Recovery of Valuable Lithium Hydroxide by Ion Exchange Process: A Review)

  • 살센벡 아샐;라즈쿠마 파텔
    • 멤브레인
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    • 제32권6호
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    • pp.401-410
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    • 2022
  • 수산화리튬(LiOH)에 대한 수요는 현재의 대안들에 비해 환경에 대한 효율성과 안전성 때문에 매년 증가하고 있다. 리튬은 다른 염분과 염수 호수에서 발견될 수 있으며, 나중에 합성되어 다양한 용도로 LiOH를 생성한다. 리튬 이온을 분리 및 회수하기 위해 다양한 방법이 사용되며, 그 중 가장 일반적인 방법은 전기투석법(ED)이다. ED는 이온을 한쪽에서 다른 쪽으로 밀어내는 구동력으로서 그 층의 전위차에 작용하는 멤브레인 기반 분리 기술이다. ED의 이온교환막(IEM)은 유체역학적 부피에 따라 상이한 이온의 선택성이 달라지기 때문에 공정을 효율적으로 만든다. 본 총설에서는 리튬이온의 회수를 향상시키기 위한 ED와 IEM의 서로 다른 변화 전략이 논의된다.

A Study of a Novel Wind Turbine Concept with Power Split Gearbox

  • Liu, Qian;Appunn, Rudiger;Hameyer, Kay
    • Journal of international Conference on Electrical Machines and Systems
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    • 제2권4호
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    • pp.478-485
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    • 2013
  • This paper focuses on the design and control of a new concept for wind turbines with a planetary gearbox to realize a power split. This concept, where the generated wind power is split into two parts, is to increase the utilization of the wind power and may be particularly suitable for large scale off-shore wind turbines. In order to reduce the cost of the power electronic devices, a synchronous generator, which is driven by the planetary gear, is directly connected to the power grid without electronic converter. A servo drive, which functions as the control actuator, is connected to the power grid by a power electronic converter. With small scale power electronic device, the current harmonics can also be reduced. The speed of the main shaft is controlled to track the optimal tip speed ratio. Meanwhile the speed of the synchronous generator is controlled to stay at the synchronous speed. The minimum rated power of the servo motor and the converter, is studied and discussed in this paper. Different variants of the wind turbine with a planetary gear are also compared. The controller for optimal tip speed ratio and synchronous speed tracking is given.

Retrieval of surface parameters in tidal flats using radar backscattering model and multi-frequency SAR data

  • Choe, Byung-Hun;Kim, Duk-Jin
    • 대한원격탐사학회지
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    • 제27권3호
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    • pp.225-234
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    • 2011
  • This study proposes an inversion algorithm to extract the surface parameters, such as surface roughness and soil moisture contents, using multi-frequency SAR data. The study areas include the tidal flats of Jebu Island and the reclaimed lands of Hwaong district on the western coasts of the Korean peninsula. SAR data of three frequencies were accordingly calibrated to provide precise backscattering coefficients through absolute radiometric calibration. The root mean square (RMS) height and the correlation length, which can describe the surface roughness, were extracted from the backscattering coefficients using the inversion of the Integral Equation Method (IEM). The IEM model was appropriately modified to accommodate the environmental conditions of tidal flats. Volumetric soil moisture was also simultaneously extracted from the dielectric constant using the empirical model, which define the relations between volumetric soil moistures and dielectric constants. The results obtained from the proposed algorithm were verified with the in-situ measurements, and we confirmed that multi-frequency SAR observations combined with the surface scattering model for tidal flats can be used to quantitatively retrieve the geophysical surface parameters in tidal flats.

An Automatic Diagnosis Method for Impact Location Estimation

  • Kim, Jung-Soo;Joon Lyou
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1998년도 제13차 학술회의논문집
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    • pp.295-300
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    • 1998
  • In this paper, a real time diagnostic algorithm fur estimating the impact location by loose parts is proposed. It is composed of two modules such as the alarm discrimination module (ADM) and the impact-location estimation module(IEM). ADM decides whether the detected signal that triggers the alarm is the impact signal by loose parts or the noise signal. When the decision from ADM is concluded as the impact signal, the beginning time of burst-type signal, which the impact signal has usually such a form in time domain, provides the necessary data fur IEM. IEM by use of the arrival time method estimates the impact location of loose parts. The overall results of the estimated impact location are displayed on a computer monitor by the graphical mode and numerical data composed of the impact point, and thereby a plant operator can recognize easily the status of the impact event. This algorithm can perform the diagnosis process automatically and hence the operator's burden and the possible operator's error due to lack of expert knowledge of impact signals can be reduced remarkably. In order to validate the application of this method, the test experiment with a mock-up (flat board and reactor) system is performed. The experimental results show the efficiency of this algorithm even under high level noise and potential application to Loose Part Monitoring System (LPMS) for improving diagnosis capability in nuclear power plants.

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난류연소 모델링을 이용한 수소-공기 비예혼합 화염의 NOx 생성 분석 (Analysis of NO Formation in Nonpremixed Hydrogen-Air Flames Considering Turbulence-Chemistry Interaction)

  • 박양호;문희장;김성룡;윤영빈;정인석
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 1999년도 제19회 KOSCO SYMPOSIUM 논문집
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    • pp.71-79
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    • 1999
  • Numerical analysis on the characteristics of nitrogen oxides (NOx) formation in turbulent nonpremixed hydrogen-air flames was carried out. Lagrange IEM model and Assumed PDF model were applied to consider turbulence-chemistry interaction known to affect the production of NOx. Partial equilibrium assumption was used to predict nonequilibrium effect to which one-half power dependence between EINOx normalized by flame residence time and global strain rate is attributed. As a result. such one-half power dependence could be reproduced only by reaction model including $HO_{2}$and $H_{2}O_{2}$, which means its dependence on Damkohler number; nonequilibrium effect. This dependence was shown better in the region of higher global strain. Besides, the improvement of turbulence model is required to predict mean flow properties quantitatively in the radial direction.

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일치하지 않는 경계를 갖는 분리된 시스템을 위한 계면 요소법 (Interface element method (IEM) for a partitioned system with non-matching interfaces)

  • 김현규
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 추계학술대회논문집A
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    • pp.324-329
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    • 2001
  • A novel method for non-matching interfaces on the boundaries of the finite elements in partitioned domains is presented by introducing interface elements in this paper. The interface element method (IEM) satisfies the continuity conditions exactly through interfaces without recourse to the Lagrange multiplier technique. The moving least square (MLS) approximation in the present study is implemented to construct the shape functions of the interface elements. Alignment of the boundaries of sub-domains in the MLS approximation and integration domains provides a consistent numerical integration due to one form of rational functions in an integration domain. The compatibility of displacements on the boundaries of the finite elements and the interface elements is always preserved in this method, and the completeness of the shape functions of the interface elements guarantees the convergence of numerical solutions. The numerical examples show that the interface element method is a useful tool for the analysis of a partitioned system and for a global-local analysis.

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Community Discovery in Weighted Networks Based on the Similarity of Common Neighbors

  • Liu, Miaomiao;Guo, Jingfeng;Chen, Jing
    • Journal of Information Processing Systems
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    • 제15권5호
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    • pp.1055-1067
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    • 2019
  • In view of the deficiencies of existing weighted similarity indexes, a hierarchical clustering method initialize-expand-merge (IEM) is proposed based on the similarity of common neighbors for community discovery in weighted networks. Firstly, the similarity of the node pair is defined based on the attributes of their common neighbors. Secondly, the most closely related nodes are fast clustered according to their similarity to form initial communities and expand the communities. Finally, communities are merged through maximizing the modularity so as to optimize division results. Experiments are carried out on many weighted networks, which have verified the effectiveness of the proposed algorithm. And results show that IEM is superior to weighted common neighbor (CN), weighted Adamic-Adar (AA) and weighted resources allocation (RA) when using the weighted modularity as evaluation index. Moreover, the proposed algorithm can achieve more reasonable community division for weighted networks compared with cluster-recluster-merge-algorithm (CRMA) algorithm.

Cation exchange membrane and anion exchange membrane aided electrolysis processes for hypochlorite generation

  • Seong K. Kim;Dong-Min Shin;Ji Won Rhim
    • Membrane and Water Treatment
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    • 제14권2호
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    • pp.55-63
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    • 2023
  • In this study, the influence of different IEMs (ion exchange membranes) to performance of the hypochlorite electrolysis unit with Cl2 recovery stream was investigated. More specifically, Nafion 117-a representative cation exchange membrane (CEM)-and aminated polypheylene oxide (APPO)-an anion exchange membrane (AEM)-were installed in the hypochlorite electrolysis unit, and the performance and the energy efficiency of the units were evaluated and compared. Regardless of whether CEM (Nafion 117) or AEM (APPO) was installed, the rate of hypochlorite generation was increased (by up to 24.3% and 22.2% for Nafion 117 and APPO, respectively) compared with the unit without an IEM. On the other hand, the power efficiency and the optimum operation condition of hypochlorite production units seem to depend on the conductivity and stability of the installed IEM. As the result, between Nafion 117 and APPO, higher performance and efficiency were achieved with Nafion 117, due to excellent conductivity and stability of the membrane.

Mechanistic insights of metal acetylacetonate-aided dehydrocoupling of liquid-state ammonia borane NH3BH3

  • Pereza, Manon;Mieleb, Philippe;Demirci, Umit B.
    • Advances in Energy Research
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    • 제4권2호
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    • pp.177-187
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    • 2016
  • Ammonia borane $NH_3BH_3$ solubilized in organic solvent is a potential liquid-state chemical hydrogen storage material. In this study, metal acetylacetonates like $Fe(O_2C_5H_7)_3$, $Co(O_2C_5H_7)_2$, $Ni(O_2C_5H_7)_2$, $Pd(O_2C_5H_7)_2$, $Pt(O_2C_5H_7)_2$ and $Ru(O_2C_5H_7)_3$ are considered for assisting dehydrocoupling of ammonia borane in diglyme (0.135 M) at $50^{\circ}C$. The molar ratio between ammonia borane and metal acetylacetonate is fixed at 100. A protocol for the separation of the soluble and insoluble fractions present in the slurry is proposed; it consists in using acetonitrile to make the precipitation of metal-based compounds easier and to solubilize boron-based intermediates/products. The nature of the metal does not affect the dehydrocoupling mechanisms, the $^{11}B\{^1H\}$ NMR spectra showing the formation of the same reaction intermediates. The aforementioned metal acetylacetonates do mainly have effect on the kinetics of dehydrocoupling. Dehydrocoupling takes place heterogeneously and dehydrogenation of ammonia borane in these conditions leads to the formation of polyborazylene via intermediates like e.g., B-(cyclodiborazanyl) amine-borane and borazine. Our main results are reported and discussed herein.