• Speech Sciences
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• v.15 no.3
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• pp.31-38
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• 2008

The aim of this study was to find how English vowels affect the pronunciation of English sibilants /$d_3,\;{_3}$, z/ by Korean learners of English. Fifteen nonsense syllables composed by five vowels /a, e, i, o, u/ were pronounced six times by twelve Korean learners of English. Test scores were measured from the scoreboard made by a speech training software program, which was designed for English pronunciation practice and improvement. Results show that 1) the subjects had the lowest scores in /a_a/ position, and 2) subjects had lower scores in the /i_i/ position than in /e_e/, /o_o/ and /u_u/ positions when they pronounced $/d_3/,\;/{_3}/$, and /z/ in their respective inter-vocalic position. This study found that for the group studied Korean learners of English have more difficulty in pronouncing sibilants in /a_a/ and /i_i/ positions than in the other positions.

• New Physics: Sae Mulli
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• v.68 no.11
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• pp.1208-1214
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• 2018

The one-step spin coating method is reported as an excellent thin film process because it can be easily used to fabricate high-quality methyl-ammonium lead tri-iodide ($MAPbI_3$) perovskite layers. One of the important things in the one-step spin coating method towards obtaining high-quality $MAPbI_3$ layers is the anti-solvent (AS) engineering, which consists of an one-step deposition of the $MAPbI_3$ film and dripping of the AS. The properties of the $MAPbI_3$ layer were found to be strongly influenced by the amount, dispensing speed, and spraying time of the AS solution. The $MAPbI_3$ solution was prepared by dissolving lead iodide and methyl-ammonium iodide in N,N-dimethylformamide and adding N,N-dimethyl sulfoxide. Diethyl ether (DE) was used for the AS solution. The results indicate that a $MAPbI_3$ layer appropriately sprayed with DE is beneficial for improving film quality and device efficiency because nucleation of $MAPbI_3$ layer is affected by the characteristics of DE, which affect the film's crystallinity, density, and surface morphology. The $MAPbI_3$ layer, which was optimized by using 0.7 mL of DE, a 3.03 mL/sec dispensing speed, and a 7 second time to spray after spinning showed the best efficiency of 13.74%, which was reproducible.

• Korean Journal of Crystallography
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• v.10 no.2
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• pp.105-109
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• 1999

Ar 기류 하에서 Re(N-C6H3-2,6-i-Pr2)2Cl3(py) (1)과 propionaldehyde (C2H5CHO)가 반응하여 생성된 혼합물에서, [cis-ReCl4(py)(N-C6H3-2,6-i-Pr2)·(NH2-C6H3-2,6-i-Pr2)] (2)가 분리되었다. 이 화합물의 구조가 X-ray 회절법으로 규명되었다. 착물 2의 결정학 자료: 단사정계 공간군 P21/n, a=11.555(1) Å, b=27.066(3) Å, c=11.881(1) Å, β=117.991(8)°, Z=4, R(wR2)=0.0332(0.0851.

• Honam Mathematical Journal
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• v.31 no.3
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• pp.421-428
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• 2009

Given operators X and Y acting on a Hilbert space $\mathcal{H}$, an interpolating operator is a bounded operator A such that AX = Y. In this paper, we showed the following : Let $\mathcal{L}$ be a subspace lattice acting on a Hilbert space $\mathcal{H}$ and let $X_i$ and $Y_i$ be operators in B($\mathcal{H}$) for i = 1, 2, ${\cdots}$. Let $P_i$ be the projection onto $\overline{rangeX_i}$ for all i = 1, 2, ${\cdots}$. If $P_kE$ = $EP_k$ for some k in $\mathbb{N}$ and all E in $\mathcal{L}$, then the following are equivalent: (1) $sup\;\{{\frac{{\parallel}E^{\perp}({\sum}^n_{i=1}Y_if_i){\parallel}}{{\parallel}E^{\perp}({\sum}^n_{i=1}Y_if_i){\parallel}}:f{\in}H,n{\in}{\mathbb{N}},E{\in}\mathcal{L}}\}$ < ${\infty}$ range $\overline{rangeY_k}\;=\;\overline{rangeX_k}\;=\;\mathcal{H}$, and < $X_kf,\;X_kg$ >=< $Y_kf,\;Y_kg$ > for some k in $\mathbb{N}$ and for all f and g in $\mathcal{H}$. (2) There exists an operator A in Alg$\mathcal{L}$ such that $AX_i$ = $Y_i$ for i = 1, 2, ${\cdots}$ and AA$^*$ = I = A$^*$A.

• Bulletin of the Korean Chemical Society
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• v.32 no.1
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• pp.179-182
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• 2011

Second-order rate constants ($k_{OH^-}$) have been measured spectrophotometrically for reactions of Y-substituted phenyl phenyl thionocarbonates (4a-i) with $OH^-$ in 80 mol % $H_2O$/20 mol % DMSO at $25.0{\pm}0.1^{\circ}C$. The $k_{OH^-}$ values for the reactions of 4a-i have been compared with those reported previously for the corresponding reactions of Y-substituted phenyl phenyl carbonates (3a-i) to investigate the effect of changing the electrophilic center from C=O to C=S on reactivity and mechanism. Thionocarbonates 4a-i are less reactive than the corresponding carbonates 3a-i although 4a-i are expected to be more reactive than 3a-i. The Bronsted-type plot for reactions of 4a-i is linear with $\beta_{lg}$ = -0.33, a typical $\beta_{lg}$ value for reactions reported to proceed through a stepwise mechanism with formation of an intermediate being the rate-determining step (RDS). Furthermore, the Hammett plot correlated with $\sigma^o$ constants results in much better linearity than that correlated with $\sigma^-$ constants, indicating that expulsion of the leaving group is not advanced in the RDS. Thus, alkaline hydrolysis of 4a-i has been concluded to proceed through a stepwise mechanism with formation of an intermediate being RDS, which is in contrast to the forced concerted mechanism reported for the corresponding reactions of 3a-i. Enhanced stability of the intermediate upon modification of the electrophilic center from C=O to C=S has been concluded to be responsible for the contrasting mechanisms.

• Journal of applied mathematics & informatics
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• v.23 no.1_2
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• pp.517-523
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• 2007

Let R/I be an Artinian algebra of codimension 3 with Hilbert function H such that $h_{d-1}>h_d=h_{d+1}$. Ahn and Shin showed that A cannot be level if ${\beta}_{1,d+2}(Gin(I))={\beta}_{2,d+2}(Gin(I))$ where Gin(I) is a generic initial ideal of I. We prove that some certain graded Artinian algebra R/I cannot be level if either ${\beta}_{1,d}(I^{lex})={\beta}_{2,d}(I^{lex})+1\;or\;{\beta}_{1,d+1}(I^{lex})={\beta}_{2,d+1}(I^{lex})\;where\;I^{lex}$ is a lex-segment ideal associated to I.

• Journal of the Korean Ceramic Society
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• v.31 no.8
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• pp.861-868
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• 1994

CaO-Al2O3 glass is a good candidate as optical fiber amplifier and laser. In this study, optical properties for 4I13/2longrightarrow4I15/2 transition of Er3+ ions doped in CaO-Al2O3 glasses were investigated. Optical absorptions, radiative transition probabilities and lifetimes for 4I13/2 level were evaluated by using Judd-Ofelt theory. Also, induced- emmision cross-sections of 4I13/2longrightarrow4I15/2 transition were calculated. Radiative transition probability and lifetime of 4I13/2 level were 144.6s-1, 690$mutextrm{s}$ respectively for 60CaO.40Al2O3 glass(FS0) and 152.6s-1, 660 $mutextrm{s}$ for 54 CaO.36Al2O3.10SiO2 glass (FS10). Each induced-emission cross sections for FS0 and FS10 was 0.749$\times$10-20 $\textrm{cm}^2$, 0.892$\times$10-20 $\textrm{cm}^2$. Obtained values were comparable with those of ZBLA glass studied as optical fiber amplifier and laser material.

• Journal of the Korean Chemical Society
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• v.53 no.1
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• pp.34-41
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• 2009

A new series of hydrazone derivatives were synthesized from 4-(2-chloroethyl)semicarbazide and their antiproliferative activity against human brain (U251) and liver (Hepg2) carcinoma cell lines were evaluated. The hydrazone compounds are benzaldehyde (2a-2g), acetophenone (3a-3f), and 3-formylindole derivatives (4a-4d). Among the acetophenone derivatives, 3e (p-methoxy substituted) and 3f (p-nitro substituted) showed the highest cytotoxic activity against Hepg2 cell line (I$C_{50}$ = 6 and 8 $\mu$g/ml, respectively). Among the 3-formylindole derivatives, 4a (hydrazone of 3-formylindole itself) showed a pronounced cytotoxic activity against both U251 (I$C_{50}$ = 21 $\mu$g/ml) and Hepg2 (I$C_{50}$ = 7 $\mu$g/ml).

• Communications of the Korean Mathematical Society
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• v.11 no.3
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• pp.569-573
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• 1996

We study some special cases of Chow groups of a ramified complete regular local ring R of dimension n. We prove that (a) for codimension 3 Gorenstein ideal I, [I] = 0 in $A_{n-3}(R)$ and (b) for a particular class of almost complete intersection prime ideals P of height i, [P] = 0 in $A_{n-i}(R)$.

• Journal of Nutrition and Health
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• v.35 no.2
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• pp.207-212
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• 2002

Acetyl-CoA carboxylase (ACC) is the enzyme that controls no devo fatty acid biogynthesis, and this enzyme catalyzes the carboxylation pathway of acetyl-CoA to malonyl-CoA. Acetyl-CoA carboxylase gene expression was regulated by nutritional and hormonal status. The present study was performed to identify the regulation mechanism of ACC gene promoter I. The fragments of ACC promoter I -1.2-kb region wert recombined to pGL3-Basic vector with luciferase as a reporter gene. The primary hepatocytes from the rat were used to investigate the hormonal regulation of ACC promoter I activity. ACC PI (-1.2)/Luc plasmid was trtransferred into primary hepatocytes using lipofectin. Activity of luciferase was increased two-fold by 10-9M, three-fold by 10-8M, 10-6M, 3.5-fold by 10-6M, and 4.5-fold by 10-7M insulin treatment, respectively. In the presence of dexamethasone (1 $\mu$M), the effects of insulin increased about 1.5-fold, showing the additional effects of dexamethasone. Moreover, the activity of luciferase increased with insulin+dexamethasone, insulin+T3, dexamethasone+T3, and dexamethasone+insulin+T3 treatment approximately 6-, 4-, 6.5-, and 10-fold, respectively. Therefore it can be postulated that 1) these hormones coordinately regulate acetyl-CoA caroxylase gene expression via regulation of promoter activity, 2) the -1.2-kb region of ACC promoter I may have the response element sequences for insulin, dexamethasone, and T3.