• Title/Summary/Keyword: I/O ratio

Search Result 861, Processing Time 0.026 seconds

The Charge/discharge Properties of $ Li_xNi_{2-x}O_2$Cathode for Lithium Rechargeable Battery (리튬 2차전지용$ Li_xNi_{2-x}O_2$ 정극의 충방전 특성)

  • 김철중;전대규;이하니;박영철;김주승;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1996.11a
    • /
    • pp.378-381
    • /
    • 1996
  • This study is to research Li$_{x}$Ni$_{2-x}$O$_2$ cathode for lithium chargeable battery. We investigated morphology and cell resistance, capacity and Ah efficiency of Li$_{x}$Ni$_{2-x}$O$_2$/Li cells using Li$_{x}$Ni$_{2-x}$O$_2$ prepared under air and $O_2$ flow. The (003)I/(104)I intensity ratio was 1.4. The cell resistance was increased with increasing Li in Li$_{x}$Ni$_{2-x}$O$_2$. The discharge capacity based on Li$_{x}$Ni$_{2-x}$O$_2$of 1st and 15th cycles was 135㎃h/g and 108㎃h/g, respectively. The Li$_{x}$Ni$_{2-x}$O$_2$ prepared with hexan under $O_2$ flow had a good properties. properties. properties.

  • PDF

High Temperature Phase Separation of $H_2SO_4-HI-H_2O-I_2$ System In Iodine-Sulfur Hydrogen Production Process (Iodine-Sulfur 수소 제조 공정에서 $H_2SO_4-HI-H_2O-I_2$ 계의 고온 상 분리)

  • Lee, Dong-Hee;Lee, Kwang-Jin;Kang, Young-Han;Kim, Young-Ho;Park, Chu-Sik;Hwang, Gab-Jin;Bae, Ki-Kwang
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.17 no.4
    • /
    • pp.395-402
    • /
    • 2006
  • Iodine-sulfur(IS) hydrogenation production process consists of three sections, which are so called a Bunsen reaction section, a HI decomposition section and a $H_2SO_4$ decomposition section as a closed cycle. For highly efficient operation of a Bunsen reaction section, we investigated the phase separation characteristics of $H_2SO_4-HI-H_2O-I_2$ system into two liquid phases($H_2SO_4$-rich phase and $HI_x$-rich phase) in the high temperature ranges, mainly from 353 to 393 K, and in the $H_2SO_4/HI/H_2O/I_2$ molar ratio of $1/2/14{\sim}30/0.3{\sim}13.50$. The desired results for the minimization of impurities in each phase were obtained in conditions with the higher temperature and the higher $I_2$ molar composition. On the basis of the distribution of $H_2O$ to each phase, it is appeared that the affinity between $HI_x$ and $H_2O$ was more superior to that between $H_2SO_4$ and $H_2O$.

AC & DC Electrical Characterization of PTC $BaTiO_3$ and Electrodes (PTC $BaTiO_3$ 및 전극의 직류 및 교류 특성)

  • 전표용;최경만
    • Journal of the Korean Ceramic Society
    • /
    • v.28 no.2
    • /
    • pp.101-108
    • /
    • 1991
  • 0.2 mo1% La doped BaTiO3 samples were prepared by a wet chemical process (Pechini process) and electrical conductivity were measured from annealing temperatures(800-110$0^{\circ}C$) to room temperature continuously. 2 probe I-V characteristics showed that Pt electrodes were non-ohmic below about 80$0^{\circ}C$ for Ladoped sample. I-V curves showed varistor behavior and breakdown voltages showed PTC-like behavior. AC complex impedance of 0.2 La and 0.05 Mn mo1% doped BaTiO3 samples with three different electrodes (electroless Ni, Pt, Ag electrodes) were measured with temperature variation. Complex impedance plots showed that the samples with electroless Ni electrodes have negligible electrode resistance. Samples with Ag or Pt paste electrodes showed large electrode resistance. PTC effect, which is defined as the ratio of maximum resistance to minimum resistance, was found to be less than 10 for 0.2 mo1% La doped dense sample however greater than 105 with codoping of 0.05 mo1% Mn and 0.2 mol% La.

  • PDF

Sintering and Electrical Properties of Cr-doped ZnO-Bi2O3-Sb2O3 (Cr을 첨가한 ZnO-Bi2O3-Sb2O3계의 소결과 전기적 특성)

  • Hong, Youn-Woo;Shin, Hyo-Soon;Yeo, Dong-Hun;Kim, Jin-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.23 no.12
    • /
    • pp.942-948
    • /
    • 2010
  • In this study we aims to examine the effects of 0.5 mol% $Cr_2O_3$ addition on the reaction, microstructure development, resultant electrical properties, and especially the bulk trap and interface state levels of ZnO-$Bi_2O_3-Sb_2O_3$ (Sb/Bi=0.5, 1.0, and 2.0) systems (ZBS). The samples were prepared by conventional ceramic process, and characterized by XRD, density, SEM, I-V, impedance and modulus spectroscopy (IS & MS) measurement. The sintering and electrical properties of Cr-doped ZBS (ZBSCr) systems were controlled by Sb/Bi ratio. Pyrochlore ($Zn_2Bi_3Sb_3O_{14}$) was decomposed more than $100^{\circ}C$ lowered on heating in ZBS (Sb/Bi=1.0) by Cr doping. The densification of ZBSCr (Sb/Bi=0.5) system was retarded to $800^{\circ}C$ by unknown Bi-rich phase produced at $700^{\circ}C$. Pyrochlore on cooling was reproduced in all systems. And $Zn_7Sb_2O_{12}$ spinel ($\alpha$-polymorph) and $\delta-Bi_2O_3$ phase were formed by Cr doping. In ZBSCr, the varistor characteristics were not improved drastically (non-linear coefficient $\alpha$ = 7~12) and independent on microstructure according to Sb/Bi ratio. Doping of $Cr_2O_3$ to ZBS seemed to form $Zn_i^{..}$(0.16 eV) and $V^{\bullet}_o$ (0.33 eV) as dominant defects. From IS & MS, especially the grain boundaries of Sb/Bi=0.5 systems were divided into two types, i.e. sensitive to oxygen and thus electrically active one (1.1 eV) and electrically inactive intergranular one (0.95 eV) with temperature.

Study properties of soft subgrade soil stabilized by sewage sludge/lime and nano-SiO2

  • Lin, Deng-Fong;Luo, Huan-Lin;Chen, Chien-Ta;Cai, Ming-Du
    • Geomechanics and Engineering
    • /
    • v.10 no.6
    • /
    • pp.793-806
    • /
    • 2016
  • The pozzolanic characteristics of a sludge incinerated into ash were determined in this study. Lime is commonly used as a stabilizer for the treatment of soils, whereas sewage sludge ash (SSA) is often applied with lime to improve soft subgrade soil. In this study, a cohesive soil categorized as A-4 (low-plasticity clay) by AASHTO classifications was mixed with SSA/lime with a 3:1 ratio. Nano-$SiO_2$ was also added to the soil. To identify changes in the workability, strength, permeability, and shear strength of the soft subgrade soil, basic soil tests were conducted, and the microstructure of the treated soil was analyzed. The results indicate that SSA/lime mixtures improve the properties of soft subgrade soil and transform the soil from "poor subgrade soil" to "good to excellent subgrade soil" with a CBR > 8. Additionally, the addition of 2% nano-$SiO_2$ increases the unconfined compressive strength of soft subgrade soil treated with SSA/lime mixture by approximately 17 kPa. However, the swelling of the treated soil increased by approximately 0.1% after the addition of nano-$SiO_2$ and lime. Thus, soil swelling should be considered before lime and nano-$SiO_2$ are applied to soft subgrade soil.

Electrical Properties of Zinc Oxide Varistor with $\alpha-Zn_7Sb_2O_{12}$ ($\alpha-Zn_7Sb_2O_{12}$ 첨가에 의한 Zinc Oxide 바리스터의 전기적 특성)

  • 김경남;한상목
    • Journal of the Korean Ceramic Society
    • /
    • v.31 no.11
    • /
    • pp.1396-1400
    • /
    • 1994
  • Electrical properties in the ZnO-Bi2O3-CoO-Zn7Sb2O12 system were investigated with Zn7Sb2O12 content (0.1~2 mol%). The increase of the Zn7Sb2O12 content inhibited the grain growth of ZnO, which showed a narrow grain size distribution of ZnO. The breakdown voltage (Vb) increased markedly with 1 mol% Zn7Sb2O12 addition due to the grain growth control behaviour of the Zn7Sb2O12 . The nonlinear I-V characteristic was significantly influenced by the Zn7Sb2O12 content (or Bi2O3/Zn7Sb2O12 ratio). Addition of 0.5 mol% Zn7Sb2O12 showed the highest nonlinear coefficient ($\alpha$) of 43. The leakage current in prebreakdown region was decreased with increasing Zn7Sb2O12 content.

  • PDF

The Evaluation of CO Concentration Level at Underground Space in Busan Metropolitan City (부산광역시 지하공간의 CO 대기질 평가)

  • 이화운;박종길;장난심;이희령;김희만
    • Journal of Environmental Science International
    • /
    • v.12 no.1
    • /
    • pp.35-40
    • /
    • 2003
  • With increasing population densities in cities, underground facilities and entertainment locations are proliferating at a rapid pace in efforts to maximize the use of land. The purpose of this study is to evaluate CO concentration level of subway stations having underground platforms in Busan Metropolitan City, from September to November 2000, over seven times. The places of inquiry include Yonsan-dong station, Somyon station, Busan station, Nampo-dong station and Dusil station. The samplings were conducted at three points of each station, i.e. gates, ticket gates, and platforms. The component of CO concentration is the main elements of indoor air quality evaluation. The total concentrations and average concentrations of CO were the higher at the Somyon station. The distribution of CO concentrations at each station, generally was higher at gate than ticket gates and platforms. The I/O ratios(I-platforms, 0-gates) were expressed highly than 1 at the Yonsan-dong station, Busan station, Nampo-dong station and were lower than 1 at the others.

Estimation of Electrical Parameters of OD Organic Semiconductor Diode from Measured I-V Characteristics

  • Moiz, Syed Abdul;Ahmed, Mansoor M.;Karimov, Kh. S.
    • ETRI Journal
    • /
    • v.27 no.3
    • /
    • pp.319-325
    • /
    • 2005
  • In this paper the effect of temperature on the electrical properties of organic semiconductor disperse orange dye 25 (OD) have been examined. Thin films of OD have been deposited on $In_{2}O_{3}$ substrates using a centrifugal machine. DC current-voltage (I-V) characteristics of the fabricated devices $(Al/OD/In_{2}O_{3)$ have been evaluated at varying temperatures ranging from 40 to $60^{\circ}C$. A rectification behavior in these devices has been observed such that the rectifying ratio increases as a function of temperature. I-V characteristics observed in $Al/OD/In_{2}O_{3)$ devices have been classified as low temperature $({\leq} 50^{\circ}C)$ and high temperature characteristics (approximately $60^{\circ}C$). Low temperature characteristics have been explained on the basis of the charge transport mechanism associated with free carriers available in OD, whereas high temperature characteristics have been explained on the basis of the trapped space-charge-limited current. Different electrical parameters such as traps factor, free carrier density, trapped carrier density, trap density of states, and effective mobility have been determined from the observed temperature dependent I-V characteristics. It has been shown that the traps factor, effective mobility, and free carrier density increase with increasing values of temperature, whilst no significant change has been observed in the trap density of states.

  • PDF

On the Study Of AlSiCa($Al_2O_3-SiC-C$) refractories: (I) Synthesis of raw material using domestic chnmotte (AlSiCa($Al_2O_3-SiC-C$)계 내화물 재료에 관한 연구: (I) 국산 chamotte로부터 원료분말합성)

  • Shim, Kwang-Bo;Joo, Kyoung;Auh, Keun-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.7 no.4
    • /
    • pp.626-631
    • /
    • 1997
  • AlSiCa powders were prepared from the domestic Hadong Kaolin ($Al_2O_3{\cdot}2SiO_2{\cdot}2H_2O$). As a result of the reaction of Hadong Kaolin and carbon powder at reducing atmosphere, $Al_2O_3{\cdot}SiC$ composite started to form at $1300^{\circ}C$ and completed at $1400^{\circ}C$. The optimum amount of carbon was 1:4 in mole ratio. It was found that only bright-green $\beta-SiC$ phase forms when the mixture was packed without carbon powder in alumina crucible.

  • PDF

Influences of Capsaicin on the Activities of Cytochrome P45O of Liver Cell (간세포내의 Cytochrome P450 활성에 미치는 Capsaicin의 영향)

  • 김성오
    • Journal of environmental and Sanitary engineering
    • /
    • v.10 no.3
    • /
    • pp.16-28
    • /
    • 1995
  • Influences of capsaicin on the activities of cytochrome P45O of liver cell were studied in rats. Rats were provided food and water ad libitum and capsaicin and methylcellulose were gavaged for 6 days. Body weight gain and liver weight/body weight ratio, microsomal protein content and serum HDL- cholesterol content, the activity of cytochrome P450 and erythromycin demethylase, the activities of ethoxyresorufin and pentoxyresorufin O- dealkylase were determined. Capsaicin increased body weight gain but showed no significant changes on liver weight as compared with control group. Capsaicin increased the microsomal protein significantly but decreased the serum HDL- cholesterol. Capsaicin decreased the microsomal cytochrome P4SO significantly and did not show any influences on erythromycin demethylase ( cytochrome P45O III A ). Capsaicin increased the activity of pentoxyresorufin O- dealkylase ( cytochrome P45O II B) and decreased the activity of ethoxyresorufin O-dealkylase ( cytochrome P45O I A). It might be concluded that capsaicin reduced the microsomal cytochrome P45O and induced the CYP III and inhibited the CYP I A. It also might be concluded that capsaicin had no influence on CYP III A and decreased serum HDL- cholesterol. In these results capsaicin can not be used as an anti- atherosclerotic agent by increasing the CYP III A and HDL- cholesterol but it is considered that the more precise study on these theme is necessary.

  • PDF