• Title/Summary/Keyword: I/O ratio

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Synthesis of $Ni_2Y$ magnetic particles by coprecipitation method (공침법에 의한 $Ni_2Y$ 자성 분말의 합성)

  • 김한근;사공건
    • Electrical & Electronic Materials
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    • v.9 no.9
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    • pp.906-910
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    • 1996
  • Ferroxplana N $i_{2}$Y(B $a_{2}$N $i_{2}$F $e_{12}$ $O_{22}$ ) magnetic particles, which is one of the hexagonal ferrite were synthesized by a coprecipitation method. The coprecipitates were prepared by adding aqueous solution of BaC $I_{2}$ - 2 $H_{2}$O, NiC $I_{2}$ - 6 $H_{2}$O and FeC $I_{3}$ - 6 $H_{2}$O(of which the mole ratio is $Ba^{+2}$ : N $i^{+2}$ : F $e^{3+}$= 1 : 1 : 6) to a mixture of NaOH and N $a_{2}$C $O_{3}$. The shape of Ferroxplana N $i_{2}$Y magnetic particles obtained at 1, 100(.deg. C) was hexagonal plate-like, average particle size and aspect ratio were 2(.mu.m) and 7, respectively.y.

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Assessment of Material Degradation of High-Temperature Components for Process Plant by Grain Boundary Etching Method (입계부식법에 의한 공정설비 고온요소의 재질열화 평가)

  • Han Sang In;Yoon Kee Bong;Kim Ji Yoon;Chung Se Hi
    • Journal of the Korean Institute of Gas
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    • v.2 no.1
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    • pp.74-82
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    • 1998
  • The grain boundary etching method as a technique for assessing degradation of structural materials used at elevated temperature has received much attention since it is simple, inexpensive and easy to apply to real plant components. In this study, the technique is applied to some aged petroleum and chemical plant components such as reactors and drums. As a degradation parameter, intersection number ratio ($N_i/N_o$), is employed. The intersection number ratio ($N_i/N_o$) is defined as the ratio of intersection number ($N_i$) obtained from 5-minute picric acid etched surface to the number ($N_o$) obtained from Nital etched surface. In order to study degradation level, several relationships were measured such as the correlation between shift in ductile brittle transition temperature, $({\Delta}DBTT)_{sp}$ and intersection number ratio, ($N_i/N_o$) and the correlation between the measured ($N_i/N_o$) values and Larson-Miller Parameter values.

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INTENSITY RATIO OF [O I] λ6300 AND Hα IN COLLISIONAL IONIZATION EQUILIBRIUM (충돌이온화평형 상태에서 [O I] λ6300과 Hα의 세기비)

  • SEON KWANG-IL;LEE DAE-HEE
    • Publications of The Korean Astronomical Society
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    • v.19 no.1
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    • pp.17-20
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    • 2004
  • In this paper, the intensity ratio of [O I] $\lambda6300$ and $H_\alpha$ lines, which plays an important role in the study of warm (or diffuse) ionized interstellar medium, is calculated assuming collisional ionization equilibrium (or coronal equilibrium). The calculated ratio is compared with the previous works, and with the observations, obtained by Reynolds (1989) and Reynolds et al. (1998) with the Wisconsin Ha Mapper facility, toward the directions that sample the faint interstellar emission-line background. The comparison confirms that most of the Ha originates from nearly fully ionized regions along the lines of sight rather than from partially ionized H I clouds or layers of H II on the surfaces of H I clouds.

Optical Emission Spectroscopy with Parameters During R.F. Discharge of BaTiO3 Target (BaTiO3 타겟의 R.F. 방전 중 변수에 따른 광반사분광 특성)

  • Park, Sang-Shik
    • Korean Journal of Materials Research
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    • v.21 no.9
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    • pp.509-514
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    • 2011
  • In this study, optical emission spectroscopy was used to monitor the plasma produced during the RF magnetron sputtering of a $BaTiO_3$ target. The intensities of chemical species were measured by real time monitoring with various discharge parameters such as RF power, pressure, and discharge gas. The emission lines of elemental and ionized species from $BaTiO_3$ and Ti targets were analyzed to evaluate the film composition and the optimized growth conditions for $BaTiO_3$ films. The emissions from Ar(I, II), Ba(I, II) and Ti(I) were found during sputtering of the $BaTiO_3$ target in Ar atmosphere. With increasing RF power, all the line intensities increased because the electron density increased with increasing RF power. When the Ar pressure increased, the Ba(II) and Ti(I) line intensity increased, but the $Ar^+$ line intensity decreased with increasing pressure. This result shows that high pressure is of greater benefit for the ionization of Ba than for that of Ar. Oxygen depressed the intensity of the plasma more than Ar did. When the Ar/$O_2$ ratio decreased, the intensity of Ba decreased more sharply than that of Ti. This result indicates that the plasma composition strongly depends on the discharge gas atmosphere. When the oxygen increased, the Ba/Ti ratio and the thickness of the films decreased. The emission spectra showed consistent variation with applied power to the Ti target during co-sputtering of the $BaTiO_3$ and Ti targets. The co-sputtered films showed a Ba/Ti ratio of 1.05 to 0.73 with applied power to the Ti target. The films with different Ba/Ti ratios showed changes in grain size. Ti excess films annealed at $600^{\circ}C$ did not show the second phase such as $BaTi_2O_5$ and $TiO_2$.

Influence of $Pr_6O_{11}/CoO$ Composition Ratio on I-V Characteristics of $ZnO-Pr_6O_{11}-CoO-Dy_2O_3$ Based varistors ($ZnO-Pr_6O_{11}-CoO-Dy_2O_3$계 바리스터의 I-V 특성에 $Pr_6O_{11}/CoO$ 조성비 영향)

  • Nahm, Choon-Woo;Ryu, Jung-Sun;Yoon, Han-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.179-184
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    • 2000
  • The I-V characteristics of $ZnO-Pr_6O_{11}-CoO-Dy_2O_3$ based varistors were investigated in the $Pr_6O_{11}/CoO$ composition ratio range of 0.5/0.5 to 1.0/1.0 and sintering temperature range of 1300 to $1350^{\circ}C$ as the basic study to develop the advanced $Pr_6O_{11}$-based ZnO varistors. All varistors except for $Pr_6O_{11}$/CoO = 0.5/1.0 exhibited the best I-V characteristics at $1350^{\circ}C$. However, the varistors with $Pr_6O_{11}$/CoO= 0.5/1.0 exhibited the best I-V characteristics at $1350^{\circ}C$. The varistors with $Pr_6O_{11}$/CoO= 0.5/1.0 of all varistors exhibited the best I-V characteristics, which the nonlinear exponent is 36.9 and the leakage current is 7.6 ${\mu}A$ Therefore, it was estimated that ZnO-$Pr_6O_{11}-CoO-Dy_2O_3$ ceramics with $Pr_6O_{11}$/CoO= 0.5/1.0 will be usefully used as varistor materials in the future.

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Effects of Gas Mixing Ratio on the Properties of Thin Films in the ZnO Synthesis by MOCVD (MOCVD에 의한 ZnO 합성에서 기체혼합비가 박막의 물성에 미치는 영향)

  • SeoMoon, Kyu;Lee, JongIn
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.2
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    • pp.109-113
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    • 2013
  • ZnO thin films were synthesized on Si substrates by MOCVD using diethyl zinc as a precursor. Effects of $O_2$/DEZ gas mixing ratio on the growth rate, surface morphology, preferred orientation, and electrical properties of the ZnO thin films were investigated with SEM, XRD, and Hall measurement. The surface reflectance variations of ZnO thin films were analyzed using laser-photometer apparatus. As the $O_2$/DEZ mixing ratio increased, growth rate and $I_{(002)}/I_{(101)}$ in XRD of ZnO thin films decreased, and the crystal structure was changed from columnar to planar structure. All ZnO films deposited at various CVD conditions exhibited c-axis (002) plane preferred orientation. The electrical properties of ZnO thin films mainly depended on the carrier mobility.

Electrical Properties as the ratio of ZnO/$Mn_3$$O_4$ of NTC Thermistor with $Mn_3$$O_4$-NiO-CuO-$Co_3$$O_4$-ZnO system for Inrush Current Limited (돌입전류 제한용 $Mn_3$$O_4$-NiO-CuO-$Co_3$$O_4$-ZnO계 NTC 써미스터에서 ZnO/$Mn_3$$O_4$비에 따른 전기적 특성)

  • 윤중락;김지균;권정렬;이현용;이석원
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.6
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    • pp.472-477
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    • 2000
  • Oxides of the form Mn$_{4}$/O$_{4}$-CuO-Co$_{3}$/O$_{4}$-NiO-ZnO present properties that make them useful as power NTC thermistor for current limited. Electrical properties of Mn$_{3}$/O$_{4}$-CuO-Co$_{3}$/O$_{4}$-CuO-Co$_{3}$/O$_{4}$-NiO-ZnO power NTC thermistor such as I-V characteristics tim constant activation energy and heat dissipation coefficient measured as a function of temperature and composition. In Mn$_{4}$/O$_{4}$-CuO-Co$_{3}$/O$_{4}$-NiO-ZnO system with the 5wt% addition of Co$_{3}$/O$_{4}$ it can be seen that resistivity and B-constant were increased as the ratio of ZnO/Mn$_{3}$/O$_{4}$ was increased. Heat dissipation constant, I-V characteristics and time constant showed similar behaviour compared with those of conventional thermistors. In particular resistance change ratio ($\Delta$R) the important factor for reliability varied within $\pm$5% indicating the compositions of these products could be available for power thermistor.

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Redox Property of Vanadium Oxide and Its Behavior in Cataltic Oxidation

  • 김영호;이호인
    • Bulletin of the Korean Chemical Society
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    • v.20 no.12
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    • pp.1457-1463
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    • 1999
  • Structure and their redox property of the vanadium oxides prepared by decomposing NH₄VO₃ at various temperatures were studied by XRD, SEM, XPS, and temperature programmed reduction/temperature programmed oxidation (TPR/TPO) experiment. All TPR profiles have two sharp peaks in the temperature range 650-750℃, and the area ratio of the two sharp peaks changed from sample to sample. There were three redox steps in TPR/TPO profiles. The oxidation proceeded in the reverse order of the reduction process, and both the reactions proceeded via quite a stable intermediates. The changes of the morphological factor $(I_{(101)}/I_{(010)})$, the ratio of $O_{1S}$ peak area (O$_{1S}$( α)/O$_{1S}$( β)) in the XPS results, and the ratio of hydrogen consumption in TPR profiles with various vanadium oxides showed the distinct relationship between the structural property and their redox property of vanadium oxides. The change of the specific yield of phthalic anhydride with various vanadium oxides showed a very similar trend to those of the peak area ratio in TPR profiles, which meant that the first reduction step related to the partial oxidation of o-xylene on the vanadium oxide catalyst.

A Comparative Study on Concentrations of Indoor and Outdoor Particulate Matters in Elementary Schools (초등학교 실내외 미세먼지 농도 비교 연구)

  • Kim, Dae-hyeon;Son, Youn-Suk;Lee, Tae-Jung;Jo, Young Min
    • Korean Journal of Remote Sensing
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    • v.36 no.6_3
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    • pp.1721-1732
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    • 2020
  • Elementary school students spend a lot of time in a school and are more exposed to indoor air pollution. Also the students are physically growing and have a relatively high respiratory rate per unit weight compared to adults, so it is known that there is a high sensitivity to indoor air pollution. Therefore, indoor air quality in a school is becoming an important factor for the student's health. In this study, a correlation analysis using levels of indoor and outdoor Particulate Matter (PM) measured from five elementary schools in Seoul was performed to evaluate the effect of outdoor PM on indoor PM. PM ratio and indoor/outdoor (I/O) ratio were also analyzed to investigate the actual condition of indoor air quality and effect of outdoor PM on indoor PM. As a result, the correlation between indoor and outdoor PM in elementary school was more significant in PM2.5 and PM1 than PM10. In the case of I/O ratio, the I/O ratio of PM10 was higher than that of 1 in four elementary schools except SD (BB:2.21, NS: 1.67, IS: 1.73, SI: 1.17). This indicates that the activity of students has a great effect on the concentration of indoor PM10.

Effects of Magnetite added with Metallic Oxide on the Decomposition Reaction of Carbon Dioxide (CO$_2$ 분해 반응에서 금속 산화물이 첨가된 $Fe_2O_4$의 영향)

  • Kim, Seung-Ho;Park, Young-Goo
    • Journal of Environmental Health Sciences
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    • v.24 no.1
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    • pp.32-37
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    • 1998
  • The Carbon Dioxide is the gas, which causes green house effects, unusual changes in the weather, destruction of the life. Almost every nation in the world is trying to search the countermeasure to this poisonous gas. I synthesized $Fe_3O_4$ and NaOH, in order to decompose the Carbon Dioxide. Among the particles synthesizing $Fe_3O_4$, I chose the equivalent ratio 1.00 which can decompose the Carbon Dioxide best, and fixed that equivalent ratio and added the 0.005-3.00 mole percentage of NiCl$_2$ and synthesized $Fe_3O_4$. I studied the decomposition of the Carbon Dioxide and methanized reaction, by measuring its crystal structure, thermochemistrical character and specific surface area. In decomposing the Carbon Dioxide, I used oxygen-deficit Magnetite which I produced by injecting the hydrogen gas into the synthesized sample. I observed the methanization reaction by raising the temperature of sample up to 650$\circ$C and having it reacted with the hydrogen gas. The decomposition of the Carbon Dioxide was added 0.005, 0.03, 0.05 mole percentage of NiCl$_2$ was more effective than pure $Fe_3O_4$. All sample in which the decomposition of the Carbon Dioxide took place produced the methane gas.

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