• 자원환경지질
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• 제25권3호
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• pp.225-232
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• 1992

The hydrothermal alteration is evaluated using multicomponent equilibrium calculations with the program CHILLER for the reactions between hydrothermal water and rhyolite at the temperature of $300^{\circ}C$ and pressure of 500 bars. The chemical-reaction model on the depositional processes of the sericitite confirms that the hydrothermal water-rock interaction(hydrothermal alteration) is the main mechanism of the sericitite formation. The principal change in the aqueous phase during the reaction is the pH increase. Overall trends for the major species are the increase in total molalities of K, Ca, $SiO_2$, Al, Mg, Fe, Na, and sulfide in solid phase with hydrothermal water-rhyolite reaction and the decrease of them in aqeous solution by precipitation of hydrothermal products. Quartz and sericite are the first minerals to form. The sequence of minerals to precipitate following them is chlorite, epidote, pyrite and microcline as water/rock ratio decreases. Although calculated results cannot duplicate the complexities of natural hydrothermal alteration, the calculation provides thermodynamic constraints on the natural process. The calculation results resemble those of experimental studies. Sericitite forms where pH decreases and water/rock ratio increases.

• Journal of the Korean Wood Science and Technology
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• 제49권3호
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• pp.213-225
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• 2021

본 논문에서는 열수 탄화(hydrothermal carbonization)에 의해 제조된 리그닌 하이드로차의 탄화 특성을 조사하였고, 근적외선 분광법과 부분 최소 제곱(partial least squares) 회귀를 이용하여 탄화 거동을 예측하기 위한 모델을 수립하였다. 온도 200℃에서 열수 탄화된 리그닌의 탄소 함량은 무처리 시료 보다 약 3 wt% 높았으며 가열 시간이 증가할수록 탄소 함량도 서서히 증가하는 경향이 나타났다. 열수 탄화는 리그닌을 더욱 탄소 집약적으로 변화시키고 마이크로 파티클을 제거하여 더욱 균질한 특성을 부여하였다. 근적외선 분광법과 부분 최소 제곱 회귀를 이용한 판별 및 예측 모델은 수열 탄화의 적용 여부를 완벽히 구분했으며 높은 정확도로 열수 탄화 리그닌의 탄소 함량을 예측하였다. 본 연구로부터 근적외선 분광법과 결합된 부분 최소 제곱 회귀 모델을 이용하여 열수 탄화에 의해 제조된 리그닌 하이드로차의 탄화 특성을 빠르고 비파괴적으로 예측할 수 있다는 것이 확인되었다.

• Bulletin of the Korean Chemical Society
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• 제20권8호
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• pp.869-874
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• 1999

In this paper, electrochemical techniques are used to investigate hydrothermal-electrochemically formation of barium titanate (BT) ceramic films. For comparison, the electrochemical behaviors of anodic titanium oxide films formed in alkaline solution were also investigated both at room temperature and in hydrothermal condition at 150.0 ℃. Film structure and morphology were identified by scanning electron microscopy (SEM) and atomic force microscopy (AFM). Titanium oxide films produced at different potentials exhibit different film morphology. The breakdown of titanium oxide films anodic growth on Ti electrode plays an important roles in the formation of BT films. BT films can grow on anodic oxide/metal substrate interface by short-circuit path, and the dissolution-precipitation processes on the ceramic film/solution interface control the film structure and morphology. Based upon the current experimental results and our previous work, extensively schematic proce-dures are proposed to model the mechanism of ceramic film formation by hydrothermal-electrochemical method.

• 한국지열·수열에너지학회논문집
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• 제14권1호
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• pp.16-21
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• 2018

This work aims to develop a platform to investigate the effect of operation schedules on the building energy consumption and to derive a simulation model based optimal start and stop daily strategy. An open-source building energy simulation tool DOE2 is used for the engine, and the developed simulation model is validated using ASHRAE guideline 14. The effect of late-start/early-stop operation of HVAC system on the daily building energy consumption was analyzed using the developed simulation model. It was found that about 10% of energy consumption cut was possible using the control strategy for an hour of advance of the stop operation, and about 3% per an hour of delay of the start operation.

• 자원환경지질
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• 제55권2호
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• pp.183-195
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• 2022

열수 금광상은 단층대 내에서 일어나는 열수 유체의 폭발적 흐름의 증거이며, 그로 인해 만들어지는 맥의 구조 및 조직은 열수유체 재분배 기작을 반영한다. 본 리뷰 논문에서는 열수 금광상의 형성을 야기하는 지각 내 유체 순환의 기작으로서 석션 펌프와 단층 밸브 모델을 소개하고 단층역학적인 측면에서 검토한다. 석션 펌프와 단층 밸브 모델은 (1) 지구조 응력의 누적과 유체압의 증가, (2) 지진성 단층파열에 따른 지구조 응력의 해소와 유체압의 감소가 주기적으로 발생됨에 따라 단층을 통해 불균질하게 발생하는 유체의 이동 및 맥의 형성 기작이다. 두 기작들이 작동하는 지질학적 환경과 응력 조건은 서로 상이하며, 결과적으로 형성된 맥의 구조 및 조직적 특성은 서로 공통점과 차이점을 가진다. 석션 펌프와 단층 밸브 모델은 향후 한국의 열수 금광상의 구조적 성인을 정교하게 해석하고 추가적인 탐사의 효율성을 제고하는데 유용하게 활용될 수 있을 것으로 판단된다.

• 자원환경지질
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• 제56권2호
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• pp.185-199
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• 2023

This study aimed to predict the effects of water ecology on the supply of hydrothermal energy to model a housing complex in Eco Delta Smart Village in Busan. Based on the results, engineering measures were recommended to minimize problems due to possible temperature variations on the supply of hydrothermal energy from the river. The current distribution of fish, benthic macroinvertebrates, and phytoplankton in the Pyeonggang Stream was monitored to determine their effects on water ecology. In the research area, five species and three families of fish were observed. The dominant species was Lepomis macrochirus, and the subdominant species was Carassius auratus. Twenty-five species and 21 families of benthic macroinvertebrates were found. The distribution of aquatic insects was poor in this area. The dominant species were Chironomidae sp., Lymnaea auricularia, Appasus japonicus, and Caridina denticulata denticulata in February, May, July, and October. Dominant phytoplankton were Aulacoseira ambigua and Nitzschia palea in February and May. Microcystis sp. was dominant in July and October. The health of the ecology the Pyeonggang Stream was assessed as D (bad) according to the benthic macroinvertebrate index (BMI). Shifts in the location of the discharge point 150 m downstream from intake points and discharge through embedded rock layer after adding equal amounts of stream water as was taken at the beginning were suggested to minimize water temperature variations due to the application of hydrothermal energy. When the scenario (i.e., quantity of water intake and dilution water, 1,600 m³/d and water temp. difference ±5 ℃) was realized, variations in water temperature were assessed at -0.19 ℃ and 0.59 ℃ during cooling and heating, respectively, at a point 10 m downstream. Water temperatures recorded at -0.20 ℃ and 0.68 ℃ during cooling and heating, respectively, at a point 10 m upstream. All stream water temperatures after the application of hydrothermal energy recovered within 24 hours. Future work on the long-term monitoring of ecosystems is suggested, particularly to analyze the influence of the water environment on hydrothermal energy supply operations.

• 한국지열·수열에너지학회논문집
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• 제17권1호
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• pp.1-13
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• 2021

Before newly-built building and building remodeling, it is important to predict and analyze building energy performance through energy simulation programs. Nevertheless, simulation results widely vary depending on individual user experience and input values. Therefore, this study uses prototypical building model, a versatile tool in building energy modeling, simulation and research for researchers and policy-makers, and ASHRAE standards. Then, it analyzed the changes in design type (roof type, number of floors) for the base case. As the result, it was found that the gap of annual energy demand per between them is maximally 9.1%.

• Structural Engineering and Mechanics
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• 제24권4호
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• pp.395-410
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• 2006

This paper reports the result of an investigation into wave propagation in orthotropic laminated piezoelectric cylindrical shells in hydrothermal environment. A dynamic model of laminated piezoelectric cylindrical shell is derived based on Cooper-Naghdi shell theory considering the effects of transverse shear and rotary inertia. The wave characteristics curves are obtained by solving an eigenvalue problem. The effects of layer numbers, thickness of piezoelectric layers, thermal loads and humid loads on the wave characteristics curves are discussed through numerical results. The solving method presented in the paper is validated by the solution of a classical elastic shell non-containing the effects of transverse shear and rotary inertia. The new features of the wave propagation in laminated piezoelectric cylindrical shells with various laminated material, layer numbers and thickness in hydrothermal environment and some meaningful and interesting results in this paper are helpful for the application and the design of the ultrasonic inspection techniques and structural health monitoring.

• 한국지열·수열에너지학회논문집
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• 제15권3호
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• pp.7-13
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• 2019

To improve the flow distribution at channel locations in the welded plate heat exchanger with "L"-type inflow, the flow visualization of Model 1 was carried out. Besides, the characteristics of flow distribution was investigated experimentally according to the header shape. The inlet flow rate for each channel location was increased at the side channels but decreased at the central channels. In the case of Model 2, which has a slant structure added to the basic header of Model 1, the unevenness of inlet flow increased by 23% from 0.019 to 0.023 as compared to Model 1. On the other hand, Model 3, which has a baffle structure added to Model 2, showed 0.064 unevenness in inlet flow, which was a 36% reduction one compared to Model 1. To improve the distribution at each channel in the welded plate heat exchanger with "L"-type flow, it is necessary to improve the header external shape for the guide of flow as well as the baffle structure for reduction of vortex flow.

• 한국지열·수열에너지학회논문집
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• 제8권2호
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• pp.27-35
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• 2012

Five zero energy house models developed in Korea for the purpose of the energy performance were compared and analyzed in the study. The standard passive house model applying common technology and efficient energy performance elements was proposed. Standard passive house 5 models have been developed commonly aiming at 100% energy saving, applying high-performance and high-efficiency exterior thermal insulation, using 3 low-e coated window system, and targeting average 0.65 ACH to enhance privacy. Energy recovery ventilators and dry and cold radiant heating floor has been partially applied. Eco-design techniques such as the awning device, heat insulating door, using natural light have been used. Solar and geothermal systems as the application of renewable energy technologies have been commonly applied. And fuel cells were applied to a partial model. The standard model based on common technical elements and average performance of each element and obtained from five model analysis has been proposed in the study.