• 제목/요약/키워드: Hydrophilic polymer

검색결과 407건 처리시간 0.027초

확장표면을 적용한 액체식 제습기에서 제습액 분배 특성에 관한 실험적 연구 (Experimental Study on Liquid Desiccant Distribution Characteristics at a Dehumidifier with Extended Surface)

  • 이민수;장영수;이대영
    • 대한설비공학회:학술대회논문집
    • /
    • 대한설비공학회 2009년도 하계학술발표대회 논문집
    • /
    • pp.645-649
    • /
    • 2009
  • Liquid desiccant cooling technology can supply cooling by using waste heat and solar heat which are hard to use effectively. For compact and efficient design of a dehumidifier, it is important to sustain sufficient heat and mass transfer surface area for water vapor diffusion from air to liquid desiccant on heat exchanger. In this study, the plate type heat exchanger is adopted which has extended surface, and hydrophilic coating and porous layer coating are adopted to enhance surface wettedness. PP(polypropylene) plate is coated by porous layer and PET(polyethylene terephthalate) non-woven fabric is coated by hydrophilic polymer. These coated surfaces have porous structure, so that falling liquid film spreads widely on the coated surface foaming thin liquid film by capillary force. The temperature of liquid desiccant increases during dehumidification process by latent heat absorption, which leads to loss of dehumidification capacity. Liquid desiccant is cooled by cooling water flowing in plate heat exchanger. On the plate side, the liquid desiccant can be cooled by internal cooling. However the liquid desiccant on extended surface should be moved and cooled at heat exchanger surface. Optimal mixing and distribution of liquid desiccant between extended surface and plate heat exchanger surface is essential design parameter. The experiment has been conducted to verify effective surface treatment and distribution characteristics by measuring wall side flow rate and visualization test. It is observed that hydrophilic and porous layer coating have excellent wettedness, and the distribution can be regulated by adopting holes on extended surface.

  • PDF

카르베딜롤을 함유하는 경구제어 방출형 제제의 제조 및 용출특성 (Preparation and Dissolution Properties of Oral Controlled Release Formulation Containing Carvedilol)

  • 최원식;김용남;남석우;양진아
    • 한국산학기술학회논문지
    • /
    • 제11권7호
    • /
    • pp.2451-2458
    • /
    • 2010
  • 고혈압 치료제인 카르베딜롤을 모델약물로 하여 새로운 서방성 방출 제어형 매트릭스 정제를 제조하기 위하여 소수성 서방성 부형제인 Compritol 888 ATO와 친수성 고분자인 hydroxypropyl methyl cellulose (HPMC) 또는 polyethylene oxide (PEO)를 이용하여 방출 제어형 매트릭스 정제를 제조하였다. 카르베딜롤 방출 제어형 매트릭스 정제의 제조 시 Compritol 888 ATO의 비율과 친수성 고분자의 종류 및 비율, hot melt coating coagglutination (HMCC) rocess의 적용 유무에 따른 카르베딜롤의 방출 양상을 위하여 용출시험기를 사용하여 pH 1.2의 인공위액과 pH 6.8의 인공장액에서 24시간 동안 $37^{\circ}C$, 50 rpm으로 용출시험을 실시하였다. 그 결과, HMCC process를 적용한 모든 제제가 약물의 방출 제어에 매우 효과적인 것을 확인하였다. 또한 소수성 서방성 부형제인 Compritol 888 ATO의 비율에 따라 약물의 방출 양상 및 시간이 기존 일반정제에 비하여 약 95%의 용출률을 나타내었으며 24시간까지 지연됨을 확인할 수 있었다.

시부트라민 고체 분산체의 특성화 및 조절된 방출거동 (Characterization and Controlled Release of Solid Dispersed Sibutramine)

  • 박정수;구정;이준희;김윤태;박종학;안식일;모종현;이해방;강길선
    • Journal of Pharmaceutical Investigation
    • /
    • 제38권2호
    • /
    • pp.119-126
    • /
    • 2008
  • Solid dispersions of poorly water-soluble drug, sibutramine, were prepared with hydrophilic polymer, poly-N-vinylpyrrolidone (PVP), hydroxypropylmethylcellulose (HPMC) and organic acid, citric acid, to improve the solubility of drug. Physicochemical variation and shape of microsphere were characterized by scanning electron microscopy (SEM), differential scanning calorimeter (DSC) and Fourier-transform infrared spectroscopy (FT-IR). Microspheres containing additives showed more spherical shape than non additive microspheres. In vitro release behavior of microspheres presented at simulated gastric fluid (pH 1.2) and simulated intestinal fluid (pH 6.8). The solid dispersion form transformed the drug into an amorphous state and dramatically improved its dissolution rate. These data suggest that the solid dispersion technique is an effective approach for developing the appetite depressant drug products and various pharmaceutical excipients are able to control the release behaviors.

SYNTHESIS AND CHARACTERIZATION OF THE POLYCATIONS FOR THE PREPAEATION OF POLYION COMPLEX MEMBRANS

  • Jegal, J.G.;park, Y.I.;Kim, J.H.;Lee, K.H.
    • 한국막학회:학술대회논문집
    • /
    • 한국막학회 1993년도 추계 총회 및 학술발표회
    • /
    • pp.58-58
    • /
    • 1993
  • Pervaporation has become important as a method to separate liquid mixtures, sepecially azeotropic and close boiling-point mixtures. Especially, water-alcohol separations have been carried out a lot because of the practical interests in the industries. However, outstanding membranes with high selectivity and high permeability have not been available in common use yet. In order to separate selectively out the water mixed with alcohols with an aim of the purification of the alcohols, a membrane has tO have excellent affinity to water. Among the hydrophilic polymers, polyacrylic acid and poly(vinyl alcohol) are used widely. In recent years, ionomers and polyion complexes, better hydrophitic materials, start to be used. The polyion complex membranes, consisting of polyacrylic acid (PAA) and polycation, showed excellent permeation rates and selectivities. It was known that among the polycations, ioneries, which have quaternary ammonium groups in the backbone chain, were more effective in giving membranes of higher permselectivities. On this base, syntheses and characterizations of the polycations, with different chemical structures from the published ones, for the polyion complex membrane formation were studied in this paper.

  • PDF

다중벽 탄소나노튜브/폴리(에틸렌 옥사이드) 복합체 합성 (Synthesis of Multi-walled Carbon Nanotube/Poly(ethylene oxide) Hybrids)

  • 홍채환;한도석;남병욱
    • 폴리머
    • /
    • 제34권3호
    • /
    • pp.198-201
    • /
    • 2010
  • 탄소나노튜브의 응집력을 완화하기 위한 표면 개질과 고분자 소재와의 상용성을 유도하기 위하여, 친수성 고분자를 도입하는 연구를 진행하였다. 산처리를 통한 표면 기능화를 시행하였으며, 카복실기 도입 탄소나노튜브를 thionyl chloride을 사용하여 acyl chloride로 치환한 후 저분자량의 아민 말단 poly(ethylene oxide)를 공유결합으로 도입하였다. TGA를 통하여 탄소나노튜브 표면에 도입된 고분자의 함량을 계산하였으며, 탄소나노튜브 표면에 도입된 고분자의 표면 형상을 SEM과 TEM을 통하여 직경이 증가하는 것을 확인할 수 있었다.

Patterning of conducting polymer at micron- scale using a selective surface treatment

  • Lee, Kwang-Ho;Kim, Sang-Mook;Kim, Ki-Seok;Song, Sun-Sik;Kim, Eun-Uk;Jung, Hee-Soo;Kim, Jin-Ju;Jung, Gun-Young
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
    • /
    • pp.834-836
    • /
    • 2008
  • We demonstrated micro-scale conducting polymer patterning based on a selective surface treatment. A substrate with a patterned photoresist was immersed into OTS (Octadecyltrichlosilnae) solution. The protected substrate areas were hydrophilic after removing the PR resist, where a conducting polymer solution was coated selectively by spin-coating method.

  • PDF

Simple Preparation of Diaphorase/Polysiloxane Viologen Polymer Modified Electrode for Sensing NAD and NADH

  • Song, Ji-Eun;Hong, Zhenyu;Nagarale, Rajaram Krishna;Shin, Woon-Sup
    • Journal of Electrochemical Science and Technology
    • /
    • 제2권3호
    • /
    • pp.163-167
    • /
    • 2011
  • Nicotinamide adenine dinucleotide, $NAD^+$, and its reduced form, NADH, play important roles as coenzymes in many enzymatic reactions. Electrochemical methods for $NAD^+$ or NADH detection or generation are drawn attention because it can provide the simple and low cost platform with fairly good sensitivity. In this study, the polysiloxane viologen polymer/diaphorase/hydrophilic polyurethane (PSV/DI/HPU) modified electrodes were simply prepared and demonstrated for bio-electrocatalytic $NAD^+$ sensors. The electrodes were co-immobilized with diaphorase and polysiloxane viologen polymer as an electron mediator followed by the overcoating with HPU membrane. The mixture of the enzyme and the electron mediator was well stabilized within HPU membrane and exhibited good reversibility and stability. The sensitivity was 0.2 $nA{\cdot}{\mu}M^{-1}$ and the detection limit was 28 ${\mu}M$ with a response time of 50 s ($t_{90%}$). The capability for NADH sensor was also observed on the PSV/DI/HPU electrode.

Effect of PEO of PS-P2VP photonic gel films

  • Shin, Sung-Eui;Kim, Su-Young;Shin, Dong-Myung
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
    • /
    • pp.1405-1407
    • /
    • 2009
  • We prepared polystyrene-b-poly(2-vinyl pyridine) (PSb-P2VP) lamellar films which is hydrophobic block-hydrophilic polyelectrolyte block polymer have 57 kg/mol-b-57 kg/mol. The result of UV-visible absorption spectra supported that effect of poly(ethylene oxide) on the band gap tuning of PS-P2VP photonic gel like salt effect.

  • PDF

플라즈마 멤브레인을 이용한 유기용매 혼합을 분리 (Separation of Organic Liquid Mixtures using Plasma Membrane)

  • 김성오;박복기;김두석;박진교;이덕출
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1999년도 춘계학술대회 논문집
    • /
    • pp.642-644
    • /
    • 1999
  • We have prepared the plasma-polymerized membrane for pervaporation of organic-liquid mixtures by the plasma polymerization technique. Plasma polymerization techniques were utilized in the development of hydrophilic composite membranes having high hydrogen ion permeability and excellent dimensional stability. To develop an organic liquid permselective Membrane, suppressing membrane swearing as well as enhancing the solubility difference is impotant. the objectives of the present study are to disign a suitable membrane for an organic-mixture system by the control of the plasma-polymer solubility.

  • PDF